首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
This work shows the extraction of cesium( Cs~+) and rubidium( Rb~+) from salt lake brine containing potassium( K~+) and magnesium( Mg~(2+)). The results show that 4-tert-butyl-2-( α-methylbenzyl) phenol( t-BAMBP) diluted in sulfonated kerosene( SK) has an excellent extraction effect. Infrared spectroscopic studies indicate that polymerize to form the dimer in the t-BAMBP when Cs~+or Rb~+were extracted. The effects of K~+,Mg~(2+),t-BAMBP concentration,the volume ratio of organic phase to aqueous phase( O/A) and the alkalinity( pH) of aqueous phase were investigated.The K~+and Mg~(2+)should be eliminated through precipitating before the extraction and separation of Cs~+and Rb~+. The optimum extraction conditions of the experimental brine were as follows: 0. 8 mol/L t-BAMBP diluted in SK,pH≥13,a phase ratio of 1: 1,and an extraction contact time of 2 min at room temperature. The optimal extraction yields of Cs~+and Rb~+were as high as 100% and 85. 8%,in addition,8. 76% of K~+was co-extracted. Further work would increase the extraction yield and selectivity of Rb~+and realize the efficient separation of Cs~+and Rb~+from brine.  相似文献   

2.
In this work, problems encountered by tri-butyl phosphate (TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The lithium extraction behavior of N, N-bi-(2-ethylhexyl) acetamide (N523) was investigated, and its defect was analyzed in the view of practical application. The N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used severally. The composition of this mixture extraction system was determined as 20%N523-30%TBP-50% kerosene. The effects of brine acidity, Fe/Li molarity ratio, phase ratio and chloride ion concentration on lithium extraction efficiency were discussed respectively. The operation conditions in single stage extraction were optimized as brine acidity=0.05 mol/L, Fe/Li molarity ratio=1.3 and phase ratio=2. The high concentration of chloride ion in brine was benefit for extraction of lithium. The structure of extracted complex was proposed as (LiFeCl4·nN523·mTBP)·(2-n)N523·(2-m)TBP (m+n=2) by chemical analysis and slope fitting methods. The extraction thermodynamic functions were calculated preliminarily, and the results suggested that the extraction process was an exothermic (ΔH<0) and spontaneous (ΔG<0) reaction, and the degree of disorder increased (ΔS>0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both fundamental theory and practical application.  相似文献   

3.
In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

4.
锂云母、铯榴石等矿物的硫酸盐焙烧浸出,是从中提取锂铷铯钾等碱金属元素的重要步骤,所得硫酸盐浸出液可近似看作Li+,Na+,K+,Rb+,Cs+ // SO42--H2O六元水盐体系;其在浓缩过程呈现复杂的成盐特征,增加了各碱金属元素分离提取的难度,研究其相关水盐体系相图和相平衡性质对理解浸出液中碱金属的分离具有重要的理论指导意义。本文采用Pitzer-Simonson-Clegg超额Gibbs自由能方程和具有内在热力学一致性的CALPHAD方法,构建了Na+,K+,Rb+,Cs+//SO42--H2O五元体系的多温固液相平衡热力学模型。借助该模型:1)实现了对Na2SO4+Rb2SO4+H2O、Na2SO4+Cs2SO4+H2O和K2SO4+Cs2SO4+H2O三元体系的多温溶解度等温线的准确描述,并进一步构建了这些体系在240.15~380.15 K温度范围内的多温相图;2)实现了对K2SO4+Rb2SO4+H2O和Rb2SO4+Cs2SO4+H2O体系中存在的固溶体相—水溶液平衡关系的准确描述,确认了(K,Rb)2SO4连续固溶体、以及(Rb,Cs)2SO4(α)和(Rb,Cs)2SO4(β)间断固溶体存在的合理性;3)预测了上述五元体系中所包含的全部4个四元子体系(Na2SO4+ K2SO4+ Rb2SO4+H2O、Na2SO4 + K2SO4+Cs2SO4+ H2O、Na2SO4+ Rb2SO4+Cs2SO4 + H2O和K2SO4+Rb2SO4+Cs2SO4+ H2O)的相图,明确了四元相图中固溶体的类型及形成区域。然而,模型预测结果与现有四元体系实验数据间存在普遍的不一致性,尤其是固溶体形成区域,但模型预测结果从非实验角度给出了重要参考,对现有实验提出了挑战,未来对这些体系开展更为精细的实验研究非常必要。  相似文献   

