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加速器质谱~(14)C制样真空系统及石墨制备方法研究 总被引：1，自引：1，他引：0
~(14)C制样真空系统和石墨制备方法是高精度低本底~(14)C加速器质谱(AMS)测量的关键,而碳污染、石墨产率不稳定和同位素分馏等问题是限制该技术发展的主要难题。为了降低传统在线还原法对制样系统长时间静态真空的要求和解决Zn-TiH_2/Fe火焰封管法中不可控的CH_4等问题,提高石墨合成的稳定性和控制本底,本文建立了基于Zn/Fe火焰封管法的~(14)C制样真空系统和石墨制备方法。通过比较Zn/Fe在线法和Zn/Fe火焰封管法对石墨束流性能以及标样的影响,发现Zn/Fe火焰封管法相较Zn/Fe在线法能明显克服大气泄漏问题,改善化学流程本底(0.24～0.32pMC),提高方法测年上限(47000～48000ya),同时石墨束流输出稳定。进一步利用标准样品和本底样品评估了Zn/Fe火焰封管法的技术特点,实验结果表明该法的精密度好(RSD=0.35%,n=20,标样OXⅡ),准确度高(IAEA系列标样的测定值与认定值线性拟合方程y=0.9969x+0.0013,R~2=1),实验本底低(无机碳46296±271ya和有机碳48341±356ya)。因此,该石墨样品制备真空系统及Zn/Fe火焰封管法技术具有石墨品质优、化学流程本底低、准确度和精密度高等特点,满足高精度低本底~(14)C-AMS测定石墨样品制备要求。 相似文献
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加速器质谱(AMS)是进行~(14)C同位素分析的主要技术手段,而高精度低本底加速器质谱~(14)C分析主要受样品制备技术限制,因此探讨如何提高石墨制备的稳定性和控制碳污染降低本底将有助于产出高质量~(14)C分析数据,突破~(14)C测年上限(约5.0万年),进一步拓宽~(14)C年代学和同位素示踪的应用范畴。本文详细阐述了催化还原法(H_2/Fe法、Zn/Fe法和Zn-TiH_2/Fe法)制备石墨样品的真空装置和主要工作原理,指出了微量样品石墨制备过程中同位素分馏、石墨产率、束流强度以及精密度与样品量之间存在严重的依赖关系及其抑制方法。着重探讨了石墨制备技术实验条件(还原剂、催化剂、温度等)的优化选择及其与石墨产率、同位素分馏、束流性能之间的内在联系,总结分析了碳污染来源并探寻合适的碳污染控制技术。目前的研究表明最佳实验条件为:H_2/Fe法宜采用还原剂H_2/CO_2(体积比2～2.5),催化剂为源自氢还原单质铁粉(-325目球粒,Fe/C=2～5),温度500～550℃;Zn/Fe法宜采用还原剂Zn/C(质量比50～80),催化剂为源自氢还原单质铁粉(-325目球粒,Fe/C=2～5),Zn反应管温度400～450℃,Fe反应管温度500～550℃。碳污染来源于制备过程中的各个方面,除采用高温除碳的方式外还可采用适当的数学模型加以校正,但还需要更多详细的实验工作来加强现有认识,以期更好地消除碳污染对测试结果的影响。对测年目标组分不稳定的样品(如地下水中的溶解无机碳)应避免样品直接暴露于大气,以减少野外采样过程中现代大气CO_2对测量结果的影响。 相似文献
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放射性碳测年国际比对活动的初步结果 总被引：1，自引：1，他引：1
中国科学院地球环境研究所^14C实验室作为中国唯一的代表参加了第四届放射性碳测年国际比对活动(FIRI），取得了比较优异的成绩。初步分析了本届比对活动的测年结果，得出如下结论：不同的^14C测年方法对测年结果无明显的影响，不同现代碳标准的选择对大部分样品的测年结果有较明显的影响，而采用不同的本底物质仅对老年龄样品的定年有显著影响；加速器质诺测年法在各种^14C测年方法中最准确、精度最高，正逐渐成为国际^14C测年方法的主流。 相似文献
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放射性同位素14C测年技术广泛应用于第四纪地质学、考古学、海洋学和古气候等学科。常规14C测年,是采用β衰变低本底液体闪烁计数仪记录一定时间间隔内一定量样品中14C原子衰变数目的方法,由于仪器操作简单、方便,在不受样品量限制的情况下,测试的精度能够满足测年的要求。14C测年液闪法样品制样前处理系统主要在真空玻璃系统中完成,但真空玻璃系统容易出现破碎、断裂,每个实验室需要配备专门的玻璃焊接师傅维护和维修真空玻璃系统,制约着14C测年技术的发展。文章探讨了常规14C制样系统的升级改造,建立了一套金属系统、不用玻璃焊接,无油污染、安装方便、拆卸灵活的常规14C测年样品制备系统,该套系统解决了常规14C发展中遇到的难点问题,使得常规14C测年技术得到更好的推广和应用。 相似文献
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天然放射性碳同位素在海洋有机地球化学中的应用 总被引：7，自引：1，他引：7
天然放射性碳（14C）是年代测定的有效手段，它在考古学和地质学的应用已有几十年的历史。过去10年中，伴随着加速器质谱仪（AMS）技术和检测灵敏度的提高，AMS已经能够检测少于mg C量级样品中自然丰度水平的14C，这大大扩展了14 C在自然科学，特别是地球科学研究中的应用范畴。简要评述了利用天然14 C进行海洋地球化学研究的应用，重点介绍了前景广阔、并已取得显著成果的应用领域。 相似文献
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通过加速器质谱方法，精确测定了南极燕窝湖沉积物陆生苔藓^14C年龄，获得该湖区沉淀速率为0．03-0．11cm／a，并据此估算出燕窝湖沉积物是距今13000a，即末次冰期以来形成的。讨论了大气^14C产生率纬度效应，以及^14C分布储存库效应、环境效应、硬水效应等对极地湖泊沉积物^14C测年之影响及校正。 相似文献
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“死碳”对14C年代测定影响的初步研究 总被引：3，自引：1，他引：2
在回顾14 C测年技术发展的基础上,指出了影响14 C测年精度的各种因素,并初步讨论了“死碳”对14 C年代的影响。通过对岩溶区“死碳”的成因分析以及对碳酸盐样品的14 C年代学研究,认为酸的来源不同,是造成岩溶区样品14 C年代偏老的原因;局部环境中“死碳”释放是造成水生样品14 C表观年龄偏老的主要原因。由于影响岩溶区样品14 C年龄的因素是多方面的,目前尚无有效的校正办法。为此,作者在讨论了洞穴碳酸盐样品年代的可靠性及影响因素的基础上,提出了用交叉对比定年的方法解决“死碳”对14 C测年的影响问题和在岩溶地区谨慎使用14 C年龄的建议。 相似文献
