共查询到20条相似文献，搜索用时 734 毫秒
1.
豫西南地区铅锌矿产勘查工作近年来进展迅速,尤其在栾川地区先后发现十余处铅锌银多金属矿脉群、上百条含矿断裂带,铅、锌、银资源前景广阔。对该区铅锌矿的科学研究丰富了华北陆块南缘区域成矿学认识,并促进了进一步找矿勘查工作。栾川地区铅锌矿产在燕山期斑岩体周围矽卡岩中和外围的断裂带(脉状)中。脉状铅锌矿脉石矿物碳酸盐C、O同位素的组成(赤土店矿床1δ3C为-3.66‰~-2.82‰,1δ8O为10.31‰~15.86‰;百炉沟矿床1δ3C为-3.00‰~1.80‰,1δ8O为9.40‰~17.70‰;冷水北沟矿床1δ3C为-4.90‰~-0.40‰,1δ8O为6.00‰~12.50‰)介于典型海相石灰岩(1δ3C为0±2‰,1δ8O为28‰~30‰)和岩浆岩(1δ3C为-3‰~-30‰,1δ8O为6‰~12‰;地幔1δ3C为-7‰~-5‰)之间,指示成矿流体、成矿物质的岩浆和地层双重作用、两种来源特点。综合分析认为,栾川地区铅锌矿有矽卡岩型和岩浆热液充填-交代型两种。 相似文献
2.
Geology and D-O-C Isotope Systematics of the Tieluping Silver Deposit,Henan, China: Implications for Ore Genesis 总被引：22，自引：0，他引：22
Franco PIRAJNO 《《地质学报》英文版》2005,79(1):106-119
The Tieluping silver deposit, which is sited along NE-trending faults within the high-grade metamorphic basement of the Xiong‘er terrane, is part of an important Mesozoic orogenic-type Ag-Pb and Au belt recently discovered. Ore formation includes three stages: Early (E), Middle (M) and Late (L), which include quartz-pyrite (E),polymetallic sulfides (M) and carbonates (L), respectively. The E-stage fluids are characterized by δD=-90%c,δ^13CCO2=2.0‰ and δ^18O=9‰ at 373℃, and are deeply sourced; the L-stage fluids, with δD=-70‰, δ^13C CO2=-1.3%c and δ^18O=-2‰, are shallow-sourced meteoric water; whereas the M-stage fluids, with δD=-109‰, δ^13C CO2=0.1%c and δ^18O2‰, are a mix of deep-sourced and shallow-sourced fluids. Comparisons of the D-O-C isotopic systematics of the Estage ore-forming fluids with the fluids derived from Mesozoic granites, Archean-Paleoproterozoic metamorphic basement and Paleo-Mesoproterozoic Xiong‘er Group, show that these units cannot generate fluids with the measured isotopic composition (high δ^180 and δ^13C ratios and low δD ratios) characteristic of the ore-forming fluids. This suggests that the E-stage ore-forming fluids originated from metamorphic devolatilization of a carbonate-shale-chert lithological association, locally rich in organic matter, which could correspond to the Meso-Neoproterozoic Guandaokou and Luanchuan Groups, rather than to geologic units in the Xiong‘er terrane, the lower crust and the mantle. This supports the view that the rocks of the Guandaokou and Luanchuan Groups south of the Machaoying fault might be the favorable sources. A tectonic model that combines collisional orogeny, metallogeny and hydrothermal fluid flow is proposed to explain the formation of the Tieluping silver deposit. During the Mesozoic collision between the South and North China paleocontinents, a crustal slab containing a lithological association consisting of carbonate-shale-chert, locally rich in organic matter (carbonaceous shale) was thrust northwards beneath the Xiong‘er terrane along the Machaoying fault.Metamorphic devolatilization of this underthrust slab provided the ore-forming fluids to develop the Au-Ag-(Pb-Zn) ore belt, which includes the Tieluping silver deposit. 相似文献
3.
