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1.
《矿物学报》2010,(3)
采用ICP-MS分析方法研究烂泥塘浅成低温热液型Cu-Au矿床中黄铜矿铂族元素(PGE),结果显示黄铜矿的∑PGE较低,其值为5.46×10-9～19.0×10-9。原始地幔标准化PGE配分模式呈Ru、Pd相对于Ir、Pt富集的趋势。Pd/Ir、Ru/Ir、Pt/Ru、Pd/Pt比值分别变化在2.35～21.9、15.6～42.3、0.02～0.20和4.83～21.8之间。除Pt/Ru比值低于原始地幔外,其他比值均高于原始地幔,这表明黄铜矿的Ir、Ru、Pt和Pd之间发生了分异。黄铜矿中相对高的Ru和Pd含量可能是热液流体对早期矿化斑岩选择淋滤的结果。 相似文献
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报道了四川冕宁稀土矿床碳酸岩7件样品的PGE和Au含量分析结果,其含量(wB/10-9)范围分别为Ir 0.5～0.78,Ru 1.61～6.75,Rh 0.08～0.14,Pt 2.62～12.15,Pd 1.11～3.65和Au 1.24～8.61.原始地幔标准化的PGE模式呈Ru、Pt、Pd相对富集和Ir、Rh相对亏损的“燕子型“.分析认为,碳酸岩具有一定携带PGE的能力;本区碳酸岩具“燕子型“PGE配分模式可能是其源区地幔PGE配分模式的反演;深源富CO2流体交代作用原始地幔可能是形成其“燕子型“PGE配分模式主要因素. 相似文献
4.
云南中旬地区烂泥塘低温热液型Cu-Au矿床铂族元素(PGE)地球化学特征 总被引：1，自引：0，他引：1
采用ICP-MS分析方法研究烂泥塘浅成低温热液型Cu-Au矿床中黄铜矿铂族元素(PGE),结果显示黄铜矿的∑PCE较低,其值为5.46×109～19.0×10-9.原始地幔标准化PGE配分模式呈Ru、Pd相对于Ir、Pt富集的趋势.Pd/Ir、Ru/Ir、Pt/Ru、Pd/Pt比值分别变化在2.35～21.9、15.6～42.3、0.02～0.20和4.83～21.8之间.除Pt/Ru比值低于原始地幔外,其他比值均高于原始地幔,这表明黄铜矿的Ir、Ru、Pt和Pd之间发生了分异.黄铜矿中相对高的Ru和Pd含量可能是热液流体对早期矿化斑岩选择淋滤的结果. 相似文献
5.
报道了四川冕宁稀土矿床碳酸岩7件样品的PGE和Au含量分析结果，其含量（WB／10^-9）范围分别为Ir0．5～0．78，Ru 1．61～6．75，Rh 0．08～0．14，Pt 2．62～12．15，Pd 1．11γ3．65和Au1．24～8．61。原始地幔标准化的PGE模式呈Ru、Pt、Pd相对富集和Ir、Rh相对亏损的“燕子型”。分析认为，碳酸岩具有一定携带PGE的能力；本区碳酸岩具“燕子型”PGE配分模式可能是其源区地幔PGE配分模式的反演；深源富CO2流体交代作用原始地幔可能是形成其“燕子型”PGE配分模式主要因素。 相似文献
6.
