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1.
全反射X射线荧光光谱法同时测定天然水中多种元素   总被引:4,自引:0,他引:4  
李国会  张天估 《岩矿测试》1998,17(2):123-126
利用自行研制的有3个反射体的全反射X射线荧光分析仪,以Se作内标,同时测定天然水中的痕量Ni、Cu、Zn、Pb、Rb和Sr。对纳克级元素,方法的检出限为10-10~10-11g,水样分析结果与无火焰原子吸收法和ICPMS法相符,精密度好,对纳克级痕量元素测定的RSD(n=5)小于72%。  相似文献   

2.
陈远盘 《矿产与地质》1995,9(5):404-409
建立了X射线荧光光谱(XRFS)分析中修正比例常数法的理论和分析方法,主要用来测定8 ̄24K黄金首饰样品中的主、次元素含量。  相似文献   

3.
采用低分辨率能量色散X射线荧光分析仪和偏最小二乘法对太平洋多金属结核中的Mn、Fe、Co、Ni和Cu等元素进行了现场分析,并对所用仪器的性能和方法的可靠性作了评价。方法经国家级标准物质验证,其测定值与标准值相符,RSD(n=42)各元素均小于1.0%,分析结果满足现场分析中矿物品位的测定要求。  相似文献   

4.
X射线荧光光谱法直接测定地质样品中多种痕量元素   总被引:2,自引:0,他引:2  
邹海峰  苏克 《岩矿测试》1998,17(3):207-210
采用低压聚乙烯镶边垫底的粉末压饼法制样,X射线荧光光谱法直接测定了地质样品中痕量元素As、Ga、Sc、La、Y、Ce、W、Mo、Sn、Co和Pb。讨论了背景校正、谱线重叠校正、基体效应校正和仪器漂移校正等问题。利用理论α系数代替经验系数,使方法具有较高的准确度和较低的检出限。所测11个元素的检出限在(0.30~2.02)×10-6水平,精度(RSD,n=11)在0.95%~13.0%。方法经国家一级标准物质分析验证,结果与标准值相符。  相似文献   

5.
密度校正法测定金饰品中的金   总被引:3,自引:0,他引:3  
通过研究共存元素及基体效应,提出了用X射线荧光密度校正法(XRF)无损检验金饰品中金。该方法测定金的含量范围为10% ̄99%,精密度为0.2%。  相似文献   

6.
陈永群  詹秀春 《岩矿测试》1994,13(3):211-213
酸分解试样,点滴麦勒膜制片,Ni元素作内标,使用X射线荧光光谱法同时测定金银标准样品中Au,Ag,Cu和Zn,分析范围为0.2%-100%。对于Au,Ag,Cu和Zn含量为83%,8.0%,6.2%,3.0%的试样,其RSD(n=6)分别为0.1%、1.1%、0.9%和1.1%。  相似文献   

7.
张彪 《国外铀金地质》2000,17(2):180-185
美国环保局环境响应队(USEPA/ERT)已广泛应用野外便携式X射线荧光仪9FPXRF)在全国范围内对危险废物污染区的土壤和沉积物中的金属进行分析。USEPA/ERT有两种X荧光仪:Outokumpu电子公司(OEI)的X-MET880型Spectrace仪器公司生产的Spectrace9000型FPXRF分析仪。文中讨论了仪器的标定、精度的确定和检出限,阐述了就地分析和分析制备的土壤术方法。各种  相似文献   

8.
X射线荧光靶线内标法测定金首饰中的银   总被引:7,自引:1,他引:7  
郑荣华 《岩矿测试》1996,15(3):229-231
采用X射线荧光靶线内标法测定黄金饰品中银含量,当w(Ag)<10%时,测定的标准偏差小于001%,测量平均值与标准值的偏差亦小于001%;当w(Ag)<8%时,测定的标准偏差小于004%,测量平均值与标准值的偏差小于007%。方法能较好地补偿了表面形状对测定结果的影响,适用w(Au)>92%的饰品中银的测定  相似文献   

9.
X射线荧光光谱集成分析系统   总被引:2,自引:2,他引:2  
选用了兼容性能好的386微机,在DOS操作系统和Windows3.1环境下,研究开发了X射线荧光光谱集成分析系统(XRFIAS),全面更新了理学公司3080系列仪器的计算机硬件和软件。采用了当前最流行的多窗口,全屏幕友好界面,在西文DOS操作系统下,显示汉字信息。有常规的(背景扣除,内标校正,谱重叠校正,基体校正)数据处理功能(多种校正模式)扩充了分析元素,内标元素、干扰元素的数量,新开发了共用背  相似文献   

10.
金银铂及首猸物的无损检测   总被引:3,自引:0,他引:3  
陈永君  邓赛文 《岩矿测试》1994,13(2):145-149
使用X射线荧光谱仪,采用透空照射、数学校正法并与比重法联用,可无损检测金、银、铂及饰物的成色,判别包、镀金饰品,较好校正了饰物的形状、面积和光法度的影响,不受宝石镶嵌物的限制,能够提供金,银,铂及饰物成色和杂质元素的配比数据,用该法测定24K及14K值饰品的RSD(=9)分别为0.01%和0.82%,测定范围在1%-100%之间。  相似文献   

11.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

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14.
正1 Introduction Geological studies established on several sections in Lanping-Simao basin have shown that the salt-bearing strata of Mengyejing formation(Yunlong Fm.in Lanping basin)are constituted by an alternation of salt layers and interbedded facies.The latter consists mainly of mudstones,and mudstone-rich conglomerate.The mineralogy and geochemistry of salt-bearing beds and  相似文献   

15.
正On 22nd April 2014,with the approach of the 45th World Earth Day,China’s Ministry of Land and resources issued the status of China’s mineral resources in 2013.The first task of the prospecting breakthrough strategy action implemented in the last five years has been completed,and China’s security capacity for mineral resources has been significantly improved.In the  相似文献   

16.
正There are more than 700 salt lakes with area of more than 1km2 on the Qinghai-Tibet Plateau of China.In recent years,an oilfield brine was also found in the Nanyishan Section of Qaidam Basin in the Qinghai-Tibet  相似文献   

17.
正1 Introduction Physical and numerical models are constructed to investigate the evolution and mechanism of salt migration driven by tectonic processes.In recent years,we have designed and ran series of models to simulate salt  相似文献   

18.
正The study of Cretaceous-Palaeogene salt-bearing strata of the Khorat Basin Laos and the Lanping-Simao Basin in Yunnan,China has an great significance not only in explaining the basin evolution and the genesis of potash  相似文献   

19.
正Potash is one of the long-term scare deposits in China,and potash prospecting has long been listed as a key brainstorm project for our nation and geological prospecting units.There have been considerable studies in search for potash deposits in the Kuqa depression of the Tarim basin(Jackson et al.,1991;Gemmer et al.,2004;Vendeville,2005;Vendeville and Jackson,1992a,1992b),  相似文献   

20.
正1 Introduction Qaidam Basin in Qinghai,including 43 salt lakes with multiple dominant mineral such as potassium,magnesium,lithium etc.,is the most intensive distribution of Saline  相似文献   

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