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放射性碳同位素(14C)是含碳物质年代测定的有效手段,它的半衰期是5730年.研究了珠江口及南海沉积物碳黑的放射性碳年龄,碳黑样品采取化学氧化方法提取,用加速器质谱仪(AMS)测定珠江三角洲沉积柱中碳黑的放射性碳同位素剂量.研究结果表明,位于珠江口的钻孔3的碳黑的14C年龄是倒置的,邻近香港的钻孔30的碳黑14C年龄旱现老.新.老的趋势,而钻孔E2的碳黑的14C年龄则儿乎是不变的.碳黑的这种14C年龄的变化趋势与碳黑的来源相关,化石燃料来源的碳黑的增加使得碳黑的14C年龄偏老. 相似文献
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环渤海泥质海岸带近30年来获得的600余个放射性碳测年数据,确定了该地区晚更新世晚期以来的基本年代地层序列。但是,对14C数据的系统校正,迄未得到应有的重视,致使在应用14C数据解释地层和地质现象的年代时,存在着一定程度的混乱。文章对作者自己所采集和由国内外有关实验室测定的126个14C数据进行了系统校正,主要步骤包括分馏效应、地区性海洋贮存库效应及大气14C含量变化校正等。建议以-2.68‰PDB作为环渤海晚更新世晚期以来半咸水和开放浅海区(潮间带与潮下带上部)贝壳的地区性δ13C平均值。另外,讨论了在地区性海洋贮存库效应值获得之前的1990年代,以MARINE93与INTCAL93程序的平均校正年龄近似地视作该地区贝壳的校正值,以抵消这一类地区小型水体与大气迅速进行14CO2交换而对年龄值的影响。CALIB4.4校正结果表明,前述近似校正是可行的,其结果仍可沿用。文章经统一校正的年龄,最大限度地接近其太阳历纪年的"真实"年龄,从而有助于更加准确地重建该地区的晚更新世晚期以来的地质年代史,并可与考古纪年及其他测年方法获得的绝对年龄直接对比。 相似文献
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Chris D. Clark Richard C. Chiverrell Derek Fabel Richard C. A. Hindmarsh Colm Ó Cofaigh James D. Scourse 《第四纪科学杂志》2021,36(5):673-680
Motivated to help improve the robustness of predictions of sea level rise, the BRITICE-CHRONO project advanced knowledge of the former British–Irish Ice Sheet, from 31 to 15 ka, so that it can be used as a data-rich environment to improve ice sheet modelling. The project comprised over 40 palaeoglaciologists, covering expertise in terrestrial and marine geology and geomorphology, geochronometric dating and the modelling of ice sheets and oceans. A systematic and directed campaign, organised across eight transects from the continental shelf edge to a short distance (10s of kilometres) onshore, was used to collect 914 samples which yielded 639 new ages, tripling the number of dated sites constraining the timing and rates of change of the collapsing ice sheet. This special issue synthesises these findings of ice advancing to the maximum extent and its subsequent retreat for each of the eight transects to produce definitive palaeogeographic reconstructions of ice margin positions across the marine to terrestrial transition. These results are used to understand the controls that drove or modulated ice sheet retreat. A further paper reports on how ice sheet modelling experiments and empirical data can be used in combination, and another probes the glaciological meaning of ice-rafted debris. 相似文献
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作为晚更新世与全新世地层年代测定的一种重要手段,14C测年被广泛应用于地质样品的年代测定。但对于14C数据的系统校正,迄今未得到应有的重视。文章在环渤海海岸带14C数据集(Ⅰ)的基础上,对所收集的421个由其他研究者获得的环渤海海岸带14C数据进行了系统校正。并讨论了百年、千年与万年尺度的14C数据校正效果。结果表明,直接测定值与系统校正值之间的差值常有数百年至两千年的差别。经统一校正的14C年龄,最大限度地接近样品太阳历纪年的“真实”年龄,从而有助于更加准确地重建该地区的晚更新世晚期以来的地质年代史,并可与考古纪年及其他测年方法获得的绝对年龄直接对比。 相似文献
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Pollen‐ and related proxy‐based studies of human–environment interactions during the Norse and later periods within Greenland have primarily involved the investigation of peat, lake and soil deposits, all of which have taphonomic and sampling problems. Many small ponds exist, but they seem to have been relatively ignored in investigations of palaeoecologically based environmental history. To evaluate their usefulness for studies of ecologically related cultural history, especially where sites are in intimate