区内各岩体的地幔橄榄岩中PGE含量及分布型式有所差异.相对于原始地幔,拉昂错和东坡岩体的PGE含量没有显著异常,标准化分布曲线大致平坦,PPGE与IPGE之间分馏不明显,总体特征与中国日喀则地区以及阿尔卑斯和东地中海地区的地幔橄榄岩相似.而当穷岩体的PPGE含量变化范围较大,出现IPGE与PPGE强分馏.单斜辉石岩脉的PGE含量及分布型式与地幔橄榄岩不同:Os、Ir、Ru、Rh亏损而Pt、Pd富集,模式曲线向左倾斜,可能反映其较高程度部分熔融作用和熔体分离作用的产物.铬铁矿石的PGE含量较高,而且变化幅度大(19.7×10-9～5526×10-9),各样品∑PGE平均值(729.33×10-9)是原始地幔的25.6倍.与原始地幔相比,Os、Ir、Ru、Rh总体上表现为较强富集,Pt、Pd富集与亏损并存.其标准化模式曲线较分散,曲线向右倾斜,IPGE与PPGE分馏较强,多数样品呈现Pt负异常.这些特点与中国罗布莎、希腊、南斯拉夫以及塞浦路斯等世界各地蛇绿岩中的铬铁矿床类似.铬铁矿石的PGE含量与相应样品的BMS含量无相关性,PGE不是主要赋存于BMs内.推测PGE主要以PGM的形式存在,具体矿物名称有待进一步发现与研究. 相似文献
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西藏路曲蛇绿岩地幔橄榄岩的贵金属元素地球化学特征 总被引：3，自引：0，他引：3
雅鲁藏布江蛇绿岩带是冈瓦纳板块与欧亚板块汇聚的几条主要缝合带之一。路曲蛇绿岩位于雅鲁藏布江蛇绿岩带中部，分析了路曲蛇绿岩中橄榄岩的铂族元素（PGE）和Au的含量，其CE 量是原始地幔的1.7-3.3倍，相对于Ir而言，岩石的Pd,Pt含量较高，变化也较大，P/Ir,Pd/Pt比值明显高于球粒陨石的比值。PGE对原始地幔标准化模式呈正斜率型，地幔橄榄岩中CaO和Al2O3分别为0.30%-1.20%和0.04%-0.42%。说明路曲橄榄岩形成于亏损型地幔，Al2O3与Pt,Pd具有比Ir组PGE（IPGE，包括Os,Ir和Ru)更好的正相关关系，说明地幔岩中Al2O3的亏损使PGE之间发生了分异作用，但这种分异作用并不显著，地幔橄榄岩的稀土元素含量为原始地幔的约1／8，稀土元素的（La/Yb)N值为0.71-4.42，平均1.51,(La/Sm)s值为0.123-19.2,平均6.55;(Gd/Yb)s为0.023-2.64，平均0.28，推测在本区地幔岩受到过交代作用的影响，这种交 有较高的REE，PGE含量和高的Pd组PGE（PPGE，包括Pt和Pd)含量，结果可以形成路曲特征PGE含量的地幔岩。 相似文献
8.
黔西地区峨眉山玄武岩（东岩区）铂族元素地球化学特征 总被引：7，自引：0，他引：7
利用同位素稀释-等离子体质谱(ICP-MS)方法测定了黔西水域、威宁等地的东岩区峨眉山玄武岩的铂族元素含量。结果表明，相对于原始地幔，东岩区峨眉山玄武岩的铂族元素发生了较强的分异作用，Os、Ir、Ru、Rh亏损，Pd、Pt发生富集，相对配分模式为Pd-Pt富集型；经球粒陨石及原始地幔标准化的铂族元素配分模式为向左陡倾斜型，具有陡的正斜率，Pd／Ir显著高于原始地幔、球粒陨石、原始上地幔等，而与地幔低度熔融形成的N-MORB、大陆拉斑玄武岩等接近，表明峨眉山玄武岩的物质来源为上地幔熔融程度偏低的玄武岩浆。 相似文献
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泽当蛇绿岩位于雅鲁藏布江缝合带东段,岩体由地幔橄榄岩、辉长辉绿岩、辉石岩、火山岩等组成。地幔橄榄岩主要为方辉橄榄岩、纯橄岩和二辉橄榄岩。在方辉橄榄岩中发现7处豆荚状铬铁矿,矿石类型主要有致密块状和浸染状。出露地表的长度0.5~3m,厚0.2~1m。矿体的延伸方向为北西向,与岩体展布的方向一致,铬铁矿的Cr~#=67.9~88.5,属于高铬型铬铁矿。泽当地幔橄榄岩岩相学特征以及矿物组合、矿物化学成份及岩相学特征,显示岩体至少存在两次的部分熔融过程,即为早期的MOR构造背景,以及后期SSZ环境的改造。铬铁矿的铂族元素(PGE)以富集Os、Rh、Pd,亏损Ir、Ru、Pt的负斜率分布模式,表明其形成过程中经受后期熔体/流体的改造。对比罗布莎岩体的矿物组合,矿物化学和地球化学等特征,显示泽当豆荚状铬铁矿矿体与典型高铬型具相似性,存在较大的找矿空间。 相似文献
10.
