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1.
玉峰金矿位于中亚造山带东天山东缘,是近年来新发现的含银高品位金矿床。该矿床目前已探明6个金矿体,均赋存在石英斑岩中。矿区热液蚀变作用发育,与成矿关系最密切的为黄铁绢英岩化和硅化,显示明显的蚀变分带:以石英硫化物脉为中心,黄铁绢英岩化带在其两侧大致对称分布。本文选取矿体上盘和下盘的石英斑岩、黄铁绢英岩进行了全岩的主、微量元素及成矿元素测试,并对其中的长石和绢云母进行电子探针成分分析。测试结果表明,黄铁绢英岩中的Au含量较蚀变前呈指数级增长,Ag、Cu、As等成矿元素大量增加,CaO、Na_2O、P_2O_5、P_2O_5、Sr、Pb、Th、U、Sb等元素显著迁出,而SiO_2、Al_2O_3、TiO_2含量和稀土元素含量变化较小,表现稳定。热液蚀变过程中,石英斑岩中71%～76%的正长石发生绢云母化,导致K_2O大量迁出;而钠长石几乎全部蚀变为绢云母,造成Na_2O大量迁出。热液流体的贡献使得蚀变岩中MgO、Fe_2O_3~T含量成倍增加,并主要富集在绢云母和/或黄铁矿晶格中。综合分析认为,绢英岩化蚀变带,Au、Cu、As和Bi等元素的综合化探异常,低电阻率、高激化率的地球物理特征可以作为玉峰矿区深部和外围找矿的标志。研究区内的石炭纪石英斑岩带,尤其是在构造叠加部位,热液活动使其更有利于矿化富集,是找矿勘探的有利部位。 相似文献
2.
位于伊勒呼里火山岩隆起带与大兴安岭火山岩带衔接部位的多布库尔河上游在1／5万水系沉积物测量中发现钼多金属异常,以Mo为主,伴生Ag、Pb、Zn、Cu、Au、As、Sb、Bi。异常面状分布,浓集中心明显,具浓度分带,浓度梯度大。经土壤测量验证,异常再现良好,经槽探揭露,发现钼矿体。矿体赋存在流纹斑岩体及隐爆角砾岩内,矿物主要为辉钼矿,少量方铅矿、闪锌矿和黄铜矿,呈微细脉状及侵染状。蚀变有硅化、绢云母化、绿帘石化、高岭土化、黄铁矿化。推测矿床成因为斑岩型钼多金属矿床,找矿前景乐观。 相似文献
3.
位于特提斯成矿域西段塞尔维亚Bor成矿带内的Mali Krivelj铜矿床是一大型斑岩型矿床。为揭示该矿床热液蚀变作用过程及元素迁移规律,文章对新鲜安山岩及不同蚀变带典型样品进行了微量元素分析及元素迁移质量平衡计算。研究结果表明,绢英岩化带及绿泥石-绢云母化带显示类似元素迁移规律,REE、Sr、Ba、Zr、Th、U、Ti、Co、Ni等元素显示一定程度迁出,而Rb、Cs等元素显示一定程度迁入,绿泥石-绢云母化带发育大量磁铁矿,而绢英岩化带则大量出现石英+绢云母+黄铁矿组合,这表明随着流体的持续演化,流体的还原性逐渐增强。青磐岩化带蚀变较弱,其元素迁移程度较低。研究区Cu与Cr、Rb、Ti/Sr、Rb/Ba、Cr/Zn比值等具较好的正相关性,Cu与REE、Ba、Zn、Mn、Sr等元素具有一定的负相关性,表明该矿床全岩元素迁移规律在一定程度上也能作为地球化学勘查指标为寻找斑岩矿化中心提供依据。 相似文献
4.
