共查询到20条相似文献，搜索用时 581 毫秒
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X射线散射法是溶液结构研究的重要手段,是研究物质微观结构起源较早的一种方法。从X射线散射图解析出的径向分布函数可以得到具体的结构参数,因此这种方法在溶液结构的研究中得以广泛应用。国内外学者应用X射线散射法对溶液结构进行了大量的研究,确定了不同离子的水合数和水合离子半径,研究了温度、浓度、压力等因素对离子水化结构的影响,发现部分离子存在第二水合层。本文将按照碱金属离子、碱土金属离子、重金属离子、稀土元素离子、卤素离子、含氧酸根离子进行分类,对X射线散射法在溶液结构研究中取得的成果进行总结。在此基础上,分析了应用X射线散射法对水溶液结构研究的现状及其面临的挑战,讨论了该领域的发展前景。 相似文献
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碳酸铷、硼酸化学计量比混合,蒸发溶液,直至五硼酸铷RbB_5O_8·4H_2O晶体析出。经粉末X射线衍射、拉曼光谱、热重/微商热重/差示扫描量热(TG/DTG/DSC)、原子吸收光谱等实验方法,确定其化学组成及结构,298.15、333.15K时测量溶液的物理化学性质(密度、电导、pH),并与经验方程进行拟合,研究五硼酸铷溶液的物化性质随浓度、温度的变化规律。根据文献报道的平衡常数、实验测量的p H数据,采用牛顿迭代法进一步探讨了五硼酸铷溶液中主要存在的硼酸根离子物种分布规律。 相似文献
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通过密度泛函理论(DFT)计算、拉曼光谱和同步辐射X射线散射法,研究了质量分数为1.0 %～28.0 %的NH4Cl水溶液的微观结构。在室温下测量了粘度、接触角和电导率。由DFT计算和拉曼光谱结果可知,当溶质浓度升高至10.0 %时,在2 900 cm-1和3 100 cm-1附近出现了明显的N-H作用峰,且随着质量分数的升高,NH4Cl水溶液中的DDAA型氢键转变为DA和DAA型氢键。X射线散射结果表明,当NH4Cl水溶液质量分数升高至10.0 %时,差值对分布函数G(r)在0.298 nm附近出现明显双峰,表明在该浓度下溶液中NH4+-Cl-接触离子对开始成为主要微观作用形式。NH4Cl水溶液的粘度、接触角和电导率均随着NH4Cl水溶液质量分数的增加而增大。NH4Cl水溶液中氢键类型的转变、O-H...N键占比增多以及逐渐增加的NH4+-Cl-接触离子是粘度和接触角变化的微观本质因素;电导率的增加与溶液中有效导电离子数量增加有关。 相似文献
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通过拉曼光谱、同步辐射X射线散射和密度泛函理论(DFT)模拟,研究了质量分数为1.0 %-28.0 %的NH4Cl水溶液的微观结构变化。同时在室温下测量了粘度、接触角和电导率。由拉曼光谱和密度泛函理论模拟结果可知,当溶质浓度升高至10.0 %时,在2900 cm-1和3100 cm-1附近出现了明显的N-H作用峰,且随着质量分数的升高,NH4Cl水溶液中的氢键类型发生了转变。X射线散射结果表明,当NH4Cl水溶液质量分数升高至10.0 %时,差值对分布函数G(r)在2.98 ?附近出现明显双峰,表明在该浓度下溶液中NH4+-Cl-接触离子对开始成为主要微观作用形式。对NH4Cl水溶液的宏观物性研究表明,粘度、接触角和电导率均随着NH4Cl水溶液质量分数的增加而增大。作者推断,NH4Cl水溶液中氢键类型的转变、O-H...N键占比增多以及逐渐增加的NH4+-Cl-接触离子对,是粘度和接触角随溶质浓度增加而增加的微观本质因素;电导率的增加与溶液中有效导电离子数量增加有关。 相似文献
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中山站高频相干散射雷达于2010年4月建成投入观测,并加盟SuperDARN雷达观测网,成为我国探测电离层对流的重要手段。首先简要介绍中山站高频雷达的工作原理及工作模式,然后利用该雷达第一年的观测数据,给出了每个波束观测的电离层回波总数随距离和回波强度、多普勒速度及谱宽的分布,以及电离层回波发生率随频率的变化特性。观测结果和射线追踪的模拟计算表明,由于波束指向不同,电波波矢方向与地磁场形成正交条件的区域有所不同,因此会造成不同频率下,不同波束观测的电离层回波发生率的差别。 相似文献
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D. Guo 《International journal of geographical information science》2013,27(7):801-823
Regionalization is to divide a large set of spatial objects into a number of spatially contiguous regions while optimizing an objective function, which is normally a homogeneity (or heterogeneity) measure of the derived regions. This research proposes and evaluates a family of six hierarchical regionalization methods. The six methods are based on three agglomerative clustering approaches, including the single linkage, average linkage (ALK), and the complete linkage (CLK), each of which is constrained with spatial contiguity in two different ways (i.e. the first‐order constraining and the full‐order constraining). It is discovered that both the Full‐Order‐CLK and the Full‐Order‐ALK methods significantly outperform existing methods across four quality evaluations: the total heterogeneity, region size balance, internal variation, and the preservation of data distribution. Moreover, the proposed algorithms are efficient and can find the solution in O(n 2log n) time. With such data scalability, for the first time it is possible to effectively regionalize large data sets that have 10 000 or more spatial objects. A detailed comparison and evaluation of the six methods are carried out with the 2004 US presidential election data. 相似文献
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Forward modelling receiver functions for crustal structure beneath station TBZ (Trabzon, Turkey) 总被引：4，自引：0，他引：4
Özcan Çak&#;r Murat Erduran Hakan Ç&#;nar & Ahmet Y&#;lmaztürk 《Geophysical Journal International》2000,140(2):341-356
We use teleseismic three-component digital data from the Trabzon, Turkey broadband seismic station TBZ to model the crustal structure by the receiver function method. The station is located at a structural transition from continental northeastern Anatolia to the oceanic Black Sea basin. Rocks in the region are of volcanic origin covered by young sediments. By forward modelling the radial receiver functions, we construct 1-D crustal shear velocity models that include a lower crustal low-velocity zone, indicating a partial melt mechanism which may be the source of surfacing magmatic rocks and regional volcanism. Within the top 5 km, velocities increase sharply from about 1.5 to 3.5 km s−1 . Such near-surface low velocities are caused by sedimentation, extending from the Black Sea basin. Velocities at around 20 km depth have mantle-like values (about 4.25 km s−1 ), which easily correlate to magmatic rocks cropping out on the surface. At 25 km depth there is a thin low-velocity layer of about 4.0 km s−1 . The average Moho velocity is about 4.6 km s−1 , and its depth changes from 32 to 40 km. Arrivals on the tangential components indicate that the Moho discontinuity dips approximately southwards, in agreement with the crustal thickening to the south. We searched for the solution of receiver functions around the regional surface wave group velocity inversion results, which helped alleviate the multiple solution problem frequently encountered in receiver function modelling.