为探讨贵州下寒武统黑色岩系中铂族元素物质来源及钼-镍、钒多金属形成的沉积环境与成矿作用,在钼-镍、钒多金属层及其顶底页岩、底部硅质岩中采集样品测试分析。通过对样品中金、铂族元素含量(质量分数)及其地球化学特征值研究,结果表明：黑色岩系中金及铂族元素含量显示协同变化特征;Pd富集,Ru、Ir亏损明显,Pt、Rh、Os基本持平或略有变化;样品的原始地幔标准值标准化模式配分曲线从Os、Ru、Rh、Ir、Pt到Pd大致呈“W”型,配分曲线略呈左倾,总体上呈现w(Pd)>w(Pt)>w(Os)>w(Rh)>w(Ru)>w(Ir)的变化关系;黑色岩系铂族元素来源与正常海水及海底热水喷流作用关系密切,地外来源可能性极小;黑色岩系钼-镍、钒多金属层中铂族元素的富集存在单独成矿作用或成矿作用的叠加,而且在钒多金属层内局部存在分层或条带分异。 相似文献
11.
中国铬铁矿的铂族元素分布特征 总被引：2，自引：0，他引：2
用NiS溶解和Te沉淀方法富集铂族元素（PGE），制成镍扣，再溶解于浓HCl中，使PGE和Te一起沉淀。制备的样品溶液在ELAN－5000型电感耦合等离子质谱仪（ICP－MS）上分析PGE。中国铬铁矿矿石，包括蛇绿岩套中的豆荚状铬铁矿床、非层状侵入体铬铁矿，计13个矿床（化）样品，其PGE模式表明，主要呈RU正异常模式，个别不同模式是由母岩不同以及铂族元素矿化叠加引起的。铬铁矿的PGE模式不取决于铬铁矿的化学成分，而取决于其母岩性质以及形成温度和铂族元素的熔点。 相似文献
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Ahmed H. Ahmed Shoji Arai Yaser M. Abdel-Aziz Moha Ikenne Abdellatif Rahimi 《Journal of African Earth Sciences》2009,55(1-2):92
The distribution of platinum-group elements (PGEs), together with spinel composition, of podiform chromitites and serpentinized peridotites were examined to elucidate the nature of the upper mantle of the Neoproterozoic Bou Azzer ophiolite, Anti-Atlas, Morocco. The mantle section is dominated by harzburgite with less abundant dunite. Chromitite pods are also found as small lenses not exceeding a few meters in size. Almost all primary silicates have been altered, and chromian spinel is the only primary mineral that survived alteration. Chromian spinel of chromitites is less affected by hydrothermal alteration than that of mantle peridotites. All chromitite samples of the Bou Azzer ophiolite display a steep negative slope of PGE spidergrams, being enriched in Os, Ir and Ru, and extremely depleted in Pt and Pd. Harzburgites and dunites usually have intermediate to low PGE contents showing more or less unfractionated PGE patterns with conspicuous positive anomalies of Ru and Rh. Two types of magnetite veins in serpentinized peridotite, type I (fibrous) and type II (octahedral), have relatively low PGE contents, displaying a generally positive slope from Os to Pd in the former type, and positive slope from Os to Rh then negative from Rh to Pd in the latter type. These magnetite patterns demonstrate their early and late hydrothermal origin, respectively. Chromian spinel composition of chromitites, dunites and harzburgites reflects their highly depleted nature with little variations; the Cr# is, on average, 0.71, 0.68 and 0.71, respectively. The TiO2 content is extremely low in chromian spinels, <0.10, of all rock types. The strong PGE fractionation of podiform chromitites and the high-Cr, low-Ti character of spinel of all rock types imply that the chromitites of the Bou Azzer ophiolite were formed either from a high-degree partial melting of primitive mantle, or from melting of already depleted mantle peridotites. This kind of melting is most easily accomplished in the supra-subduction zone environment, indicating a genetic link with supra-subduction zone magma, such as high-Mg andesite or arc tholeiite. This is a general feature in the Neoproterozoic upper mantle. 相似文献
13.
