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中国K-Ar法地质年龄标准物质ZBH-15黑云母的研制 总被引：3，自引：0，他引：3
为满足K-Ar定年中K和40Ar*分析的质量监控及Ar-Ar定年时中子通量监测的需要,我国氩同位素专家研制了一种K-Ar法年龄标准物质———采自北京房山花岗闪长岩体的ZBH-15黑云母。其40Ar/39Ar阶段加热实验结果表明,年龄谱平坦,39Ar析出量高达98.3%。坪年龄为132.2±0.2 Ma,总气体年龄为131.3±0.5 Ma,证明该黑云母结晶以后未受过热扰动。36Ar/40Ar-39Ar/40Ar反等时线年龄为132.3±0.8 Ma,40Ar/36Ar初始值为293.9±1.4,与大气氩丰度比值(295.5±0.5)处于同一范围,表明该样品不含过剩氩。在0.05显著性水平下经统计学检验,证明K和40Ar*的F值小于F临界值,说明该样品是均匀的。国内外7个实验室参加了K和40Ar*的定值分析。用同位素稀释法测定40Ar*含量,火焰光度法测定K含量。统计检验结果显示,K和40Ar*的全部定值数据服从正态分布并具等精度。定值分析结果的认定值及不确定度分别为:40Ar*=(1.814±0.014)×10-9mol/g,K=7.59%±0.02%,K-Ar年龄t=132.8±1.3 Ma(2σ)。此标准物质纯度为98.8%,粒度为0.15~0.25 mm,重量为2070 g,缩分成225瓶,每瓶9.2 g。可供我国K-Ar和Ar-Ar法实验室使用43 a。 相似文献
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K-Ar法地质年龄国家一级标准物质ZBH-25黑云母的研制 总被引：3，自引：4，他引：3
ZBH-25黑云母采自北京房山花岗闪长岩体。它的~(40)Ar/~(39)Ar 阶段加热实验结果表明,~(40)Ar~*在矿物晶格中保存均匀稳定,年龄谱平坦,~(39)Ar 析出量高达96%,~(40)K-~(40)Ar~*同位素体系封闭良好,证明该黑云母结晶以后未受过热扰动。坪年龄为133.0±0.3Ma,总气体年龄为132.1±0.6Ma;~(36)Ar/~(40)Ar-~(39)Ar/~(40)Ar 反等时线年龄为133.1±1.3 Ma,~(40)Ar/~(36)Ar 初始值为293.5±1.6,与大气氩丰度比(295.5±0.5)处于同一范围,表明样品不含过剩氩。激光显微探针单颗粒坪年龄为132.8±0.2Ma,年龄谱和 K/Ca 谱线平坦,激光熔样总气体年龄为131.3±0.2Ma(图6)。这几个 Ar-Ar 年龄的一致性,说明样品具有良好的均匀性和稳定性,是理想的 K-Ar 和 Ar-Ar 法年龄标准物质。对均匀性检验数据进行统计学方法检验,在0.05显著性水平下,证明 K 和~(40)Ar~*的 F 分布值小于 F 临界值,说明该样品是均匀的。国内外14个实验室参加了 K 含量的定值分析,15个实验室参加了~(40)Ar~*含量的定值分析,经统计学方法检验,结果显示全部定值数据都服从正态分布并具等精度。在置信概率为0.95时,~(40)Ar~*和 K 含量的相对标准偏差都小于0.5%。两个特性量值定值分析结果的一致值和不确定度分别为:~(40)Ar~*=1.817±0.013×10~(-9)mol/g,K=7.60±0.02%,K-Ar 年龄(标准值)=132.9±1.3Ma(2σ).此标准物质纯度为98.8%,粒度为0.25-0.63mm,总重量为5800g,缩分成最小样品单元共400瓶,每瓶重量为14.5g。可供我国 K-Ar 和 Ar-Ar 法同位素年代学实验室使用120年。 相似文献
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为了满足K-Ar和Ar-Ar法定年的需要,年代学工作者研制了一个用于中新生代定年的K-Ar法年龄标准物质——ZGC粗面岩。该粗面岩采自广东省南海市走马营第三纪火山岩。~(40)Ar/~(39)Ar定年结果表明,~(40)Ar~*在矿物晶格中保存均匀稳定,年龄谱平坦,~(39)Ar析出量高达97.9%。证明该粗面岩结晶以后未受过热扰动,完好地保持了~(40)K-~(40)Ar~*同位素计时的化学封闭体系。坪年龄为52.8±0.3 Ma,总气体年龄为52.9±0.8 Ma。~(36)Ar/~(40)Ar-~(39)Ar/~(40)Ar反等时线年龄为52.5±0.4 Ma,~(40)Ar/~(36)Ar初始值为296.6±4.2,此值与(~(40)Ar/~(36)Ar)。大气氩丰度比(295.5±0.5)一致,表明样品不含过剩氩。国内12个实验室参加了ZGC粗面岩K含量和~(40)Ar~*含量的定值分析。经统计学方法检验,结果显示全部定值数据服从正态分布并具等精度。当置信概率为0.95时,~(40)Ar~*和K含量的相对标准偏差都小于1%。~(40)Ar~*和K含量分析的认定值和不确定度分别为:~(40)Ar~*=4.199±0.022×10~(-10)mol/g,K=4.576±0.028%,由此计算得K-Ar年龄为52.2±0.5 Ma。根据国家一级标准物质技术规范的相关要求,经统计学方法检验在0.05显著性水平下,K和~(40)Ar~*的F分布小于F临界值,说明该标准物质是均匀的。t检验法表明,该标准物质具有良好的稳定性,~(40)Ar~*和K含量在有效期内不会发生显著性变化。ZGC粗面岩粒度为0.3～0.7mm,重量为850 g,缩分成最小样品单元100瓶,每瓶8.5 g。可供K-Ar和Ar-Ar法实验室使用43年。 相似文献
