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1.
The Middle Jurassic Barcroft mafic granodiorite and Late Cretaceous, ternary-minimum McAfee Creek Granite are important components of the igneous arc sited along the SW North American margin. Bulk-rock analyses of 11 samples of the metaluminous, I-type Barcroft comagmatic suite have an average δ18O value of 7.4±0.6‰ (all values±1σ). Four Barcroft specimens average εNd=?3.6±1.8, 87Sr/86Sr=0.707±0.001. The pluton consists of petrochemically gradational, Ca-amphibole-rich gabbro/diorite, granodiorite, metadiorite, and rare alaskite–aplite; for most of the pluton, oxygen isotope exchange of quartz, feldspar(s), biotite, and Ca-amphibole accompanied local deuteric alteration. Eight specimens of slightly peraluminous granitic rocks of the muscovite-bearing McAfee Creek series have an average δ18O of 8.6±0.5‰. Four McAfee-type samples average εNd=?7.8±1.7, 87Sr/86Sr=0.711±0.004. For both plutons, bulk-rock evidence of exchange with near-surface water is lacking, suggesting ~5–10 km cooling depths. Barcroft minerals exhibit regular oxygen isotopic partitioning from high to low δ18O in the sequence quartz>plagioclase>K-feldspar>>amphibole≥biotite. Along the SE margin of the pluton, quartz and biotite in Lower Cambrian quartzites are higher in δ18O, and show slightly larger fractionations than igneous analogues. Exchange with fluids derived from these heated, contact-metamorphosed country rocks increased bulk 18O/16O ratios of Barcroft border rocks (and constituent plagioclase+subsolidus tremolite–actinolite), especially of granitic dikes transecting the wall rocks. Oxygen isotope thermometry for seven Barcroft pluton quartz–amphibole and six quartz–biotite pairs indicate apparent subsolidus temperatures averaging 519±49 °C. Quartz–plagioclase pairs from two Barcroft granodiorites yield values of 519 and 515 °C. A quartz–biotite pair from a quartzite adjacent to the Barcroft pluton yields an apparent temperature of 511 °C, in agreement with estimates based on contact metamorphic parageneses. Except for its SE margin, Barcroft pluton silicates evidently exchanged oxygen isotopes under local deuteric conditions. Compatible with Ca-amphibole thermobarometric analyses, areal distributions for quartz–plagioclase, quartz–amphibole, and quartz–biotite pairs reveal that putative annealing temperatures are lowest in NE-trending axial portions of the Barcroft body, so it simply cooled inwards. Intrusion ~70 million years later by the McAfee Creek Granite had no discernable effect on δ18O values of Barcroft minerals and bulk rocks.  相似文献   

2.
《Chemical Geology》2002,182(2-4):473-482
Three lithological Groups I (medium-grained, with magmatogenic arfvedsonite), II (medium-grained, with secondary arfvedsonite) and III (fine-grained, with magmatogenic arfvedsonite) are identified in the Saertielieke alkali granite pluton, Ulungur of the northern Xinjiang, China. A weak negative correlation between the δ18O values of alkali feldspar and quartz separates from each group, and the distinctly lower δ18O values of alkali feldspar separates from Groups I and II than those from Group III are interpreted in terms of superimposed closed-system and open-system isotope exchange. A small amount of locally exsolved magmatic fluid is involved in the development of the perthitic texture in alkali feldspar at ∼400 °C that results in a volume increase and, hence, causes quartz deformation. The microtextural changes promote the closed-system oxygen isotope exchange between quartz and alkali feldspar that causes a dispersion in the quartz δ18O values. However, the distinctly lower δ18O values of alkali feldspar and secondary arfvedsonite coupled with their microtextural characteristics indicate that meteoric-derived water plays an important role in the further development of alkali feldspar exsolution texture at T<400 °C and directly causes secondary arfvedsonite formation. The estimated relative exchange rates kQuartz/kFeldspar/kArfvedsonite of ∼10/100/1 for Groups I and III, and ∼10/100/100 for Group II suggest that alkali feldspar, quartz, and secondary arfvedsonite have exchanged with meteoric-derived water mainly via dissolution–reprecipitation, whereas magmatogenic arfvedsonite has exchanged via diffusion.  相似文献   