大兴安岭铜钼矿床主要与古生代和中生代浅成侵入岩和火山-次火山岩有关,矿床形成于陆缘岩浆岩带、造山带和深大断裂带中.成矿期主要为加里东期、华力西期和燕山期.矿化围岩为花岗闪长岩、花岗闪长玢岩、二长花岗岩、安山岩、英安岩、流纹岩、安山玢岩、流纹斑岩和火山碎屑岩.围岩蚀变主要有硅化、绢云母化、钾长石化、水白云母化、伊利石化、绿泥石化、碳酸岩化.矿石中主要工业元素为Cu和Mo,伴生有益组分为Ag、Au、Re等.成矿类型有：①斑岩型铜钼矿床;②火山-次火山热液型铜钼矿床.大兴安岭铜钼矿床主要由陆缘岩浆岩带、造山带、深大断裂带的火山-次火山作用及小型侵入作用形成,成矿流体沿着火山机构、岩浆侵入构造、区域构造等运移,热动力、压力、扩散力等使成矿流体产生上升运动和局部循环运动,成矿流体的迁移、萃取、扩散、交代作用等使成矿物质产生富集. 相似文献
5.
《地质与资源》2010,(3)
大兴安岭铜钼矿床主要与古生代和中生代浅成侵入岩和火山-次火山岩有关,矿床形成于陆缘岩浆岩带、造山带和深大断裂带中.成矿期主要为加里东期、华力西期和燕山期.矿化围岩为花岗闪长岩、花岗闪长玢岩、二长花岗岩、安山岩、英安岩、流纹岩、安山玢岩、流纹斑岩和火山碎屑岩.围岩蚀变主要有硅化、绢云母化、钾长石化、水白云母化、伊利石化、绿泥石化、碳酸岩化.矿石中主要工业元素为Cu和Mo,伴生有益组分为Ag、Au、Re等.成矿类型有:①斑岩型铜钼矿床;②火山-次火山热液型铜钼矿床.大兴安岭铜钼矿床主要由陆缘岩浆岩带、造山带、深大断裂带的火山-次火山作用及小型侵入作用形成,成矿流体沿着火山机构、岩浆侵入构造、区域构造等运移,热动力、压力、扩散力等使成矿流体产生上升运动和局部循环运动,成矿流体的迁移、萃取、扩散、交代作用等使成矿物质产生富集. 相似文献
6.
戴屋金矿床位于大瑶山成矿带,其矿化主岩是寒武系浅变质细碎屑岩和板岩。岩石具较高的Au、As、Ag、Sb、Hg含量。区内广泛发育酸性斑岩类(花岗斑岩、石英斑岩)岩石。斑岩类岩石经历了明显的热液蚀变作用,主要的蚀变作用是硅化、黄铁绢英岩化和绢云母化。蚀变花岗斑岩内存在Cu、Au、As(Ag)矿化。赋存于变质岩内的金矿化体分为石英脉型矿体和硅化砂岩型矿体。石英脉型矿体受近EW向褶皱和NEE、NWW向断裂控制,硅化砂岩型矿体具层(岩)控特点,矿床的地质地球化学特征和矿体类型表明,该矿床类似于造山型金矿床。 相似文献
7.
本文对毕力赫金矿床Ⅱ矿带围岩蚀变及其与金矿化关系进行了研究.矿床主要蚀变类型为硅化、钾化、黄铁矿化、绢云母化、电气石化、绿泥石化、高岭土化、碳酸盐化,其中硅化、绢云母化、黄铁矿化与金矿化关系密切;蚀变分带明显,由地表向下,依次为青磐岩化带→绢英岩化带→钾质蚀变带,绢英岩化带与金矿化关系最为密切. 相似文献
8.