Station TBZ is a recently deployed broadband seismic station, and the aim of this study is to report on the analysis of new receiver function data. The analysis of new data in such a structurally complex region provides constraining starting models for future structural studies in the region. 相似文献
Station TBZ is a recently deployed broadband seismic station, and the aim of this study is to report on the analysis of new receiver function data. The analysis of new data in such a structurally complex region provides constraining starting models for future structural studies in the region. 相似文献
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Standard data and methods, such as the inversion of seismic and GPS data, have been used extensively to infer the details of the 2004 December 26 earthquake. The unprecedented large size of this event gave the opportunity to modern altimeters to provide the first clear records of a tsunami in deep ocean, therefore allowing us to study the rupture history from an independent perspective. We invert the Jason-1 and Topex–Poseidon altimetry records, considering the new constraints available on the geometry of the fault plane, and taking them into account in a 3-D rupture model. The data are corrected for the non-negligible effect of satellite motion during measurements. Our results show that the rupture propagated over the 1500 km of subduction zone initially identified by the aftershock distribution, with a magnitude of M w = 9.1 . Our solution compares well with the latitudinal distribution of slip inferred from other data sets, with a maximum of energy release north of Sumatra, and two other slip patches near the Nicobar and Andaman islands. Based on waveform comparison, we assert that the shallow portion of the megathrust offshore Banda Aceh had slip amplitudes of more than 20 m. Also, we find that significant amounts of slip (about 10 m) concentrated below the Andaman islands and did not propagate on the shallow portion of the interface. Although synthetic tests tend to show less resolution in the northern part of the rupture, this solution is compatible with the near-field data (GPS, coral heads and imagery), and would allow one to explain the apparent paradox between the large local displacements and the moderate tsunami observed locally. Finally, we demonstrate the rapidly dominating effect of propagation and slip distribution over the rupture velocity, and how it precludes the direct estimate of this latter parameter. 相似文献
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基于运单数据的中国快递型物流网络格局、结构与功能 ——以宅急送为例 总被引：5，自引：3，他引：2
物流联系是城市间联系的重要形式,能够反映城市网络的格局、结构和功能。当前研究主要借助引力模型、企业分支、货运班次等对物流联系进行间接估算,常常难以准确反映货物流通的实际格局。因此以宅急送为例,直接基于快递运单提取微观物流数据,探讨中国物流网络的空间格局、结构特征和功能组织。研究表明,物流网络呈现高度不均衡的空间格局,区域尺度上轴辐结构明显;在结构特征上具有较强的时空衰减效应,并呈现幂律分布特征;在功能组织上由少数中转枢纽和主干联系所支撑,对网络效率影响较强的枢纽呈点状分布。 相似文献
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We suggest methods for the analysis of the spatial distribution of plant species in a research area divided into a quadrat lattice. In particular, information about the topography and the spaces without plants is used for the analysis. At sites with a homogeneous substratum, we classify the topography by whether a target grid is concave or convex with respect to a standard surface of altitude. At other sites, we classify the topography according to whether the grid is located at the edge of rock and/or at a water pool. Information about the topography and the plant existence is used for constructing 2 × 2 contingency tables. In order to determine the strength of dependence between the topography and plant existence, the Akaike information criterion (AIC) is used. The methods are applied to data of the microtopography and distribution of mosses in continental Antarctica. 相似文献
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“双十一”期间中国快递流通的时空结构与效率——基于时间地理学视角 总被引：2，自引：0，他引：2