3.
Peralkaline syenite and granite dykes cut the Straumsvola nepheline syenite pluton in Western Dronning Maud Land, Antarctica. The average peralkalinity index (PI?=?molecular Al/[Na?+?K]) of the dykes is 1.20 (n?=?29) and manifests itself in the presence of the Zr silicates eudialyte, dalyite and vlasovite, and the Na–Ti silicate, narsarsukite. The dykes appear to have intruded during slow cooling of the nepheline syenite pluton, and the petrogenetic relationship of the dykes and the pluton cannot be related to closed-system processes at low pressure, given the thermal divide that exists between silica-undersaturated and oversaturated magmas. Major and trace element variations in the dykes are consistent with a combination of fractional crystallization of parental peralkaline magma of quartz trachyte composition, and internal mineral segregation prior to final solidification. The distribution of accessory minerals is consistent with late-stage crystallization of isolated melt pockets. The dykes give an Rb–Sr isochron age of 171?±?4.4 Ma, with variable initial 87Sr/86Sr ratio (0.7075?±?0.0032), and have an average ε Nd of ? 12.0. Quartz phenocrysts have δ18O values of 8.4–9.2‰, which are generally in O-isotope equilibrium with bulk rock. Differences in the δ18O values of quartz and aegirine (average Δquartz?aegirine = 3.5‰) suggest aegirine formation temperatures around 500 °C, lower than expected for a felsic magma, but consistent with poikilitic aegirine that indicates subsolidus growth. The negative ε Nd (< ? 10) and magma δ18O values averaging 8.6‰ (assuming Δquartz?magma = 0.6‰) are inconsistent with a magma produced by closed-system fractional crystallization of a mantle-derived magma. By contrast, the nepheline syenite magma had mantle-like δ18O values and much less negative ε Nd (average ??3.1, n?=?3). The country rock has similar δ18O values to the granite dykes (average 8.0‰, n?=?108); this means that models for the petrogenesis of the granites by assimilation are unfeasible, unless an unexposed high-δ18O contaminant is invoked. Instead, it is proposed that the peralkaline syenite and granite dykes formed by partial melting of alkali-metasomatised gneiss that surrounds the nepheline syenite, followed by fractional crystallization.  相似文献   

4.
This paper investigates the origin of low-δ18O quartz porphyry dykes associated with the 144–133 Ma Koegel Fontein Igneous Complex, which was intruded during the initial phase of breakup of Africa and South America. The 25-km diameter Rietpoort Granite is the largest and youngest phase of activity, and is roofed by a 10-km diameter pendant of gneiss. Quartz porphyry (QP) dykes, up to 15 m in width, strike NW–SE across the complex. The QP dykes that intruded outside the granite have similar quartz phenocryst δ18O values (average 8.0‰, ± 0.7, n?=?33) to the granite (average 8.3?±?1.0, n?=?7). The QP dykes that intruded the roof pendant have quartz phenocrysts with more variable δ18O values (average 1.6‰, ± 2.1, n?=?55). In some cases quartz phenocrysts have δ18O values as low as ? 2.5‰. The variation in δ18O value within the quartz crystal population of individual dykes is small relative to the overall range, and core and rim material from individual quartz phenocrysts in three samples are identical within error. There is no evidence that quartz phenocryst δ18O values have been affected by fluid–rock interaction. Based on a ?quartz?magma value of 0.6‰, magma δ18O values must have been as low as ? 3.1‰. Samples collected along the length of the two main QP dykes that traverse the roof pendant have quartz phenocryst δ18O values that range from +?1.1 to +?4.6‰, and ? 2.3 to +?5.6‰, respectively. These δ18O values correlate negatively (r = ? 0.96) with initial 87Sr/86Sr, which can be explained by the event that lowered δ18O values of the source being older than the dykes. We suggest that the QP dykes were fed by magma produced by partial melting of gneiss, which had been variably altered at high temperature by 18O-depleted meteoric water during global glaciation at ~?550 Ma. The early melts had variable δ18O value but as melt pockets interconnected during melting, the δ18O values approached that of average gneiss. Variable quartz phenocryst δ18O values in the same dyke can be explained by vertical emplacement, at variable rates of ascent along the dyke. The lateral variation in quartz, and hence magma δ18O value at a particular point along a single dyke would depend on the rate of ascent of magma at that point along the dyke, and the ‘age’ of the particular magma batch.  相似文献   

