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1.
铜陵狮子山矿田金矿床和铜矿床矿石稀土元素地球化学   总被引:5,自引:0,他引:5  
在全面收集前人有关安徽铜陵狮子山矿田主要矿床矿石和蚀变岩石稀土元素分析结果的基础上,对比研究了矿田内金矿床和铜矿床的稀土元素地球化学特征。研究表明,金矿床和铜矿床矿石和蚀变岩石的稀土元素组成、轻重稀土比值和(La/Yb)N 值等特征参数承袭了矿区岩浆岩的特征,显示成矿物质的来源以岩浆来源为主,富集地壳组分,反映在成矿过程中深部热液对已固结岩浆岩的淋滤萃取作用和对沉积围岩的叠加改造作用,成矿作用与岩浆作用密切相关;不同成矿阶段和不同类型矿石或蚀变岩石的REE 特征反映REE 的来源和演化可能与成矿金属元素的来源及其富集成矿机制相一致。此外,金矿床和铜矿床矿石稀土元素地球化学行为亦显示出明显的差异性,铜矿床矽卡岩阶段矿石比石英硫化物阶段矿石相对低的REE 含量,以及部分矽卡岩矿石具有La,Ce 明显亏损的富集LREE 折线型配分模式,反映铜矿床这部分矽卡岩具有岩浆成因的特征;而金矿床和部分铜矿床中的矽卡岩及矽卡岩型矿石则以热液交代成因为主;金矿床和铜矿床Eu异常特征则反映了其成矿热液流体起源压力的差异及流体性质的阶段性演化。  相似文献   

2.
J. Arif  T. Baker 《Mineralium Deposita》2004,39(5-6):523-535
Gold is an important by-product in many porphyry-type deposits but the distribution and chemistry of gold in such systems remains poorly understood. Here we report the results of petrographic, electron microprobe, laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), and flotation test studies of gold and associated copper sulfides within a paragenetic framework from the world-class Batu Hijau (914 mt @ 0.53% Cu, 0.40 g/t Au) porphyry copper–gold deposit, Indonesia. Unlike many other porphyry copper–gold deposits, early copper minerals (bornite–digenite–chalcocite) are well preserved at Batu Hijau and the chalcopyrite–pyrite overprint is less developed. Hence, it provides an excellent opportunity to study the entire gold paragenesis of the porphyry system. In 105 polished thin sections, 699 native gold grains were identified. Almost all of the native gold grains occurred either within quartz veins, attached to sulfide, or as free gold along quartz or silicate grain boundaries. The native gold grains are dominantly round in shape and mostly 1–12 m in size. The majority of gold was deposited during the formation of early A veins and is dominantly associated with bornite rather than chalcopyrite. The petrographic and LA-ICP-MS study results indicate that in bornite-rich ores gold mostly occurs within copper sulfide grains as invisible gold (i.e., within the sulfide structure) or as native gold grains. In chalcopyrite-rich ores gold mostly occurs as native gold grains with lesser invisible gold. Petrographic observations also indicate a higher proportion of free gold (native gold not attached to any sulfide) in chalcopyrite-rich ores compared to bornite rich ores. The pattern of free gold distribution appears to correlate with the flotation test data, where the average gold recovery value from chalcopyrite-rich ores is consistently lower than bornite-rich ores. Our data suggest that porphyry copper-gold deposits with chalcopyrite-rich ores are more likely to have a higher proportion of free gold and may require different ore processing strategies.Editorial handling: R. P. Richards  相似文献   

3.
金牙金矿载金矿物及金的赋存状态研究   总被引:3,自引:0,他引:3  
李福春  叶荣 《矿产与地质》1996,10(5):300-305
应用电子探针、电子衍射、电子顺磁共振和化学分析等多种现代方法和手段,综合研究载金矿物的特征及金的赋存状态,认为金牙金矿中载金矿物主要是毒砂和黄铁矿,金的主要赋存形式是超显微包体金,为解决金芽金矿床难处理的原生矿石提供了科学数据资料。  相似文献   