“双十一”作为电商促销活动,其引致的短期高强度快递服务需求对快递业造成极大压力。借鉴时间地理学方法,基于宅急送公司2017年数据,对“双十一”期间中国快递流通的时空结构与效率进行分析。研究表明：快递流通整体上速度较快并由沿海向内陆扩散,在空间结构上各地区快递主要来自其内部和华东地区,在时间结构上绝大多数快递在2~5 d左右即可完成全部配送流程,且耗时主要集中于运输环节。此外,取件、离开、派送活动仍保持原有周期性,但在1 d内的时间分配趋于均衡;路径束主要呈水滴状、分段式形态,快递压力集中于少数枢纽城市,快递处理能力则呈现分层特征。 相似文献
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青藏高原地气温差变化及空间分布 总被引：2，自引：0，他引：2
The difference between ground soil and air temperature （Ts-Ta） was studied by using the data of ground and air temperature of 99 stations over the Qinghai-Xizang （Tibet） Plateau from 1960 to 2000,and its spatial distribution and time changing tendency have been diagnosed by principal component analysis and power spectral analysis methods. The results show that the values of （Ts-Ta） are the maximum in June and the minimum in December. The first three loading eigenvectors, which reflect the main spatially anomalous structure of （Ts-Ta） over the Qinghai-Xizang Plateau, contain the contrary changing pattern between the northwestern and the southeastern regions, the pattern response of the sea level elevation and the geography, and the pattern response of the distribution of the permafrost. There are four patterns of time evolution including the patterns of monotonous increasing or decreasing trends, the basic stability pattern and the parabola pattern with the minimum value. （Ts-Ta） has a periodic variation about 2 years. According to the spatial distribution of the third loading eigenvectors of （Ts-Ta） over the Qinghai-Xizang Plateau in cold season, the permafrost response region and the seasonal frozen ground response region are identified. 相似文献
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探索性空间分析及其与GIS集成模式探讨 总被引：2，自引：1，他引：2
探索性空间分析基于让数据说话的理念,可以避免野值或非典型观测值的误导。在对探索性空间分析的基本原理和概念界定的基础上,探讨交互式和动态空间数据分析、地学可视化及可视化空间分布、确认性空间分析、空间数据挖掘等探索性空间分析的主要技术。由于统计分析软件和GIS的数据格式差异很大,直接将二者简单集成存在一定困难,因此切实可行的集成方式是采用对象连接和嵌入(OLE)技术,分别调用统计分析软件的探索性分析功能(或者函数)以及GIS的地图显示和空间分析功能,并进行必要开发,实现二者的集成。最后对探索性空间分析的发展方向进行展望。 相似文献
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China’s southwestern special terrain pattern as parallel arrangement between longitudinal towering mountains and deep valleys has significant effects on the differentiation of local natural environment and eco-geographical pattern in this region.The 1:50,000 Digital Elevation Model(DEM) data of Longitudinal Range-Gorge Region(LRGR),meteorological observation data from the station establishment to 2010,hydrological observation data,Normalized Difference Vegetation Index(NDVI) and Net Primary Productivity(NPP) products of MOD13 and MOD17 as well as 1:1,000,000 vegetation type data were used.Moisture indices including surface atmospheric vapor content,precipitation,aridity/humidity index,surface runoff,and temperature indices including average temperature,annual accumulated temperature,total solar radiation were selected.Based on ANUSPLIN spline function,GIS spatial analysis,wavelet analysis and landscape pattern analysis,regional differentiation characteristics and main-control factors of hydrothermal pattern,ecosystem structure and function in this region were analyzed to reveal the effects of terrain pattern on regional differentiation of eco-geographical elements.The results show that:influenced by terrain pattern,moisture,temperature and heat in LRGR have shown significant distribution characteristics as intermittent weft differences and continuous warp extension.Longitudinal mountains and valleys not only have a north-south corridor function and diffusion effect on the transfer of major surface materials and energy,but also have east-west barrier function and blocking effect.Special topographic pattern has important influences on vegetation landscape diversity and spatial pattern of ecosystem structure and function,which is the main-control factor on vegetation landscape diversity and spatial distribution of ecosystem.Wavelet variance analysis reflects the spatial anisotropy of environmental factors,NDVI and NPP,while wavelet consistency analysis reveals the control factors on spatial distribution of NDVI and NPP as well as the quantitative relationship with control degree.Special terrain pattern in LRGR is the major influencing factor on eco-geographical regional differentiation in this region.Under the combined effect of zonality and non-zonality laws with "corridor-barrier" function as the main characteristic,special spatial characteristics of eco-geographical regional system in LRGR is formed. 相似文献