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K-Ar、40Ar/39Ar定年中, 用以计算囚禁40Ar绝对量的40Ar/36Ar, 称为初始氩比值.现代大气中的初始氩比值叫尼尔值, 为295.5.K-Ar、40Ar/39Ar定年的表观年龄都是在假设初始氩比值与现代大气中的尼尔值一致的基础上得到的.事实证明, 地球样品的初始氩比值不总是尼尔值, 因此这种假定不可靠, 尤其在对年轻样品进行K-Ar、40Ar/39Ar定年时, 会带来错误的表观年龄结果.对于K-Ar、40Ar/39Ar精细年代学, 特别对于年轻样品和低钾含量样品, 只有初始氩比值才对定年研究有意义, 而初始氩比值只能通过40Ar/39Ar等时线法求得.所以严格地讲, 只有等时线年龄才是可靠的.结合实验流程, 本文分析了40Ar/39Ar定年中为什么大多数等时线获取的初始氩比值接近尼尔值, 一是因为常规40Ar/39Ar坪年龄的计算方法, 二是因为吸附氩的干扰.初始氩比值的一致性, 被用来证明样品同位素同源和封闭特性, 对年龄数据的精度及可靠性有非常大的影响, 尤其是年轻样品.因此, 在40Ar/39Ar定年中要选取氩同位素初始比值一致的同源样品, 并在实验流程中尽量克服样品吸附气体.本文对传统40Ar/39Ar方法中坪年龄、年龄坪的意义提出了质疑, 对提高40Ar/39Ar定年的精度具有重要意义, 并使之能够应用到极年轻的火山岩定年中. 相似文献
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对具有不同地质历史背景的3类40Ar/39Ar法样品中的40Ar和39Ar释出特征进行对比,研究结果表明,40Ar/39Ar法样品中的40Ar、39Ar释气曲线主要表现为以下3种形式:完全重合型、过剩氩型和不规则型。当40Ar与39Ar释气曲线呈完全重合型时,40Ar/39Ar法全熔年龄代表了岩体的形成年龄;当40Ar、39Ar释气曲线是过剩氩型时,40Ar/39Ar法全熔年龄则大于岩体的形成年龄;当40Ar与39Ar释气曲线呈不规则型时,表明样品中的放射成固氩(40Ar*)发生了丢失,其全熔年龄一般较岩体的形成年龄小。对于40Ar、39Ar释气曲线呈过剩氩型的样品,40Ar/39Ar法年龄谱通常呈马鞍形,且马鞍形年龄谱的底部年龄一般都具有地质意义,代表了岩体的形成年龄。对于40Ar、39Ar释气曲线呈不规则型的样品,对其年龄谱的解释应持谨慎态度。 相似文献
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为了满足Ar-Ar快中子活化法定年的需要,经过十几年的连续测定与检验,一个用于早前寒武纪矿物定年的K-Ar法年龄标准物质——ZMT04白云母已被研制成功。它采自内蒙古自治区卓资县天皮山。40Ar-39Ar定年结果表明,40Ar*在矿物晶格中保存均匀稳定,年龄谱平坦,39Ar析出量为99.1%,40Ar/39Ar坪年龄为1823±15Ma,说明该白云母结晶以来未受热扰动,40K-40Ar*同位素计时体系封闭良好。40Ar/39Ar等时年龄为1824±15Ma,与坪年龄一致,代表了伟晶岩中白云母的结晶时间。(40Ar/36Ar)0初始值为288±16,此值与(40Ar/36Ar)a大气氩丰度比(295.5±0.5)处于同一范围,表明该白云母不含过剩氩。根据国家一级标准物质技术规范(JJG1006-1994)的有关规定,对ZMT04白云母进行了一系列分析检验。均匀性检验结果表明,在0.05显著性水平下,K和40Ar*的F分布值小于F临界值,证明该白云母是均匀的。t检验法和稳定性检验与分析表明,ZMT04白云母完全满足国家一级标准物质技术规范对稳定性的要求。国内8个实验室参加了ZMT04白云母K和40Ar*含量的定值分析,正态性和等精度检验结果显示,全部定值分析数据服从正态分布并具等精度。当置信概率为0.95时,该白云母40Ar*和K含量的相对标准偏差都小于1%。经过严格计算最后获得40Ar*和K含量及年龄的认定值和不确定度分别为:40Ar*=4.449±0.060×10-8mol/g(2σ),K=8.28±0.04%(2σ),K-Ar年龄=1804±21Ma(2σ)。此标准物质纯度达100%,总重量为1080g,缩分为196瓶,每瓶5.51g。可供我国K-Ar和Ar-Ar法年代学实验室至少使用54年。此标准物质于2009年3月4日被国家质量监督检验检疫总局审核批准为国家二级标准物质(见国质检量函[2009]89号文),国家质检总局认定的ZMT04白云母制造计量器具许可证编号为GBW(E)040019。 相似文献
