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1.
利用旋转盘装置结合离子选择电极研究了LiCl、NaCl、KCl在20℃~35℃水中溶解动力学,得到了溶解动力学方程.  相似文献   

2.
研究了不同温度下,不同浓度的NaCl溶液对钾光卤石溶解转化的影响.得出NaCl的浓度对溶解转化的影响不大,且温度对光卤石的溶解转化的影响不是简单线性关系的结论.计算了该体系光卤石的溶解动力学方程和氯化钾结晶动力学方程.  相似文献   

3.
研究了不同浓度MgCl2(1.998、3.867、5.735%)溶液,在不同温度(25、55℃)下,对软钾镁矾在K+,Mg2+/SO_4 ̄2-,Cl-H2O四元体系中溶解转化过程的影响,采用龙格-库塔微分数值法拟合其溶解过程和结晶过程动力学方程。结果表明在一定浓度MgCl2溶液中软钾镁矾是不相称溶解,K2SO4先于MgSO4溶解进入溶液中,MgCl2溶液浓度越大,温度越高,溶解速度越快,K2SO4结晶速度也越快.溶解受扩散和表面反应控制,K2SO4结晶受扩散控制.  相似文献   

4.
本文利用合成纯软钾镁矾晶体,研究了不同浓度NaCl(1.028、3.054%)溶液,不同温度(25、50、75℃)地软钾镁矾溶解转化过程的影响。并且采用龙格-库塔微分数值法拟合求解其溶解过程和结晶过程动力学方程。结果表明在一定浓度NaCl溶液中软钾镁矾是不相称溶解。MgSo4先于K2SO4溶解进入溶液中,温度越高,溶解速度赵快,K2S 晶速度也赵  相似文献   

5.
本文利用合成纯软钾镁矾晶体,研究了不同浓度NaCl(1.028、3.054%)溶液、不同温度(25、50、75℃)对软钾镁矾溶解转化过程的影响。并且采用龙格—库塔微分数值法拟合求解其溶解过程和结晶过程动力学方程。结果表明在一定浓度NaCl溶液中软钾镁矾是不相称溶解。MgSO4先于K2SO4溶解进入溶液中,温度越高,溶解速度越快,K2SO4结晶速度也越快,NaCl的盐析作用越明显,软钾镁矾溶解达到K2SO4过饱和并析出所需时间缩短,溶解受扩散和表面反应控制,K2SO4结晶受扩散控制。  相似文献   

6.
本工作采用pH值,电导率和Na+、Ca(2+)选择电极的电极电位四种物理参数跟踪测定了钠硼解石在10℃~35℃纯水中的溶解过程,结合取样进行化学分析和对固相的物相鉴定确定了溶解机制.拟合出溶解动力学方程,计算了Arrhanius活化能,并根据最终平衡的各离子浓度计算出溶度积常数、溶解度、溶解热和溶解熵等热力学函数.  相似文献   

7.
测定了三元体系MgCl2─KCl─H2O在28℃与30℃下的溶解曲线,并在此基础上结合文献中该体系一些温度下的溶解度曲线,对从盐卤提取的KCl·MgCl2·6H2O复盐中KCl的分离,提出一个简便可行的方法。  相似文献   

8.
本文对软钾镁矾在水中不同粒度和10~40℃时的溶解过程进行研究,并建立溶解速率方程,获得该复盐的溶解动力学方程,探明它们的溶解和转化机理.  相似文献   

9.
毕渭滨  孙柏 《盐湖研究》1997,5(3):42-46
用等温溶解法测定了Mg^2+/Cl^-,Borate-H2O三元体系25℃时的溶解度,此三元体系等温溶解度图为简单共饱型,它的平衡固相分别为三方硼镁石(Mg2B12O20·15H2O)和MgCl2·6H2O,未产生新的复盐或固溶体。拟合了MgB6O10随MgCl2浓度变化的溶解度曲线方程,并且对平稳溶液的物化性质(密度、粘度、折光度、电子率、电导、PH值)进行了测定,用半经验公式描述了一些物化性质  相似文献   

10.
孙柏  李冰 《盐湖研究》1995,3(4):50-56
用等温溶解平衡法研究了L^+,K^+,Mg^2+/Cl^-,SO^2-4-H2O五元交互体系℃的溶解度。该体系相图由十五个盐或复盐的结晶区 构成,饱和溶液的某些物化性质的测定结果与经验公式计算结果吻合,实验测定值与理论预测结果非常一致。  相似文献   

