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1.
冈底斯中段尼木斑岩铜矿田的K-Ar、^40 Ar/^39 Ar年龄：对岩浆-热液系统演化和成矿构造背景的制约 总被引：7，自引：0，他引：7
青藏高原冈底斯斑岩成矿带不同于经典的产于岛弧和大陆边缘的斑岩铜矿,而形成于后碰撞挤压向伸展转变期,显示了极好的成矿前景。本文对冈底斯中段尼木矿田白容、厅宫和冲江斑岩铜矿区斑岩体进行了系统研究,确定出斑岩体演化和侵入序列为:似斑状二长花岗岩→成矿二长花岗斑岩→石英闪长玢岩→花岗闪长斑岩。K-Ar和~(40)Ar/~(39)Ar年代学研究获得白容矿区似斑状二长花岗岩中角闪石的K-Ar年龄为16.9±2.4Ma;石英闪长玢岩中黑云母的K-Ar年龄为12.3±0.2Ma、~(40)Ar/~(39)Ar坪年龄为12.5±0.2Ma;花岗闪长斑岩中黑云母的K-Ar年龄为11.5±0.2Ma、~(40)Ar/~(39)Ar坪年龄为12.4±0.2Ma;厅宫矿区石英闪长玢岩中黑云母的K-Ar年龄为13.8±0.2Ma、~(40)Ar/~(39)Ar坪年龄为14.9±0.2Ma;花岗闪长斑岩中黑云母的K-Ar年龄为13.5±0.3Ma、~(40)Ar/~(39)Ar坪年龄为14.2±0.2Ma,这些年龄表明:石英闪长玢岩晚于似斑状二长花岗岩,略早于花岗闪长斑岩。成矿与二长花岗斑岩有关,其侵位时间晚于似斑状二长花岗岩,早于石英闪长玢岩和花岗闪长斑岩。尼木斑岩铜矿田这种复式杂岩体较充分的分异演化有利于含矿热液的集中与逐渐富集成矿。白容斑岩铜矿蚀变矿化二长花岗斑岩的蚀变绢云母的K-Ar年龄为11.8±0.2Ma,~(40)Ar/~(39)Ar坪年龄为12.0±0.1Ma,代表了中低温蚀变和矿化末期的年龄。白容矿区绢云母化带的蚀变年龄与石英闪长玢岩和花岗闪长斑岩的黑云母~(40)Ar/~(39)Ar年龄基本一致,与厅宫矿区辉钼矿Re-Os年龄及石英闪长玢岩和花岗闪长斑岩的黑云母~(40)Ar/~(39)Ar年龄同样基本一致,暗示两个矿区石英闪长玢岩和花岗闪长斑岩的岩浆结晶冷却与成矿二长花岗斑岩后期热液成矿时间上有重叠。结合前人年龄数据大致确定出白容矿区岩浆-热液活动时限为0.5～5Ma,厅宫为4Ma,冲江为4.5Ma。尼木矿田成矿斑岩~(40)Ar/~(39)Ar年龄晚于冈底斯碰撞后第一次快速隆升时间≈21Ma,15Ma冈底斯中段NS向正断层开始活动,表明含矿斑岩体可能侵位于地壳加厚、冈底斯山大规模隆升到一定程度后出现弱伸展环境的构造背景下,即斑岩铜矿形成于从南北向挤压隆升到东西向伸展初始发育的过渡构造背景。 相似文献
2.