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氩-氩定年法国际标准物质BSP-1角闪石的研制 总被引：11，自引：5，他引：11
BSP-1角闪石选自中国吉林省桦甸县老牛沟的角闪石岩。~(40)Ar-~(39)Ar分析和均匀性检查表明:此角闪石结晶以后未受过热扰动,~(40)Ar~*保存性好,谱线平坦,K/Ca和Cl/K比值稳定。定值结果显示,在置信概率为0.95时,~(40)Ar~*和K含量的相对偏差均<5‰,是目前最理想的Ar-Ar和K-Ar法国际标准物质,可供全世界Ar-Ar实验室使用80年以上。 相似文献
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同位素地质年龄标准样的建立,是一项重要的基础工作,它在检查和比较各种实验流程,衡量各种定年方法的可信度,标定同位素稀释剂等方面,都是必不可少的。从1977年初开始,我国同位素地质标准样小组着手建立K-Ar法标准样。为了外检,笔者曾将ZBH-25黑云母、ZBJ角闪石带到澳大利亚国立大学地球科学院进行测定。这两个样品的K-Ar稀释法年龄、40Ar/39Ar坪年龄及40Ar/39Ar等时年龄的一致性表明,这些矿物结晶以后,未受过热的挠动,也不存在过剩氩,是作标准样的理想样品。本文还介绍样品中放射成因40Ar的析出特征,并指出40Ar可能有两种存在状态,它们各具不同的晶格能。 相似文献
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The 40Ar/39Ar dating technique is based on the knowledge of the age of neutron fluence monitors (standards). Recent investigations have improved the accuracy and precision of the ages of most of the Phanerozoic-aged standards (e.g. Fish Canyon Tuff sanidine (FCs), Alder Creek sanidine, GA1550 biotite and LP-6 biotite); however, no specific study has been undertaken on the older standards (i.e. Hb3gr hornblende and NL-25 hornblende) generally used to date Precambrian, high Ca/K, and/or meteoritic rocks.In this study, we show that Hb3gr hornblende is relatively homogenous in age, composition (Ca/K) and atmospheric contamination at the single grain level. The mean standard deviation of the 40Ar?/39ArK (F-value) derived from this study is 0.49%, comparable to the most homogeneous standards. The intercalibration factor (which allows direct comparison between standards) between Hb3gr and FCs is RFCsHb3gr = 51.945 ± 0.167. Using an age of 28.02 Ma for FCs, the age of Hb3gr derived from the R-value is 1073.6 ± 5.3 Ma (1σ; internal error only) and ± 8.8 Ma (including all sources of error). This age is indistinguishable within uncertainty from the K/Ar age previously reported at 1072 ± 11 Ma [Turner G., Huneke, J.C., Podosek, F.A., Wasserburg, G.J., 1971. 