湘西北花垣矿集区位于扬子地台东南缘,是湘西-鄂西成矿带上最典型的超大型铅锌矿床所在地.通过对花垣矿集区典型铅锌矿床流体包裹体显微测温、成分分析及C、H、O同位素研究,结果表明,该区铅锌矿床闪锌矿与方解石中流体包裹体的均一温度范围集中在120~200℃,盐度范围集中在8%~20% NaCleqv.流体中液相离子成分主要为Ca2+、Na+、Mg2+、SO42-、Cl-,气相成分主要为H2O、N2和CO2及少量的CO、CH4和H2.流体的δDSMOW值范围为-60.4‰~-33.0‰,δ18O流体值范围为3.8‰~9.2‰.以上流体包裹体和稳定同位素分析结果表明,花垣矿集区铅锌矿床的成矿流体具有热卤水的性质,主要来源于建造水和大气降水.成矿期方解石的δ13CPDB值范围为-4.89‰~0.57‰,δ18OSMOW值范围为13.37‰~21.73‰,略低于碳酸盐围岩,说明成矿流体中的碳主要来源于碳酸盐围岩的溶解作用.矿石沉淀机制可能为两种流体的混合,即来自深部的富含金属物质的热卤水与富含有机质和硫酸盐的建造水及下渗大气降水的混合导致了铅锌矿石的沉淀.对地质和地球化学资料的综合结果表明,花垣矿集区铅锌矿床属于密西西比河谷型（MVT）铅锌矿床. 相似文献
4.
Source Diversity of Ore Sulfur from Mesozoic-Cenozoic Mineral Deposits in the Korean Peninsula Region 总被引：2，自引：0，他引：2
Abstract: Sulfides from the Daebo Jurassic granitoids and some ore deposits from Korean Peninsula and Sikhote Alin occurring in different basement settings were analyzed for δ34S values. Highly positive values were obtained from Jurassic Mo skarn deposit at Geumseong of the Ogcheon belt (average +13. 0%), Au‐quartz vein deposits at Unsan, North Korea (+6. 7%), and late Paleozoic Sn‐F deposit at Votnesenka (+8. 2%), Khanka massif, Russia. Together with published data of that region, regional variation of δ34S values is shown across Korean Peninsula. Sulfur isotopic data published are compiled on 88 ore deposits, whose mineralization epochs belong to Cretaceous (58 deposits), Jurassic (25 deposits) and Precambrian (4 deposits) in South Korea. Average sulfur isotopic values vary across South Korea as follows: Cretaceous deposits in the Gyeongsang basin, +4. 8% ranging +1.2 ? +12.7‰ (n=28); Jurassic and Cretaceous deposits in the Sobaegsan massif, +3. 5% ranging 0.0 ? +7.8‰ (n=20); those of the Ogcheon belt, +6. 4% ranging ‐0.5 ? +15.4‰(n=19); those of the Gyeonggi massif, +5. 5% ranging +2.1 ? +9.0‰(n = 21). The δ34S values of South Korea tend to be concentrated around +5. 5 permil, exhibiting little, if any, a systematic variation across the geotectonic belts. This tendency is seen also in North Korea and Northeast China within the Cino‐Korean Block, and may be called as Cino‐Korean type. Sulfur of this type is derived mostly from the crystalline basement. Khanka massif of Russia seems to have features of the Cino‐Korean type. In contrast, paired positive/negative belts corresponding to magnetite‐series/ilmenite‐series granitic belts are overwhelming in the Japanese Islands, especially in Southwest Japan. The similar trend is also seen in southern Sikhote Alin and northern Okhotsk Rim, which may be called as Japanese type. Source of the sulfur in this type is likely in the subducting oceanic slab for positive value and accreted sedimentary complex for the negative value, respectively. The Daebo granitoids have an average rock δ34S value of +5. 3 permil, which should have reflected that of the source rocks in the continental crust. The ore sulfur heavier than this value may have been originated in other granitoids having even higher δ34S values, or the ore fluids interacted directly with sulfate sulfur of the host evaporites or carbonate rocks. Rock isotopic values of granitoids and basement rocks need to be examined in future from the above point of view in mind. 相似文献
5.
洒西白钨矿床位于滇东南老君山矿集区内,呈层状、似层状产出。矿区围岩为一套中深变质岩,其稀土元素组成特征为:矿区围岩LREE/HREE比值为4.37~6.87,δEu为0.67~1.49,δCe值为0.62~0.98;外围混合片麻岩LREE/HREE比值为4.51~5.58,δEu平均为0.14。矿石Eu正异常与Ce负异常同时存在说明矿石沉淀时相对高温的热水流体和较低温的海水在海底发生了对流混合,部分样品中Eu负异常的形成可能与后期岩浆热液叠加改造作用有关。结合矿床地质特征,洒西白钨矿床成因为喷流沉积-后期岩浆热液改造型。 相似文献
6.