华北地块中东部中生代侵入杂岩中角闪石和黑云母的40Ar/39Ar定年:对岩石圈减薄时间的制约 总被引：49，自引：3，他引：46
华北地块中东部中生代侵入杂岩存在有富闪侵入岩和花岗闪长岩类两套岩石组合.对其中 8个侵入杂岩体中的角闪石和黑云母进行了 40Ar/39Ar定年研究.山西临汾塔儿山正长闪长斑岩、山西长治西安里岩体和河南安阳东冶岩体富闪侵入岩中角闪石的 40Ar/39Ar坪年龄分别为(124.9± 0.3)Ma,(127.7± 0.3)Ma和(127.1± 0.1)Ma;鲁西临朐铁寨正长闪长岩和枣庄流井花岗闪长斑岩中角闪石的 40Ar/39Ar坪年龄均为(124.9± 0.2)Ma;鲁西莱芜铁铜沟辉石闪长岩和蒙阴虎头崖花岗闪长斑岩中黑云母的 40Ar/39Ar坪年龄分别为(132.8± 0.3)Ma和(124.4± 0.3)Ma;皖北管店花岗闪长斑岩中角闪石的 40Ar/39Ar坪年龄为(126.9± 0.2)Ma.上述结果显示华北地块中生代的岩浆活动主要发生在早白垩世.含有丰富幔源捕虏体的富闪侵入岩类和具有地壳成因的花岗闪长岩类岩石的共存,暗示早白垩世华北地块中生代岩石圈减薄达到了峰期. 相似文献
3.
西藏列廷冈铁多金属矿床位于冈底斯-念青唐古拉岩浆弧北缘,是冈底斯北缘Pb_Zn_Ag_Cu_Fe多金属成矿带上典型的铁多金属矿床,与成矿关系最为密切的岩体为花岗闪长岩和花岗斑岩。采用锆石LA_ICP_MS对花岗闪长岩和花岗斑岩进行了定年,结果显示花岗闪长岩的成岩年龄为58.69±0.68 Ma,花岗斑岩成岩年龄为60.69±0.98 Ma。与加拉普铁多金属矿、沙让钼矿、亚贵拉铅锌银矿等冈底斯-念青唐古拉岩浆弧上其它矿床的对比分析表明,这一系列矿床受印度-欧亚大陆碰撞过程中地幔的岩浆底侵作用影响,形成于印度-亚洲大陆碰撞早期。列廷冈锆石的Lu-Hf测试结果显示岩体的εHf(t)值为-3.01~3.0,Hf二阶段模式年龄742~1 322 Ma,表明岩浆具有壳幔混源的特点。结合列廷冈的目前勘探情况,认为在区域的铁多金属矿中,深部的Cu、Pb、Zn矿产将是今后勘查方向。 相似文献
4.
云南澜沧老厂花岗斑岩锆石SHRIMP定年及其地质意义 总被引：5，自引：0，他引：5
澜沧老厂矿山继上世纪80年代末在钻孔中揭露到花岗斑岩细脉以来,2007年又在ZK153101、ZK14827中揭露到厚大的斑岩脉及主岩体。为了查明隐伏花岗斑岩体的年代,本文应用锆石SHRIMP U-Pb同位素法对老厂花岗斑岩进行了精确的定年,获得的加全平均年龄为44.6±1.1Ma,代表花岗斑岩的结晶年龄。继承锆石的年龄为529.3±13Ma,可能反映了岩浆的源岩年龄。年代学研究表明,花岗斑岩形成于始新世,为老厂斑岩型钼矿的成矿母岩。澜沧老厂斑岩钼矿的成岩成矿作用发生在新生代陆内碰撞造山的主碰撞阶段,与三江地区新生代斑岩型矿床成矿高峰期吻合。澜沧老厂的成岩成矿表明"三江"地区在澜沧江断裂以西也存在新生代斑岩成矿作用。 相似文献
5.
洞中拉铅锌矿床是念青唐古拉山地区扎雪—亚贵拉成矿带内新发现的矿床,矿区出露的花岗斑岩侵入体与洞中拉铅锌多金属矿床的形成密切相关。为精确限定其形成时代,笔者对洞中花岗斑岩进行单颗粒锆石SHRIMPU-Pb定年,结果显示其206Pb/238U加权平均年龄为(124.4±1.9)Ma(MSWD=5.09),该年龄对应于冈底斯—念青唐古拉火山岩浆岩带东段的早白垩世岩浆活动事件(介于109~130Ma),与扎雪—金达铅锌多金属矿成矿带内出露的花岗类岩体年龄(120~130Ma)一致。结合区域资料,洞中拉花岗斑岩是早白垩世弧间裂谷伸展作用下地壳挤压增厚局部熔融的产物。为念青唐古拉地区早白垩世岩浆侵位活动以及铅锌铜钼多金属矿产找矿方向研究提供了重要证据。 相似文献
6.