40Ar-39Ar ages and cosmic ray exposure ages of Apollo 14 samples. Earth Planet. Sci. Lett. 12, 19-35].The R-value determined in this study can also be used to intercalibrate FCs if we consider the K/Ar date of 1072 Ma as a reference age for Hb3gr. We derive an age of 27.95 ± 0.19 Ma (1σ; internal error only) for FCs which is in agreement with the previous determinations. Altogether, this shows that Hb3gr is a suitable standard for 40Ar/39Ar geochronology. 相似文献
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Abstract 40Ar/39Ar age spectrum analysis of phengite separates from Naxos, part of the Attic Cycladic Metamorphic Belt in Greece, indicates that cooling following high-pressure, low- to medium-temperature metamorphism, M1, occurred about 50 Ma ago. Phengite has 40Ar* gradients that suggest that part of the scatter observed in conventional K–Ar ages was caused by diffusion of radiogenic argon from the minerals during a younger metamorphism, M2. In central Naxos, this metamorphism (M2) has overprinted the original mineral assemblages completely, and is associated with development of a thermal dome. Excellent 40Ar/39Ar plateaus at 15.0 ± 0.1 Ma, 11.8 ± 0.1 Ma, and 11.4 ± 0.1 Ma, obtained on hornblende, muscovite and biotite, respectively, from the migmatite zone, indicate that relatively rapid cooling followed the M2 event, and that no significant thermal overprinting occurred subsequent to M2. Toward lower M2 metamorphic grade, 40Ar/39Ar plateau ages of hornblendes increase to 19.8 ± 0.1 Ma; concomitantly the proportion of excess 40Ar in the spectra increases as well. We propose that the peak of M2 metamorphism occurred beween 15.0 and 19.8 Ma ago. K–Ar ages of biotites from a granodiorite on the west coast are indistinguishable from those found in the metamorphic complex, and hornblende K–Ar ages from the same samples are in the range 12.1–13.6 Ma. As the latter ages are somewhat younger than most ages obtained from the metamorphic complex, intrusion of the granodiorite most likely followed the peak of the M2 metamorphism. The metamorphic evolution of Naxos is consistent with rapid crustal thickening during the Cretaceous or early Tertiary, causing