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1.
次玛班硕矿床是近年来在冈底斯西段新发现的斑岩型铜矿,距朱诺超大型斑岩铜矿床西南约10 km,周围分布着北姆朗、落布岗木、懂师布等矿床,为朱诺铜多金属矿集区的重要组成部分.为了进一步明确次玛班硕找矿潜力及勘查方向,本次对该矿床开展了系统的锆石U-Pb年代学和锆石微量元素分析、精细的岩芯蚀变-矿化编录以及详细的岩相学观察.研究发现次玛班硕铜矿主成矿期中新世岩体为一套复式杂岩体,分别由细粒二长花岗斑岩（F斑岩:16±0.30 Ma）、粗粒二长花岗斑岩（C斑岩:15.89±0.06 Ma）、含角闪石二长花岗斑岩（H斑岩:15.81±0.06 Ma）、闪长玢岩和二长花岗岩（15.51±0.07 Ma）组成,且不同期次岩浆沉淀Cu金属量差异较大.锆石Ce4+/Ce3+（平均值190）和10 000×（Eu/Eu*）/Y（平均值13）比值指示次玛班硕中新世各岩体,氧逸度和含水性均高于朱诺矿床.次玛班硕热液演化可划分为4个阶段和14种脉体,根据次玛班硕矿床蚀变-矿化对应关系,铜主要沉淀于钾硅酸盐化阶段,特别是与黑云母化密切相关,青磐岩化阶段亦沉淀部分的铜,绢英岩化阶段沉淀最少.与经典的斑岩铜矿蚀变-矿化分带模式不同,次玛班硕铜矿表现出深部钾硅酸盐化被青磐岩化强烈叠加和部分高温脉体穿插低温蚀变的反常特征,证明存在多期次岩浆-热液过程,为成矿提供了源源不断的热动力、成矿物质和成矿流体,形成了各种蚀变相互叠加的复杂热液系统.分布于次玛班硕矿区北部的F斑岩为主要致矿岩体.矿区北部蚀变-矿化作用强而南部较弱,且深部发育强烈的青磐岩化蚀变.综合分析认为,次玛班硕矿床还具有较大的找矿潜力,下一步勘查方向应以矿区深部和北部为主,重点关注F斑岩和C斑岩且发育钾硅酸盐化的部位. 相似文献
2.
马沙始尔铜矿化赋存于切割克洛斯佩特花岗岩套（２，４００－２，０００ｍ．ｙ．）粉红色斑状花岗岩的断裂和角砾岩带（剪切带）中。矿化属断裂控制的后生热液裂隙充填类型，伴生的围岩蚀变为绿泥石化、钠黝帘石化、绢云母化和硅化。矿石矿物主要是黄铜矿和黄铁矿，其次有斑铜矿、辉铜矿、铜蓝、蓝辉铜矿和硫钴矿，偶见有极少的自然铜。赤铁矿（镜铁矿）和磁铁矿通常与矿化密切伴生。推断有三个矿化阶段，其中第二阶段以黄铁矿沉淀为 相似文献
3.
铀矿石及含铀岩石中四价铀和六价铀分析方法的研究 总被引：5，自引：0，他引：5
本文介绍的是测定铀矿石及含铀岩石中铀（Ⅳ）和铀（Ⅵ）的新方法。本分析方法设计了独特的样品分解体系和溶解、分离程序。从矿样在低温下（４０℃±５℃）分解、四氟化铀沉淀的形成、铀（Ⅵ）及部分干扰离子溶解进入溶液，到固、液两相的分离，整个过程在２ｍｉｎ内完成。本方法确保了样品处理过程中铀的价态不变，并使铀（Ⅵ）完全溶出，铀（Ⅳ）快速沉淀以及两者定量分离，是测定铀矿石及含铀岩石中铀（Ⅳ）和铀（Ⅵ）的简便、快速的分析方法，其准确度和精密度可满足地质科研的需要。 相似文献
4.
地热回灌是解决地热田开发利用中热储压力下降的一个有效办法．用地球化学方法模拟了在Ｌａｕｇａｌａｎｄ低温（９５℃）地热田回灌过程中可能发生的化学作用．在模拟中考虑了石英等矿物的化学动力学因素．模拟结果表明：在用地热尾水回灌时,虽然混合水对于石英等矿物是饱和的,但由于它们沉淀速度很慢,在实际中不会产生沉淀．至于产生的较少的方解石沉淀,其全部或至少一部分是模型为使混合水达到对于方解石理论上的平衡而产生的．如果用地下水回灌,地下水中的镁将会和地热水中的二氧化硅形成较多的含镁硅酸盐沉淀． 相似文献
5.