Zhang Ligang Liu Jingxiu Yu Guixiang Chen Zhensheng Yichang Institute of Geology Mineral Resources CAGS Yichang Hubei Jiang Minxi 《《地质学报》英文版》1996,70(3):274-289
The δ18O values of vein quartz of different stages from the Yinshan ore deposit are constant around 16‰ and the calculated δ18OH2O values attain 8‰± ; the δDH2O values of fluid inclu-sions in vein quartz are constant at about-60‰. From the surface down to 1200 m below the δ18O values of altered rocks gradually decrease from 15‰± to 11‰± . Various water-rock inversion calculations indicate that the ore fluids were formed by the interaction between meteoric water and phyllite at 350℃ and the effective W/ R value of around 0.1. When the water-rock exchange in the upper mineralization system took place, the effective W / R value increased to 5.0 or more. As a result, an evolution and mineralization model of a buffered open system with two-stage water-rock interactions is proposed in this study. 相似文献
7.
辽宁白云金矿床稳定同位素地球化学特征及矿床成因 总被引：1，自引：0，他引：1
白云金矿床是辽东地区的一个大型金矿床,其成矿物质来源及矿床成因一直存在争议。本文系统地研究了白云金矿床的氢、氧、硫和碳同位素地球化学特征。研究结果显示:成矿流体中δ~(18)OV-SMOW值变化范围为13.5‰15.9‰,δD_(V-SMOW)为-107‰-83‰,表明成矿流体以岩浆水为主;矿石中黄铁矿的δ~(34)S_(V-CDT)为-8.3‰2.9‰,以富轻硫和贫重硫为特征,与辽河群围岩中黄铁矿的硫同位素组成(δ~(34)S_(V-CDT)为7.0‰18.7‰)有明显差异;矿石中方解石的碳同位素δ~(13)C_(V-PDB)为-2.2‰-0.4‰,类似于火成碳酸岩或地幔包体来源的碳同位素特征,也与辽河群大理岩的碳同位素组成明显不同。成矿元素特征对比也显示,成矿物质来源与辽河群没有必然联系。综合矿床地质特征和地球化学特征,认为白云金矿床是与深部岩浆流体活动有关的岩浆热液型金矿床。 相似文献
8.
Tianli Zhang Jia Liu Qun Zhang Yingnan Zhang Liping Qin 《Geostandards and Geoanalytical Research》2023,47(1):169-183
This study presents high-precision W isotopic measurement results using the 180W-183W double spike technique with MC-ICP-MS. The effects of isobaric and polyatomic interferences on W isotopic measurements were evaluated. The δ186/184W values were not significantly affected when the solution had Hf/W ≤ 3 × 10-4, Ta/W ≤ 1, Os/W ≤ 0.06, Ce/W ≤ 0.0075, Nd/W ≤ 3.5 and Sm/W ≤ 5. The intermediate measurement precisions of both standard solutions (NIST SRM 3163 and Alfa Aesar W) and geological reference materials (NOD-A-1) were better than ±0.024‰ (2s). We also obtained a precision of 0.026‰ for a minimum sample loading mass of 5 ng, allowing the analysis of samples with low W contents. Replicated measurements of geological reference materials (AGV-2, BCR-2, BHVO-2, GSP-2, RGM-1, SDC-1, NOD-A-1 and NOD-P-1) yielded δ186/184W values ranging from 0.017‰ to 0.144‰. The δ186/184W values of two major tungsten ore minerals (scheelite and wolframite) were reported and compared herein. Scheelites had systematically slightly heavier W isotopic compositions than wolframites, which may reflect differences in the crystal structure. The resolvable variations of stable/mass-dependent W isotopic compositions in rocks and ore minerals make W isotopes a novel tool for studying hydrothermal mineralisation processes and the W cycle of geological reservoirs. 相似文献
9.