Kreshimir N. Malitch Oskar A. Thalhammer Vladimir V. Knauf Frank Melcher 《Mineralium Deposita》2003,38(3):282-297
We report highly unusual platinum-group mineral (PGM) assemblages from geologically distinct chromitites (banded and podiform) of the Kraubath massif, the largest dismembered mantle relict in the Eastern Alps. The banded chromitite has a pronounced enrichment of Pt and Pd relative to the more refractory platinum-group elements (PGEs) of the IPGE group (Os, Ir, Ru), similar to crustal sections of ophiolites. On the contrary, the podiform chromitite displays a negatively sloping chondrite-normalised PGE pattern typical of ophiolitic podiform chromitite. The chemical composition of chromite varies from Cr# 73-77 in the banded type to 81-86 in the podiform chromitite. Thirteen different PGMs and one gold-rich mineral are first observed in the banded chromitite. The dominant PGM is sperrylite (53% of all PGMs), which occurs in polyphase assemblages with an unnamed Pt-base metal (BM) alloy and Pd-rich minerals such as stibiopalladinite, mayakite, mertieite II, unnamed Pd-Rh-As and Pd(Pt)-(As,Sb) minerals. This banded type also contains PGE sulphides (about 7%) represented by a wide compositional range of the laurite-erlichmanite series and irarsite (8%). Os-Ir alloy, geversite, an unnamed Pt-Pd-Bi-Cu phase and tetrauricupride are present in minor amounts. By contrast, the podiform chromitite, which yielded 21 different PGMs, is dominated by laurite (43% of all PGMs) which occurs in complex polyphase assemblages with PGE alloys (Ir-Os, Os-Ir, Pt-Fe), PGE sulphides (kashinite, bowieite, cuproiridsite, cuprorhodsite, unnamed (Fe,Cu)(Ir,Rh)2S4, braggite, unnamed BM-Ir and BM-Rh sulphides) and Pd telluride (keithconnite). A variety of PGE sulpharsenides (33%) including irarsite, hollingworthite, platarsite, ruarsite and a number of intermediate species have been identified, whereas sperrylite and stibiopalladinite are subordinate (2%). The occurrence of such a wide variety of PGMs from only two, 2.5-kg chromitite samples is highly unusual for an ophiolitic environment. Our novel sample treatment allowed to identify primary PGM assemblages containing all six PGEs in both laurite-dominated podiform chromitite as well as in uncommon sperrylite-dominated banded chromitite. We suggest that the geologically, geochemically and mineralogically distinct banded chromitite from Kraubath characterises the transition zone of an ophiolite, closely above the mantle section hosting podiform chromitite, rather than being representative of the crustal cumulate pile. 相似文献
14.