中国铬铁矿的铂族元素分布特征 总被引：2，自引：0，他引：2
用NiS溶解和Te沉淀方法富集铂族元素（PGE），制成镍扣，再溶解于浓HCl中，使PGE和Te一起沉淀。制备的样品溶液在ELAN－5000型电感耦合等离子质谱仪（ICP－MS）上分析PGE。中国铬铁矿矿石，包括蛇绿岩套中的豆荚状铬铁矿床、非层状侵入体铬铁矿，计13个矿床（化）样品，其PGE模式表明，主要呈RU正异常模式，个别不同模式是由母岩不同以及铂族元素矿化叠加引起的。铬铁矿的PGE模式不取决于铬铁矿的化学成分，而取决于其母岩性质以及形成温度和铂族元素的熔点。 相似文献
6.
成矿流体中金属沉淀机制研究综述 总被引：26，自引：1，他引：26
概述了成矿流体中金属沉淀机理研究的新进展；（１）单纯的降温冷却可能不是引起金属沉淀最有效的机制；（２）压力的降低并不总造成矿矿物质的沉淀；（３）热液蚀变作用是引起矿物沉淀的重要机制之一；（４）缓冲体系对矿物沉淀的意义需要引起民重视；（５）流体的混合作用是许多矿床也可能是大型一特大型矿床形成的主要原因之一。自然热液成矿环境是很复杂的，引起矿物沉淀的原因也是非常复杂的，因此，结合具体成矿体系，对客观实 相似文献
7.
采用2次注入菌液方式,制备不同浓度营养盐处理的微生物诱导碳酸钙沉淀（MICP）胶结砂样。通过固结排水三轴试验和碳酸钙定量化学试验测定试样强度参数及碳酸钙（CaCO3）含量,分析了营养盐浓度对胶结砂物理力学特性的影响及碳酸钙沉淀量试样强度指标间的关系。结果表明,同等反应时间、同等体积营养盐溶液条件下,随着营养盐浓度的提高试样强度逐渐升高,且达到一定峰值后再下降;碳酸钙晶体分布形态较好条件下,变形模量随着试样干密度的增加而增加;碳酸钙晶体分布形态和沉淀含量共同影响MICP试样强度的提高,试验中0.5 M试样强度提高效果最好,碳酸钙含量、黏聚力、内摩擦角分别为6.03%、46.9 kPa和41.31°。 相似文献
8.
胶东矿集区金成矿系统组成与演化概论 总被引：3，自引：1，他引：3
由于中生代以来构造动力体制多次转换及火山-侵入岩活动形成了胶东矿集区金成矿系统。成矿类型主要以石英脉型、复合脉带型、浸染细脉带型等类型为主，多种类型金矿多为同源成矿溶液在不同构造背景和物化条件下的沉淀产物，从而发育类似的构造-蚀变-矿化分带结构。胶东矿集区存在3期成矿作用，金成矿作用主期明显集中于燕山中期（130~120 Ma），（含金）银矿化为燕山晚期（<97 Ma），含金（银）铅锌矿化介于两者之间、更接近于燕山晚期（100 Ma前后），区域地质事件的定年与因果分析显示这三期成矿过程的物质来源、成矿作用均受壳-幔相互作用等大尺度构造体制转折事件控制。 相似文献
9.
淡水湖泊碳酸钙自生沉淀生物成因新证据和成因解释吴丰昌，万国江（中国科学院地球化学研究所，贵阳５５０００２）关键词淡水湖泊碳酸钙、生物成因、自生沉淀淡水湖泊中引起方解石过饱和及碳酸钙沉淀的可能因素有两个：（１）生物因素，由植物和浮游生物的光合作用形成二... 相似文献
10.
根据包裹体分析资料和热力学计算结合矿床地质特征，本文研究了江西六二一七花岗岩型铀矿床形成的物理化学条件，并对红化（赤铁矿化）与热液铀矿化之间的因果关系进行了探讨。结果得到，热液铀矿化形成于中低温、中压、低氧逸度、高流逸度、中性至弱碱性的还原环境。成矿热液中，铀主要呈［UO2（CO3）2］2-和［UO2F4］2-形式迁移，至一定的物理化学条件下发生沥青铀矿沉淀。红化是矿前期高氧逸度流交代热液对围岩氧化所至，红化蚀变岩石因含有Fe3+，从而有利于热液铀矿化的发生。 相似文献
11.