巴达铜金矿位于藏东富碱斑岩带南段,是藏东地区近年来新发现的大型铜金矿。虽然对巴达铜金矿开展了大量勘查工作,但对该矿床的成因尚未取得共识。本文基于详细的野外调研、岩心与坑道编录及系统的镜下鉴定,对巴达铜金矿床地质特征进行研究。巴达矿床主要产于石英二长斑岩中,局部产于斑岩和砂岩地层的接触带内。矿床发育的围岩蚀变主要为青磐岩化、钾化、绢英岩化,高岭土化、蛋白石化、蒙脱石化次之,蚀变分带从内向外依次为钾硅酸盐化带、绢英岩化带、青磐岩化带、高岭土化带,铜金矿体主要赋存于钾硅酸盐化和绢英岩化带内,铜矿化主要以黄铜矿形式产出,金矿化主要以银金矿形式产于白云石±石英+细粒黄铁矿±黄铜矿脉中,铜矿化与金矿化呈正相关,矿体的产出受北西向逆冲断层的控制。与典型斑岩和浅成低温热液矿床不同,巴达铜金矿化主要产于白云石±石英+黄铁矿脉中;矿床内既发育碳酸盐、伊利石、绢云母和黄铁矿、黄铜矿、方铅矿、黝铜矿、低FeS闪锌矿等一套中硫型浅成低温热液矿床的蚀变矿物组合,又发育符合碱性斑岩系统的特征矿物赤铁矿。基于以上特征判断,巴达铜金矿矿床成因类型应为与富碱斑岩有关的浅成低温热液矿床,巴达铜金矿矿床成因的厘定,为下一步找矿提供了理论指导。 相似文献
9.
江西冷水坑斑岩型铅锌银矿床地质特征、热液蚀变与成矿时限 总被引：14，自引：1，他引：13
江西冷水坑铅锌银矿床是我国重要的铅锌银矿床之一,也是世界上少有的斑岩型铅锌银矿床.冷水坑斑岩型铅锌银矿床位于中国东部中生代月凤山火山盆地边缘,含矿斑岩为燕山中期碱性花岗斑岩,侵位于上侏罗统火山岩地层内,斑岩体边部发育大量的隐爆角砾岩.矿区发育两种矿化类型,即斑岩型矿化与层状改造型矿化,此两种均与碱性花岗斑岩有关.矿化以Pb、Zn、Ag为主,伴生少量的Cu、Au.斑岩型的铅锌银矿化发生在斑岩体内以及接触带中,具有面型矿化特点并显示出明显的矿化分带性.层状改造型以铁锰银铅锌矿化为主,矿体均为隐伏状分布于碱性花岗斑岩附近的火山岩含铁锰地层中,产状与火山岩地层一致.铁锰碳酸盐铅锌银矿体在靠近斑岩体时,银铅锌矿化相应逐渐增强,而远离花岗斑岩体,矿化明显较弱.围岩蚀变作用明显,主要为绢云母化、绿泥石化、碳酸盐化、硅化和黄铁矿化.矿化蚀变特征、蚀变类型与典型的斑岩型铜(钼)矿床不同,缺少斑岩铜(钼)矿床早期蚀变的钾交代作用(黑云母化与钾长石化),发育大量铁锰碳酸盐蚀变.矿田矿化蚀变具有一定的分带性,由岩体内向外蚀变可以分为三个带:绿泥石绢云母化带、绢云母化碳酸盐化硅化黄铁矿化带和碳酸盐化绢云母化带.斑岩型矿床的铅锌银矿化与绢云母化和绿泥石化蚀变密切相关.通过对蚀变矿物绢云母的~(40)Ar/~(39)Ar同位素测定,获得冷水坑斑岩型铅锌银矿化年龄为162.8 ±1.6Ma,与含矿斑岩形成时间一致,说明冷水坑斑岩型铅锌银成矿作用发生于中国东部燕山中期陆内环境. 相似文献
10.