The Bir Tuluha ophiolite is one of the most famous chromitite-bearing occurrences in the Arabian Shield of Saudi Arabia, where chromitite bodies are widely distributed as lensoidal pods of variable sizes surrounded by dunite envelopes, and are both enclosed within the harzburgite host. The bulk-rock geochemistry of harzburgites and dunites is predominately characterized by extreme depletion in compatible trace elements that are not fluid mobile (e.g., Sr, Nb, Ta, Hf, Zr and heavy REE), but variable enrichment in the fluid-mobile elements (Rb and Ba). Harzburgites and dunites are also enriched in elements that have strong affinity for Mg and Cr such as Ni, Co and V. Chromian spinels in all the studied chromitite pods are of high-Cr variety; Cr-ratio (Cr/(Cr + Al) atomic ratio) show restricted range between 0.73 and 0.81. Chromian spinels of the dunite envelopes also show high Cr-ratio, but slightly lower than those in the chromitite pods (0.73–0.78). Chromian spinels in the harzburgite host show fairly lower Cr-ratio (0.49–0.57) than those in dunites and chromitites. Platinum-group elements (PGE) in chromitite pods generally exhibit steep negative slopes of typical ophiolitic chromitite PGE patterns; showing enrichment in IPGE (Os, Ir and Ru), over PPGE (Rh, Pt and Pd). The Bir Tuluha ophiolite is a unimodal type in terms of the presence of Ru-rich laurite, as the sole primary platinum-group minerals (PGM) in chromitite pods. These petrological features indicates that the Bir Tuluha ophiolite was initially generated from a mid-ocean ridge environment that produced the moderately refractory harzburgite, thereafter covered by a widespread homogeneous boninitic melt above supra-subduction zone setting, that produced the high-Cr chromitites and associated dunite envelopes. The Bir Tuluha ophiolite belt is mostly similar to the mantle section of the Proterozoic and Phanerozoic ophiolites, but it is a “unimodal” type in terms of high-Cr chromitites and PGE-PGM distribution. 相似文献
15.
J. A. Proenza F. Ortega-Gutirrez A. Camprubí J. Tritlla M. Elías-Herrera M. Reyes-Salas 《Journal of South American Earth Sciences》2004,16(8):129
The serpentinites and associated chromitite bodies in Tehuitzingo (Acatlán Complex, southern Mexico) are in close relationship with eclogitic rocks enclosed within a metasedimentary sequence, suggesting that the serpentinites, chromitites and eclogitic rocks underwent a common metamorphic history.Primary chromites from the chromitite bodies at Tehuitzingo are of refractory-grade (Al-rich) and have a chemical composition similar to that expected to be found in an ophiolitic environment. The chromite grains in chromitites and serpentinites are systematically altered to ‘ferritchromite’. The alteration trend is usually characterized by a decrease in the Al, Mg and Cr contents coupled by an increase in Fe3+ and Fe2+.The Tehutizingo chromitites have low Platinum Group Elements (PGE) contents, ranging from 102 to 303 ppb. The chondrite-normalized PGE patterns are characterized by an enrichment in the Ir-subgroup elements (IPGE=Os, Ir, Ru) relative to the Pd-subgroup elements (PPGE=Rh, Pt, Pd). In addition, all chromitite samples display a negative slope from Ru to Pd [(Os+Ir+Ru)/(Pt+Pd)=4.78−14.13]. These patterns, coupled with absolute PGE abundances, are typical of ophiolitic chromitites elsewhere. Moreover, all the analyzed samples exhibit chondrite-normalized PGE patterns similar to those found for non-metamorphosed ophiolitic chromitites. Thus, the PGE distribution patterns found in the Tehuitzingo chromitites have not been significantly affected by any subsequent Paleozoic high-pressure (eclogite facies) metamorphic event.The chondrite-normalized PGE patterns of the enclosing serpentinites also indicate that the PGE distribution in the residual mantle peridotites exposed in Tehuitzingo was unaffected by high-pressure metamorphism, or subsequent hydrothermal alteration since the serpentinites show a similar pattern to that of partially serpentinized peridotites present in mantle sequences of non-metamorphosed ophiolites.Our main conclusion is that the chromitites and serpentinites from Tehuizingo experienced no significant redistribution (or concentration) of PGE during the serpentinization process or the high-pressure metamorphic path, or during subsequent alteration processes. If any PGE mobilization occurred, it was restricted to individual chromitite bodies without changing the bulk-rock PGE composition.Our data suggest that the Tehuitzingo serpentinites and associated chromitites are a fragment of oceanic lithosphere formed in an arc/back-arc environment, and represent an ophiolitic mantle sequence from a supra-subduction zone, the chemical composition of which remained essentially unchanged during the alteration and metamorphic events that affected the Acatlán Complex. 相似文献
16.