5.
Oxygen isotope studies of the Suzhou granite have been made based on drill-hole samples. In the inner part, the δ18O values are less variable either in the whole-rock, quartz or in feldspar. Oxygen isotopic compositions are in equilibrium between coexisting quartz and feldspar. Data points from the inner part are plotted in a small area in the δ18OQ-δ18Of diagram, indicating that this part has not been affected by meteoric hydrothermal fluids. But the whole-rock δ18O values of the marginal part vary greatly. Oxygen isotopic compositions are in extreme disequilibrium between quartz and feldspar. Data points from the marginal part are displayed with a nearly vertical slope in the δ18OQ-δ18Of diagram, implying that rocks of this part are affected by the meteoric hydrothermal fluids. Extreme water-rock interactions lead to mineralizations of rare-elements (Nb, Ta, as well as Zr, Hf, Th) in the marginal part. Source materials of the Suzhou granite are also discussed in this paper.  相似文献   

6.
Oxygen isotope compositions of mineral separates were determined from two metaluminous granitoids (Emas and São Rafael plutons) from northeastern Brazil. The I-type Emas pluton has high δ18O (WR) values (11.5–11.8‰), whereas the São Rafael pluton has low δ18O (WR) values (7.5–8.1‰), but Sr and Nd are characteristics of S-type granitoids. Measured mineral–mineral fractionations suggest continuous sub-solidus inter-mineral isotope exchange among all minerals except zircon. There is a large and consistent quartz–epidote fractionation that gives apparent temperatures that are much lower than anticipated closure temperatures for epidote. Oxygen isotope fractionation between natural zircon and magmatic epidote is opposite to that predicted from theoretical determinations, as δ18O (epidote) <δ18O (zircon). An empirical calibration based on these results would suggests a closure T for oxygen in epidote of ~500 °C and Δ(qtz–epi) ~5.19 at 500 °C.  相似文献   

7.
Tourmalinization associated with peraluminous granitic intrusions in metapelitic host-rocks has been widely recorded in the Iberian Peninsula, given the importance of tourmaline as a tracer of granite magma evolution and potential indicator of Sn-W mineralizations. In the Penamacor-Monsanto granite pluton (Central Eastern Portugal, Central Iberian Zone), tourmaline occurs: (1) as accessory phase in two-mica granitic rocks, muscovite-granites and aplites, (2) in quartz (±mica)-tourmaline rocks (tourmalinites) in several exocontact locations, and (3) as a rare detrital phase in contact zone hornfels and metapelitic host-rocks. Electron microprobe and stable isotope (δ18O, δD, δ11B) data provide clear distinctions between tourmaline populations from these different settings: (a) schorl–oxyschorl tourmalines from granitic rocks have variable foititic component (X□ = 17–57 %) and Mg/(Mg + Fe) ratios (0.19–0.50 in two-mica granitic rocks, and 0.05–0.19 in the more differentiated muscovite-granite and aplites); granitic tourmalines have constant δ18O values (12.1 ± 0.1 ‰), with wider-ranging δD (?78.2 ± 4.7 ‰) and δ11B (?10.7 to ?9.0 ‰) values; (b) vein/breccia oxyschorl [Mg/(Mg + Fe) = 0.31–0.44] results from late, B- and Fe-enriched magma-derived fluids and is characterized by δ18O = 12.4 ‰, δD = ?29.5 ‰, and δ11B = ?9.3 ‰, while replacement tourmalines have more dravitic compositions [Mg/(Mg + Fe) = 0.26–0.64], close to that of detrital tourmaline in the surrounding metapelitic rocks, and yield relatively constant δ18O values (13.1–13.3 ‰), though wider-ranging δD (?58.5 to ?36.5 ‰) and δ11B (?10.2 to ?8.8 ‰) values; and (c) detrital tourmaline in contact rocks and regional host metasediments is mainly dravite [Mg/(Mg + Fe) = 0.35–0.78] and oxydravite [Mg/(Mg + Fe) = 0.51–0.58], respectively. Boron contents of the granitic rocks are low (<650 ppm) compared to the minimum B contents normally required for tourmaline saturation in granitic melts, implying loss of B and other volatiles to the surrounding host-rocks during the late-magmatic stages. This process was responsible for tourmalinization at the exocontact of the Penamacor-Monsanto pluton, either as direct tourmaline precipitation in cavities and fractures crossing the pluton margin (vein/breccia tourmalinites), or as replacement of mafic minerals (chlorite or biotite) in the host-rocks (replacement tourmalinites) along the exocontact of the granite. Thermometry based on 18O equilibrium fractionation between tourmaline and fluid indicates that a late, B-enriched magmatic aqueous fluid (av. δ18O ~12.1 ‰, at ~600 °C) precipitated the vein/breccia tourmaline (δ18O ~12.4 ‰) at ~500–550 °C, and later interacted with the cooler surrounding host-rocks to produce tourmaline at lower temperatures (400–450 °C), and an average δ18O ~13.2 ‰, closer to the values for the host-rock. Although B-metasomatism associated with some granitic plutons in the Iberian Peninsula seems to be relatively confined in space, extending integrated studies such as this to a larger number of granitic plutons may afford us a better understanding of Variscan magmatism and related mineralizations.  相似文献   