罗卜岭矿床是与晚中生代花岗闪长斑岩体有关的隐伏斑岩型铜钼矿床, 矿区位于紫金山矿田的东北部; 铜钼矿体主要产于绿泥石化-绢英岩化和(弱)钾化-绢英岩化带中, 矿石矿物组合为黄铜矿+辉钼矿; 少量过渡类型矿体产于高级泥化带中, 矿石矿物组合为蓝辉铜矿+铜蓝+辉钼矿。罗卜岭矿区的原生晕地球化学三维模型显示, 微量元素具有一定的分带特征, 低温元素Au与高温元素组合W、Sn、Bi分布于矿体上方, 中低温元素Pb、Zn、Ag分布于Cu、Mo元素之间; 元素直观垂向分带序列大致为: (As、Sb、Hg)-(W、Bi、Sn)-Ga-Au、Ba-Cu、Ag-Pb、Zn-Mn-Mo; 前缘晕的元素与氧化物组合为As、Sb、Au、Ga、Al2O3, 矿体近矿晕元素组合为Ag、Pb、Zn, 缺失尾晕元素组合; Cu、Mo可直接作为找矿指示元素, Au、Ag、Pb、Zn、As、Sb、Ga、Ba、Mn可作为间接指示元素, 矿床深部K2O正异常与Al2O3负异常可作为斑岩型铜钼矿的重要找矿标志, 这一规律对紫金山矿田深部和外围隐伏斑岩型矿体的勘查工作具有重要的参考意义。 相似文献
11.
台湾东北部的龟山岛浅海热液体系产生大量的热液自然硫.为了理解微量元素在自然硫中的富集规律和机制,采用激光剥蚀等离子体质谱仪（LA-ICPMS）对龟山岛自然硫进行了元素含量分析.结果显示,硫磺基底仅含有As、Se和Te等岩浆脱气产生的挥发性亲铜元素.Fe、Mn、Co、Ni等亲铁元素主要来自于安山岩基岩,富集于富铁或含硅包体中.Al、Zn、Ba、Pb、La、Ce、Au、Ag等元素显著富集于含硅包体中,表明这些元素受硅酸盐矿物控制.富铜包体具有最高的Hg、Pb、Zn等亲铜元素的单位富集程度.首次对龟山岛热液自然硫中的微量元素分布进行了原位微区分析,有助于理解微量元素在热液活动中的来源、分布和分配等地球化学行为. 相似文献
12.
湘西南漠滨地区元古界地层地球化学研究 总被引：1，自引：0，他引：1
本文研究了湘西南漠滨地区元古界板溪群五强溪组地层中金的分布、微量元素地球化学及其与金的成矿关系,研究表明,本区五强溪组呈现明显的金亏损,而地层则具有富As、Sb,贫Hg、Sr,以及Co/Ni比值大于 1、Au/Ag及 Sr/Ba比值低的地球化学特点。金的分布在空间上有一定变化规律,从远离矿区的地层岩石到矿床内部的脉旁围岩,根据其丰度高低,相应地划分出背景区—亏损区—富集区—亏损区—富集区五个区段,后四者组成一个共轭体系。两次金亏损都是水热淋滤作用的结果,但二者在形成的时间、规模及地球化学特征上都存在显著差异。这种淋滤的阶段性,导致了漠滨金矿床的两期成矿作用。金以及其他成矿元素的亏损区或亏损带的出现有一定普通性,因而对找矿具有重要的指导意义。 相似文献
13.
在胶东莱州吴一村地区完成的3266.06 m深钻,是目前焦家金成矿带最深见矿钻孔,研究钻孔揭露的深部矿石中金矿物及黄铁矿微量元素特征,对探讨深部成矿作用演化具有重要意义。笔者采取深钻中2420~3206 m垂深的岩（矿）芯样品进行了详细的岩相学和矿相学研究,结合扫描电镜和电子探针微区分析,研究了矿石中金矿物的赋存状态和成分。对不同成矿阶段形成的黄铁矿进行了LA-ICPMS微量元素分析。研究结果表明,深部矿石中载金矿物主要为黄铁矿,其次为石英、黄铜矿、方铅矿,可见金主要以自然金和银金矿的形式存在,以晶隙金和裂隙金为主,其次为包体金。与浅部金矿床比较,深部金的成色较高。黄铁矿分为6种类型,第Ⅰ成矿阶段形成富Co型黄铁矿Py1,第Ⅱ成矿阶段形成富Ni型黄铁矿Py2a和Py2b,第Ⅲ成矿阶段形成富Au、As型黄铁矿Py3a和富Au、Ag、Pb、Bi型黄铁矿Py3b,第Ⅳ成矿阶段形成贫微量元素黄铁矿Py4。其中,Py1和Py2a发生强烈破碎,裂隙表面对热液中的Au络合物产生吸附作用,对金沉淀富集起重要作用。黄铁矿中Co、Ni、As等微量元素主要以类质同象形式赋存,而Au、Ag、Cu、Pb、Zn、Bi等主要以纳米级、微米级矿物包体形式赋存。Pb+Bi、Cu+Pb+Zn、Te+Bi与Au+Ag呈明显正相关,而Au与As相关性较差。黄铁矿中Co、Ni含量较低,而Au+Ag+As或Au+Ag+Pb+Bi+Cu含量较高指示成矿有利。另外,黄铁矿中Co、Ni含量较高,并且破碎强烈,成矿相关元素含量较高也指示成矿有利。 相似文献
14.