季德屯钼矿床是近年内在吉林中东部地区发现并初步探明的一个大型斑岩型钼矿床,钼矿体主要赋存在花岗闪长岩体内和花岗闪长岩体与二长花岗岩体的接触带及其附近。花岗闪长岩和二长花岗岩岩体的地质、岩石地球化学和单颗粒锆石U-Pb年代学研究揭示:它们均属于偏铝质、高钾钙碱性系列的I型花岗岩;均富集Rb、K等大离子亲石元素,亏损Nb、Ta、P、Ti、Y等高场强元素;锆石U-Pb年龄分别为(180.2±0.8)Ma和(180.1±0.6)Ma;矿床辉钼矿Re-Os同位素等时线年龄为(169±3)Ma。综合研究表明,季德屯斑岩型钼矿床类型属于与钙碱性、高钾钙碱性岩石系列有关的深成侵入体型钼矿床,形成于古太平洋板块俯冲背景下形成的活动大陆板块边缘岩浆弧环境,其成矿物质主要来源于地壳,从岩体侵位成岩到最终形成钼矿床大致经历了11 Ma。 相似文献
7.
白乃庙铜钼矿是华北地块北缘最重要的大型铜钼矿,矿区中部花岗闪长斑岩与成矿关系密切。为探讨成岩成矿关系,笔者选取花岗闪长斑岩进行了LA-ICP-MS锆石U-Pb定年和岩石地球化学特征研究。花岗闪长斑岩测年分别为432.4±2.2 Ma、440.7±2.1Ma和443±1Ma,岩体侵位时代为早志留世,与铜矿石中辉钼矿Re-Os等时线年龄440.5±4.4Ma(待刊)基本一致。岩体属高钾钙碱性岩石组合系列,稀土曲线右倾,δEu 14.83~-19.54,弱亏损,富集Rb、Ba、Th、U、K,亏损Nb、Ta、Ti,具有岛弧花岗岩的地球化学性质。结合区域地质背景,认为白乃庙铜钼矿成矿与早志留世花岗闪长斑岩岩浆期后热液活动密切相关,成矿构造背景为早古生代古亚洲板块向华北板块俯冲形成的白乃庙古火山岛弧带。 相似文献
8.
西藏邦铺大型斑岩钼-铜矿床二长花岗斑岩锆石SHRIMP定年及其地质意义 总被引：3，自引：1，他引：2
利用锆石U-Pb SHRI MP定年技术,测定了西藏冈底斯斑岩铜矿带东段邦铺斑岩钼铜矿床中二长花岗斑岩的年龄,获得该含矿岩体真实侵位年龄为13.9±0.3 Ma(MSWD=3.05),属于喜马拉雅晚期。邦铺二长花岗斑岩的形成时代介于冈底斯成矿带后碰撞期伸展构造环境的斑岩体的形成时代(12~18 Ma),该年龄的厘定进一步丰富了冈底斯带岩浆活动,并为整个冈底斯成矿带岩浆岩演化历史提供年代学数据和新的启示:可以认为其与冈底斯斑岩铜矿带具有相同的动力学背景,同属于大规模的快速爆发成矿作用过程。 相似文献
9.