5.
The crystal structure of metal borates has been extensively investigated by X-ray and neutron diffraction,but,the structure of aqueous polyborate solutions are still largely unknown.Over the last decade,our group has focused on studying the structure of complex aqueous polyborate solutions of Li,Na,K,Rb,Cs,and Mg using synchrotron radiation X-ray scattering(XRS),EXAFS,Raman,NMR,and DFT,as well as determining the density,conductivity and pH of such solutions.Polyborate species distributions were calculated using pH measurements,and the main species in the solution have been confirmed by NMR and Raman spectra.For alkali-metal metaborates,the dominant species is always B(OH)-4in a wide range of concentration,while the presence of others species is negligible.For alkali metal tetraborates,when concentration is in the extreme low range,only B(OH)3 and B(OH)-4 are present in these solutions.As the total boron concentration increases,B(OH)3 and B(OH)-4 polycondensated to form more complex oligomers.Of them,while B4O5(OH)2-4 in the tetraborate solutions is the main species,B(OH)3,B(OH)-4,and B3O3(OH)-4 are minor species,and B3O3(OH)2-5 and B5O6OH)-4 are present only in negligible amounts.As solution continues to concentrate,B4O5(OH)2-4 eventually becomes the dominant species,which is consistent with the congruent compound M2B4O7·nH2O(M=Li,Na,K,Rb,Cs) in the system M2O-B2O3-H2O(M=Li,Na,K,Rb,Cs).For alkali metal pentaborates,B(OH)3 and B(OH)-4 are the main species at low concentrations.The species distribution,Raman and NMR spectroscopy results verified that the dominant species in concentrated pentaborate solutions with Li and Na is pentaborate B5O6OH)-4,but it is surprising that the main species with K,Rb,and Cs is always the triborate monoanion B3O3(OH)-4.Although all M[B5O6OH)4]·nH2O(M=Li,Na,K,Rb,Cs) are all congruent compounds in the system M2O-B2O3-H2O(M=Li,Na,K,Rb,Cs) ,the main species in aqueous solutions are quite different because of various cation hydration distance(d),hydration number(CN),and configuration,especially charge(Z).For bivalent Mg2+,three borate minerals,namely,Inderite(2MgO·3B2O3·15H2O),Hungchaoite(MgO·2B2O3·9H2O),and Mcallisterite(MgO·3B2O3·7.5H2O),exist in the system MgO-B2O3-H2O at 298K.Inderite is a congruent compound,but Hungchaoite and Mcallisterite are incongruent compounds.The species distribution and Raman spectra demonstrat that the predominant species in all the solutions with magnesium borates is bivalent triborate B3O3(OH)2-5,while the subordinate species are B(OH)-4 at a low B2O3/MgO ratio and B(OH)3at a high B2O3/MgO ratio,and the other anions are negligible,as the high Z of the borate anion must match that of Mg2+.The disappearance of divalent B4O5(OH)2-4 is in agreement with its incongruent nature.The DFT and XRS results showed that tetrahedral Li(H2O)+4(d=0.20 nm,CN=4),octahedral Na(H2O)6+(d=0.236 nm,CN=6),and Mg(H2O)2+6(d=0.210 nm,CN=6) in the first hydration shell belong to Platonic polyhedra.However,K(H2O)+8(d=0.28 nm,CN=8,XRS and DFT),Rb(H2O)+8(d=0.293 nm,CN=7.7-8.2,EXAFS),and Cs(H2O)+8(d=0.320-0.326 nm,CN=7.6-7.9,EXAFS) are inclined Voronoi polyhedra.Therefore,the effects of cation Z and d on the structure of polyborates in aqueous solutions are deterministic,while the effect of hydrated-cation symmetry is secondary.Their hydrolysis order was:Mg＞Li＞Na＞K＞Rb＞Cs,in step with hydration power.Among them,Mg2+ and Li+have a strong tendency towards hydrolysis,but Na+ scarcely hydrolyzes,especially Rb+ and Cs+ have a little protonation.X-ray scattering of aqueous alkaline sodium borohydride solutions confirmed that dihydrogen bonds exist in an aqueous solution.The four distinct features of dihydrogen bonds in aqueous solution-unidirectionality,divaricativity,multicentricity,and multidentativity have been also described here in brief.  相似文献   