8.
The δ18O values of vein quartz of different stages from the Yinshan ore deposit are constant around 16‰ and the calculated δ18OH2O values attain 8‰± ; the δDH2O values of fluid inclu-sions in vein quartz are constant at about-60‰. From the surface down to 1200 m below the δ18O values of altered rocks gradually decrease from 15‰± to 11‰± . Various water-rock inversion calculations indicate that the ore fluids were formed by the interaction between meteoric water and phyllite at 350℃ and the effective W/ R value of around 0.1. When the water-rock exchange in the upper mineralization system took place, the effective W / R value increased to 5.0 or more. As a result, an evolution and mineralization model of a buffered open system with two-stage water-rock interactions is proposed in this study.  相似文献   

9.

Metamorphosed turbidites from the Omeo Metamorphic Complex show only minor changes in δ18O values with increasing metamorphic grade from 13.4 ± 1.7% in the chlorite and biotite zones to 12.3 ± 1.0% in the sillimanite + K‐feldspar zone. Rocks within 5 km of the S‐type granite at Hume Dam have δ18O values of 6.8–8.1% that probably reflect interaction with heated meteoric‐igneous fluids. Interaction with igneous fluids has also occurred close to other I‐ and S‐type granites in this region. However, pervasive metamorphic fluid‐rock interaction in this terrain did not occur, which limits the region's potential for hydrothermal mineralisation. Anatexis at high grades was probably via dehydration‐melting reactions that consumed muscovite and biotite, which is consistent with there being little fluid present during metamorphism. Small (kilometre scale or less) S‐type granites in the sillimanite + K‐feldspar zone have δ18O values similar to those of the surrounding metasediments and probably formed by melting of those rocks. By contrast, larger (tens of kilometres scale) Ca‐rich, peraluminous, S‐type granites have lower δ18O values than the surrounding metasediments, and may represent melts of underlying middle to lower crust.  相似文献   

10.
It is well established that A-type granites enriched in high field strength elements, such as Zr, Nb and the REE, form in anorogenic tectonic settings. The sources of these elements and the processes controlling their unusual enrichment, however, are still debated. They are addressed here using neodymium and oxygen isotope analyses of samples from the 1.24 Ga Strange Lake pluton in the Paleoproterozoic Core Zone of Québec-Labrador, an A-type granitic body characterized by hyper-enrichment in the REE, Zr, and Nb. Age-corrected εNd values for bulk rock samples and sodic amphiboles (mainly arfvedsonite) from the pluton range from ?0.6 to ?5.7, and ?0.3 to ?5.3, respectively. The εNd values for the Napeu Kainiut quartz monzonite, which hosts the pluton, range from ?4.8 to ?8.1. The 147Sm/144Nd ratios of the suite and the host quartz monzonite range from 0.0967 to 0.1659, large variations that can be explained by in situ fractionation of early LREE-minerals (Strange Lake), and late hydrothermal HREE remobilization. Oxygen isotope analyses of quartz of both Strange Lake and the host yielded δ18O values between +8.2 and +9.1, which are considerably higher than the mantle value of 5.7 ± 0.2‰. Bulk rock oxygen isotope analyses of biotite-gneisses in the vicinity of the Strange Lake pluton yielded δ18O values of 6.3, 8.6 and 9.6‰. The negative εNd values and positive δ18O values of the Strange Lake and Napeu Kainiut samples indicate that both magmas experienced considerable crustal contamination. The extent of this contamination was estimated, assuming that the contaminants were sedimentary-derived rocks from the underlying Archean Mistinibi (para-) gneiss complex, which is characterized by low εNd and high δ18O values. Mixing of 5–15% of a gneiss, having an εNd value of ?15 and a δ18O value of +11, with a moderately enriched mantle source (εNd = +0.9, δ18O = +6.3) would produce values similar to those obtained for the Strange Lake granites. Based on analogies between the Nain Plutonic Suite and the Gardar alkaline igneous province (SW-Greenland), we conclude that the Strange Lake pluton and associated REE-mineralized anorogenic bodies formed from a combination of subduction-induced fertilization of the sublithospheric mantle, crustal extension and in situ magma evolution.  相似文献   

