共查询到20条相似文献，搜索用时 125 毫秒
1.
2.
徐宿地区新元古代辉绿岩床的地球化学特征 总被引：13，自引：1，他引：12
同位素测年数据显示,徐宿地区的辉绿岩床是震旦纪早期和震旦纪晚期两次侵入的 产物。岩床多呈板状或楔状,为超浅成—浅成侵入体,其化学成分以高SiO2、CaO和低Al 2O3、MgO及(K2O+Na2O)为特征,属大陆拉斑玄武岩系列。稀土元素配分模式为轻 稀土富集型,但稀土元素分馏并不强烈。Rb、K、La等不相容元素富集,而Nb、Sr亏损明显 。δ18O值在6.63‰～9.93‰之间,多数>8‰。研究表明,该区基性岩浆来源于过 渡型地幔,主要通过部分熔融方式形成,在岩浆上侵过程中遭到陆壳或花岗质岩石的混染。 相似文献
3.
Geochemical and geochronological studies were conducted on basalts and laterites from the Bolaven Plateau in southern Laos in order to evaluate the mobility and mineralization of REE, Y and Sc during laterization. The basalts are classified into three categories: (i) small volumetric alkali basalt (eruption age: 15.7 Ma), large volumetric olivine tholeiite (1.2 Ma) and quartz tholeiite with olivine tholeiite (younger than 0.5 ± 0.2 Ma). Formation of REE minerals during laterization result in mobilization and fractionation of REE and Y in laterite profiles. Occurrence of florencite‐(Ce) in a laterite profile derived from alkali basalt immobilizes REE (particularly LREE) and this leads the laterites to be enriched in LREE relative to the parent basalt. Few positive Ce anomalies in this profile suggest that florencite‐(Ce) [(Ce)Al3(PO4)2(OH)2] formation was followed by CeO2 precipitation due to the change of redox condition. In tholeiite‐derived laterite profiles, florencite is not recognized and REE and Y tend to be depleted relative to the parent basalts with positive Ce anomalies. This is interpreted as scavenging REE3+ except for Ce4+ from the laterite profile in oxidizing conditions. Sc behaves similarly to Fe during laterization and it is more abundant in the tholeiitic laterite than that in the alkali basaltic laterite. Results of sequential extraction indicate that REE of the alkali basaltic laterite are contained in residual phase, which is dominantly florencite‐(Ce), but they are rarely present in ion‐adsorption phase. It is concluded that basaltic laterites have a low potential of REE resource in terms of low REE contents and a difficulty in REE extraction. 相似文献
4.
The Role of Pressure in Producing Compositional Diversity in Intraplate Basaltic Magmas 总被引：3，自引：0，他引：3
Whitaker M. L.; Nekvasil H.; Lindsley D. H.; Difrancesco N. J. 《Journal of Petrology》2007,48(2):365-393
Basaltic magmas found in intraplate suites appear to followmore than one differentiation trend. Many ocean island suitesfollow the ocean island tholeiitic trend, with the basalts differentiatingfrom olivine tholeiite through basaltic andesite, andesite,and dacite to sodic rhyolite. Many continental intraplate magmaticregimes, such as those of the Snake River Plain and the plutonicsequences associated with massif anorthosites, follow the potassicsilica-saturated alkalic trend, in which basalt differentiatesfrom olivine tholeiite through ferrobasalt (jotunite or ferrodiorite),Fe-rich intermediate rocks (trachybasalt or monzonite), andtrachyte (syenite) to potassic rhyolites and granites. Crystallizationexperiments on an olivine tholeiite from the Snake River Plainshow that the basaltic portions of the ocean island tholeiitictrend and the potassic silica-saturated alkalic trend (whichleads to strong alkali, P, Ti, and Fe enrichment and silicadepletion) can arise from the same ‘dry’ tholeiiticparental magma. These compositional differences are inducedby changes in phase equilibria as a function of pressure, withthe ocean island tholeiitic series arising from crystal–liquiddifferentiation at low pressure and the potassic silica-saturatedalkalic series arising via differentiation at elevated pressures. KEY WORDS: tholeiite differentiation; experimental petrology; phase equilibria; ferrodiorite; ferrobasalt 相似文献
5.