6.
The carbon isotopic composition (δ13C) of tree rings was used to assess changes in intrinsic water-use efficiency (Wi) to increasing atmospheric CO2 and climate change during the period of 1891–2003. Five Qinghai spruce (Picea crassifolia) stands were selected in the Qilian Mountains, growing along a precipitation gradient. All five δ13C were correlated to each other, but two sites (DDS and CLS), which are far from the main body of the mountains, show relative weak connections to other sites. Although trees at all sites had improved their Wi in response to increasing atmospheric CO2 concentration, spruce growing in the regions far away from the main body of the mountains were less sensitive to improved Wi than those of other sites. Based on the correlation between carbon isotope discrimination (Δ) and Palmer Drought Severity Index (PDSI), the drought history covering the period of 1891–2003 was reconstructed in the study region. The two most severe drought epochs of the late 1920s and the last decade were caused by reduced precipitation and climate warming, respectively. Our results will be useful in assessing any further spatial climate-related bioclimatic information.  相似文献   

7.
四苯硼钠—季铵盐质量滴定法分析钾含量研究   总被引：1，自引：1，他引：0       下载免费PDF全文
依据四苯硼钠—季铵盐容量法滴定K+离子的原理,采用质量滴定法,考察了滴定速度、松节油加入量对四苯硼钠与季铵盐反应的影响及共存离子(包括Li+、Mg2+、Ca2+、SO2-4、B4O2-7、CO2-3)对K+含量测定结果的影响。当测定K+离子含量在5～15 mg范围内,松节油最佳加入量为25滴,分析误差< 0.3%。  相似文献   

8.
Based on monitored data from 840 samples, we assessed the spatial and temporal variability of groundwater salinization in the Tarim River lower reaches combining classical statistics and geostatistics. Results show that total dissolved solids (TDS) is significantly correlated with other related ions, such as Na+, Mg2+, Ca2+, Cl? and K+. TDS and underground water level have characteristics of spatial autocorrelation, both of which present the isotropic characteristic and conform to the spherical model in each year from 2001–2009. TDS is basically greater than 1 g/L but less than 2 g/L in the Tarim River lower reaches, which indicates that salt stagnation pollution is more serious. The most serious salinization (3 g/L < TDS ≤ 35 g/L) contaminated area is mainly in the middle and lower part of the study area.  相似文献   

9.
Quality-controlled and serially complete daily air temperature data are essential to evaluating and modelling the influences of climate change on the permafrost in cold regions. Due to malfunctions and location changes of observing stations, temporal gaps (i.e., missing data) are common in collected datasets. The objective of this study was to assess the efficacy of Kriging spatial interpolation for estimating missing data to fill the temporal gaps in daily air temperature data in northeast China. A cross-validation experiment was conducted. Daily air temperature series from 1960 to 2012 at each station were estimated by using the universal Kriging (UK) and Kriging with an external drift (KED), as appropriate, as if all the observations at a given station were completely missing. The temporal and spatial variation patterns of estimation uncertainties were also checked. Results showed that Kriging spatial interpolation was generally desirable for estimating missing data in daily air temperature, and in this study KED performed slightly better than UK. At most stations the correlation coefficients (R2) between the observed and estimated daily series were >0.98, and root mean square errors (RMSEs) of the estimated daily mean (Tmean), maximum (Tmax), and minimum (Tmin) of air temperature were <3℃. However, the estimation quality was strongly affected by seasonality and had spatial variation. In general, estimation uncertainties were small in summer and large in winter. On average, the RMSE in winter was approximately 1℃ higher than that in summer. In addition, estimation uncertainties in mountainous areas with complex terrain were significantly larger than those in plain areas.  相似文献   