11.
The Huaixi copper-gold polymetallic deposit of SE Zhejiang Province, China, is a typical hydrothermal-vein ore body. The Caomen K-feldspar granite porphyry, the dominant intrusion in the mining district, has been dated by laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) analyses of zircon, which yielded a weighted mean 206Pb/238U age of 101.6 ± 0.9 Ma (MSDW?=?1.3). Rb-Sr dating of fluid inclusions in auriferous quartz from ore bodies yielded an isochron age of 101 ± 2 Ma. These results indicate that intrusion of the Caomen pluton and Cu-Au mineralization was contemporaneous and corresponds to the third episode of Mesozoic magmatism and metallogenesis in South China. Calculated δ18O values of fluid inclusions from ore-bearing quartz range from??0.89 to??1.98‰ and δD from??42.60 to??60.20‰, suggesting that the ore-forming fluids are derived from a mixed source of magmatic and meteoric waters. δ18S values of 8 pyrites range from??2.14 to?+4.14‰ with a mean of?+1.67‰, similar to magmatic sulphur. These isotope data support a genetic relationship between the Huaixi copper-gold deposit and the Caomen alkaline granite and probably indicate a common deep source. Petrography and chemical compositions show that the Caomen alkaline granite crystallized from shoshonitic magmas characterized by high SiO2 (75.64–78.00%) and alkali (K2O?+?Na2O?=?7.96–8.82%) but low FeOT (1.34–3.31%), P2O5 (0.05–0.13%) and TiO2 (0.12–0.18%). The granitic rocks are enriched in Ga, Rb, Th, U, and Pb but depleted in Ba, Nb, Sr, P, and Ti. REEs are characterized by marked negative Eu anomalies (Eu/Eu*?=?0.06–0.13) and exhibit right-dipping ‘V’ patterns with LREE enrichment. These are similar to the Late Cretaceous alkaline granites in the coastal areas of Zhejiang and Fujian provinces, implying that the Caomen granite formed in a post-collisional extensional tectonic setting. Combined with previous studies, we interpret the Huaixi copper-gold deposit and the associated Caomen alkaline granite as related to back-arc extension due to high-angle subduction of the palaeo-Pacific plate, caused by northward movement of the Indian plate.  相似文献   

12.
Oxygen isotope ratios of quartz inclusions (QI) within garnet from granulite and amphibolite facies gneisses in the Adirondack Mountains, NY were analysed and used to determine metamorphic temperatures. Primary QI for eight of 12 samples have δ18O values significantly lower than matrix quartz (MQ). The primary QI retain δ18O values representative of thermal conditions during garnet crystallization, whereas the δ18O values of MQ were raised by diffusive exchange with other matrix minerals (e.g. mica and feldspar) during cooling. The δ18O differences between QI and MQ show that garnet (a mineral with slow diffusion of oxygen) can armour QI from isotopic exchange with surrounding matrix, even during slow cooling. These differences between δ18O in MQ and QI can further be used to test cooling rates by Fast Grain Boundary diffusion modelling. Criteria for identifying QI that preserve primary compositions and are suitable for thermometry were developed based on comparative tests. Relations between δ18O and inclusion size, distance of inclusion to host–garnet rim, core–rim zonation of individual inclusions, and presence or absence of petrological features (healed cracks in QI, inclusions in contact with garnet cracks lined by secondary minerals, and secondary minerals along the inclusion grain boundary) were investigated. In this study, 61% of QI preserve primary δ18O and 39% were associated with features that were linked to reset δ18O values. If δ18O in garnet is homogeneous and inclusions are removed, laser‐fluorination δ18O values of bulk garnet are more precise, more accurate, and best for thermometry. Intragrain δ18O(Grt) profiles measured in situ by ion microprobe show no δ18O zonation. Almandine–rich garnet (Alm60–75) from each sample was measured by laser‐fluorination mass‐spectrometry (LF‐MS) for δ18O and compared with ion microprobe measurements of δ18O in QI for thermometry. The Δ18O(Qz–Grt) values for Adirondack samples range from 2.66 to 3.24‰, corresponding to temperatures of 640–740 °C (A[Qz–Alm] = 2.71). Out of 12 samples that were used for thermometry, nine are consistent with previous estimates of peak temperature (625–800 °C) based on petrological and carbon–isotope thermometry for regional granulite and upper amphibolite facies metamorphism. The three samples that disagree with independent thermometry for peak metamorphism are from the anorthosite–mangerite–charnockite–granite suite in the central Adirondacks and yield temperatures of 640–665 °C, ~100 °C lower than previous estimates. These low temperatures could be interpreted as thermal conditions during late (post‐peak) crystallization of garnet on the retrograde path.  相似文献   