马厂箐矿集区铜、钼、金矿化之间的关系对于认识该矿床的成矿作用过程及地质勘查具有重要意义。利用40Ar-39Ar同位素定年方法对乱硐山矿段夕卡岩型铜钼金矿化和人头箐矿段蚀变岩型金矿石中热液白云母进行同位素定年,得到夕卡岩化矿石中白云母样品(B119)40Ar-39Ar坪年龄为35.25±0.36Ma,等时线年龄为35.0±1.8Ma,反等时线年龄为34.8±1.9Ma。蚀变岩型金矿化矿石中白云母样品(B118)40Ar-39Ar坪年龄为35.35±0.32Ma,等时线年龄为34.44±0.99Ma,反等时线年龄为34.4±1.2Ma。这与正长斑岩(35.6±0.3Ma)、花岗斑岩(35.0±0.2Ma)、斑岩型铜钼矿化成矿年龄(35.8±1.6Ma)和(33.9±1.1Ma)较为一致,显示马厂箐铜钼金矿床与正长(斑)岩+二长(斑)岩+花岗斑岩+斑状花岗岩岩性组合有关,铜钼金成矿属于同一个构造—岩浆—成矿系统的产物。 相似文献
10.
11.
A. J. ZINGG 《Journal of Metamorphic Geology》1995,13(3):431-443
Abstract End-member, continuous and degenerate reactions are derived for the multisystem with the six components Na2O, CaO, (Mg/Fe)O, Al2O3, SiO2, H2O among the phases plagioclasess, garnetss, amphiboless, cpx, opx, olivine, spinel, quartz and an aqueous fluid. The chemography of this system is degenerate due to the co-linearity 2Opx = Ol + Qtz. This co-linearity has its implications both on reaction space and phase equilibria. From a total of 28 reaction systems, reaction space is derived for nine subsystems (phases in parentheses are absent): Case A1: (Cpx,Ol) (Cpx,Opx) and (Cpx,Qtz), Case A2: (Spl,Ol) (Spl,Opx) and (Spl,Qtz), Case B: (Ol,Opx) (Ol,Qtz) and (Opx,Qtz). In the absence of either cpx or spl (case A), three reactions form an invariant point, either [Cpx] or [Spl], where the co-linear phases olivine, opx and quartz coexist on the transformation line 2Opx = Ol + Qtz. Changing mineral compositions force invariant points to move along the line with the different reaction curves changing their relative position according to Schreinemakers’rules. Zero contours, i.e. the location where (a) phase(s) disappear(s) in reaction space correspond to singular points in phase diagrams. Two types are distinguished; singular points of indispensable and of substitutable phases. In the first case the phase disappears from the entire bundle while in the second it disappears from a single reaction. In the specific case where the substitutable phases are also the co-linear ones, two of the three co-linear phases disappear simultaneously. Two of the three reaction curves coincide. In the system including Cpx and Spl (Case B) three reactions, (Ol,Opx) (Ol,Qtz) and (Opx,Qtz), oppose three invariant points, [Ol], [Opx] and [Qtz]. Invariant points no longer move along the line 2Opx = Ol + Qtz. The coincidence of the zero contours of all three co-linear phases in reaction space-the result of the chemographic degeneracy-causes the respective singular points to coincide in the phase diagrams. This is the location where curves must be rearranged in a bundle to conform Schreinemakers’rules. The reaction Grs1Prp2= 2 Ol + An is fourth order degenerate and part of all nine subsystems (cases A and B). It can be used to relate the different phase diagrams to one another. 相似文献
12.
Dr. P. B. Moore Dr. A. M. Davis Dr. D. G. Van Derveer Dr. P. K. Sen Gupta 《Mineralogy and Petrology》1993,48(2-4):97-113
Summary Joesmithite is a complex clinoamphibole which contains at least 14 components in its formula. Its ideal formula would be PbCa2 Mg3 Fe
2
3+
(Si6Be2O22) (OH)2. It is monoclinic holosymmetric, an ordered derivative of theC2/m clinoamphiboles,a = 9.915(2),b = 17.951(4),c = 5.243(1)Å, = 105.95(2)°, Z = 2, space groupP2/a, D(obs) = 3.83(1), D(cal) = 3.91 g cm-3. R = 0.056 for 2299 independent F0.The cells of joesmithite and pargasitic amphibole were compared according to differences, , in their structure cells. The same procedure was applied to the margarosanite, PbCa2Si3O9 and walstromite, BaCa2Si3O9 pairs. In both pairs, the anion positions differed by 0.2 Å at most, but the Pb/A, Pb/Ba differences ranged from 0.4 to 0.6 Å. The lone pair Pb2+ cation responds according to the bond valence sums of its coordinating anions compared with its closed core counterpart.It appears that when the bond valence sums for the coordinating anions are different, Pb2+ moves toward the most underbonded anion. If the anion bond valence sums are equal for all vertices of the coordinating polyhedron (as in wulfenite, Pb2+Mo6+O4), then Pb2+ does not shift.