Thermodynamic study of the association and separation of copper and gold in the Shizishan ore field, Tongling, Anhui Province, China 总被引：1，自引：0，他引：1
Xiao-chun Xu Zan-zan Zhang Qi-neng Liu Jing-wei Lou Qiao-qin Xie Ping-li Chu Ray L. Frost 《Ore Geology Reviews》2011,43(1):347-358
The Shizishan ore field is the largest gold–copper ore field in the Tongling ore district of Anhui Province, China. Copper and gold deposits in the district are present as one-commodity deposits or as deposits with both commodities. Copper and gold mineralization are either cogenetic or are temporally and spatially distinct. We present the results of systematic geochemical analysis of fluid inclusions from typical Au–Cu deposits in the Shizishan ore field; these data are used to determine the solubility of Cu and Au in the ore-forming fluids and to ascertain the mechanisms and factors that controlled variations in the association and separation of copper and gold mineralization. Our results indicate that copper in the ore-forming fluids was transported as CuCl2− and CuCl0 complexes and that the solubility of copper was controlled by variations in Cl− concentration. In addition, the precipitation of copper was controlled by changes in temperature, pH, fO2, and fO2. In comparison, gold in the ore-forming fluids was transported as Au(HS)2− and Au2S(HS)22− complexes, and the solubility of gold was controlled by variations in total sulfur concentration; the precipitation of gold was controlled by temperature, pH, fO2, and fO2. These differences between the two elements meant that copper and gold in the ore-forming fluids responded in different ways to changes in physicochemical conditions. Copper precipitated under relatively acidic conditions at high temperatures, while gold precipitated under weakly alkaline conditions at relatively low temperatures; this dissociation resulted in the temporal and spatial separation and zonation of copper and gold mineralization in the Shizishan ore field. 相似文献
12.
西秦岭凤太矿集区丝毛岭金矿床地质地球化学特征 总被引：1，自引：0，他引：1
西秦岭凤太矿集区丝毛岭金矿床位于八卦庙造山型金矿床西侧5km左右,是一个新探明的剪切带型金矿。其成矿作用过程可分为早期石英-绢云母-硫化物阶段、中期多金属-硫化物阶段和晚期碳酸盐阶段。对早、中期的石英流体包裹体测试结果表明,丝毛岭金矿床成矿流体以富CO2、中温、低盐度为特征,总体上属于中温低盐度CO2-H2O体系,流体包裹体类型的多样性是流体不混溶性的产物。从早阶段到主成矿阶段成矿流体的温度、压力和盐度均有降低,硫逸度增高,有利于金的沉淀富集。H、O、S、C同位素研究结果,以及与八卦庙金矿床的对比分析表明,二者的成矿流体具有相似性和同源性,都是以深部来源为主的多源流体。由于丝毛岭金矿床产出的层位高于八卦庙金矿床,其成矿环境相对开放。 相似文献
13.
Vein-type, structurally controlled Cu–Au mineralisation hosted by turbidites of late Silurian to earliest Devonian age, forms an important resource close to the eastern margin of the Cobar Basin. Here we report 103 new sulfur isotope analyses, together with homogenisation temperatures and salinity data for 545 primary two-phase fluid inclusions for the mineralised zones from the central area of the Cobar mining district. A range in δ34S values from 3.8 to 11.2‰ (average 7.9‰) is present. Sulfur is likely to have been derived from rock sulfur/sulfide in basin and basement rocks, but there may be an additional connate-derived component. Homogenisation temperatures (Th) for inclusion fluids trapped in quartz and minor calcite veins range from near 150°C to 397°C. Fluid inclusions are characterised by a low CO2 content and low, but variable salinities (2.1–9.1 wt% NaCl equivalent). Generations of inclusion fluids correspond to six paragenetic stages of vein quartz deposition and recrystallisation at the Chesney mine. Primary fluid inclusions in the first two stages were subjected to re-equilibration resulting from increased confining pressure. Their Th range (151–317°C) is considered a minimum for the temperature of these fluids. Sulfide and gold deposition at Chesney appears to be related to fluids of moderately high Th (range 270–397°C) associated with the final paragenetic stage. Th for the ore-related fluids may be close to the solvus of the H2O–NaCl–CO2 system and hence near trapping temperatures. Late-stage entry of a hot, moderately saline ore-forming fluid is implicated as the origin of the Cu–Au mineralisation. However, comparison with geochemical data for the vein-style Zn–Pb–Ag deposits at Cobar demonstrates that differences in metal content for individual zones cannot be attributed to major differences in fluid temperature or salinity. Rather, these differences are probably due to variations in source-rock reservoirs and structural pathways along which the ore-forming fluids moved. 相似文献
14.