Many metallic ore deposits of the Late Cretaceous to Early Tertiary periods are distributed in the Gyeongsang Basin. Previous and newly analyzed sulfur isotope data of 309 sulfide samples from 56 ore deposits were reviewed to discuss the genetic characteristics in relation to granitoid rocks. The metallogenic provinces of the Gyeongsang Basin are divided into the Au–Ag(–Cu–Pb–Zn) province in the western basin where the sedimentary rocks of the Shindong and Hayang groups are distributed, Pb–Zn(–Au–Ag–Cu), Cu–Pb–Zn(–Au–Ag), and Fe–W(–Mo) province in the central basin where the volcanic rocks of the Yucheon Group are dominant, and Cu(–Mo–W–Fe) province in the southeastern basin where both sedimentary rocks of the Hayang Group and Tertiary volcanic rocks are present. Average sulfur isotope compositions of the ore deposits show high tendencies ranging from 2.2 to 11.7‰ (average 5.4‰) in the Pb–Zn(–Au–Ag–Cu) province, ?0.7 to 11.5‰ (average 4.6‰) in the Cu–Pb–Zn(–Au–Ag) province, and 3.7 to 11.4‰ (average 7.5‰) in the Fe–W(–Mo) province in relation to magnetite‐series granitoids, whereas they are low in the Au–Ag(–Cu–Pb–Zn) province in relation to ilmenite‐series granitoids, ranging from ?2.9 to 5.7‰ (average 1.7‰). In the Cu(–Mo–W–Fe) province δ34S values are intermediate ranging from 0.3 to 7.7‰ (average 3.6‰) and locally high δ34S values are likely attributable to sulfur derived from the Tertiary volcanic rocks during hydrothermal alteration through faults commonly developed in this region. Magma originated by the partial melting of the 34S‐enriched oceanic plate intruded into the volcanic rocks and formed magnetite‐series granitoids in the central basin, which contributed to high δ34S values of the metallic deposits. Conversely, ilmenite‐series granitoids were formed by assimilation of sedimentary rocks rich in organic sulfur that influenced the low δ34S values of the deposits in the western and southeastern provinces. 相似文献
10.
黔东南地处江南造山带西南段雪峰隆起西南端,区内金矿床(点)广布,是湘黔金矿集中区的重要组成部分。平秋金矿是该区金矿床的典型代表,其矿体产于下江群番召组浅变质火山-沉积岩,严格受北东向断裂褶皱控制。为理清其成因,对平秋金矿床含矿石英脉中的石英包裹体进行了氢、氧同位素测试。结果显示,其δD为-51.3‰~-59‰,δ18OH2O-SMOW为4.46‰~8.16‰,表明平秋金矿成矿期流体以变质水为主。对成矿期黄铁矿的硫同位素分析结果表明,其δ34S值为-1.86‰~4.55‰,而围岩下江群浅变质岩中黄铁矿的δ34S值为9.63‰~13.56‰,二者相差巨大,表明矿床中硫不是直接来自于赋矿围岩。根据上述氢、氧、硫同位素测定结果并结合区域地质背景,本文认为平秋金矿的成矿流体和成矿物质源自下伏地层的变质脱水作用,成矿作用与加里东运动造成的变质变形有关。 相似文献
11.
白云鄂博地区相关地质单元的铁同位素特征及其对白云鄂博矿床成因的制约 总被引：4，自引：0，他引：4
白云鄂博Fe-REE-Nb矿床是世界著名的巨型多金属矿床,它的成因一直是个激烈争论的问题,观点主要集中在沉积成因和岩浆成因上,而铁的物质来源问题是争论的焦点之一。近年来Fe同位素的快速发展为解决白云鄂博铁矿的成因提供了新思路。对白云鄂博地区发育的白云鄂博群尖山组铁质板岩、宽沟北沉积型铁矿、腮林忽洞微晶丘、灰绿岩墙这些相关地质单元的Fe同位素组成特征进行了研究,为白云鄂博矿床成因研究提供了最直接的参考。结果表明,尖山组铁质板岩的δ56Fe值为-0.49‰～0.48‰,平均值为-0.03‰±0.84‰,2SD,n=5;宽沟北沉积型铁矿的δ56Fe值为-0.68‰～0.23‰,平均值为-0.10‰±0.78‰,2SD,n=5;腮林忽洞微晶丘δ56Fe值为-0.64‰～0.12‰,平均值为-0.28‰±0.57‰,2SD,n=6;辉绿岩的Fe同位素组成δ56Fe值集中在0.11‰～0.16‰。腮林忽洞微晶丘总体上比白云鄂博赋矿白云岩富集Fe的轻同位素,Fe同位素组成变化也相对更大,表明两者可能有不同的成因。白云鄂博地区尖山组铁质板岩、宽沟北沉积型铁矿与世界其他地区含铁沉积建造的Fe同位素组成类似,其共同特征是,Fe同位素变化较大,总体上δ56Fe大于0‰。这一特征与白云鄂博铁矿的Fe同位素组成差别较大。白云鄂博矿床的δ56Fe集中在0‰附近,与白云鄂博地区灰绿岩、世界不同地区火成岩和岩浆型铁矿的Fe同位素组成特征一致。表明白云鄂博铁矿可能不是沉积成因的,更有可能与岩浆作用有关。 相似文献
12.