10.
Acetylcholinesterase (AChE) plays an important role in enzyme-based detection of pesticides in the environment. In this paper, AChE from the Triton X-100 extract of brain tissues of Oreochromis aurea was purified by (NH4)2SO4 fractional precipitation, Sephadex G-100 gel filtration, and DEAE-cellulose ion exchange chromatography. Certain biochemical characterizations of the purified enzyme and inhibition of pesticides on the enzyme were also studied. The specific activity of this purified enzyme was 20.628 U/mg protein, fold of purification was 139, and recovery was 22.1%. The optimal temperature of this enzyme was between 35–40 °C, and optimal pH was between 7.5–8.0. The Michaelis constant (Km) for acetylthiocholine iodide was 0.183 mmol/L. The enzyme activity was inhibited by excess substrate, and optimal substrate concentration was 6 mmol/L. Four pesticides (dichlorvos, phoxim, triazophos, and methomyl) exhibited strong inhibitions on this enzyme with IC50 less than 5 μg/mL. This study suggests that Oreochromis aurea (tilapia) could be a good enzyme source for pesticide monitoring in water environments.  相似文献   

11.
内蒙古西部地区盐湖水化学特征   总被引：3，自引：1，他引：2       下载免费PDF全文
2008年9~10月和2009年9月对内蒙古西部地区14个盐湖进行了考察、采样和分析。研究发现,本区盐湖卤水主要离子含量顺序为Na+>Cl->SO2-4>Mg2+>K+,次要离子为Ca2+ >HCO-3>CO2-3,微量元素为B2O3>Br->Li+。Na+的分布特征为东部高,北部中等,西南部偏低;而Cl-为东高西低;K+大致为南高北低;Mg2+为中部高,西部低,北部与南部中等。SO2-4、 Ca2+和CO2-3的区域分布特征均不明显;微量元素Li+ 、Br-、B2O3含量虽局部(两大沙漠连接带)有所富集,但绝对含量不高。对天然盐湖和人工采盐池的卤水进行了对比。采盐池中卤水因为蒸发强烈,离子浓度显著高于天然盐湖。分析天然盐湖与采盐池卤水离子浓度的变化规律发现,卤水蒸发初期Na+、Cl-、SO2-4离子浓度随矿化度的升高而增大,Ca2+离子浓度明显下降,卤水蒸发后期Mg2+、K+大量富集,整个卤水蒸发过程中微量元素Li+与B2O3浓度一直随矿化度的升高而增大。这些结果对内蒙古西部盐湖的研究与开发都具有积极意义。  相似文献   

12.
The contents and distribution characteristics of ions, n-alkanes, and polycyclic aromatic hydrocarbons in snow pits on the Yuzhufeng (YZF) Glacier and the Xiao Dongkemadi (XDKMD) Glacier are studied. Parameter characteristics and correlation coefficients between ions and two organic compounds are used to explore the possible sources of these chemical compositions. The results indicated that both glaciers are influenced by west wind circulation, but the contents of ions, n-alkanes, and polycyclic aromatic hydrocarbons in the YZF Glacier are higher than in the XDKMD Glacier because of differences in geographical position. The ratios of ΣnC21–/ΣnC22+ and CPI values (CPI: carbon preference index) indicate that the n-alkanes from natural sources in these two glaciers are mainly derived from higher plants, whereas the contribution from lower organisms was small, also, n-alkanes from anthropogenic sources in the YZF Glacier are higher than in the XDKMD Glacier. The ratios of LPAHs/HPAHs and (Fly+Pyr)/(BghiP+INP) indicate that the polycyclic aromatic hydrocarbons in these two glaciers are mainly derived from low temperature combustion of coal and biomass, and, in the XDKMD Glacier, partially from the vehicle exhaust.  相似文献   

13.
Spatial and temporal change patterns of air temperature (T), precipitation (P), relative humidity (RH), lower vapor pressure (VP), potential evapotranspiration (PET) and drought situation of 690 meteorological stations for all of China were evaluated in this study to understand the effects of warming on regional drought and hydrological processes. Here, the drought extent is expressed by aridity index (AI), which is the ratio of precipitation and reference crop evapotranspiration (ET0) calculated by FAO Penman-Monteith equation, taking into account air temperature, atmospheric humidity, solar radiation, and wind. Our results indicate that there are different patterns of climate change from 1961 to 2008 and from 1981 to 2008. Little precipitation change occurred in China and ET0 decreased from 1961 to 2008. But, the warming trend has intensified and the area with significant increasing precipitation has reduced since the early 1980’s and ET0 has increased in most areas of China from 1981 to 2008 and decreased from 1961 to 2008. The areas affected by drought have shifted from North China and Northeast China to East China and South China since 1981. It is speculated that the increasing warming intensity after 1981 possibly strengthened the power of potential evapotranspiration and resulted in drought in most areas of Northeast China, North China, eastern Southwest China, and especially in East China and South China.  相似文献   