Gehad M. Saleh 《中国地球化学学报》2006,25(4):307-317
1 Introduction The association of massive Fe-Ni-Cu sulfides andchromite is a very unusual feature of podiformchromitites occurring in mantle tectonites of ophioliticcomplexes. It has only been described in theSoutheastern Desert, Egypt, where sulfides a… 相似文献
17.
《Russian Geology and Geophysics》2014,55(2):259-272
Data are presented on chromitites from the northern and southern sheets of the Il’chir ophiolite complex (Ospa–Kitoi and Khara-Nur (Kharanur) massifs). The new and published data are used to consider similarities and differences between ore chrome-spinel from the chromitites of the northern and southern ophiolite sheets as well as the species diversity of PGE minerals and the evolution of PGE mineralization. Previously unknown PGE minerals have been found in the studied chromitites.Ore chrome-spinel in the chromitites from the northern sheet occurs in medium- and low-alumina forms, whereas the chromitites from the southern sheet contain only medium-alumina chrome-spinel. The PGE minerals in the chromitites from the southern sheet are Os–Ir–Ru solid solutions as well as sulfides and sulfoarsenides of these metals. The chromitites from the northern sheet contain the same PGE minerals and diverse Rh–Pt–Pd mineralization: Pt–Ir–Ru–Os and isoferroplatinum with Ir and Os–Ir–Ru lamellae. Areas of altered chromitites contain a wide variety of low-temperature secondary PGE minerals: Pt–Cu, Pt–Pd–Cu, PdHg, Rh2SnCu, RhNiAs, PtAs2, and PtSb2. The speciation of the PGE minerals is described along with multiphase intergrowths. The relations of Os–Ir–Ru solid solutions with laurite and irarsite are considered along with the microstructure of irarsite–osarsite–ruarsite solid solutions. Zoned Os–Ir–Ru crystals have been found. Zone Os82–99 in these crystals contains Ni3S2 inclusions, which mark off crystal growth zones. Different sources of PGE mineralization are presumed for the chromitites from the northern and southern sheets.The stages of PGE mineralization have been defined for the chromitites from the Il’chir ophiolite belt. The Pt–Ir–Ru–Os and (Os, Ru)S2 inclusions in Os–Ir–Ru solid solutions might be relics of primitive-mantle PGE minerals. During the partial melting of the upper mantle, Os–Ir–Ru and Pt–Fe solid solutions formed syngenetically with the chromitites. During the late-magmatic stage, Os–Ir–Ru solid solutions were replaced by sulfides and sulfarsenides of these metals. Mantle metasomatism under the effect of reduced mantle fluids was accompanied by PGE remobilization and redeposition with the formation of the following assemblage: garutiite (Ni,Fe,Ir), zaccariniite (RhNiAs), (Ir,Ni,Cu)S3, Pt–Cu, Pt–Cu–Fe–Ni, Cu–Pt–Pd, and Rh–Cu–Sn–Sb. The zoned Os–Ir–Ru crystals in the chromitites from the northern sheet suggest dissolution and redeposition of Os–Ir–Ru primary-mantle solid solutions by bisulfide complexes. Most likely, the PGE remobilization took place during early serpentinization at 450–600 ºC and 13–16 kbar.During the crustal metamorphic stage, tectonic movements (obduction) and a change from reducing to oxidizing conditions were accompanied by the successive transformation of chrome-spinel into ferrichromite–chrome-magnetite with the active participation of a metamorphic fluid enriched in crustal components. The orcelite–maucherite–ferrichromite–sperrylite assemblage formed in epidote-amphibolitic facies settings during this stage.The PGE mineral assemblage reflects different stages in the formation of the chromitites and dunite-harzburgite host rocks and their transformation from primitive mantle to crustal metamorphic processes. 相似文献
18.
