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利用高分辨电镜对四川攀枝花富含钒、钛的磁铁矿的精细结构进行了研究，[110]方向的高分辨像清楚地显示了磁铁矿与钒磁铁矿沿[110]方向的波状紧密连生，在两相界面处和钒磁铁矿中观察到了反相畴结构及与元素间化学比有关的各种层措，并对其成因进行了讨论。 相似文献
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在含于磁铁矿中的四方对称结构氧化铅中观察到柏格斯矢量为２／１１（３１０）的（１１）层错，这些层错平行排列并相互交截，穿插形成沿（１００）方向的调制结构，调制波的平均波长约为１００ｎｍ同时，由多相关性区域的选区电子衍射图测定了磁铁矿中四方和正交氧化铅及方铁矿的取向关系。 相似文献
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利用高分辨电子显微镜及微区X射线能谱成分测定的方法,对含钒的天然磁铁矿的精细结构进行了研究。结果表明,[110]方向的高分辨像清楚地显示钒钛磁铁矿在磁铁矿基体中以共(110)面紧密连生的方式与基体共生,形成波状连生体。这种成份调制波结构表明它们是出溶产物。 相似文献
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塔里木盆地西北缘库孜贡苏剖面晚白垩世-早中新世沉积物岩石磁学研究 总被引：1，自引：0，他引：1
对塔里木盆地西北缘库孜贡苏剖面晚白垩世-早中新世沉积物进行了热退磁及岩石磁学研究,结果表明岩石热退磁及岩石磁学特征随沉积环境可分为三种类型:潮下、台地边缘浅滩相岩石主要磁性矿物为磁铁矿及少量针铁矿、磁赤铁矿,磁性矿物含量较少、颗粒较小（假单畴）,其天然剩磁强度较小,一般小于1×10-2 A/m,在250℃~500℃能获得稳定特征剩磁方向,特征剩磁由磁铁矿携带;潮间、潮上带岩石主要磁性矿物为磁铁矿,〖JP2〗并含有少量磁赤铁矿、赤铁矿、针铁矿,磁性矿物颗粒为假单畴和多畴,天然剩磁强度一般在1×10-2 ~1 A/m之间,在250℃~580℃能获得稳定特征剩磁方向,特征剩磁由磁铁矿携带;河湖相岩石主要磁性矿物为磁铁矿、赤铁矿,并含有少量磁赤铁矿、针铁矿,磁性矿物含量较多、颗粒较小（假单畴）,天然剩磁强度一般在1×10-1 A/m以上,多数样品特征剩磁由赤铁矿携带,少数由磁铁矿与赤铁矿共同携带。岩石磁学研究对于在沉积环境复杂剖面进行古地磁研究具有重要的意义。 相似文献
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鄂东矿集区矽卡岩型铁矿的叠加富集机制:来自磁铁矿结构和矿石品位数据的制约 总被引：1，自引：0，他引：1
矽卡岩型铁矿是我国重要的铁矿类型之一,但该类型铁矿床的品位存在两极分化的现象。本文对鄂东矿集区内典型的矽卡岩型铁矿:大冶铁铜矿、程潮铁矿和金山店铁矿开展详细的磁铁矿显微结构对比,并利用概率图解法对这三个矿床的矿石品位数据进行了筛分。发现在大冶铁铜矿和程潮铁矿中的磁铁矿至少有两个世代,发育明显的叠加结构,且叠加结构在光学显微镜和背散射电子照片中可以识别出来;金山店铁矿中局部矿石也发育叠加结构。这些矿床中代表性勘探线的钻孔品位数据的累积频率曲线具有由低值(TFe 18. 04%～33. 03%)和高值(TFe 48. 97%～55. 63%)两个非相交总体所形成的混合分布模式,剔除低品位数据(TFe 20%)再次筛分其分布模式不变,但单一总体的参数有所改变。磁铁矿结构和品位数据筛分结果表明,这些矿床可能是两个或多个期次/阶段成矿作用叠加的结果,但不同矿床的叠加程度略有区别,大冶和程潮铁矿叠加程度较高,而金山店则相对较弱,这可能是导致大冶和程潮矿床整体为富铁矿而金山店铁矿只有局部是富铁矿的重要原因。因此,叠加富集可能是矽卡岩型铁矿中铁高效富集的一种重要机制,多世代磁铁矿的发育范围和叠加程度可以在一定程度上反映高品位矿石的分布状况,其叠加程度可以作为矽卡岩型富铁矿的找矿线索。 相似文献
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四川冕西霓石碱性花岗岩中的稀土矿物主要为钙稀土氟碳酸盐矿物系列，通过选区电子衍射（SAED）和高分辨透射电子显微术（HRTEM）研究发现该系列矿物晶体结构中广泛发育复杂多样的微观地质异常现象，其主要类型有：（1）由该系列两个端员矿物氟碳铈矿结构层（B）与直氟碳钙铈矿结构层（S）以不同比例沿C轴方向有序堆垛形成的BmSn型规则混层结构；（2）无序堆垛形成的有序一无序结构晶畴；（3）由堆垛层错形成的无序混层结构，氟碳钙铈矿中不同多型体间的共格连生结构和相转变等；（4）氟碳铈矿结构中的平行于[001]方向的平移畴及一维无公度调制结构，该类调制结构可能是由于矿物中原子占位有序度的变化而形成的无序结构状态。 相似文献
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任思明 《矿物岩石地球化学通报》1984,(2)
磁铁矿是最常见的金属矿物之一,以往研究的也比较详细。其内部结构一般有环带结构,双晶结构和固溶体分解结构,分别由不同的形成环境所决定。我们在研究安徽霍邱,辽宁鞍山等地磁铁石英岩型铁矿床的磁铁矿时,发现它们还具有一种“鳞片结构”,形状特殊,分布普遍,尚未见报导。 相似文献
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辽宁省凤城市四道门沟铁矿床地质特征及成因分析 总被引：1，自引：0，他引：1
辽宁省凤城市四道门沟铁矿床位于辽东铁、硼成矿带内。以下元古界辽河群变质岩系最为发育,褶皱构造是直接控制本区变质层控铁硼矿的重要控矿条件,其控制着矿体的产出空间位置,并控制着区内铁矿体的展布特征。该区的铁矿属于火山沉积变质-超变质热液迭生层控矿床,矿石自然类型为磁铁矿-透闪石型,局部有磁铁矿-蛇纹石型和磁铁矿-硼镁铁矿型。 相似文献
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P. Sharma B. K. Mohapatra P. K. Nayak S. Mishra P. P. Singh 《Journal of the Geological Society of India》2017,89(5):541-546
Elongated NE-SW trending bodies of iron-rich rock are exposed adjacent to pyroxenite dyke within Sukinda ultramafic complex, Odisha. Field study followed by optical and electron microscopy, XRD and EPMA investigation reveal the rocks to be fine grained, weathered, limonitised; containing quartz, magnetite, hematite/martite and goethite. The rock has suffered from deformation during intrusion of chromiferous magma. It rarely shows banding/lamination, but largely exhibits mylonitic fabric, resulting from magmatic intrusion. The stronger deformation is evident from sub-grain formation, deformed mineral grains; often with orientation, stretching (boudinage) and shortening (folding); presence of porphyroclasts, pull-apart structure, undulose extinction, dynamic recrystallisation etc. From the microstructure and mineral abundance, the rock is designated as “Mylonitic Magentite Quartzite” (MMQ).Enrichment