Dedicated to Prof. Josef Zemann, Keeper of the flame of chemical crystallography
Deceased
With 2 Figures 相似文献
Joesmithit, Neubearbeitung eines bleihältigen Amphibols und Kommentar zu den Bindungsstärken
Zusammenfassung Joesmithit ist ein komplex zusammengesetzter Klinoamphibol, der rumindest 14 Komponenten in seiner Formel aufweist. Die idealisierte Formel lautet PbCa2Mg3Fe 2 3+ (Si6Be2O22)(OH)2. Er ist monoklin holoedrisch und von den geordnetenC2/m-Klinopyroxenen abgeleitet,a = 9,915(2),b = 17,951(4),c = 5,243(1) Å,ß = 105,95(2)°, Z = 2, RaumgruppeP2/a, D(beob) = 3,83(1), D(ber) = 3,91 g cm-3. R = 0,056 für 2299 unabhängige F0.Die Elementarzellen von Joesmithit und einem pargasitischen Amphibol wurden in Bezug auf deren Struktur verglichen, ebenso jene von Margarosanit, PbCa2Si3O9, und Walstromit, BaCa2Si3O9, In beiden Paaren differieren die Positionen der Anionen um maximal 0,2 Å, die Unterschiede Pb/A = (Na, K, ) und Pb/Ba betragen 0,4 und 0,6 Å. Das ein einsames Elektronenpaar aufweisende Kation Pb2+ folgt den Bindungsstärken der koordinierenden Anionen im Vergleich zu den Pendents mit abgeschlossener Elektronenschale.Differieren die Bindungsstärken der koordinierenden Anionen, bewegt sich Pb2+ offensichtlich auf das am schwächsten abgesättigte Anion zu. Falls die Summe der Bindungsstärken an den Anionen in allen Richtungen des Koordinationspolyeders gleich sind (wie im Wulfenit, Pb2+Mo6+O4), dann kommt es zu keiner Verschiebung des Pb-Atoms.
Dedicated to Prof. Josef Zemann, Keeper of the flame of chemical crystallography
Deceased
With 2 Figures 相似文献
13.
Petrographic and microprobe investigations of calc-alkaline (CA) rocks from the High Cascade Range (i.e., Mt. St. Helens, Mt. Jefferson, Crater Lake and Mt. Shasta) of western North America show that crystal clots represent primary igneous phase assemblages and are not products of amphibole reactions with melt. For each eruptive complex, crystal clots display diverse modal proportions even within a single eruptive unit. Nevertheless, in all cases the crystal-clot minerals are also represented in the rock as phenocrysts or microphenocrysts. Basalts contain clots of ol+plag+mgt, ol+mgt, cpx+ plag+mgt, cpx+mgt and plag+mgt; andesites, clots of cpx+mgt, opx+mgt, cpx+opx+plag+mgt, cpx+plag+mgt, opx+plag+mgt and plag±mgt; and dacites, clots of opx+mgt, cpx+opx+plag+ mgt, opx+plag+mgt, amph+plag+mgt±ilm, amph+mgt±ilm and plag±mgt. The bulk compositions of most of these clot assemblages could not have been derived from amphibole percursors. Although some amphiboles in dacitic rocks display a breakdown reaction of amph=plag+cpx+opx +mag, these mineral clusters, unlike those of clots, typically have a relict amphibole crystal outline and a fine-grained metamorphic texture. Plagioclase grains in the mineral clusters lack oscillatory zoning which is typical of crystal clot plagioclase grains. The euhedral to subhedral shapes of most clot minerals and the oscillatory zoning present in most clot plagioclase grains are not likely to have formed from the breakdown of amphibole. Crystal clots are also observed in Hawaiian and ocean floor basalts, although amphibole fractionation has not been proposed for those lavas. Magnetite fractionation may be the controlling process limiting iron enrichment in CA magmas rather than amphibole fractionation. Textural evidence indicates that magnetite is an early-forming phase in CA magmas. V, which is concentrated in magnetite, shows a strong decrease with increasing silica in many CA rocks, supporting a magnetite fractionation model.Hawaii Institute of Geophysics Contrib. No. 969 相似文献
14.