The effect of metasomatism on the Cr-PGE mineralization in the Finero Complex, Ivrea Zone, Southern Alps 总被引：1，自引：0，他引：1
The magmatic metasomatism that was responsible for producing chromitite–dunite bodies in the unusual phlogopite peridotite of the Finero Complex in Permian to Triassic times also influenced the Cr-platinum group elements (PGE) mineralization. At least the end stages of this metasomatism are recorded in compositional zoning of chromite grains in the podiform chromitite. Metasomatic melt, with or without vapor, reacted with chromite to produce core-to-rim Cr enrichment of extant chromite grains and was concurrent with pyroxene crystallization. Under conditions of lower melt/rock ratio, metasomatism resulted in core-to-rim Al enrichment in chromite and crystallization of amphibole between chromite and clinopyroxene. This early, high-temperature metasomatism is unrelated to the later and pervasive K-metasomatism that crystallized phlogopite and was associated with the intrusion of clinopyroxenite dikes that cut the peridotite. Much later, serpentinization of olivine locally depleted chromite in Al and enriched it in Fe and formed minor amounts of magnetite.The PGE, which are present mainly as laurite inclusions in chromite, were remobilized by the early metasomatism. This resulted in substantial variation in the PGE contents of chromitites and imposed a characteristic PGE pattern in which chondrite-normalized Os, Ir, Ru and Rh contents are high but Pt and Pd contents are low. The slopes of PGE chondrite-normalized concentration patterns are systematically related to absolute PGE abundance and to rock mode. Chromitites with low modal orthopyroxene, clinopyroxene, and amphibole exhibit negative PGE slopes and contain relatively high PGE concentrations, whereas chromitites rich in these silicate minerals have positive slopes and low PGE contents. 相似文献
19.
İbrahim Uysal Mahmud Tarkian M. Burhan Sadiklar Federica Zaccarini Thomas Meisel Giorgio Garuti Stefanie Heidrich 《Contributions to Mineralogy and Petrology》2009,158(5):659-674
Ultramafic rocks around the city of Muğla in SW Turkey are represented by mantle peridotites depleted to various degrees,
ranging from cpx-rich harzburgites to depleted harzburgite and dunite. Cpx-rich harzburgites are thought to be the residua
left after extraction of MORB-type basalt, from which high-Al chromitite [49.2 < Cr# = 100 × Cr/(Cr + Al) < 53.5] crystallised
with a higher proportion of 187Os/188Os (average of 0.1361). However, depleted harzburgites are assumed to be the residua left after extraction of hydrous boninitic
melt produced by second stage partial melting of already depleted mantle due to a subducting slab, from which high-Cr chromitites
(64.2 < Cr# < 85.9) with lower and heterogeneous 187Os/188Os ratio (average of 0.1324) were crystallised as a result of melt–rock interaction in a supra-subduction environment. Dunites
around the chromite deposits are considered to be the product of melt–peridotite interaction. Most of the chromitites contain
high-Cr chromite and display enrichment in IPGE (Os, Ir, Ru) over PPGE (Rh, Pt, Pd), with PGE concentrations between 61 and
1,305 ppb. Consistently, laurite-erlichmanite series minerals with various Os concentrations are found to be the most abundant
PGM inclusions in chromite. Os–Ir–Ru alloy, irarsite, and kashinite, as well as Pt–Fe alloy and Pt-oxide, which are not common
in ophiolitic chromitites, were also detected as magmatic PGM inclusions. Pentlandite, millerite, and, rarely heazlewoodite
form the magmatic inclusions of base-metal sulphide. The presence of olivine and clinopyroxene, as well as hydrous silicate
inclusions such as amphibole and phlogopite, in high-Cr chromitite supports the idea that high-Cr chromitites were formed
in a supra-subduction environment. 相似文献