of some elements like Ni, Mg, Cr in the magnetite phase of MMQ is attributed to solid state diffusion of these elements from chromiferous mafic magma during thermal metamorphism. This is determined from electron probe microanalysis of iron-rich phase in MMQ, which is found to contain 88-90 wt% of FeO(t) with ~1%, NiO, ~1%, MgO and 0.1% Cr2O3 having around 3 mole% of trevorite; 4-6% of magnesioferrite; 0.15-0.3% of chromite; 86-87% of magnetite and 3-4% of wustite. Considering presence of wustite as temperature indicator, the temperature of magma envisaged to be around 950-1100°C.In a later period, the MMQ has undergone oxidation and lateritisation owing to its prolonged exposure. During this process, new minerals like hematite and goethite substituted magnetite, resulting leaching of iron (FeO: 62-68%) and magnesium (MgO: 0.1-0.35) and enrichment of chromium (Cr2O3:4-7%) and nickel (NiO: 1.6-2.3%). The silica (SiO2: 4-5%), alumina (Al2O3:~1%) are contributed by kaolinite, formed during lateritisation.The field and laboratory studies confirm these iron-rich exposures to be enclaves of BIFs, banded magnetite quartzite (BMQ) in particular, within the Sukinda chromiferous ultramafic complex. Micro-structural features and microchemical composition of iron minerals in these exposures are interpreted as the influence of forceful ultramafic intrusion into the existing BMQ and effect of thermal metamorphism followed by oxidation, weathering/lateritisation. 相似文献
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记录地幔中存在氧元素的自然铁-方铁矿组合 总被引：2，自引：0，他引：2
笔者在西藏蛇绿岩的铬铁矿石中发现了十分复杂的地幔矿物群,其中包括自然铁-方铁矿的共生组合,它们被认为是外地核和下地幔的物质通过地幔柱作用携带到上地幔的。新发现的自然铁-方铁矿组合表明,外地核液态铁溶解有部分氧,当液态铁由外地核上升时,氧从液态铁中析出并呈不混溶状态存在于液态铁中。随着乳滴状自然铁球粒向上运移,在降压条件下液态铁和氧元素发生化学反应生成方铁矿(包括NI AS结构)。当氧耗尽时,在方铁矿中遗留下氧耗尽的空洞,形成眼球状构造。因此,眼球构造可能是外地核向地幔释放氧,下地幔内存在氧元素的历史记录。 相似文献
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Beate Orberger Christiane Wagner Alina Tudryn Richard Wirth Rachael Morgan José D. Fabris Jean Marc Greneche Carlos Rosière 《Physics and Chemistry of Minerals》2014,41(9):651-667
The pseudomorphic transformation of magnetite into hematite (martitization) is widespread in geological environments, but the process and mechanism of this transformation is still not fully understood. Micro- and nano-scale techniques—scanning electron microscopy, focused ion bean transmission electron microscopy, and Raman spectroscopy—were used in combination with X-ray diffraction, Curie balance and magnetic hysteresis analyses, as well as Mössbauer spectroscopy on martite samples from a banded iron formation (2.9 Ga, Dharwar Craton, India), and from lateritic soils, which have developed on siliciclastic and volcanic rocks previously affected by metamorphic fluids (Minas Gerais, Brazil). Octahedral crystals from both samples are composed of hematite with minor patches of magnetite, but show different structures. The Indian crystals show trellis of subhedral magnetite hosting maghemite in sharp contact with interstitial hematite crystals, which suggests exsolution along parting planes. Grain boundary migrations within the hematite point to dynamic crystallization during deformation. Dislocations and fluid inclusions in hematite reflect its precipitation related to a hydrothermal event. In the Brazilian martite, dislocations are observed and maghemite occurs as Insel structures and nano-twin sets. The latter, typical for the hematite, are a transformation product from maghemite into hematite. For both samples, a deformation-induced hydrothermally driven transformation from magnetite via maghemite to hematite is proposed. The transformation from magnetite into maghemite comprises intermediate non-stoichiometric magnetite steps related to a redox process. This study shows that martite found in supergene environment may result from earlier hypogene processes. 相似文献