High-alumina basalts and basic andesites, which represent the most “primitive” magma types of the Cenozoic andesitic series of Sardinia, show a spatial chemical zonation with respect to REE. The basaltic rocks from the northern and south-central part of the island have REE patterns typical of calc-alkaline rocks with an enrichment of light REE and fractionation of heavy REE. In contrast, those from the southernmost part have a pattern similar to typical continental tholeiites with only a small light-REE enrichment and unfractionated heavy REE.The present data suggest that basaltic rocks may be formed by anatexis of upper-mantle material with mineral assemblages containing either garnet (calc-alkaline rocks) or spinel (rocks of tholeiitic affinities). The presence of garnet or spinel could merely reflect mineral phase transformation and indicates a different depth of fusion for the various types of basaltic rocks with those of tholeiitic affinities originating at a shallower depth than the calcalkaline rocks. The REE data are consistent with the generation of the basaltic rocks by partial melting of mantle peridotite overlying a subducted plate. 相似文献
6.
长白山区二道白河流域早更新世玄武质熔岩的成因 总被引：2，自引：1，他引：1
采用岩石化学和同位素分析方法,研究了二道白河流域早更新世玄武质熔岩的成因。玄武质熔岩由钠质拉斑玄武岩和钾质粗面玄武岩、玄武质粗面安山岩组成。它们的REE分配形式比较相近,表明它们来自共同的源区。Sr、Nd、Pb同位素示踪表明,二道白河流域早更新世玄武质熔岩岩浆源区接近于似原始地幔。它们的Mg#=100Mg O/(Mg O+Fe O)低于中国东部新生代玄武岩原始岩浆的Mg#(60~68),Ni(27.76×10-6~200.6×10-6)低于原始地幔,Rb/Sr(0.05~0.09)、Ba/Rb(15.64~264)高于原始地幔,说明这些岩石不是源自原始地幔。玄武质熔岩的DI变化于42~67,具有高Ca、高Sr、Eu正异常,微量元素图解显示玄武岩保留部分熔融趋势,粗面玄武岩、玄武质粗安岩具有结晶分异趋势,岩浆上升过程中发生了不同程度的地壳混染作用。玄武质熔岩的Nb/Ta之比为14.8~15.8,与勘察加半岛深俯冲带火山类似。Nb/Ta-(Na2O-K2O)关系图解显示研究区玄武质岩浆的形成与俯冲板片的部分熔融有关。 相似文献
7.
在天池火山造锥阶段,长白山火山区玄武质火山活动频繁。文章在野外调查的基础上,通过年代学及地球化学研究,对其活动期次进行划分,并探讨其岩浆来源与演化。天池火山造锥阶段的玄武质火山岩主要呈火山渣锥或小型河谷玄武岩形式分布,其形成可划分为两期:一期为老房子小山期,形成时限为0.87~0.54 Ma,属碱性岩石系列;另一期为老虎洞期,形成时限为0.34~0.1 Ma,属碱性岩石系列和拉斑岩石系列。地球化学特征显示,碱性系列玄武岩具高Al、Ti、K、P和低Mg特征,拉斑系列玄武岩具高Mg、富Fe、Ca和低Na特征;二者稀土和微量特征较为一致,稀土元素配分曲线呈右倾型,略显正铕异常,并富集Ba、K、Pb、P、Ti,亏损Th、U、Sr,但拉斑系列玄武岩的稀土元素和微量元素含量及轻重稀土分馏强度均低于碱性系列。天池火山造锥阶段形成的玄武质火山岩均来源于进化岩浆,具有同源特征,经历了一致或相似的演化过程,岩浆房赋存位置相当于上地幔—下地壳的过渡部位,结晶分异岩浆作用显著、地壳混染作用微弱,其成分变化受控于多期次结晶分异作用和早期结晶再循环的岩浆作用过程。 相似文献
8.
Xueyuan Yu 《中国地球化学学报》1985,4(2):150-158
The Niutoushan basaltic cone, consisting of subalkali (quartz-tholeiite and olivine-tholeiite) and alkali basalts, is Late Tertiary in age. Its major characteristics are generalized as follows:
- Both early subalkali and late alkali bali basalts are formed under the same geological environment.
- The continuity in chemical composition from subalkali to alkali and the low FeO/MgO in alkali basalts show that they are the products of cognate magmatic differentiation.