association with the archaeology, a pond in the Norse Eastern Settlement has been examined to investigate three principal questions: (i) Does such a site contain a useful record of environmental history? (ii) Does it offer a record of sufficient resolution and sensitivity for the study of anthropogenic landscape impacts? (iii) Are there any apparent drawbacks to these sequences? Using data obtained from palynological, diatom, sedimentological and radiocarbon analyses, it is concluded that environmental data for each proxy – aside from 14C dating – are clearly capable of being explained in a reasonably straightforward and compatible manner and fulfil the hopes for the sampling medium. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
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《第四纪科学杂志》2002,17(7):633-637
Interlaboratory comparisons have been widely used in applied radiocarbon science. These are an important part of ongoing quality assurance (QA) programmes, which are vital to the appropriate interpretation of the evidence provided by the 14C record in Quaternary applications (including climate change and environmental reconstruction). International comparisons of laboratory performance are an essential component of the quality assurance process in radiocarbon dating. If the user community is to have confidence in radiocarbon results, it needs to be assured that laboratories world wide are producing measurements that are reliable and in accordance with ‘good practice’. The findings from the most recent (completed in 2001) and extensive (more than 90 participating laboratories) radiocarbon intercomparison (FIRI) are reported here. This study was designed (i) to assess comparability, or otherwise, of the results from different laboratories and (ii) to quantify the extent and possible causes of any interlaboratory variation. The results demonstrate that there are no significant differences amongst the main measurement techniques (gas proportional counting, liquid scintillation counting and accelerator mass spectrometry (AMS)) but there is evidence of small laboratory offsets relative to known age samples for some laboratories. There is also evidence in some cases of underestimation of measurement precision. Approximately 10% of all results were classified as extreme (outliers) and these results were generated by 14% of the laboratories. Overall, the evidence supports the fact that radiocarbon laboratories are generally accurate and precise but that, notwithstanding internal QA procedures, some problems still occur, which can best be detected by participation in independent intercomparisons such as FIRI, where the results allow individual laboratories to assess their performance and to take remedial measures where necessary. The results from FIRI are significant in that they show a broad measure of agreement between measurements made in different laboratories on a wide range of materials and they also demonstrate no statistically significant difference between measurements made by radiometric or AMS techniques. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