conditions at which supracrustal rocks experienced pressures in the range 900–1500 MPa. Transition to normal crustal thicknesses ended the M1 metamorphism about 50 Ma ago. The M2 metamorphism and granodiorite intrusion occurred during a period of heat input into the crust, possibly related to the migration of the Hellenic volcanic ar°C in a southerly direction through the area. 相似文献
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铜陵舒家店斑岩铜矿成矿年代学研究及其成矿意义 总被引：9，自引：8，他引：1
舒家店铜矿床是长江中下游成矿带中新发现的斑岩型铜矿床,位于铜陵断隆区与繁昌断凹区(盆地)的过渡部位,矿床成矿时代确定对该矿床成因研究及区域成矿规律的认识具有重要意义.在详细野外地质工作的基础上,选择与黄铜矿密切共生的辉钼矿和热液蚀变矿物黑云母为对象,分别利用Re-Os和40Ar-39 Ar阶段加热同位素定年方法,得到舒家店铜矿床辉钼矿Re-Os模式年龄和黑云母40 Ar-39 Ar坪年龄分别为140.6±2.0Ma和142.8±1.1Ma,分别代表了舒家店铜矿床的矿化年龄和钾硅酸盐化蚀变年龄.并通过与铜陵断隆区和繁昌断凹区成岩作用和成矿时代的对比,表明舒家店铜矿床属于铜陵断隆区中生代岩浆热液活动的产物. 相似文献
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40Ar/39Ar dating was conducted on the Da Lien granite related to greisen‐skarn type polymetallic (W‐CaF2‐Cu‐Bi‐Au) mineralization in Nui Phao, northern part of Vietnam in the South China Plate. Biotite and muscovite separates from the biotite‐muscovite granite and greisenized granite indicate four plateau ages: 82.2 ± 0.4 Ma, 82.8 ± 0.3 Ma, 81.5 ± 0.3 Ma and 82.5 ± 0.4 Ma. The plateau ages were not significantly influenced by excess 40Ar in dated minerals or by loss of radiogenic 40Ar due to hydrothermal activities. The results indicate that solidification of granite related to the polymetallic mineralization occurred in the Late Cretaceous between 82.8 Ma and 81.5 Ma. 相似文献
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个旧卡房层状铜矿床金云母和云英岩化白云母40Ar-39Ar同位素年龄及意义 总被引：1，自引：0，他引：1
在个旧锡铜多金属矿集区发育有矽卡岩型和热液脉型等锡铜矿化体,其形成时代是晚白垩世,属与花岗岩有关的岩浆热液成因矿床。赋存于三叠纪蚀变玄武岩层中,呈(似)层状的铜矿体的精确年龄尚未有报道,成因仍备受争议。文章选择赋存于卡房矿田蚀变玄武岩层中,呈(似)层状分布的铜矿体中的金云母,及新山岩体接触带云英岩中的白云母为研究对象,利用40Ar-39Ar阶段加热同位素定年方法对它们进行了年代学研究,获得了金云母和白云母的40Ar-39Ar同位素坪年龄分别为(79.55±0.47) Ma和(79.53±0.57) Ma,对应等时线年龄分别为(79.8±1.3) Ma和(79.7±1.0) Ma,反等时线年龄分别为(79.7±2.0) Ma和(79.61±0.75) Ma,两者年龄基本一致。结合矿物共生组合特征和流体包裹体测温资料,认为金云母的坪年龄(79.55±0.47) Ma,可以代表卡房蚀变玄武岩中(似)层状铜矿的形成时代,而白云母的坪年龄(79.53±0.57) Ma,则代表新山岩体形成后期岩浆热液活动的年龄。这2个年龄与个旧锡铜多金属矿床的成矿时代基本一致,应是同一构造-岩浆-流体活动形成的成矿系列产物。 相似文献
17.