13.
The Sin Quyen-Lung Po district is an important Cu metallogenic province in Vietnam, but there are few temporal and genetic constraints on deposits from this belt. Suoi Thau is one of the representative Cu deposits associated with granitic intrusion. The deposit consists of ore bodies in altered granite or along the contact zone between granite and Proterozoic meta-sedimentary rocks. The Cu-bearing intrusion is sub-alkaline I-type granite. It has a zircon U-Pb age of ~776 Ma, and has subduction-related geochemical signatures. Geochemical analysis reveals that the intrusion may be formed by melting of mafic lower crust in a subduction regime. Three stages of alteration and mineralization are identified in the Suoi Thau deposit, i.e., potassic alteration; silicification and Cu mineralization; and phyllic alteration. Two-phase aqueous fluid inclusions in quartz from silicification stage show wide ranges of homogenization temperatures(140–383℃) and salinities(4.18wt%–19.13wt%). The high temperature and high salinity natures of some inclusions are consistent with a magmatic derivation of the fluids, which is also supported by the H-O-S isotopes. Fluids in quartz have δD values of –41.9‰ to –68.8‰. The fluids in isotopic equilibrium with quartz have δ~(18)O values ranging from 7.9‰ to 9.2‰. These values are just plotted in the compositional field of magmatichydrothermal fluids in the δD_(water) versus δ~(18)O_(water) diagram. Sulfide minerals have relatively uniform δ~(34)S values from 1.84‰ to 3.57‰, which is supportive of a magmatic derivation of sulfur. The fluid inclusions with relatively low temperatures and salinities most probably represent variably cooled magmatic-hydrothermal fluids. The magmatic derivation of fluids and the close spatial relationship between Cu ore bodies and intrusion suggest that the Cu mineralization most likely had a genetic association with granite. The Suoi Thau deposit, together with other deposits in the region, may define a Neoproterozoic subduction-related ore-forming belt.  相似文献   

14.
碾子山晶洞碱性花岗岩矿物-水氧同位素交换反应动力学   总被引：4，自引：0，他引：4  
对黑龙江碾子山碱性花岗岩的全岩及其主要单矿物进行了氧同位素分析，结果表明，全岩和单矿物不仅δ^18O 值变化范围较大（全岩－2．4－2．0‰，石英0．0－5．8‰，碱性长石－3．8－0．1‰，磁铁矿－8．5－1．0‰），而且强烈亏损^18O。共生矿物之间表现出明显不平衡的氧同位素分馏特征，指示在花岗岩侵位之后与水之间发生了同位素交换，根据锆石和现代大气降水的氧同位素组成，对岩石与外来流体的δ^18O值进行了估计，多维矿水－岩反应时限约为0．3－3Ma，水／岩比（氧摩尔比）介于0．11－1．02之间。水－岩反应温度较高（约400度）和反应时间较长是导致石英δ^18O值降低的主要原因。  相似文献   