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Artur Sobczyk Ryszard K. Borówka Janusz Badura Renata Stachowicz-Rybka Julita Tomkowiak Anna Hrynowiecka Joanna Sławińska Michał Tomczak Mateusz Pitura Mariusz Lamentowicz Piotr Kołaczek Monika Karpińska-Kołaczek Dariusz Tarnawski Marcin Kadej Piotr Moska Marek Krąpiec Krzysztof Stachowicz Bartosz Bieniek Krzysztof Siedlik Małgorzata Bąk Jan van der Made Adam Kotowski Krzysztof Stefaniak 《第四纪科学杂志》2020,35(4):539-558
The sedimentary succession exposed in the Gorzów Wielkopolski area includes Eemian Interglacial (MIS 5e) or Early Weichselian (MIS 5d–e) deposits. The sedimentary sequence has been the object of intense interdisciplinary study, which has resulted in the identification of at least two palaeolake horizons. Both yielded fossil remains of large mammals, alongside pollen and plant macrofossils. All these proxies have been used to reconstruct the environmental conditions prevailing at the time of deposition, as well as to define the geological context and the biochronological position of the fauna. Optically stimulated luminescence dating of the glaciofluvial layers of the GS3 succession to 123.6 ± 10.1 (below the lower palaeolake) and 72.0 ± 5.2 ka (above the upper palaeolake) indicate that the site formed during the Middle–Late Pleistocene (MIS 6 – MIS 5). Radiocarbon-dating of the lacustrine organic matter revealed a tight cluster of Middle Pleniglacial Period (MIS 3) ages in the range of ~41–32 ka cal bp (Hengelo – Denekamp Interstadials). Holocene organic layers have also been found, with 14C ages within a range of 4330–4280 cal bp (Neolithic). Pollen and plant macrofossil records, together with sedimentological and geochemical data, confirm the dating to the Eemian Interglacial. 相似文献
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The behaviour of ice sheets as they retreated from their Last Glacial Maximum (LGM) positions provides insights into Lateglacial and early Holocene ice‐sheet dynamics and climate change. The pattern of deglaciation of the Laurentide Ice Sheet (LIS) in arctic fiord landscapes can now be well dated using cosmogenic exposure dating. We use cosmogenic exposure and radiocarbon ages to constrain the deglaciation history of Clyde Inlet, a 120 km long fiord on northeastern Baffin Island. The LIS reached the continental shelf during the LGM, retreated from the coastal lowlands by 12.5 ± 0.7 ka (n = 3), and from the fiord mouth by 11.7 ± 2.2 ka (n = 4). Rapid retreat from the outer fiord occurred 10.3 ± 1.3 ka (n = 6), with the terminus reaching the inner fiord shortly after 9.4 ka (n = 2), where several moraine systems were deposited between ca. 9.4 and ca. 8.4 ka. These moraines represent fluctuations of the LIS during the warmest summers since the last interglaciation, and this suggests that the ice sheet was responding to increased snowfall. Before retreating from the head of Clyde Inlet, the LIS margin fluctuated at least twice between ca. 7.9 and ca. 8.5 ka, possibly in response to the 8.2 ka cold event. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献