Geochemical studies of the Paiting and Miaolong Carlin-type gold deposits in the Sandu-Danzhai metal-logenic zone,Guizhou Province,have shown that the mineralized-altered rocks show LREE-enrichment patterns,generally displaying negative Eu anomalies(δEu=0.51?0.97) and unobvious negative Ce anomalies(δCe=0.86?0.99).Calcite and fluorite in relation with metallogenesis show MREE-enrichment patterns,generally displaying rather weak negative Eu anomalies(δEu=0.74?0.93) and weak negative Ce(δCe=0.70?0.98) anomalies.The δ13CPDB values of carbon in calcite are-1.61‰?-5.82‰,the δ18OSMOW values of oxygen are 13.97‰?19.24‰,and the δ34SCDT values of sulfur in stibnite are 17.72‰?21.68‰.In regard to δD and δ18O,ore-forming fluids pos-sess the characteristics of metamorphic water.The process of metallogenesis of the Carlin-type gold deposits is con-trolled by the Yanshanian tectonic activities.The Yanshanian movement promoted the migration and mobilization of metamorphic fluids in the extensively developed medium-to high-grade metamorphic rocks in this region,carrying primarily enriched gold and associated elements such as Hg,As,and Sb in the Sinian metamorphosed black shales and Lower Cambrian black shales.The ore-forming fluids found their way into a suitable metallogenic environment along the fault zone,followed by gold precipitation to form gold deposits. 相似文献
15.
《International Geology Review》2012,54(8):715-731
The Prestea lode gold deposit occurs in a graphitic shear zone in the Birimian system of Ghana. The Birimian is an Early Proterozoic greenstone assemblage (≈ 2100 Ma) with large gold deposits, consisting of a lower unit predominantly of metasediments and an upper unit of metavolcanics with interbedded sediments. The metamorphic stage is of greenschist facies grade. The gold generally occurs as free gold or closely associated with sulfides, particularly arsenopyrite and sulfosalts. It is usually coarse grained and occurs along grain boundaries, as inclusions and in fractures with the ore minerals. The gold is nearly pure, with analyzed grains containing 95-96 wt% Au, 4-5 wt% Ag, and less than 0.1 wt% Sb, Bi, Zn, or Cu. Associated metallic phases consist of pyrite, arsenopyrite, chalcopyrite, pyrrhotite, sphalerite, galena, and sulfosalts such as tetrahedrite, boulangerite, bournonite, and jamesonite. The fluid associated with the gold mineralization was H2O-CO2-NaCl in composition, with a mean salinity = 3.6 wt% NaCl equivalent, CO2 density (mean) = 0.84 ± 0.09 g/cm3, and XCO2 = 13 to 33 mole %. Total homogenization temperatures range from 250° to 380° C. The ore fluid exhibits features suggesting contamination of volatiles such as N2 ± CH4 ± H2S, or post-depositional leakages. Arsenopyrite geothermometry indicates a temperature of mineralization from 325° to 450° C. Estimated pressures of trapping range from 1.0 to 2.2 kbars, with corresponding depths from 3.5 to 7.7 km, assuming the pressure is lithostatic. The gold deposition occurred from fluids with δ18O water = +9.6 to +13.9o and δDfluid irclusion = ?29 to ?65%0, suggesting a crustal origin for the ore-forming fluid, including a metamorphic and a magmatic source. A δ34Spyrite value of ?7.1 to ?11.7%o and δ34SΣS = ?9.6%o suggests a sedimentary origin for the sulfur. The gold deposition is attributed to destabilization of the bisulfide complex as a result of ore fluid reaction with host rock, resulting in a probable reduction by the carbonaceous matter in the host rock, and/or a decrease in the total sulfur concentration in the co-precipitation of sulfides. 相似文献
16.
17.