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C. J. Goss 《Physics and Chemistry of Minerals》1988,16(2):164-171
This study has characterised the oxidation products of a fine-grained single domain magnetite which was made synthetically by a colloidal method. Changes in the intrinsic magnetic properties (saturation magnetisation, saturation remanence, and coercive force) during progressive oxidation are correlated with lattice parameter changes and an oxidation mechanism. It is proposed that magnetite oxidises to hematite via at least two metastable maghemites. The first of these, formed on low temperature oxidation by the formation of a magnetite/maghemite solid solution, is a face centered maghemite with lattice parameter a= 8.3419±0.0006 Å. A second maghemite, produced on oxidation at higher temperatures, has a primitive cubic structure and a lattice parameter a = 8.3505±0.0005 Å. Maghemite cation distributions are derived to explain the reduced saturation magnetisations of between 56 and 74 Am2 kg-1 observed, and a maghemite structure containing an increase in tetrahedral Fe3+ ions and up to 3 octahedral vacancies per 32 oxygen unit cell is proposed. 相似文献
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《矿物学报》2013,(Z1)
Qara-aghaj and Skandian as hard rock titanium deposit and Kahnooj one as a placer deposit were investigated from applied mineralogical point of view. The mineralogical studies were carried out using XRD, XRF, optical microscopy, scanning electron microscopy and microprobe analysis. These studies indicated that ilmenite and magnetite are main valuable minerals in the studied ores. Pyroxene, olivine and plagioclase are the main gangue minerals in Qara-aghaj ore while chlorite and plagioclase are the major gangue minerals in Skandian ore. Plagioclase, clinopyroxene, amphibole, feldspate and some quartz are the important gangue minerals in kahnooj deposit. In all three ores ilmenite is mainly in the form of ilmenite grains but some lamellae of ilmenite with thickness between 0.1 to 20 μm have been occurred as exsolution textures inside magnetite grains, where the magnetite here can be referred to as ilmenomagnetite. In the hard rock ores some fine ilmenites have been disseminated in silicate minerals. The liberation degree of granular ilmenite was determined 150, 140 and 200 μm for Qara-aghaj, Skandian and Kahnooj, respectively. So, only the granular form of ilmenite is recoverable by physical methods. Some sphene and rutile as titanium containing minerals were observed mainly inside ilmenite phase in kahnooj ore. Some fine rutile was also found inside Skandian ilmenite while there were not any other titanium minerals inside Qara-aghaj ilmenite. Apatite is another valuable mineral which was found only in Qara-aghaj ore. Using SEM and microprobe analysis it was found that there are different amounts of exsolved fine lamellae of hematite inside ilmenite in Qara-aghaj and Kahnooj ores while it was not observed in Sckandian one. The average contents of TiO2 in the lattice of Qara-aghaj, Skandian and Kahnooj ilmenite were determined 51.13, 50.9% and 52.02%, respectively. FeO content of ilmenite lattice for all three samples is clearly lower than the theoretical content. This is due to the substitution of Mg and Mn for some Fe2+ ions in the ilmenite lattice. V2O3 content of magnetite lattice is up to 1%. So, magnetite can be a suitable source for production of vanadium as a by-product in all three deposits. 相似文献