14.
In order to reveal the variation characteristics of ozone (O3) concentration in the atmosphere boundary layer over a desert in winter, an observation experiment was carried out in the Tazhong area by means of a tethered balloon during January 18–25, 2008. The vertical distribution of O3 concentration and its correlation with temperature and humidity were analyzed based on experimental observation data and related data. Results show that: (1) The concentration of O3 mainly ranges from 10 to 50 μg/L, with a maximum of 56.1 μg/L, minimum of 2.6 μg/L, and a daily average concentration of 34.4 μg/L. (2) O3 profiles can be divided into three types: peak, uniform, and growth, where uniform accounts for the majority. (3) Temperature and moisture are influential on O3 concentrations in atmospheric boundary layer. Temperature inversion and water vapor increase in an atmospheric boundary layer leads to a decrease of O3. (4) O3 concentration has an obvious daily change in Tazhong. It is lower at night, begins to increase after sunrise, and reaches a maximum at noon. The maximum appears at 17:00 BJT (Beijing Time), and the minimum appears at 08:00 BJT.  相似文献   

15.
During the course of a major sandstorm from April 17 to April 23, 2008 in the Taklimakan Desert, data pertaining to the mass concentrations of different-sized atmospheric particulate matter were observed continuously with Grimm 1.108, Thermo RP 1400a, TSP, and CAWS-600 instruments. The results showed that: (1) during the entire sandstorm process there were some differences between the daily mean particle concentration peaks and the hourly mean particle concentration peaks because the actual sandstorm lasted for only about 4 hr, whereas more particles were accumulated in the floating dust days before and after the actual sandstorm; (2) the intensity of the sandstorm was enhanced with the increase of wind speed, and this was related to the peak mass concentrations of atmospheric particulate matter; the wind speed directly affected the concentration of atmospheric particulate matter: the higher the wind speed, the higher the mass concentration (>0.23 μm was 39,496.5 μg/m3, and >20.0 μm was 5,390.7 μg/m3); (3) the concentration changes of PM10 and TSP were also related to the course and intensity of the sandstorm; and (4) the mass concentration of atmospheric particulate matter had the following sequence during the dust weather: clear day < floating dust < floating and blowing dust < sandstorm. Temperature, relative humidity, and barometric pressure are important factors affecting the strength of storms, which could also indirectly affect the concentration change of atmospheric particulate matter.  相似文献   

16.
松嫩平原西部盐沼湿地水环境化学特征   总被引：10，自引：1，他引：9  
邓伟  何岩  宋新山  阎百兴 《地理研究》2000,19(2):113-119
松嫩平原西部盐沼湿地水环境碱化程度高,水中的pH值普遍高于8.0,多数为苏打钠型水。在对本区盐沼基本水环境化学特征阐述的基础上,通过对水化学的基本变量CO32-、HCO32-、Cl-、Ca2+、Mg2+、SO42-、Na+和派生变量(Cl-+SO42-)/HCO32-及Na+/(Ca2+ Mg2+)等的相关分析,得出各水化学变量之间的相关关系,并以pH值为分类基础得到了判别函数和判别区域图,对区域盐沼湿地水环境化学特征的研究方法作出了有意义的尝试。  相似文献   

17.
We examined the changes of chemical composition and protein conformation in Arabidopsis leaves by Fourier transform–infrared (FT-IR) spectrometry Arabidopsis under 50 mmol/L NaCl salt and ?0.5 mPa polyethylene glycols 8000 (PEG 8000) drought stress during the early stages of growth. We primarily analyzed the absorption band areas in the 1,745 cm-1 (ester), 1,600–1,700 cm-1 (amide I), and 1,100 cm-1 (carbohydrate) changes under salt stress and drought stress within 24 hours. The results showed that ester content declined at the beginning and then increased steadily during 24 hours of drought stress. But under salt stress, it declined steadily, and it was about 40 percent of the control after 24 hours. The protein synthesis increased by 25 percent after one hour of salt stress and then reached about 85 percent of the control after 24 hours. Under drought stress, the protein synthesis decreased and reached a minimal level at the 4-hr time point; it then recovered to the control level at the 24-hr point. The patterns of the accumulation of carbohydrates in the 1,100 cm-1 band areas resembled that of amide I band changes under drought stress and salt stress. Analyzing the ratio A1,627cm-1/A1,658cm-1 under drought stress revealed that the leaves’ entire protein structure maintained a higher-level ordered form than did those under salt stress. Thus our results indicate the existence of different strategies of the Arabidopsis adaptation to salt stress and drought stress.  相似文献   