赵家堡子金矿位于猫岭-卧龙泉金矿化集中区,是典型的中低温热液矿床。通过区域变质作用,使岩层中的Au、Ag等成矿元素活化,随着变质热液运移到有利的构造部位初步富集;通过应力作用,使岩石发生塑性变形,形成了北西向的韧性剪切带。同时,使Au、Ag等成矿元素再次活化转移、富集;通过后期构造岩浆的大面积侵入,形成了叠加在韧性剪切带之上的北西向韧-脆性断裂和北东向的脆性断裂,同时宏大的热源使地层中的Au再次活化、迁移、富集,同岩浆所带来的大量成矿物质一起在有利的构造部位富集成矿,是本区金矿的主要成矿阶段。 相似文献
15.
The rhyolitic dome in the Rangan area has been subjected to hydrothermal alterations by two different systems, (1) A fossil magmatic–hydrothermal system with a powerful thermal engine of a deep monzodioritic magma, (2) An active hydrothermal system dominated by meteoric water. Based on mineralogical and geochemical studies, three different alteration facies have been identified (phyllic, advanced argillic and silicic) with notable differences in REE and other trace elements behaviour. In the phyllic alteration zone with assemblage minerals such as sericite, pyrite, quartz, kaolinite, LREE are relatively depleted whereas HREE are enriched. The advanced argillic zone is identified by the presence of alunite–jarosite and pyrophyllite as well as immobility of LREE and depletion in HREE. In the silicic zone, most of LREE are depleted but HREE patterns are unchanged compared to their fresh rock equivalents. All the REE fractionation ratios (La/Yb)cn, (La/Sm)cn, (Tb/Yb)cn, (Ce/Ce1)cn and (Eu/Eu1)cn are low in the phyllic altered facies. (Eu/Eu1)cn in both advanced and silicic facies is low too. In all alteration zones, high field strength elements (HFSE) (e.g. Ti, Zr, Nb) are depleted whereas transition elements (e.g. V, Cr, Co, Ni, Fe) are enriched. Geochemically speaking, trace and rare earth elements behave highly selective in different facies. 相似文献
16.
通过对陈耳金矿床两类不同构造-岩相带微量元素分布特征分析,发现元素特别是成矿元素Au的含量从片理化带→破碎蚀变带→石英脉逐渐增强。构造-岩相带内变形岩石的石英Rf/φ法有限应变测量表明,片理化带应变强度最大,破碎蚀变带应变强度小,应变集中在韧性剪切带边部的片理化带内。R型聚类分析表明Au与Ag、Cu、Pb及Zn的相关系数远大于Au与Ni、Co元素的相关系数,甚至接近于1。研究认为:破碎蚀变带内由于应变软化导致脆性裂隙大量发育,易于成矿流体的迁入与淀积而强富集;片理化带由于应变集中,造成成矿流体的迁出而弱富集。韧性剪切带脆-韧性变形转换不仅控制了矿体就位空间,同时也决定着元素迁移的方向。 相似文献
17.