4.
甘肃寨上金矿床矿物组成特征与矿质沉淀机理   总被引:2,自引:0,他引:2       下载免费PDF全文
位于西秦岭礼(县)—岷(县)成矿带西段的寨上金矿床,是近年发现的一个大型微细浸染型金矿。笔者通过显微镜观察、电子探针和扫描分析等综合分析技术,确认金矿床中矿物组成相当丰富,既有大量硫化物、硫盐、氧化物、硫酸盐、碳酸盐、钨酸盐,又有碲化物、自然金属及多金属互化物。除常见矿物为自然金、黄铁矿、黄铜矿、黝铜矿、方铅矿、闪锌矿、辉锑矿、石英、白钨矿、方解石、菱铁矿、铁白云石和重晶石外,笔者还鉴定出在卡林型金矿床较少见的一些矿物,如硫铜锑矿、车轮矿、辉锑铅矿、辉钼矿、碲汞矿、碲镍矿、Cu-Zn-Ni-Sn-Fe的金属互化物和白钨矿等。矿石中矿物种类较多,组成较复杂以及存在显微自然金,构成寨上金矿床的一大特色。赋矿围岩中含Fe碳酸盐矿物溶解释放Fe以及溶解Fe的大量硫化物化,是寨上金矿床中存在显微可见自然金的最重要因素和金沉淀富集的有利条件。  相似文献   

5.
The Chinkuashih is a group of dacite-related hydrothermal enargite-gold deposits of the Quaternary age, which produced 94 tons of gold and 119,101 tons of copper from 1895 to 1987. It has remaining reserves of 656 tons of gold with an average grade range of 1.5–3.5 g/ton of Au for all orebodies discovered.Mercury content in different media such as stream sediments, heavy minerals in stream sediments, soils, rocks/ores, and pyrite samples was analyzed by a gold–film mercury detector to evaluate whether mercury is a good pathfinder for these types of deposits at Chinkuashih. The gold film technique is more rapid and cheaper than the traditional fire assay or fire assay/ICP-MS gold and trace element analyses.Mercury in stream sediments and soils indicated the border zone of gold mineralization 12 km away from the center of mineralization at Chinkuashih. Mercury in heavy minerals of the stream sediments distinguished the intermediate zone with gold veins and gold/gold–copper breccia pipes from the core or inner zone with the gold–copper zone. It has been found that contours of 1000 or 500 ppb Hg of soil samples can delineate the outcropping gold orebodies. The gold ores generally contain 1000 ppb or more Hg.  相似文献   

6.
本文对发现于河南毛堂金矿田氧化矿石中的含锡自然铜进行了矿物学研究。该矿物属等轴晶系,O_h~5-F_(m3m),a_0=3.655?,Z=4。化学成分中Cu 90.38(wt)%,Sn 9.38(wt)%,分子式Cu_(18)Sn。含锡自然铜相当于Cu_(18)Sn合金中的a相,在自然界属首次发现。  相似文献   

7.
陕西省潼关县碾头岔含金石墨矿工艺矿物学研究   总被引:2,自引:0,他引:2  
工艺矿物学系统研究表明:碾头岔含金石墨矿床的矿石中除石墨外,可综合利用的有用元素还有金、铜等。金矿物颗粒较细,主要以独立矿物形式赋存于载体矿物黄铜矿、黄铁矿及石墨中。黄铜矿是主要的铜矿物,其次有蓝辉铜矿。石墨呈独立矿物存在,片大且较平直,属于大鳞片石墨,矿石中总碳仅有65%左右以石墨碳形态存在。上述3种有用元素均可通过合理磨矿,选择适宜的选矿条件得到金精矿、铜精矿和石墨精矿。然而由于石墨精矿中杂质较多且颗粒细小,主要为极细的片状硅酸盐,要得到高品级石墨,用机械选矿办法是无能为力的,需要对精矿进一步加工处理方可奏效。  相似文献   