15.
The Siljan Ring is a 362-Ma-old impact structure formed in 1700-Ma-old I-type granites. A 6.8-km-deep borehole provides a vertical profile through granites and isolated horizontal diabase sills. Fluid-inclusion thermometry, and oxygen-isotope compositions of vein quartz, granite, diabase, impact melt, and pseudotachylite, reveal a complex history of fluid activity in the Siljan Ring, much of which can be related to the meteorite impact. In granites from the deep borehole, 18O values of matrix quartz increase with depth from near 8.0 at the surface to 9.5 at 5760 m depth. In contrast, feldspar 18O values decrease with depth from near 10 at the surface to 7.1 at 5760 m, forming a pattern opposite to the one defined by quartz isotopic compositions. Values of 18O for surface granites outside the impact structure are distinct from those in near-surface samples from the deep borehole. In the deep borehole, feldspar coloration varies from brick-red at the surface to white at 5760 m, and the abundances of crack-healing calcite and other secondary minerals decrease over the same interval. Superimposed on the overall decrease in alteration intensity with depth are localized fracture zones at 4662, 5415, and 6044 m depth that contain altered granites, and which provided pathways for deep penetration of surface water. The antithetic variation of quartz and feldspar 18O values, which can be correlated with mineralogical evidence of alteration, provides evidence for interaction between rocks and impact-heated fluids (100–300° C) in the upper 2 km of the pluton. Penetration of water to depths below 2 km was restricted by a general decrease in impact-fracturing with depth, and by a 60-m-thick diabase sill at 1500 m depth that may have been an aquitard. At depths below 4 km in the pluton, where water/rock ratios were low, oxygen isotopic compositions preserve evidence for limited high-temperature (>500° C) exchange between alkali feldspar and fluids. The high-temperature exchange may have been a post-impact event involving impact-heated fluids, or a post-magmatic event.  相似文献   

16.
Oxygen isotope ratios, whole rock major and trace element compositions, and petrological characteristics of 52 samples from nine distinct igneous lithologies in the lower plate of the Whipple Mountain metamorphic core complex of south-eastern California indicate that both mylonitic and non-mylonitic lithologies underwent exchange with surface-derived meteoric waters. Broadly granodioritic lithologies are characterized by whole rock δ18O values that range from 10.6 to 2.6‰. Isotopic compositions of quartz and feldspar mineral separates indicate that quartz has largely retained original igneous compositions but that feldspar has undergone variable and often large 18O-depletions (up to 6.5‰). Over 4 km of structural relief is exposed in lower plate gneisses below the Whipple detachment fault including non-mylonitic lithologies at shallow structural levels above the mylonite front, and mylonitic gneisses at intermediate to deep levels below the mylonite front. Coupled δ18Oqtz - δ18OFsp systematics of non-mylonitic and mylonitic andesite to rhyolite dykes from shallow and intermediate structural levels of the lower plate document two episodes of hydrothermal alteration: a high-temperature (>c.600d?C) episode involving a metamorphic or magmatic fluid with δ18O values ～ 7‰ and a low-temperature (c.350d?C) episode involving low-δ18O meteoric fluids. All the dykes that document exchange with meteoric fluids are non-mylonitic. Coupled δ18OFsp systematics of non-mylonitic and mylonitic granodioritic gneisses from above and below the mylonite front also document low-temperature (c. 350d? C) exchange with meteoric fluids. The data indicate that infiltration of meteoric fluids occurred as lower plate lithologies were juxtaposed against the base of the faulted upper plate. High-angle normal faults in the upper plate served as the conduits for the downward circulation of surface-derived fluids. Meteoric fluids were able to penetrate across the detachment fault into the lower plate. Uplift rates coupled with independent cooling rates indicate that surface-derived fluids penetrated to a depth of c.4km and possibly as deep as c.8km. Penetration of surface-derived fluid into the ductile deformation regime is not required to explain the low δ18O values observed in lower plate lithologies of the Whipple Mountain metamorphic core complex.  相似文献   

17.
Crystallization of anatectic melts in high-temperature metamorphic terrains releases volatile-rich magmas that can be transported into adjacent lithologies. This study addresses the variations in the oxygen, boron and hydrogen isotopic composition of aplite-pegmatite dikes that formed during the crystallization of anatectic melts in regional high-temperature metamorphism on the island of Naxos, Greece, and propagated upward into the overlying sequences of metamorphic schist. The transport distance of these dikes was increased through a significant horizontal component of travel that was imposed by contemporaneous low-angle extensional shearing. Laser fluorination oxygen isotope analyses of quartz, tourmaline, garnet, and biotite mineral separates from the aplite-pegmatite dikes show a progressive rise in δ18O values with increasing distance from the core. Oxygen isotope fractionations among quartz, tourmaline, and garnet show temperature variations from > 700°C down to ∼400°C. This range is considered to reflect isotopic fractionation beginning with crystallization at high temperatures in water-undersaturated conditions and then evolving through lower temperature crystallization and retrograde sub-solidus exchange. Two processes are examined for the cause of the progressive increase in δ18O values: (1) heterogeneous δ18O sources and (2) fluid-rock exchange between the aplite/pegmatite magmas and their host rock. Although the former process cannot be ruled out, there is as yet no evidence in the exposed sequences on Naxos for the presence of a suitable high δ18O magma source. In contrast, a tendency for the δ18O of quartz in the aplite/pegmatite dikes to approach that of the quartz in the metamorphic rock suggests that fluid-rock exchange with the host rock may potentially be an important process. Advection of fluid into the magma is examined based on Darcian fluid flow into an initially water-undersaturated buoyantly propagating aplitic dike magma. It is shown that such advective flow could only account for part of the 18O-enrichment, unless it were amplified by repeated injection of magma pulses, fluid recycling, and deformation-assisted post-crystallization exchange. The mechanism is, however, adequate to account for hydrogen isotope equilibration between dike and host rock. In contrast, variations in the δ11B values of tourmalines suggest that 11B/10B fractionation during crystallization and/or magma degassing was the major control of boron geochemistry rather than fluid-rock interaction and that the boron isotopic system was decoupled from that of oxygen.  相似文献   