- The change from low REE abundance and weak enrichment of LREE in subalkali to high REE abundance and strong enrichment of LREE in alkali basalts indicates obvious REE enrichment and fractionation during magmatic differentiation. Weak positive Eu anomalies in the REE patterns are indicative of their formation under low oxygen fugacity conditions.
- According to the calculated values, 70–75% of the primary olivine tholeiitic magma had been separated as subalkaline basaltic magma, the rest residual magma became alkaline basaltic magma. This result is consistent to the field observation that the outcrop area of subalkali basalts is four times as much as that of alkali basalts.
- The basaltic rocks of Niutoushan show an S-type distribution straddling the thermal barrier on Ol′-Ne′-Qu′ diagram and an evolution tendency for Ne to increase with increasing FeO/MgO. This is in agreement with the melting experimental data on olivine basalts at 10–20 kb.
- Mantle-derived inclusions (spinel lherzolite) in this area occur in both alkali olivine basalts and olivine tholeiites. The latter is of extremely rare occurrence. The formation temperature and pressure of the inclusions in alkalibasalts and olivine tholeiites have been calculated. The results show that the alkaline basaltic magma was separated from the subalkaline basaltic magma at about 20 kb.
9.
湘东北中生代基性岩脉岩石地球化学及构造意义 总被引：8，自引：1，他引：8
湘东北中生代发育以辉绿岩类和煌斑岩类为代表的基性岩脉,属陆内拉斑玄武岩系,部分煌斑岩属于碱性系列。岩石富集LREE,δEu负异常不明显,其形成主要受软流圈地幔部分熔融作用制约。煌斑岩类微量元素总体上具有洋岛玄武岩(OIB)岩浆源区特征,富集Nd、P、Cs而K、Rb、Sr、U、Th等富集程度不明显,Ta、Nb略有富集。辉绿岩类表现出Ta、Nb、Ti亏损,但LILE并不富集,反映地壳混染程度的增强。基性岩脉形成于陆内拉张带的构造环境,岩浆活动未受到中生代大洋板块俯冲的影响。基性岩脉在时、空及物质组成上与湘东南玄武质岩石基本一致,属于整个湘东南岩石圈拉张-减薄带的一部分。 相似文献
10.
白银厂矿田玄武岩地球化学特征及其形成地质环境 总被引：3，自引：0，他引：3
白银厂矿田玄武岩主要由玄武岩和碱性玄武岩组成 ,其中玄武岩属于钙碱性系列和拉斑系列 ,碱性玄武岩属于钾质碱性玄武岩系列和钠质碱性玄武岩系列。相对于N -MORB ,本区钙碱性系列和拉斑系列玄武岩明显富集Ba、Rb、Th、U ,而亏损Ti;碱性系列玄武岩高度富集K、Ba、Rb、Th、U ,而Ti、Zr、Ce相对亏损 ,表明该区玄武岩的形成与板块俯冲作用有关。钙碱性玄武岩系列和拉斑玄武岩系列玄武岩具有低的REE含量和亏损的LREE配分型式 ,表明它是由LREE亏损和HREE略有富集的地幔部分熔融形成 ;碱性系列玄武岩的REE含量和 (La/Yb) N 比值高 ,LREE和HREE的分馏程度较高 ,表明其形成于演化的岩浆 ,可能来自于富集LREE的地幔源区或地幔橄榄岩较低程度的熔融。痕量元素地球化学特征表明 ,本区玄武岩应是与板块俯冲作用有关的地幔部分熔融形成 ,成岩环境为火山弧环境 ,是岛弧向成熟岛弧转化过程中的产物。 相似文献
11.
冀北赤城退变榴辉岩的岩石地球化学及原岩恢复 总被引：3，自引：0，他引：3
冀北赤城退变榴辉岩主元素特征显示所有样品均属拉斑玄武岩系列,可分出三种不同的REE配分型式。在MORB标准化微量元素配分图中,LREE亏损型与REE平坦型样品的HFSE与MORB相似,LREE富集型样品则具有较高的Zr、Hf和Y值,Nb和Ta明显富集,显示出陆壳物质混染的特征。这些特征表明,冀北赤城退变榴辉岩的原岩可能为兼具洋中脊和岛孤地球化学属性的洋壳拉斑玄武岩类,在后期俯冲消减过程中,发生榴辉岩相高压变质作用,并混入了部分陆壳物质。 相似文献
12.