8.
The distribution of noble metals has been studied in ores and sulfide concentrates from the Gai, Uchaly, Uzel’ga, Aleksandrinsky, Degtyarsk, and Saf’yanovka deposits. The ores, technological products, and hand-picked monofractions were analyzed with INAA; PGE were determined with kinetic and chromatographic methods after their preliminary chemical separation. The ultraheavy fractions from Au-rich samples were used for examining minerals of noble metals. Phase relations and compositions of ore minerals were studied with an X-ray microprobe and electron microscope equipped with an energy dispersive X-ray analyzer. Gold is associated largely with Fe and Cu minerals (pyrite, chalcopyrite, fahlore) and has been detected as an admixture in Pb, Bi, and Ag tellurides. Pyrite—the major mineral of massive sulfide ores—is the main gold concentrator (up to 20 ppm, ~1 ppm on average). As follows from the results of rational analysis, the concentration of finely dispersed gold in sulfide ores from the studied deposits ranges from 0.8 to 5.0 ppm, i.e., is less than the bulk Au content in the respective samples (0.93–21.2 ppm). Formation conditions of Au-enriched massive sulfide ores were estimated from the homogenization temperature of fluid inclusions in minerals and on the basis of the electrum-argentite-pyrite-sphalerite and electrum-hessite geothermometers, taking into account the sulfur and tellurium fugacities. The appearance of visible gold and tellurides in ores is caused by recrystallization of their fine-grained intergrowths with ore-forming minerals and, likely, by release of isomorphic admixtures contained in sulfides during epigenetic hydrothermal alteration.  相似文献   

9.
The mineralogy of two gold deposits in southwestern China, which contain gold entirely in the form of microscopic or submicroscopic grains or inclusions, is examined. They contain refractory or low-grade ores similar in type to those near Carlin, Nevada. Mineralogical studies of ore samples from the two deposits (e.g., proton microprobe analysis, scanning electron microscope analysis, electron microprobe analysis, X-ray diffraction studies, ore microscopy) indicate that the predominant gold-bearing minerals are pyrite (Dongbeizhai deposit) and arsenopyrite and pyrite (Jinya deposit). Gold in the two deposits is closely correlated with As, S., and Fe.  相似文献   

10.
Bodies of cryptovolcanic rocks (fluidolites) play a significant role in the structure of the Poperechnoe ferromanganese deposit, Lesser Khingan, Russia. Fe-Mn ores in association with fluidolites are localized in ancient carbonate rocks. PGM, gold, and silver minerals up to tenths of a millimeter in size are established in the rocks and ores of the deposit. Characteristic admixtures in the platinum are iron (9-11%), with less common copper, iridium, and osmium. An intergrowth of isoferroplatinum polycrystal with forsterite is observed. There are also individual grains of Os-Ir-Ru-Rh intermetallides. The gold grains (up to 93% Au) are characterized by dendritic and clumpy morphology, frequently showing faceting elements. The grains are frequently rounded and sometimes have an almost perfect spherical shape. Native silver is distributed among the dolomites, as well as in the dolomitic fragments from the fluidolites. Ubiquitous admixtures in the silver are copper, iron, and more rarely zinc; single grains contain admixtures of molybdenum, nickel, gold, and palladium. PGM and high-fineness gold are related to the fluidolites, which are the only magmatic rocks in the studied range of the deposit. Silver, its minerals, low-fineness gold, and sulfides are confined to the rocks and ores subjected to the regional dolomitization, low-temperature hydrothermal reworking, and silicification. Samples contain up to 11.3 g/t platinum, 2.35 g/t gold, 296.2 g/t silver, which allows us to consider the studied object as economically promising for noble metals.  相似文献   

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