共查询到19条相似文献，搜索用时 140 毫秒
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研究了Rb2 CO3-CH3CH2 OH -H2 O体系在 2 0°C下的相平衡 ,绘制了相应的溶度图。发现Rb2 CO3·2 .5H2 O的新物相 ,与以往报道的结果不一致 相似文献
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利用迎头气相色谱分析、量热法、热重法、X -衍射法和化学分析相结合 ,对氯化镁水合物吸水和脱水过程进行了热力学研究。在不同温度下对MgCl2 ·4H2 O和MgCl2 ·2H2 O对水的吸附等温线所进行的数学模拟结果表明 ,Bolzmann函数是描述该等温线较为理想的方程。两种氯化镁水合物对水的吸附热分别为 -1 3 0 6kJ/mol和 -1 6 1 1kJ/mol。也给出了该吸附过程的吸附平衡常数。从所获得的数据来看 ,以部分脱水的氯化镁水合物为吸附剂来吸附水氯镁石脱水设备尾气中的水蒸气 ,从而使保护性气体HCl得以循环使用 ,从热力学角度而言存在这种可能性。 相似文献
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采用结晶动力学方法对Li2 O :B2 O3=1 :4和 1 :5在 2 0 %LiCl-H2 O中的过饱的溶液在 2 0℃时的结晶动力学过程进行了研究 ,两种不同Li2 O :B2 O3(摩尔比 )配比的过饱和溶液均析出LiB5O8·5H2 O一种固相 ,通过X -ray粉末衍射、IR光谱和热分析对结晶析出固相进行了表征。同时拟合给出了结晶动力学方程 ,并对结晶反应机理进行了探讨。 相似文献
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进行了 L i Cl_ Mg Cl2 _ H2 O体系的参数化工作 ,得到了该体系在 40°C时 Mg Cl2 的单盐参数、两离子和三离子相互作用参数 θli Mg和 ψL i Mg Cl,以及三种复盐的溶解平衡常数 Ksp( Mg Cl2 · 6 H2 O) ,Ksp( L i Cl· Mg Cl2 · 7H2 O) 和Ksp( L i Cl2 · H2 O) 。利用得到的参数 ,预测该体系在 40°C时的溶解度 ,获得满意结果。本研究工作为 HCl- L i Cl- Mg Cl2 - H2 O四元体系 40°C时的溶解度计算提供了最基本的、必需的参数。将 Pitzer模型从室温推广到高温时的溶解度预测 ,结果对盐湖资源中 L i Cl和 Mg Cl2 的提取工艺具有重要的指导意义。将计算机技术应用到了实验研究中 ,减少了繁重的实验测定工作 相似文献
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Natural Gas Hydrate Stability in the East Coast Offshore-Canada 总被引：1，自引：0，他引：1
The methane hydrate stability zone beneath the Canadian East Coast oceanic margin has developed to a depth of more than 600 meters beneath the deep water column in the area of the deep shelf and the slope. This zone is continuous spreading from the Labrador continental shelf in the north to the slope of the Nova Scotia shelf in the south. Gas hydrates within the methane hydrate stability zone are detected only in one situation, however, they are numerous in the deeper zone in which type II gas hydrates are present through the whole area at water depths as low as 100-200 m. Well-log indications of gas hydrate situated deeper than the base of the methane hydrate stability zone may be an indication of wetter, compositionally more complicated hydrates that probably are not of bacterial only origin. This could indicate a deep thermogenic source of gas in hydrates. The presence of hydrates in the upper 1000 m of sediments also can be considered as an indicator of deeper hydrocarbon sources. 相似文献
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At present, gas hydrates are known to occur in continental high latitude permafrost regions and deep sea sediments. For middle latitude permafrost regions of the Tibetan Plateau, further research is required to ascertain its potential development of gas hydrates. This paper reviewed pertinent literature on gas hydrates in the Tibetan Plateau. Both geological and ge- ographical data are synthesized to reveal the relationship between gas hydrate formation and petroleum geological evo- lution, Plateau uplift, formation of permafrost, and glacial processes. Previous studies indicate that numerous residual basins in the Plateau have been formed by original sedimentary basins accompanied by rapid uplift of the Plateau. Ex- tensive marine Mesozoic hydrocarbon source rocks in these basins could provide rich sources of materials forming gas hydrates in permafrost. Primary hydrocarbon-generating period in the Plateau is from late Jurassic to early Cretaceous, while secondary hydrocarbon generation, regionally or locally, occurs mainly in the Paleogene. Before rapid uplift of the Plateau, oil-gas reservoirs were continuously destroyed and assembled to form new reservoirs due to structural and thermal dynamics, forcing hydrocarbon migration. Since 3.4 Ma B.P., the Plateau has undergone strong uplift and extensive gla- ciation, periglacier processes prevailed, hydrocarbon gas again migrated, and free gas beneath ice sheets within sedi- mentary materials interacted with water, generating gas hydrates which were finally preserved under a cap formed by frozen layers through rapid cooling in the Plateau. Taken as a whole, it can be safely concluded that there is great temporal and spatial coupling relationships between evolution of the Tibetan Plateau and generation of gas hydrates. 相似文献
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The methane hydrate stability zone beneath Sverdrup Basin has developed to a depth of 2 km underneath the Canadian Arctic Islands and 1 km below sea level under the deepest part of the inter-island sea channels. It is not, however, a continuous zone. Methane hydrates are detected in this zone, but the gas hydrate/free gas contact occurs rarely. Interpretation of well logs indicate that methane hydrate occurs within the methane stability zone in 57 of 150 analyzed wells. Fourteen wells show the methane hydrate/free gas contact. Analysis of the distribution of methane hydrate and hydrate/gas contact occurrences with respect to the present methane hydrate stability zone indicate that, in most instances, the detected methane hydrate occurs well above the base of methane hydrate stability. This relationship suggests that these methane hydrates were formed in shallower strata than expected with respect to the present hydrate stability