Regional‐scale 40Ar–39Ar data presented in this paper reveal significant across‐strike and along‐strike age differences in the Committee Bay belt (CBb), Rae Province, Nunavut, Canada, that complement variations in observed monazite ages. 40Ar–39Ar hornblende ages are c. 1795, 1775, and 1750 Ma in the western, eastern and central parts of the Prince Albert Group (PAG) domain respectively. The migmatite domain and Walker Lake intrusive complex are characterized by c. 1750–1730 40Ar–39Ar hornblende ages without significant along‐strike variation. The 40Ar–39Ar data provide important constraints on the cooling history and on thermal modelling that elucidates the controls on diachroneity and metamorphic patterns within the belt. In the western CBb, prograde monazite growth occurred 26 ± 10 Myr earlier in the migmatite domain (1864 ± 9 Ma; peak P–T = 5 kbar?700 °C) than in the PAG domain (1838 ± 5 Ma; peak P–T = 5 kbar?580 °C). Calculations indicate that this earlier monazite growth results from tectonic thickening of higher heat productivity Archean lithologies in the migmatite domain, which undergoes more rapid prograde heating than the less radiogenetic and lower grade rocks of the PAG domain. Granite generation via biotite dehydration melting at 800 °C and 20 km depth is predicted to occur c. 1835 Ma, in agreement with geochronological constraints. The tectonic burial of crustal domains with contrasting radiogenic properties also explains the general congruence of lower to upper amphibolite facies metamorphic zones generated during the two main orogenic cycles (i.e. M2–D1 and M3–D2). The modelled timing of prograde monazite growth in the migmatite domain suggests that D2 tectonic thickening began at 1872 ± 9 Ma, some 8 ± 3 Myr before monzazite growth, coeval with the inferred time of collision of the Meta Incognita terrane with the southern Rae Province. Along‐strike diachroneity, reflected in 25 Myr younger monazite and 40Ar–39Ar hornblende ages in the eastern relative to the western PAG domain, cannot be accounted for by heat productivity contrasts along the belt. Instead the younger deformation and metamorphism in the eastern CBb was driven by its proximity to the eastern promontory of the Superior Province which collided with the Rae Province at c. 1820 Ma. The 40Ar–39Ar data presented here support the interpretation that the youngest monazite in the CBb crystallized at c. 1790 Ma in the central CBb when this part of the belt was downfolded into a gentle synformal structure while the western part of the belt cooled through 40Ar–39Ar hornblende closure. The results of this study illustrate the important influence of contrasting rock properties on the thermal evolution of orogenic belts and on the temporal record of this evolution. 相似文献
18.
Youjuan Li Brian R. Jicha Wanfeng Zhang Wen Chen Brad S. Singer Dewen Zheng Huaiyu He 《Geostandards and Geoanalytical Research》2023,47(3):657-668
The precision and accuracy of 40Ar/39Ar dates are ultimately linked to co-irradiated reference materials of known age. Here we provide new data from the SK01 sanidine, which was analysed in three different laboratories to evaluate it as a 40Ar/39Ar reference material. Aliquots of 5 mg, incrementally heated in two laboratories, yielded indistinguishable results with a weighted mean age of 27.58 ± 0.06 Ma (95% confidence level). Single-crystal step heating and single-crystal total fusion analyses of SK01 sanidine were undertaken in the third laboratory to further test the intracrystalline homogeneity. For the seven step-heating analyses, six crystals yielded nearly concordant age spectra with 40Ar/39Ar ages ranging from 26.853 ± 0.094 Ma to 26.963 ± 0.067 Ma, whereas one crystal gave an older age of 27.774 ± 0.071 Ma with a slightly discordant age spectrum. Twenty-three single-crystal total fusion analyses yielded 40Ar/39Ar ages ranging from 27.070 ± 0.108 Ma to 27.736 ± 0.062 Ma with a dispersion of ~ 3.8%. The older ages from single-crystal total fusion dates are interpreted to reflect an inherited or excess argon component in some crystals. This is an initial characterisation of the SK01 sanidine, and additional work needs to be conducted to further evaluate the age dispersion so that it can be utilised as a 40Ar/39Ar reference material. 相似文献
19.
西昆仑库地以南有一套变质变形较强的岩系,前人依照区域对比关系将其划为前寒武的古老基底。对西昆仑早期构造演化的论述均基于该观点,但没有提供确凿的同位素年代学证据。笔者通过野外观察、室内研究,确认库地以南的变质变形岩系是大型韧性推覆剪切作用的产物。通过对新生变质矿物角闪石和黑云母单矿物的40Ar/39Ar年龄分析,确定剪切变质年龄为426-451Ma,说明库地的变质变形岩系是形成于早古生代晚期的一条大型韧性剪切带,这对于解释西昆仑的早期构造演化具有重要意义。 相似文献