Granulite facies amphibole and biotite equilibria,and calculated peak-metamorphic water activities 总被引：2，自引：0，他引：2
Samples located near the Oregon Dome anorthosite massif in the south-central Adirondack Mountains, New York contain the fluid-buffering mineral assemblages: amphibole + clinopyroxene + orthopyroxene + quartz or biotite + quartz + orthopyroxene + K-feldspar. These rocks were metamorphosed under granulite-facies conditions (T=725°–750°C, P=7.5 kbar) during the Grenville orogeny. The Mg-rich nature of amphiboles, micas, and pyroxenes allow accurate calculation of water activities because corrections for the effects of solid solution are relatively small. The activity of water was low during the peak of granulite-facies metamorphism, with H2O0.15±0.14. Wollastonite occurrences indicate that the CO2 was low (<0.3) in nearby rocks, demonstrating that large quantities of CO2 did not infiltrate in a pervasive manner. The combination of low H2O with low CO2 is consistent with the hypothesis that magmatic processes were dominant, generating dry, fluid-absent conditions.Abbreviations
fi
Fugacity of species i in a fluid
-
Xi
mole fraction of component i in a phase
-
T
temperature
-
P
lithostatic pressure
-
P
F
fluid pressure
-
i
x
activity of component i phase X 相似文献
15.
Jonathan D. Blundy Timothy J. B. Holland 《Contributions to Mineralogy and Petrology》1990,104(2):208-224
There is currently a dearth of reliable thermobarometers for many hornblende and plagioclase-bearing rocks such as granitoids and amphibolites. A semi-empirical thermodynamic evaluation of the available experimental data on amphibole+plagioclase assemblages leads to a new thermometer based on the Aliv content of amphibole coexisting with plagioclase in silica saturated rocks. The principal exchange vector in amphiboles as a function of temperature in both the natural and experimental studies is \(\left( {Na\square _{ - 1} } \right)^A \left( {AlSi_{ - 1} } \right)^{T1}\) . We have analysed the data using 3 different amphibole activity models to calibrate the thermometer reactions 1. $$1. Edenite + 4 Quartz = Tremolite + Albite$$ 2. $$2. Pargasite + 4 Quartz = Hornblende + Albite.$$ The equilibrium relation for both (1) and (2) leads to the proposed new thermometer $$T = \frac{{0.677P - 48.98 + Y}}{{ - 0.0429 - 0.008314 ln K}} and K = \left( {\frac{{Si - 4}}{{8 - Si}}} \right)X_{Ab}^{Plag} ,$$ where Si is the number of atoms per formula unit in amphiboles, with P in kbar and T in K; the term Y represents plagioclase non-ideality, RTlnγab, from Darken's Quadratic formalism (DQF) with Y=0 for X ab>0.5 and Y=-8.06+25.5(1-X ab)2 for X ab<0.5. The best fits to the data were obtained by assuming complete coupling between Al on the T1 site and Na in the A site of amphibole, and the standard deviation of residuals in the fit is ±38°C. The thermometer is robust to ferric iron recalculation procedures from electron probe data and should yield temperatures of equilibration for hornblende-plagioclase assemblages with uncertainties of around ±75° C for rocks equilibrated at temperatures in the range 500°–1100° C. The thermometer should only be used in this temperature range and for assemblages with plagioclase less calcic than An92 and with amphiboles containing less than 7.8 Si atoms pfu. Good results have been attained on natural examples from greenschist to granulite facies metamorphic rocks as well as from a variety of mafic to acid intrusive and extrusive igneous rocks. Our analysis shows that the pressure dependence is poorly constrained and the equilibria are not suitable for barometry. 相似文献
16.