新田宁远道县一带玄武质火山岩的地球化学研究 总被引：17，自引：1，他引：17
本文阐述了该区玄武质火山岩及其中包体的微量元素及同位素地球化学特征,并对玄武岩浆成因与演化进行了探讨。玄武岩与其中的包体具有不同的过渡金属元素分配型式。二辉橄榄岩包体具亏损地幔岩性质。玄武岩稀土元素的配分特点与世界上典型的大陆裂谷型玄武岩相似。锶、铅、氧同位素的初步研究结果对岩浆的幔源性质及所经受的同化混染作用提供了一些线索。 相似文献
13.
大兴安岭吉峰科马提岩地质地球化学特征 总被引：3，自引：0，他引：3
野外地质调查和室内岩石学研究表明,大兴安岭北段吉峰林场一带变质超基性岩为具有典型鬣刺结构的科马提岩。科马提岩系列由橄榄质科马提岩、玄武质科马提岩及拉斑玄武岩、辉长岩等岩石组成。科马提岩显示了从超镁铁质到镁铁质地球化学趋势,拉斑玄武岩具有从富镁到富铁的趋势,而上覆长英质火山岩则遵循钙-碱趋势。科马提岩稀土配分型式为类似于南非超镁铁质科马提岩的平坦型或轻稀土略富集而重稀土平坦型。科马提岩系列8件样品的Sm-Nd同位素数据构成一条相关性较好的等时线,等时线年龄为1727Ma±74.7Ma,INd=0.510725±0.0000798,εNd(t)=6.94±1.56,表明科马提岩形成于中元古代早期,其源区为亏损的软流圈地幔。这一地壳增生事件可能与松嫩地块从西伯利亚地台南缘裂解有关。 相似文献
14.
S.A. Drury 《Precambrian Research》1978,7(3):237-257
Seventeen rocks from the Lewisian Gneiss of the Inner Hebrides of Scotland, which represent three distinct lithological types at granulite to greenschist facies of metamorphism show rare-earth element patterns which seem not to have been disturbed by their complex metamorphic history. Some indication of their origin can be obtained by simple geochemical models.Three tonalitic pyroxene gneisses are characterized by: (1) light REE enrichment and heavy REE depletion; (2) low total REE contents; (3) moderate Eu enrichment. Their REE chemistry can be approximated by a model involving 10% partial melting of various garnet-bearing basaltic source materials. Alternatively, they may be some form of crystal cumulate, preserving their original anhydrous mineralogy, representing 30% crystallization of a parent tonalitic magma.Three tonalitic to granodioritic hornblende-biotite gneisses are characterized by: (1) light REE enrichment and heavy REE depletion; (2) significantly higher total REE contents than the pyroxene gneisses; (3) moderate Eu depletion. Their REE patterns can be approximated by a residual silicic melt in a model involving 30% fractional crystallization of solids with the modal mineralogy of the pyroxene gneisses or 40% removal of pure anorthosite from a parent dacitic magma.Two strongly metasomatised diopside-actinolite gneisses and one highly sheared epidote-chlorite gneiss have REE patterns which are not significantly different from the hornblende-biotite gneisses which were their precursors before metasomatism and late greenschist-facies shearing. This suggests that strong alteration has not enciphered the REE systematics of the gneisses.Basic gneisses of quartz tholeiite composition occurring as early dykes, which shared the same metamorphic history as the tonalitic to granodioritic gneisses, are characterised by: (1) slight enrichment in light REE relative to heavy REE; (2) variable total REE contents; (3) little difference between granulite and amphibolite facies types. Their REE patterns can be matched by models involving 5–15% partial melting of ultrabasic mantle with 3 times chondritic REE abundances, leaving a residue of olivine and orthopyroxene. 相似文献
15.