黔西北天桥铅锌矿床热液方解石C、O同位素和REE地球化学 总被引：9，自引：0，他引：9
利用连续流动质谱和电感耦合等离子体质谱(ICP-MS)对黔西北天桥铅锌矿床原生矿石中脉石矿物热液方解石C、O同位素组成和稀土元素含量进行了分析,结果表明热液方解石C、O同位素组成相对均一,不同标高方解石C、O同位素组成不具明显差别,其δ13CPDB和δ18OSMOW分别为-3.4‰～-5.3‰和14.7‰～19.5‰,在δ13CPDB-δ18OSMOW图上介于原始碳酸岩与海相碳酸盐岩之间。热液方解石总稀土元素含量较低(ΣREE=6.80×10-6～49.1×10-6),表现为轻稀土富集、Eu负异常的"M"型,其Eu/Eu*变化范围为0.30～0.55,与硫化物具有相似的稀土配分模式。根据热液方解石与蚀变围岩、远矿围岩及不同时代地层碳酸盐岩的C、O同位素组成和REE含量特征对比结果,结合前人研究成果,认为该矿床成矿流体具"多来源混合"特征,其中围岩碳酸盐岩为成矿流体提供了主要的C和REE来源,地层中膏岩海相硫酸盐岩为成矿流体提供了主要的S来源,而成矿流体中的水则主要为变质基底昆阳群等提供的变质水,并受到大气降水的影响。 相似文献
13.
江西省崇义县淘锡坑钨锡矿床流体包裹体特征及矿床成因 总被引：1，自引：0，他引：1
为研究赣南淘锡坑钨锡矿床的成矿物理化学条件和流体来源,对不同中段黑钨矿-石英脉矿体中包裹体进行了岩相学、显微测温、激光拉曼探针和氢、氧同位素分析。岩相学观察和显微测温表明：该矿区发育气相包裹体、液相包裹体、富液相包裹体、富气相包裹体、含液相CO2的三相包裹体等5种类型原生包裹体;存在2个流体演化阶段,即早期硅酸盐-氧化物成矿阶段（310～390 ℃）和晚期氧化物-硫化物成矿阶段（180～270 ℃）。7个典型包裹体的气相和液相激光拉曼探针成分分析显示：包裹体中气相属富含CO2的NaCl-H2O系列,液相属贫CO2的NaCl-H2O系列。5件黑钨矿-石英脉矿石中石英流体包裹体的δD为－64‰～－79‰,δ18O水为5.51‰～6.53‰,表明成矿流体来源于深部岩浆水。结合区域最新研究成果,认为该矿床属与陆壳改造型花岗岩有关的岩浆热液型钨矿床。 相似文献
14.
通过对凤太盆地八卦庙金矿和八方山一二里河铅锌矿的矿床地质、矿床地球化学、流体地球化学的研究，发现两类矿床δ（^30Si）分布范围与海底喷流沉积成因硅质岩的硅同位素接近，表明其属热水沉积成因。矿床δ（^34S）比较接近，但铅锌矿矿石中硫源来源更广。碳酸盐的碳、氧同位素特征显示两类矿床均具有热水沉积特点，金矿的样品更趋向于火成岩，表明受后期岩浆热液影响更大。经过流体包裹体测温，金矿床均一温度变化范围大，具有多期次多阶段的特征。矿床同位素和流体包裹体特征表明，金矿床与铅锌矿床在成矿物源、成矿流体特征等方面都存在很多相似性，反映出热水喷流作用与两类矿床成因有密切的关系，但二者又存在差异。结合成矿地质背景，认为铅锌矿的形成与定位受区域热变质改造和动力作用控制，而金矿的形成主要受晚期岩浆热液活动控制，由此建立了金矿与铅锌矿的成矿模式。 相似文献
15.