18.
基于密度泛函理论,采用ωB97XD方法和6-311++G(d,p)基组,系统研究了[K(H2O)n]+,[NO3(H2O)n]-和KNO3(H2O)n水合团簇的结构和性质;并结合经典分子动力学、OPLS-AA全原子力场以及SPC/E水模型模拟了不同水盐比(WSR) KNO3溶液,目的在于深入理解KNO3溶液中K+和 NO-3的微观水合结构,以及K+-NO-3离子间缔合作用特征。研究发现,对于KNO3(H2O)n (n=6,8,10和12)水合团簇,K+第一水合层稳定结构为四、五和六水合结构,其中五水合结构最稳定。K+和NO-3主要以溶剂共享离子对形式存在。随着团簇尺寸减小,直接接触离子对(CIP)物种出现。同时,分子动力学模拟证实KNO3溶液中形成了直接接触K+-NO-3离子对,且随着溶液浓度增加,CIP物种形成需越过更大能垒。以上结果表明在KNO3稀溶液中主要存在物种为水合K+和NO-3,随浓度增大,单齿直接接触离子对(MCIP)逐渐出现。在高浓溶液或过饱和溶液中,K+-NO-3离子缔合主要以单齿CIP和少量双齿CIP结构存在。  相似文献   

19.
Based on data from six meteorological stations in the permafrost regions, 60 boreholes for long-term monitoring of permafrost temperatures, and 710 hand-dug pits and shallow boreholes on the Qinghai-Tibet Plateau (QTP), the spatiotemporal variability of permafrost degradation was closely examined in relation to the rates of changes in air, surface, and ground temperatures. The decadal averages and increases in the mean annual air temperatures (MAATs) from 1961–2010 were the largest and most persistent during the last century. MAATs rose by 1.3 °C, with an average increase rate of 0.03 °C/yr. The average of mean annual ground surface temperatures (MAGSTs) increased by 1.3 °C at an average rate of 0.03 °C/yr. The rates of changes in ground temperatures were ?0.01 to 0.07 °C/yr. The rates of changes in the depths of the permafrost table were ?1 to +10 cm/yr. The areal extent of permafrost on the QTP shrank from about 1.50×106 km2 in 1975 to about 1.26×106 km2 in 2006. About 60% of the shrinkage in area of permafrost occurred during the period from 1996 to 2006. Due to increasing air temperature since the late 1980s, warm (>?1 °C) permafrost has started to degrade, and the degradation has gradually expanded to the zones of transitory (?1 to ?2 °C) and cold (相似文献   

20.
The analysis of chironomid taxa and environmental datasets from 46 New Zealand lakes identified temperature (February mean air temperature) and lake production (chlorophyll a (Chl a)) as the main drivers of chironomid distribution. Temperature was the strongest driver of chironomid distribution and consequently produced the most robust inference models. We present two possible temperature transfer functions from this dataset. The most robust model (weighted averaging-partial least squares (WA-PLS), n = 36) was based on a dataset with the most productive (Chl a > 10 μg l−1) lakes removed. This model produced a coefficient of determination () of 0.77, and a root mean squared error of prediction (RMSEPjack) of 1.31°C. The Chl a transfer function (partial least squares (PLS), n = 37) was far less reliable, with an of 0.49 and an RMSEPjack of 0.46 Log10μg l−1. Both of these transfer functions could be improved by a revision of the taxonomy for the New Zealand chironomid taxa, particularly the genus Chironomus. The Chironomus morphotype was common in high altitude, cool, oligotrophic lakes and lowland, warm, eutrophic lakes. This could reflect the widespread distribution of one eurythermic species, or the collective distribution of a number of different Chironomus species with more limited tolerances. The Chl a transfer function could also be improved by inputting mean Chl a values into the inference model rather than the spot measurements that were available for this study.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号