11.
Base-salt relief influences salt flow, producing three-dimensionally complex strains and multiphase deformation within the salt and its overburden. Understanding how base-salt relief influences salt-related deformation is important to correctly interpret salt basin kinematics and distribution of structural domains, which have important implications to understand the development of key petroleum system elements. The São Paulo Plateau, Santos Basin, Brazil is characterized by a >2 km thick, mechanically layered Aptian salt layer deposited above prominent base-salt relief. We use 3D seismic reflection data, and physical and conceptual kinematic models to investigate how gravity-driven translation above thick salt, underlain by complex base-salt relief, generated a complex framework of salt structures and minibasins. We show that ramp-syncline basins developed above and downdip of the main pre-salt highs record c. 30 km of Late Cretaceous-Paleocene basinward translation. As salt and overburden translated downdip, salt flux variations caused by the base-salt relief resulted in non-uniform motion of the cover, and the simultaneous development of extensional and contractional structures. Contraction preferentially occurred where salt flow locally decelerated, above landward-dipping base-salt and downdip of basinward-dipping ramps. Extension occurred at the top of basinward-dipping ramps and base-salt plateaus, where salt flow locally accelerated. Where the base of the salt layer was broadly flat, structures evolved primarily by load-driven passive diapirism. At the edge of or around smaller base-salt highs, salt structures were affected by plan-view rotation, shearing and divergent flow. The magnitude of translation (c. 30 km) and the style of salt-related deformation observed on the São Paulo Plateau afford an improved kinematic model for the enigmatic Albian Gap, suggesting this structure formed by a combination of basinward salt expulsion and regional extension. These observations contribute to the long-lived debate regarding the mechanisms of salt tectonics on the São Paulo Plateau, ultimately improving our general understanding of the effects of base-salt relief on salt tectonics in other basins.  相似文献   

12.
13.
《Basin Research》2018,30(1):148-166
Determining the response of fluvial systems to syn‐sedimentary halokinesis is important for reconstructing the palaeogeography of salt basins, determining the history of salt movement and predicting development and architecture of sandstone bodies for subsurface fluid extraction. To assess both the influence of salt movement on fluvial system development and the use of lithostratigraphic correlation schemes in salt basins we have analysed the Triassic Chinle Formation in the Paradox Basin, Utah. Results indicate that sandstone body development proximal to salt bodies should be considered at two scales: intra‐ (local) and inter‐ (regional) mini‐basin scale. At the intra‐mini basin or local scale, conformable packages of up to 12 m deep meandering fluvial channel deposits and associated overbank deposits are developed, which may thin, pinch‐out or become truncated towards salt highs. When traced down the axis of a mini‐basin, individual stories extend for a few hundred metres, and form part of amalgamated channel‐belt packages up to 60 m thick that can be traced for at least 25 km parallel to palaeoflow. Where salt movement outpaces sediment accumulation, progressive low angle unconformities are developed along the flanks of salt highs. Significantly, in mini‐basins with high sand supply, sandstone bodies are present across salt highs where they show increased amalgamation, decrease in thickness due to truncation and no change in internal sandstone body character. At inter mini‐basin or regional scale, spatial and temporal variations in accommodation space generated by differential salt movement strongly influence facies distributions and facies correlation lengths. Broad lithostratigraphic packages (5–50 m thick) can be correlated within mini‐basins, but correlation of these units between adjacent mini‐basins is problematic. Knowledge of fluvial system development at a regional scale is critical as, fluvial sediment distribution is focussed by topography generated by growing salt bodies, such that adjacent mini‐basins can have significant differences in sandstone body thickness, distribution and lateral extent. The observations from the Chinle Formation indicate that lithostratigraphic‐based correlation schemes can only be applied within mini‐basins and cannot be used to correlate between adjacent mini‐basins or across a salt mini‐basin province. The key to predicting sandstone body development is an understanding of the timing of salt movement and reconstructing fluvial drainage system development.  相似文献   

14.
In Death Valley, California, an area of high aridity and great salinity, alluvial fans de scend into the zone of salt accumulation. When the rounded fan gravels come into contact with salt, some of which is sodium sulfate, they are rapidly shattered and reduced in size. Silt and clay are formed by this salt weathering process and this fine material may be subject to deflation processes.  相似文献   

15.
呼伦贝尔盟盐湖众多,主要集中分布于新巴尔虎旗附近、乌尔逊河沿岸和呼伦湖以南三个成盐区.呼盟地区盐湖盐类矿物主要有芒硝、泡碱、石膏和石盐.在矿物组成上,东部和西部有较大差异,东部为芒硝、泡碱和石盐,无石膏沉积,西部则是芒硝、石膏和石盐,无泡碱沉积.盐湖卤水主要由K+、Na+、Ca_(2+)、Mg_(2+)、Cl-、SO_(2-)、CO_3(2-)和HCO_3-组成,并含有一定量的溴、硼、碘等微量元素.呼盟地区盐湖矿物以芒硝为主,天然碱、石膏次之,石盐较少.盐湖矿床以小型为主,埋藏较浅,易于开采,矿层组份简单,易于加工利用.  相似文献   