Nickel content of basaltic magmas: identification of primary magmas and a measure of the degree of olivine fractionation 总被引：4，自引：0，他引：4
Hiroaki Sato 《Lithos》1977,10(2):113-120
Available NiO analyses of olivine in peridotites of probable mantle origin are consistent in giving values around 0.40 weight per cent. Assuming that basaltic magma forming from the mantle was in equilibrium with such peridotitic olivine, the NiO content of primary basaltic magmas is estimated to be about 0.030–0.050 weight per cent. The fractionation behaviour of nickel in basaltic magma due to the crystallization of olivine has been calculated using constant NiMg and FeMg exchange partition coefficients between olivine and magma. It is shown that the NiO content of both magma and olivine decreases by 50 per cent after fractional crystallization of 6–12 per cent of olivine. The nickel distribution in some basaltic rocks and olivines is examined in the light of these results, and it is suggested that basaltic magmas, such as some of the ocean-floor basalt and the Hawaiian tholeiite and alkali basalts, represent primary magmas from mantle peridotites. 相似文献
16.
Geochemistry of eocene calc-alkaline volcanic rocks from the Kastamonu area,Northern Turkey 总被引：294，自引：3，他引：294
Analytical data for Sr, Rb, Cs, Ba, Pb, rare earth elements, Y, Th, U, Zr, Hf, Sn, Nb, Mo, Ni, Co, V, Cr, Sc, Cu and major elements are reported for eocene volcanic rocks cropping out in the Kastamonu area, Pontic chain of Northern Turkey. SiO2% versus K2O% relationship shows that the analyzed samples belong to two major groups: the basaltic andesitic and the andesitic ones. High-K basaltic andesites and low-K andesites occur too. Although emplaced on continental type basement (the North Anatolian Crystalline Swell), the Pontic eocene volcanics show elemental abundances closely comparable with typical island arc calc-alkaline suites, e.g. low SiO2% range, low to moderate K2O% and large cations (Cs, Rb, Sr, Ba, Pb) contents and REE patterns with fractionated light and almost flat heavy REE patterns. REE and highly charged cations (Th, U, Hf, Sn, Zr) are slightly higher than typical calc-alkaline values. Ferromagnesian elements show variable values. Within the basaltic andesite group the increase of K%, large cations, REE, La/Yb ratio and high valency cations and the decrease of ferromagnesian element abundances with increasing SiO2% content indicate that the rock types making up this group developed by crystalliquid fractionation of olivine and clinopyroxene from a basic parent magma. Trace element concentration suggest that the andesite group was not derived by crystal-liquid fractionation processes from the basaltic andesites, but could represent a distinct group of rocks derived from a different parent magma. 相似文献
17.
Musa Alpaslan Taner Eki&#x;ci&#x; Nazmi&#x; Otlu Durmu Boztug Abi&#x;di&#x;n Temel 《Geological Journal》2005,40(2):193-214
The Miocene Karamağara volcanics (KMV) crop out in the Saraykent region (Yozgat) of Central Anatolia. The KMV include four principal magmatic components based on their petrography and compositional features: basaltic andesites (KMB); enclaves (KME); andesites (KMA); and dacites (KMD). Rounded and ellipsoidal enclaves occur in the andesites, ranging in diameter from a few millimetres to ten centimetres. A non‐cognate origin for the enclaves is suggested due to their mineralogical dissimilarity to the enclosing andesites. The enclaves range in composition from basaltic andesite to andesite. Major and trace element data and primitive mantle‐normalized rare‐earth element (REE) patterns of the KMV exhibit the effects of fractional crystallization on the evolution of the KME which are the product of mantle‐derived magma. The KMA contain a wide variety of phenocrysts, including plagioclase, clinopyroxene, orthopyroxene, hornblende and opaque minerals. Comparison of textures indicates that many of the hornblende phenocrysts within the KMA were derived from basaltic andesites (KMB) and are not primary crystallization products of the KMA. Evidence of disequilibrium in the hybrid andesite includes the presence of reacted hornblendes, clinopyroxene mantled by orthopyroxene and vice versa, and sieve‐texture and inclusion zones within plagioclase. The KMV exhibit a complex history, including fractional crystallization, magma mixing and mingling processes between mantle and crust‐derived melts. Textural and geochemical characteristics of the enclaves and their hosts require that mantle‐derived basic magma intruded the deep continental crust followed by fractional crystallization and generation of silicic melts from the continental material. Hybridization between basic and silicic melts subsequently occurred in a shallow magma chamber. Modelling of major element geochemistry suggests that the hybrid andesite represents a 62:38 mix of dacite and basaltic andesite. The implication of this process is that calc‐alkaline intermediate volcanic rocks in the Saraykent region represent hybrids resulting from mixing between basic magma derived from the mantle and silicic magma derived from the continental crust. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
18.