A. J. R. White B. W. Chappell P. Jakeš 《Contributions to Mineralogy and Petrology》1972,34(3):185-191
Analyses of major and rare earth elements are presented for co-existing garnet, clinopyroxene, and amphibole from a Kakanui eclogite.New and previously published analyses of garnets suggest a gradual increase of Fe and decrease of Mg from xenocrysts through garnet pyroxene eclogitic rocks to amphibole-rich eclogitic rocks. Clinopyroxenes show a parallel increase in Fe/Mg ratio and an increase in Jadeite component and decrease in Tschermak's component. These data indicate crystallization of garnet and clinopyroxene from an alkali-rich undersaturated magma and are consistent with the concept of eclogite fractionation, but rare earth data allow severe constraints to be placed on this process. The eclogites are considered to be deep-seated crystallization products of nephelinite, but eclogite fractionation is small and cannot account for the association of alkali basalt, basanite and nephelinite. 相似文献
17.
The following reactions involving gedrite were experimentally investigated at 500, 1,000 and 2,000 bars H2O pressure:
- (1)Mg, Fe, Al-chlorite + quartz ? gedrite + cordierite + H2O and 相似文献
18.
Summary The formation of cummingtonite in two Ca and Al-poor and Mg-rich amphibolites from the Austroalpine Schneeberg complex occurred at a maximum temperature of about 550°C (5 kb). This is a result of the amphibolite facies Alpine overprint in this part of the Eastern Alps.Textural and chemical relations suggest (Mg–1Si–1Al2)-continuous reactions in the bivariant CMASH-assemblageCam-Cum-Chl
* followed by the discontinuous reactionCam+Chl+Qu=Cum+Plg+H2O to be responsible for the formation of cummingtonite in these samples.The Mg–Fe distribution coefficient
with values of 0.6–0.7 is similar to cummingtonite-Ca-amphibole pairs from amphibolites with oligoclase+quartz reported in the literature. The Mg/(Mg+Fe) ratio of the calcic amphiboles is lower (0.539–0.555) than the coexisting cummingtonites (0.648–0.662).
With 4 Figures 相似文献
Koexistierende Cummingtonite und Hornblenden in Amphiboliten des Schneeberger Zuges, Tirol, Österreich
Zusammenfassung In zwei Ca- und Al-armen Amphiboliten des nördlichen Schneebergerzuges (Rotmoostal) bildete sich Cummingtonit bei Maximaltemperaturen von 550°C (5 kb) bei der Altalpidschen Metamorphose.Texturelle und chemische Beziehungen lassen vermuten, daß sich Cummingtonite sowohl nach kontinuierlichen Reaktionen (in bezug auf den Tschermak-Vektor Mg–1Si–1Al2) gebildet hat, als auch aus Hornblende und Chlorit nach der diskontinuierlichen ACF-ReaktionCam+Chl+Qu=Cum+Plg+H2O hervorgegangen ist.Der Mg–Fe-Verteilungskoeffizient zwischen Hornblende und Cummingtonit entspricht den aus der Literatur bekannten Werten. Er beträgt zwischen 0.6–0.7 für die beginnende Amphibolitfazies. Die Mg/(Mg+Fe)-Verhältnisse sind höher in Cummingtonit (0.648–0.662) als in der koexistierenden Hornblende (0.539–0.555).
With 4 Figures 相似文献
19.