贵州水银洞金矿床成矿物理化学条件及金的迁移和沉淀 总被引：1，自引：0，他引：1
对水银洞金矿床流体包裹体开展了研究和热力学计算,解析了该矿床成矿物理化学条件及金的迁移形式和沉淀机制。研究表明:金的主成矿温度为215℃～267℃,压力28.5MPa～37.2MPa;成矿流体具弱酸性(pH=4.312)、还原性(fO2﹤10-35.315×105 Pa)。金在成矿溶液中主要以AuHS0等络合物形式进行迁移,HS-活度和氧逸度降低以及pH值升高是促使金沉淀的主要机制。 相似文献
18.
中国南方红土型金成矿系列研究综述 总被引：6，自引：0，他引：6
红土型金矿床是原生金矿化遭受红土化作用改造所形成的一种表生金矿床,包括"红色粘土型"和"铁帽型"金矿床.中国红土型金矿以风化再造型为主,受气候影响而主要分布在南方,并与岩金成矿系列分布基本一致.风化壳常量元素、稀土元素、粘土矿物系统研究表明,成矿作用环境时空变化整体受风化强度控制,其风化作用早期呈中碱性、晚期呈酸性,风化壳下部偏碱性、还原,项部偏酸性、氧化的特点.典型矿床因子分析揭示,红土型金成矿作用可分为氧化和水解两个阶段.氧化阶段风化较弱,基岩释放大量碱性离子,使成矿流体保持中性,金溶解并主要以Au(S2O3)23-形式迁移;水解阶段风化较强,硅酸盐矿物发生脱碱去硅作用,随着大气降水不断参与,成矿流体性质由中碱性缓慢过渡到中-酸性条件,金以胶体或氯化物络合物形式迁移.金一般在风化壳下部富集,表生矿物吸附、氧化还原界面处被Fe2 、Mn2 还原以及不同性质流体混合都能促使金的沉淀. 相似文献
19.
Yang Liqiang Deng Jun Zhang Jing Guo Chunying Gao Bangfei Gong Qingjie Wang Qingfei Jiang Shaoqing Yu Haijun 《中国地质大学学报(英文版)》2008,19(4):378-390
The recently discovered Damoqujia (大磨曲家) gold deposit is a large shear zone-hosted gold deposit of disseminated sulphides located in the north of the Zhaoping (招平) fault zone, Jiaodong (胶东) gold province, China. In order to distinguish the temperature range of cluster inclusions from different mineralization stages and measure their compositions, 16 fluid inclusions and 5 isotopic geochemistry samples were collected for this study. Corresponding to different mineralization stages, the multirange peaks of quartz decrepitation temperature (250-270, 310-360 and 380-430℃(2) indicate that the activity of ore-forming fluids is characterized by multistage. The ore-forming fluids were predominantly of high-temperature fluid system (HTFS) by CO2-rich, and SO2-4-K type magmatic fluid during the early stage of mineralization and were subsequently affected by low-temperature fluid system (LTFS) of CH4-rich, and Cl--Na /Ca2 type meteoric fluid during the late stage of mineralization. Gold is transferred by Au-HS- complex in the HTFS, and Au-Cl- complex can be more important in the LTFS. The transition of fluids from deeper to shallow environments results in mixing between the HTFS and LTFS, which might be one of the most key reasons for gold precipitation and large-scale mineralization. The ore-forming fluids are characterized by high-temperature, strong-activity, and superimposed mineralization, so that there is a great probability of forming large and rich ore deposit in the Damoqujia gold deposit. The main bodies are preserved and extend toward deeper parts, thereby suggesting a great potential in future. 相似文献
20.
惠家沟地区金矿化地质特征及其成因探讨 总被引：1，自引：0，他引：1
惠家沟金矿化区位于南秦岭印支冒地槽褶皱带东南端公馆—回龙汞锑矿带边缘。矿体呈层状,似层状赋存于中泥盆统杨岭沟组中上部碎屑岩—碳酸盐岩建造的浅变质细碎屑岩中。受层位、有利岩性和顺层韧～脆性剪切破裂带控制。矿化与硅化、黄铁矿化、毒砂化关系密切。金主要呈超显微自然金包含于毒砂黄铁矿中。矿化区中除 Au 外,尚伴有 As、Sb、Hg 等元素,并形成 Au—As—Sb—Hg 组合异常。成矿物质主要来源于容矿地层。成矿热液属大气降水与变顾热水的混合热液。成矿温度偏低、压力小。在矿化地质特征上,经初步研究认为类似卡林型金矿。由于该矿床多属地表工程控制,所获样品结果品位偏低,矿石中砷含量较高,且经初步选矿试验,金回收率较低,因此,矿石是否能被工业利用,尚待进一步研究探讨。 相似文献