16.
以艾比湖东南部历史时期干涸湖底为研究区,对6种不同景观类型下富盐沉积物进行采样分析。运用经典统计研究了干涸湖底各景观类型下富盐沉积物盐分含量及盐分积聚特征。结果表明:不同景观类型的沉积物可溶性盐分含量差异显著。从平均值角度看,各景观类型表层沉积物中0~30 cm层的盐分含量占0~60 cm层盐分含量的70%,即沉积物盐分垂直分布呈强表聚性。各景观类型的沉积物盐分含量均属于中等变异强度(30%相似文献   

17.
The zooplankton of two salt ponds at Aveiro was studied to evaluate its density and diversity. Samples were collected biweekly from the salt ponds Esmolas and Tanoeiras. Samples were first separated into Holoplankton (Copepoda, nauplii,Acartia, Ostracoda and Anostraca) and Meroplankton (Mollusca, Insecta, annelidan larvae and Ichthyoplankton). The Holoplankton was mainly composed of:Acartia tonsa, Acartia sp.,Eurytemora velox, Artemia sp., and harpacticoids and calanoids. In both salt ponds, species diversity was identical, but total zooplankton density was higher in the Tanoeiras salt pond, probably because its physical and chemical characteristics allowed the development of stable communities.  相似文献   

18.
老挝万象盆地通芒地区盐构造特征及成因机制   总被引:4,自引:2,他引:2       下载免费PDF全文
万象坳陷盆地腹地通芒地区古新世—始新世沉积了巨厚的膏盐岩,塔贡组下盐层钾镁盐矿体呈盐构造,钾镁盐矿体与上覆碎屑岩之间整合接触,在喜马拉雅运动中晚期的强烈挤压与差异载荷等作用下,形成通芒地区狭长形隆起的盐背斜构造。研究表明通芒地区盐构造的成因受多重作用影响,差异负载是通芒地区盐构造初始形成时的动力来源,盐上盖层快速沉降是盐构造生长缓慢的主要原因。强烈的区域挤压作用促进了差异负载、重力作用与浮力作用的进一步发展,所形成的构造样式相对较简单,以发育盐构造初期的盐枕及盐背斜为主。盐构造对于研究钾镁盐体的成因、运动规律和成矿作用具有重要意义。  相似文献   

19.
Loading of subsurface salt during accumulation of fluvial strata can result in halokinesis and the growth of salt pillows, walls and diapirs. Such movement may eventually result in the formation of salt‐walled mini‐basins, whose style of architectural infill may be used to infer both the relative rates of salt‐wall growth and sedimentation and the nature of the fluvial‐system response to salt movement. The Salt Anticline Region of the Paradox Basin of SE Utah comprises a series of elongate salt‐walled mini‐basins, arranged in a NW‐trending array. The bulk of salt movement occurred during deposition of the Permian Cutler Group, a wedge of predominantly quartzo‐feldspathic clastic strata comprising sediment derived from the Uncompahgre Uplift to the NE. The sedimentary architecture of selected mini‐basin fills has been determined at high resolution through outcrop study. Mini‐basin centres are characterized by multi‐storey fluvial channel elements arranged into stacked channel complexes, with only limited preservation of overbank elements. At mini‐basin margins, thick successions of fluvial overbank and sheet‐like elements dominate in rim‐syncline depocentres adjacent to salt walls; many such accumulations are unconformably overlain by single‐storey fluvial channel elements that accumulated during episodes of salt‐wall breaching. The absence of gypsum clasts suggests that sediment influx was high, preventing syn‐sedimentary surface exposure of salt. Instead, fluvial breaching of salt‐generated topography reworked previously deposited sediments of the Cutler Group atop growing salt walls. Palaeocurrent data indicate that fluvial palaeoflow to the SW early in the history of basin infill was subsequently diverted to the W and ultimately to the NW as the salt walls grew to form topographic barriers. Late‐stage retreat of the Cutler fluvial system coincided with construction and accumulation of an aeolian system, recording a period of heightened climatic aridity. Aeolian sediments are preserved in the lees of some salt walls, demonstrating that halokinesis played a complex role in the differential trapping of sediment.  相似文献   

20.
据有关历史资料,分析研究了运城盐湖资源利用的科技发展史,阐述了运城盐湖在古代文明中的地位,同时较为详尽地分折了各历史阶段利用盐湖制业的古老工艺并概括了他们的特点.  相似文献   

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