zone from methane gases which migrated upward into hydrate trap zones. Presently, only a small proportion of gas hydrate occurrences occur in close proximity to the base of predicted methane hydrate stability. The association of the majority of detected hydrates with deeply buried hydrocarbon discoveries, mostly conventional natural gas accumulations, or mapped seismic closures, some of which are dry, located in structures in western and central Sverdrup Basin, indicate the concurring relationship of hydrate occurrence with areas of high heat flow. Either present-day or paleo-high heat flows are relevant. Twenty-three hydrate occurrences coincide directly with underlying conventional hydrocarbon accumulations. Other gas hydrate occurrences are associated with structures filled with water with evidence of precursor hydrocarbons that were lost because of upward leakage. 相似文献
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《Natural Resources Research》2014,23(1):19-98
This report contains nine unconventional energy resource commodity summaries and an analysis of energy economics prepared by committees of the Energy Minerals Division of the American Association of Petroleum Geologists. Unconventional energy resources, as used in this report, are those energy resources that do not occur in discrete oil or gas reservoirs held in structural or stratigraphic traps in sedimentary basins. These resources include coal, coalbed methane, gas hydrates, tight-gas sands, gas shale and shale oil, geothermal resources, oil sands, oil shale, and U and Th resources and associated rare earth elements of industrial interest. Current U.S. and global research and development activities are summarized for each unconventional energy commodity in the topical sections of this report. 相似文献
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American Association of Petroleum Geologists 《Natural Resources Research》2011,20(4):279-328
This report contains nine unconventional energy resource commodity summaries prepared by committees of the Energy Minerals
Division (EMD) of the American Association of Petroleum Geologists. Unconventional energy resources, as used in this report,
are those energy resources that do not occur in discrete oil or gas reservoirs held in structural or stratigraphic traps in
sedimentary basins. These resources include coal, coalbed methane, gas hydrates, tight gas sands, gas shale and shale oil,
geothermal resources, oil sands, oil shale, and uranium resources. Current U.S. and global research and development activities
are summarized for each unconventional energy commodity in the topical sections of this report. Coal and uranium are expected
to supply a significant portion of the world’s energy mix in coming years. Coalbed methane continues to supply about 9% of
the U.S. gas production and exploration is expanding in other countries. Recently, natural gas produced from shale and low-permeability
(tight) sandstone has made a significant contribution to the energy supply of the United States and is an increasing target
for exploration around the world. In addition, oil from shale and heavy oil from sandstone are a new exploration focus in
many areas (including the Green River area of Wyoming and northern Alberta). In recent years, research in the areas of geothermal
energy sources and gas hydrates has continued to advance. Reviews of the current research and the stages of development of
these unconventional energy resources are described in the various sections of this report. 相似文献
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极地天然气水合物分布于南北极大陆及其毗邻海域的沉积物（岩）中,与广泛分布的永久冻土带密切相关,资源潜力巨大。极地天然气水合物储层类型主要为富砂沉积物储层,能提供天然气水合物高浓度聚集所需的储集渗透性,最可能实现远景勘探和商业利用。随着全球气候变暖,北冰洋海冰加速融化和航道开通,北极地区蕴藏的丰富资源都将从潜在利益变成现实利益,各国的权益纷争也将愈演愈烈。本文综述了极地天然气水合物勘探开发现状和相关国家的水合物开发政策,依据中国海陆域天然气水合物勘查开发现状,提出了中国参与极地天然气水合物研究和开发的思路和途径,为中国极地资源开发利用战略提供参考。 相似文献
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American Association of Petroleum Geologists Energy Minerals Division 《Natural Resources Research》2009,18(2):65-83
This paper summarizes five 2007–2008 resource commodity committee reports prepared by the Energy Minerals Division (EMD) of
the American Association of Petroleum Geologists. Current United States and global research and development activities related
to gas hydrates, gas shales, geothermal resources, oil sands, and uranium resources are included in this review. These commodity
reports were written to advise EMD leadership and membership of the current status of research and development of unconventional
energy resources. Unconventional energy resources are defined as those resources other than conventional oil and natural gas
that typically occur in sandstone and carbonate rocks. Gas hydrate resources are potentially enormous; however, production
technologies are still under development. Gas shale, geothermal, oil sand, and uranium resources are now increasing targets
of exploration and development, and are rapidly becoming important energy resources that will continue to be developed in
the future.
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经对硼氢化物的形成条件、内生硼矿物化学成分、矿物共生组合及盐湖卤水、热泉的有关物质浓度值研究后 ,认为硼氢化物是形成硼矿床的重要活化、迁移形式 相似文献