18.
LIU  WEI 《Journal of Petrology》2000,41(9):1455-1466
18O/16O and D/H isotope compositions are reported for coexistingquartz, feldspar and biotite from four lithological units withinthe Aral granite batholith, Altay Mts of China. The data exhibita reversed and an anomalously large positive quartz–feldspar18O/16O fractionation. These two 18O/16O fractionations, togetherwith a marked decrease in the D values of biotite, are interpretedin terms of a model involving two stages of isotopic exchangewith aqueous fluids. The first stage of 18O/16O exchange withan 18O-rich aqueous fluid occurred during subsolidus cooling.Kinetic effects of the first stage of 18O/16O exchange are characterizedby the reversed quartz–feldspar 18O/16O fractionationthat was recorded in the megacrystic coarse-grained granitesof Group I and the megacryst-bearing medium- to coarse-grainedgranites of Group II. Robust parameters for the first stageof exchange are obtained by modelling on the hypothesis of initial18O/16O heterogeneity in the granite plus subsolidus 18O/16Oexchange. The spread in the measured 18O values of quartz reflectsthe initial heterogeneity of the granite. Calculated isochronsillustrate that an initially heterogeneous system reacting withan externally buffered fluid can generate arrays that mimicisotherms. The second stage of isotopic exchange with 18O- andD-depleted meteoric water occurred after magma solidification,resulting in the anomalously large positive quartz–feldspar18O/16O fractionation and a marked decrease in the D valuesof biotite. These kinetic effects have been recorded in thefiner-grained granites of Groups III and IV. However, the coarser-grainedgranites of Groups I and II have essentially survived the secondstage of 18O/16O exchange. KEY WORDS: Altay; granite; initial 18O/16O heterogeneity; pseudoisotherm; quartz–feldspar 18O/16O reversal  相似文献   

19.
Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The εHf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ18O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H2O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H2O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H2O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.  相似文献   

20.
The highest grade pelitic and semipelitic rocks of the Ballachulish aureole are dominantly potash feldspar + cordierite + biotite hornfelses with widely variable amounts of quartz, plagioclase, andalusite, sillimanite and corundum (together with accessory phases). On a microscopic scale these hornfelses show textural evidence of the presence of melt, whilst on a mesoscopic scale they contain a variety of leucosomes. Oxygen isotope studies have been carried out on both whole rocks and mineral separates in order to: (1) assess the sources of molten and volatile constituents and (2) determine the extents of isotopic homogenization and equilibration. Data from localities with both restricted and extensive evidence of leucosomes and melt development are compared, as well as one locality with petrographic evidence of melt incursion from the igneous complex. The whole-rock δ18O values of the leucosomes (10.5–14.9%.) are in general similar to the immediately adjacent mesosomes (9.9–14.5%.) which are typically cordierite- and feldspar-rich hornfelses. Isotopic evidence is thus consistent with an in-situ partial melt origin for the leucosomes, without the substantial addition of externally derived components. In the area of extensive melt development, the ‘chaotic zone’, it is possible there was addition of an H2O-rich fluid phase (6-13 wt%) from the igneous complex which resulted in a slight lowering of δ18O values by 0.5–1.0%. Quartz mineral separates were used to assess the degree of local isotopic homogenization. In the extensively molten area (chaotic zone) there is extensive homogenization between rock layers (quartz δ18O usually within 1.0%), whilst in less molten areas δ18O quartz has a range of c. 3.0%. The greater homogenization in the chaotic zone is attributed to the increased degree of melting and infiltration of H2O-rich fluid from the igneous complex.  相似文献   

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