16.
《International Geology Review》2012,54(4):334-354
This study examines the rare-earth-elemenl and isotopic geochemistry of sulfide ores and associated rocks in the Bajiazi sulfide deposits of northeastern China. The distribution and concentration of rare earth elements (REE) in sulfide ores and associated rocks from the Bajiazi deposits have been determined by inductively coupled plasma spectroscopy (ICP) methods. Birdwing-shaped rare-earth-element profiles are only observed in granitic rocks at Bajiazi. Diverse rare-earth-element profiles of the ores and dolostones are different from those of granite and are interpreted to reflect an early sedimentary-diagenetic mineralization stage during which rare earth elements were added to the ores and host rocks. The characteristic features of the abundances of REE in the Bajiazi samples, including granite and sedimentary host rocks, are demonstrated by a variety of Eu anomalies in the chondrite-normalized REE pattern. Eu is the most mobile element, exhibiting increasingly negative anomalies in granite rock samples relative to the depletion of the sulfide ores and associated sedimentary host rocks, which are considered to be caused by preferential scavenging of Eu from sea water to sediments. The δ34S values of sulfide minerals at Bajiazi generally range from ?12.3 to 14.2%, suggesting reduction both of marine sulfate and biogenic sources. The δ34S values from different ore types, sulfide minerals, and mines indicate a sedimentary exhalative origin, although they were, to some extent, homogenized during late overprinting. The late-stage sulfides from Bajiazi are isotopieally remarkably homogeneous and are significantly, although slightly, enriched in δ34S. These results imply multiple sources of sulfur derived from biogenic reduction, and/or sulfate in oceanic and/or connate waters, or from marine evaporites, and/or from magmatic hydrothermal sources. Isotopic temperatures from intersulfide fractionations (pyrite, sphalerite, and galena) range from 75° to 542°C, indicating the Bajiazi sulfide minerals have experienced different mineralizing stages. Galena in the Bajiazi Proterozoic sediment-hosted Pb-Zn sulfide deposits has a very uniform Pb-isotope composition, with 206Pb/204Pb = 16.07 to 16.58, 207Pb/204Pb = 15.00 to 15.66, and 208Pb/204Pb = 36.13 to 36.92, suggesting that it all formed from a common mineralizing fluid. The variation of lead-isotopic values of ores is similar to that of their host sedimentary strata. The lead in the various ore types and host rocks within the Bajiazi district is virtually identical. Lead-isotope signatures, which generally plot very close to model crustal growth curves, characterized by a model age of ～1350 Ma, indicate a normal, nonradiogenic origin and an Early Proterozoic upper-crustal source for the lead in the ores. That lead was unrelated to the radiogenic lead in the Mesozoic granite. The δ13C values range from +1 to ?5% PDB, and the δ18O values from ?6 to ?15% PDB. Later crystallization generations are enriched in the light isotopes of carbon and oxygen compared to early generations. The characteristics of carbon and oxygen isotopes of the Bajiazi deposits indicate that: (1) primary ores were precipitated in the Proterozoic marine environment; (2) both ores and host carbonates from the Bajiazi district are remarkably homogeneous in their carbon- and oxygen-isotope compositions during later tectonic, conlact-metamorphic stages; (3) although the variations in isotopic composition of carbon and oxygen are relatively small, a significant evolution toward a lighter isotopic composition with advancing diagenetic, tectonic, and contact metamorphic processes is observed; and (4) this evolution is independent of the presence or absence of ore minerals. 相似文献
17.
18.