CAO Yangtong LIU Chenglin XUAN Zhiqiang JIAO Pengcheng CHEN Yongzhi WANG Chunlian 《《地质学报》英文版》2011,85(6):1448-1465
A large-scale evaporate series is developed in Paleogene-Neogene strata in the Kuqa basin. The series is composed mainly of evaporate with thin beds of clastic rock (mainly mudstone and siltstone). In grayish white medium- and coarse-grained sandstone in Miocene strata, the formation of copper minerals is in close connection with brine. In joint planes, which are developed in vertical strata, are filled with gypsum. Gypsum and copper-mineralized sandstone contains enormous copper minerals, mainly atacamite. According to the SEM analysis for salt rock, gypsum rock, limestone, grayish green siltstone, grayish white medium-coarse-grained sandstone, some minerals are composed of metallic elements including Au, Ag, Cu, Zn, Pb, Co, Ni and U etc., in which Au occurs in a native form, Cu occurs in a native form or as atacamite in salt rock, gypsum rock and limestone, Ag occurs as silver sulfide in gypsum, and Zn, Pb, Co, Ni, U occur as compounds along with the above metallic ions in evaporate or clastic rock. From SEM images, we can see that metallic elements or their compounds (oxides or sulfides) “take root” as grains in salt or gypsum crystals, which belong to primary chemical sedimentation along with evaporate, while some grains “float” on surface of salt or gypsum. In the former case, mineral grains were formed together with salt (gypsum) crystals; while in the latter case, minerals were enriched from internal metallic ions (Paleogene evaporate samples) or external metallic ions (Neogene gypsum samples) in the late stage of evaporate formation. The metallic ions in Paleogene evaporate samples might originate from weathered or denudated materials in the south Tianshan Mountains. The metallic ions in the Neogene evaporate samples might be from metal-bearing brine, which migrated upward to surface along fractures and leached into evaporate (gypsum). Occurrence of metallic minerals and their compounds (elementary substance) in Paleogene evaporate proves that diversified metallic minerals exist in evaporate. The source of metallic ions in the Neogene evaporate series shows that evaporate could provide materials for late-stage metallic mineralization. 相似文献
18.
Zhekai Zhou Kotaro Yonezu Akira Imai Thomas Tindell Huan Li Jillian Aira Gabo-Ratio 《Resource Geology》2022,72(1):e12279
The Woxi Au-Sb-W deposit is one of the largest polymetallic ore deposits in the Xuefengshan Range, southern China, hosted in low-grade metamorphosed Neoproterozoic volcaniclastic rocks. The orebodies of the deposit are predominantly composed of banded quartz veins, which are strictly controlled by bedding and faults. Petrographic observations and geochemical results are reported on the occurrence of Au and properties of the ore-forming processes for different stages in the deposit. The veins extend vertically up to 2 km without obvious vertical metal zoning. The ore-forming process can be subdivided into four mineralization stages: Pre-ore stage; Early stage (scheelite-quartz stage); Middle stage (pyrite-stibnite-quartz stage); and Late stage (stibnite-quartz sage). Four types of pyrite (Py0, Py1, Py2, and Py3) were identified in the ores and host-rock: Py0 occurs as euhedral grains with voids in the core, ranging in size from 50 to 100 μm and formed mainly in the Pre-ore stage and Early stage; Py1 occurs as subhedral grains. Small grains (around 10 μm) of Py1 form irregularly shaped clusters of variable size ranging from tens to hundreds of μm and mainly formed in the Middle stage; Euhedral-subhedral fine-grained Py2 formed in the Late stage; Minor subhedral fine-grained Py3 was deposited in the Late-stage. Stibnite is widely distributed in the Middle and Late stage ore veins. No systemic difference was recognized in mineralogical features among stibnite formed in different stages. In addition to native gold, the lattice bound Au+1 widely exists in Py1 and Py2 in the deposit, and widespread Py1 is considered as the main Au-bearing mineral with the highest Au contents. Most elements (such as Co, Ni, Cu, As, Sb, Ba, and Pb) are considered to occur as solid solution within the crystal lattice and/or invisible nanoparticles in sulfides minerals. The Co/Ni ratio of most pyrite is lower than 1, suggesting that the metals in the ore-forming fluid are sourced from sedimentary rocks. The coupled behavior between Au and As; Au and Sb suggests that the substitution of As and Sb in pyrite can enhance the incorporation of Au. Variation of trace elements in pyrites of different stages suggests some information on the mineralization processes: Large ion lithophile elements (such as Ba and Pb) are enriched in Py0 indicating that water-rock reaction occurred in the Early stage; Fine-grained Py1 with a heterogeneous distribution of elements suggests fast crystallization of pyrite in the Middle stage. 相似文献
19.