对桂北新寨侵入岩体中的角闪花岗岩进行了详细的偏光显微镜观察和系统的矿物化学研究，并在此基础上，基于电子探针分析结果选取共生的角闪石和斜长石，估算了该岩体侵位时的温压条件、氧逸度和含水量。岩相特征观察显示，新寨角闪花岗岩中主要发育有自形、未蚀变半自形/他形和强交代半自形/他形3种主要类型的角闪石，是岩浆侵位过程中在不同深度的结晶产物或交代蚀变产物。电子探针研究结果显示，新寨花岗岩中角闪石成分变化较大，且在岩浆侵位过程中呈现出Al2O3、FeOT、Na2O、TiO2、K2O含量降低但MgO、SiO2含量升高的趋势。矿物温压计估算结果显示自形和未蚀变半自形/他形角闪石的结晶压力分别为0.28~0.30 GPa和0.19~0.26 GPa，对应的结晶温度分别为767~783℃和740~764℃。温压计算结果表明新寨岩体初始侵位深度应大于11.3 km，且侵位过程是一个近乎等温降压的过程，变压结晶作用为新寨侵入体持续侵位过程中的主要结晶方式。角闪石结晶时具有较高的氧逸度，变化范围在ΔNNO+0.1（log fO2=－13.5）到ΔNNO+0.5（log fO2=－12.9）之间。角闪石结晶时熔体含水量为4.9%~6.4%，但在侵位到中地壳7.0~9.5 km时经历了由于降压引起的流体出溶。角闪石化学组成指示其母岩浆属于钙碱性的中酸性岩浆，来源于壳幔混合，且在侵位过程中不断有壳源物质加入。 相似文献
20.
Absolute ages of migmatization in the polymetamorphic, parautochthonous basement of the Sveconorwegian Province, Sweden, have been determined using U–Pb ion probe analysis of zircon domains that formed in leucosome of migmatitic orthogneisses. Migmatite zircon was formed by recrystallization whereas dissolution–reprecipitation and neocrystallization were subordinate. The recrystallized migmatite zircon was identified by comparison of zircon in mesosomes and leucosomes. It is backscatter electron‐bright, U‐rich (800–4400 ppm) with low Th/U‐ratios (generally 0.01–0.1), unzoned or ‘oscillatory ghost zoned’, and occurs as up to 100 μm‐thick rims with transitional contacts to cores of protolith zircon. Protolith ages of 1686 ± 12 and 1668 ± 11 Ma were obtained from moderately resorbed, igneous zircon crystals (generally Th/U = 0.5–1.5, U < 300 ppm) in mesosomes; protolith zircon is also present as resorbed cores in the leucosomes. Linkage of folding, synchronous migmatization and formation of recrystallized zircon rims allowed direct dating of south‐vergent folding at 976 ± 7 Ma. At a second locality, similar recrystallized zircon rims in leucosome date pre‐Sveconorwegian migmatization at 1425 ± 7 Ma; an upper age bracket of 1394 ± 12 Ma for two overprinting phases of deformation (upright folding along gently SSW‐plunging axes and stretching in ESE) was set by zircon in a folded metagranitic dyke. Lower age brackets for these events were set at 952 ± 7 and 946 ± 8 Ma by zircon in two crosscutting and undeformed granite–pegmatite dykes. Together with previously published data the present results demonstrate: (i) Tectonometamorphic reworking during the Hallandian orogenesis at 1.44–1.42 Ga, resulting in migmatization and formation of a coarse gneissic layering. (ii) Sveconorwegian continent–continent collision at 0.98–0.96 Ga, involving (a) emplacement of an eclogite unit, (b) regional high‐pressure granulite facies metamorphism, (c) southvergent folding, subhorizontal, east–west stretching and migmatization, all of which caused overprint or transposition of older Mesoproterozoic and Sveconorwegian structures. The Sveconorwegian migmatization and folding took place during or shortly after the emplacement of Sveconorwegian eclogite and is interpreted as a result of north–south shortening, synchronous with east–west extension and unroofing during late stages of the continent–continent collision. 相似文献