在系统分析重庆秀山小茶园锰矿区大批钻孔数据资料的基础上,基于野外地质调查和室内沉积学、地球化学等分析得出,盆地中心相的沉积物厚度大,TOC、U、Mo、V、δ34Spy的含量高,草莓状黄铁矿丰富,指示了缺氧的水体条件,且锰矿的品位和厚度大。向盆地边缘相、斜坡相,沉积物厚度减小,TOC、U、Mo、V、δ34Spy含量降低,指示水体缺氧程度减弱,同时锰矿的品位和厚度减小。锰矿体厚度的变化与含锰岩系厚度的变化规律一致,二者呈正相关关系。小茶园矿区矿体展布方向与小茶园次级地堑盆地长轴方向基本一致,为NE60°左右。因此,小茶园矿区锰矿床矿体产出受到次级地堑盆地和沉积相带的控制,缺氧的盆地中心相成矿最佳,其次为盆地边缘相,斜坡相成矿较差。 相似文献
19.
《International Geology Review》2012,54(8):715-731
The Prestea lode gold deposit occurs in a graphitic shear zone in the Birimian system of Ghana. The Birimian is an Early Proterozoic greenstone assemblage (≈ 2100 Ma) with large gold deposits, consisting of a lower unit predominantly of metasediments and an upper unit of metavolcanics with interbedded sediments. The metamorphic stage is of greenschist facies grade. The gold generally occurs as free gold or closely associated with sulfides, particularly arsenopyrite and sulfosalts. It is usually coarse grained and occurs along grain boundaries, as inclusions and in fractures with the ore minerals. The gold is nearly pure, with analyzed grains containing 95-96 wt% Au, 4-5 wt% Ag, and less than 0.1 wt% Sb, Bi, Zn, or Cu. Associated metallic phases consist of pyrite, arsenopyrite, chalcopyrite, pyrrhotite, sphalerite, galena, and sulfosalts such as tetrahedrite, boulangerite, bournonite, and jamesonite. The fluid associated with the gold mineralization was H2O-CO2-NaCl in composition, with a mean salinity = 3.6 wt% NaCl equivalent, CO2 density (mean) = 0.84 ± 0.09 g/cm3, and XCO2 = 13 to 33 mole %. Total homogenization temperatures range from 250° to 380° C. The ore fluid exhibits features suggesting contamination of volatiles such as N2 ± CH4 ± H2S, or post-depositional leakages. Arsenopyrite geothermometry indicates a temperature of mineralization from 325° to 450° C. Estimated pressures of trapping range from 1.0 to 2.2 kbars, with corresponding depths from 3.5 to 7.7 km, assuming the pressure is lithostatic. The gold deposition occurred from fluids with δ18O water = +9.6 to +13.9o and δDfluid irclusion = ?29 to ?65%0, suggesting a crustal origin for the ore-forming fluid, including a metamorphic and a magmatic source. A δ34Spyrite value of ?7.1 to ?11.7%o and δ34SΣS = ?9.6%o suggests a sedimentary origin for the sulfur. The gold deposition is attributed to destabilization of the bisulfide complex as a result of ore fluid reaction with host rock, resulting in a probable reduction by the carbonaceous matter in the host rock, and/or a decrease in the total sulfur concentration in the co-precipitation of sulfides. 相似文献
20.
The Badi copper deposit is located in Shangjiang town, Shangri-La County, Yunnan Province. Tectonically, it belongs to the Sanjiang Block. Vapor–liquid two-phase fluid inclusions, CO2-bearing fluid inclusions, and daughter-bearing inclusions were identified in sulfide-rich quartz veins. Microthermometric and Raman spectroscopy studies revealed their types of ore-forming fluids: (1) low-temperature, low-salinity fluid; (2) medium-temperature, low salinity CO2-bearing; and (3) high-temperature, Fe-rich, high sulfur fugacity. The δ18O values of chalcopyrite-bearing quartz ranged from 4.96‰ to 5.86‰, with an average of 5.40‰. The δD values of ore-forming fluid in equilibrium with the sulfide-bearing quartz were from ? 87‰ to ? 107‰, with an average of ? 97.86‰. These isotopic features indicate that the ore-forming fluid is a mixing fluid between magmatic fluid and meteoric water. The δ34S values of chalcopyrite ranged from 13.3‰ to 15.5‰, with an average of 14.3‰. Sulfur isotope values suggest that the sulfur in the deposit most likely derived from seawater. Various fluid inclusions coexisted in the samples; similar homogenization temperature to different phases suggests that the Badi fluid inclusions might have been captured under a boiling system. Fluid boiling caused by fault activity could be the main reason for the mineral precipitation in the Badi deposit. 相似文献