南澜沧江结合带火山岩岩浆成因——洋脊洋岛与弧岩浆作用的性质 总被引：10，自引：1，他引：9
在对滇西南昌宁—孟连带石炭—二叠纪火山岩和南澜沧江带二叠—三叠纪火山岩的微量元素和稀土元素研究的基础上,划分了岩浆作用类型和岩浆演化系列,探讨了岩浆源区成分特点。昌宁—孟连带玄武质岩浆的演化主要受部分熔融和分离结晶作用控制;这些岩浆可以划分为３个岩浆演化系列：（１）稀土曲线平坦型的洋脊型拉斑玄武岩浆演化系列,其岩浆起源于亏损型地幔;（２）稀土曲线中等富集型的准洋脊型拉斑玄武岩浆演化系列,其岩浆起源于过渡型地幔;（３）稀土曲线强烈富集型的洋岛型碱性玄武岩浆演化系列,其岩浆起源于富集型地幔。南澜沧江带弧火山岩的岩浆成因主要受分离结晶作用控制,也可以划分为３个岩浆演化系列：（１）二叠纪低钾拉斑—中钾钙碱性岩浆演化系列;（２）中南段的晚三叠世低钾拉斑—中钾钙碱性岩浆演化系列;（３）北段的晚三叠世钾玄岩—高钾钙碱性岩浆演化系列 相似文献
19.
Albert Günter Herrmann Mark J. Potts Doris Knake 《Contributions to Mineralogy and Petrology》1974,44(1):1-16
Analytical data including major elements, the Rare Earths, Ni, Cu, Zn, Rb, and Sr are presented for twenty-three spilites from the Mid-Atlantic Ridge, the Hercynian part of the Variscan geosyncline in Germany, and several localities in Switzerland. Low grade metamorphism (up to approximately 400° C) and spilitization of basaltic rocks apparently do not alter the original Rare Earth element (REE) distributions. This fact permits comparison of the spilites and unaltered tholeiitic basalts from the Mid-Atlantic Ridge. The relative REE distributions thus appear suitable for delineating the original basalt types of spilites formed by metamorphism. The spilites from the Hercynian part of the Variscan geosyncline have a REE distribution pattern which is characteristic of continental tholeiites. It is thus probable that during the formation of this geosyncline the principal magma extruded was of tholeiitic composition and that these rocks were later converted to spilites by metamorphism. 相似文献
20.
The Archean greenstone belts of the Nyanzian System in western Kenya are composed principally of andesite with minor tholeiitic basalt and siliceous volcanics. The Nyanzian tholeiite is an intermediate-K tholeiite with a flat REE pattern. There are two chemically-distinct andesites: a low-K andesite (Andesite I) and a high-K andesite (Andesite II). The REE pattern of the Andesite II is enriched in light REE and depleted in heavy REE relative to Andesite I.Major and trace element calculations indicate an origin for the Nyanzian tholeiite by 35–40% equilibrium melting of a lherzolite source followed by 10% shallow fractional crystallization. Similar calculations best explain Andesite I and Andesite II by 20 and 5% melting, respectively, of an ecologite or garnet amphibolite source of Nyanzian tholeiite composition. The rhyolite may have formed either by 20–30% partial melting of a siliceous granulite or by 20–30% fractional crystallization of a granodiorite parent magma.With respect to total exposure areas, the Nyanzian volcanics have significantly less tholeiite and more Andesite and siliceous volcanics than other Archean greenstone belts. If these abundances are representative, two models are proposed to explain the anomalous abundances of Andesite and siliceous volcanics. The first model involves an Archaen upper mantle with a relatively low geothermal gradient beneath Kenya, while the second model involves a relatively cool mantle plume. Both models inhibit ascent of a significant amount of primary tholeiite to the surface and prevent formation of secondary tholeiite. Other Archean greenstone terranes with higher mantle geotherms or hotter mantle plumes would receive higher proportions of mafic and ultramafic magmas. 相似文献