胶东西北部仓上金矿床上盘围岩蚀变和黄铁矿标型特征研究 总被引：1，自引：1，他引：0
上盘围岩是矿床钻探过程中首先遇到的围岩,研究其蚀变特征具有重要的找矿指导意义。对胶东西北部露天开采的仓上金矿床的详细研究表明,上盘围岩蚀变以绿泥石化为主,蚀变分带自远矿端到近矿端依次为方解石绿泥石化带、赤铁矿绿泥石化带、绿帘石化带和绢英岩化带。黄铁矿的形态、成分和热电性标型显示,成矿过程中上盘围岩提供了丰富的Ｆｅ、Ｃｏ、Ｎｉ、Ｃｕ、Ｐｂ、Ｚｎ和Ａｕ、Ｐｔ等。上盘围岩的近矿标志是绢英岩化增强,黄铁矿的｛１００｝＋｛２１０｝增多,Ｓ、Ｃｕ、Ｐｂ、Ｚｎ和Ａｕ、Ｐｔ增高,Ｓ／Ｆｅ离子比和ｗ（Ｃｏ＋Ｎｉ）／ｗ（Ａｓ＋Ｓｂ）降低,Ｐ型黄铁矿出现率增高,蚀变岩的金含量增高。 相似文献
20.
Sarah-Jane Barnes R. A. Cox M. L. Zientek 《Contributions to Mineralogy and Petrology》2006,152(2):187-200
Concentrations of Ag, Au, Cd, Co, Re, Zn and Platinum-group elements (PGE) have been determined in sulfide minerals from zoned sulfide droplets of the Noril’sk 1 Medvezky Creek Mine. The aims of the study were; to establish whether these elements are located in the major sulfide minerals (pentlandite, pyrrhotite, chalcopyrite and cubanite), to establish whether the elements show a preference for a particular sulfide mineral and to investigate the model, which suggests that the zonation in the droplets is caused by the crystal fractionation of monosulfide solid solution (mss). Nickel, Cu, Ag, Re, Os, Ir, Ru, Rh and Pd, were found to be largely located in the major sulfide minerals. In contrast, less than 25% of the Au, Cd, Pt and Zn in the rock was found to be present in these sulfides. Osmium, Ir, Ru, Rh and Re were found to be concentrated in pyrrhotite and pentlandite. Palladium and Co was found to be concentrated in pentlandite. Silver, Cd and Zn concentrations are highest in chalcopyrite and cubanite. Gold and platinum showed no preference for any of the major sulfide minerals. The enrichment of Os, Ir, Ru, Rh and Re in pyrrhotite and pentlandite (exsolution products of mss) and the low levels of these elements in the cubanite and chalcopyrite (exsolution products of intermediate solid solution, iss) support the mss crystal fractionation model, because Os, Ir, Ru, Rh and Re are compatible with mss. The enrichment of Ag, Cd and Zn in chalcopyrite and cubanite also supports the mss fractionation model these minerals are derived from the fractionated liquid and these elements are incompatible with mss and thus should be enriched in the fractionated liquid. Gold and Pt do not partition into either iss or mss and become sufficiently enriched in the final fractionated liquid to crystallize among the iss and mss grains as tellurides, bismithides and alloys. During pentlandite exsolution Pd appears to have diffused from the Cu-rich portion of the droplet into pentlandite. 相似文献