共查询到20条相似文献，搜索用时 46 毫秒
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研究了不同浓度ＭｇＣｌ２（１．９９８、３．８６７、５．７３５％）溶液，在不同温度（２５、５５℃）下，对软钾镁矾在Ｋ＋，Ｍｇ２＋／ＳＯ_４￣２－，Ｃｌ－Ｈ２Ｏ四元体系中溶解转化过程的影响，采用龙格－库塔微分数值法拟合其溶解过程和结晶过程动力学方程。结果表明在一定浓度ＭｇＣｌ２溶液中软钾镁矾是不相称溶解，Ｋ２ＳＯ４先于ＭｇＳＯ４溶解进入溶液中，ＭｇＣｌ２溶液浓度越大，温度越高，溶解速度越快，Ｋ２ＳＯ４结晶速度也越快．溶解受扩散和表面反应控制，Ｋ２ＳＯ４结晶受扩散控制． 相似文献
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本文利用合成纯软钾镁矾晶体，研究了不同浓度ＮａＣｌ（１．０２８、３．０５４％）溶液、不同温度（２５、５０、７５℃）对软钾镁矾溶解转化过程的影响。并且采用龙格—库塔微分数值法拟合求解其溶解过程和结晶过程动力学方程。结果表明在一定浓度ＮａＣｌ溶液中软钾镁矾是不相称溶解。ＭｇＳＯ４先于Ｋ２ＳＯ４溶解进入溶液中，温度越高，溶解速度越快，Ｋ２ＳＯ４结晶速度也越快，ＮａＣｌ的盐析作用越明显，软钾镁矾溶解达到Ｋ２ＳＯ４过饱和并析出所需时间缩短，溶解受扩散和表面反应控制，Ｋ２ＳＯ４结晶受扩散控制。 相似文献
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本工作采用ｐＨ值，电导率和Ｎａ＋、Ｃａ（２＋）选择电极的电极电位四种物理参数跟踪测定了钠硼解石在１０℃～３５℃纯水中的溶解过程，结合取样进行化学分析和对固相的物相鉴定确定了溶解机制．拟合出溶解动力学方程，计算了Ａｒｒｈａｎｉｕｓ活化能，并根据最终平衡的各离子浓度计算出溶度积常数、溶解度、溶解热和溶解熵等热力学函数． 相似文献
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Ｈ＾＋,Ｌｉ＾＋,Ｍｇ＾２＋／Ｃｌ＾－－Ｈ２Ｏ四元体系０℃,２０℃,４０℃的溶解度预测中需要大量参数,而这些参数的获得,依赖于盐酸－碱金属氯化物－水三元体系和ＨＣｌ－ＬｉＣｌ－ＭｇＣｌ２－Ｈ２Ｏ四元体系的热力学性质。总结了近５０年来国内外对上述体系的热力学性质的研究,为Ｈ＾＋,Ｌｉ＾＋,Ｍｇ＾２＋／Ｃｌ＾－－Ｈ２Ｏ四元体系０℃,２０℃,４０℃的溶解度预测奠定基础,同时为Ｐｉｔｚｅｒ模型增添更合理的 相似文献
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Robert G. Darmody & Colin E. Thorn 《Geografiska Annaler: Series A, Physical Geography》1997,79(4):215-222
Chemical weathering and associated soil development trends on glacial forelands are commonly assumed to exhibit increases with time elapsed since glaciation. However, this gross trend is complicated by several other factors including elevation, aspect, and microtopography. This paper demonstrates that on the glacial foreland at Storbreen, Jotunheimen, Norway, chemical weathering and associated soil development trends show significant elevational influences. We sampled soils at shallow depths (0–1, 1–5, and 15–20 cm) at two sites on a moraine dated to 1750 at its elevational extremes of 1155 m (site L) and 1385 m (site H). The two moraine sites also differed developmentally from an adjacent 9000-year-old surface (site T) at an intermediate elevation, 1205 m. Analyses were conducted on the fine-earth fractions. Extractable elemental composition exhibited detectable differences between the same-age soils at different elevations with the lower site L tending to have measured parameters intermediate between the high site H and the older site T. Weathering, as indicated by mineralogy, was more pronounced at the 9000-year-old site T and least evident at the high elevation site H. In addition, elevation under the conditions of the field research may inhibit pedogenesis as indicated by the chemical data. Site H, for example, showed little variation with depth and had in general, less organic matter accumulation, smaller C:N ratio, greater pH, and lesser amounts of the measured extractable elements than the soil at site L. Site T generally had smaller pH and larger levels of the measured elements than the other sites. It was concluded that elevation has a significant control on weathering and pedogenesis that may mask the effects of age in this cold and wet environment. 相似文献
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Women,Politics, Elections,and Citizenship 总被引：1，自引：1，他引：0
《The Journal of geography》2012,111(1):1-10
Abstract Significantly more women than men are registered voters in the United States, and a higher proportion of women voters actually cast ballots on election day. Yet the 106th Congress (1999-2001) includes only 56 women members, 12% of the total membership of the House and Senate. Likewise, women hold only 22% of the total seats in state legislatures. The purpose of this article is to examine this paradox. It first examines the history of the women's movement in the United States. It then turns to an evaluation of women's progress in gaining elected office. Finally it considers three primary obstacles to women gaining equitable representation: solidarity among women, political culture, and the single-member district system now employed in the United States. 相似文献
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Rolf Sternberg 《Geographical review》1998,88(3):327-348
ABSTRACT. Wilhelm Richard Wagner fused fantasy based on epic and lore with seamless scores, using landscapes and urban images to forge spatial order on stage. As a footloose composer-conductor, Wagner was considered a globetrotter for his time, and from trans-European tours he drew inspiration for numerous stagings. Nine of his operas have rustic pastoral settings, with actors silhouetted against geological formations, forests, vistas of undulating terrain for pilgrimages, or raging seas, all visually believable scenery. Rienzi and Die Meistersinger von Nürnberg are urban in setting, whereas Die Feen and Das Liebesverbot are set in a castle-like format. 相似文献
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