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1.
This paper deals with the infrared spectra of “amino acid-clay, calcium carbonate and γ-AlOOH” and “Cu(II)-clay-amino acid” model systems, and shows that the model of the ternary surface complex is M-OHLCu (L=amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area, and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor,F TSC, quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.  相似文献   

2.
A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c  相似文献   

3.
A study on the curves of the exchange ratioE(%)- pH on the liquid-solid interface of the systems Zn (II) with clay minerals, (Kaolinite, illite and montmorillonite), Zn (II) with hydrous ferric oxides (amorphous ferric oxide, geothite and hematite), Zn (II) with hydrous manganese oxide (γ-MnOOH, manganite and δ-MnO2) etc. in seawater resulted in the discovery of new plateau type exchange ratioE(%)-pH curves not yet reported in literature. The two factors that decide the growth, decline and the change of the “plateau type” curve are: (1) the inherent characteristics of systems, which can be explained by the exchange constants (i=1, 2, 3, etc.) of interfacial stepwise ion/coordination particle exchange between liquid and solid; and (2) . The theory of interfacial stepwise ion/coordination particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratioE(%)-pH curves. The theoretically simulated and calculated curves coincided well with the experimental results. This paper provides new and powerful experimental basis to support the theory of interfacial stepwise ion/coordination particle exchange in seawater. The project was supported by the National Natural Science Foundation of China.  相似文献   

4.
Summarized results of studies on the physical and interfacial chemistry of the Huanghe estuary are presented as follows: 1. The relationship between the exchange ratio (%) and pH for the Cu (II)-Sedi.ments of the Huanghe Estuary and that of the Cu (II)-illite system were observed to be very similar. 2. A stepwise ion/coordination particle exchange isotherm of trace metal in Huanghe estuary sediment was derived. 3. The ion/coordination particle exchange between trace metal and Huanghe Estuary sediment is analogous to the interfacial chemical characteristic of illite.  相似文献   

5.
The results obtained from the Cu(II)%-pH curve of the system in the presence of added amino acid indicated that the added amino acids of higher concentration can inhibit the Cu(II)-σ-MnO2 ion exchange and that their inhibiting effects decrease in the following sequence when the initial amino acid concentrations are 20.00 ppm: histidine > cystine > glutamic acid > proline > alanine > glycine. The determination of amino acid in solution performed with an amino acid analyser showed that added amino acids react chemically on the surface of the σ-MnO2 According to thermodynamic equilibria relations in the system, amino acids can be changed to amines because of their decarboxylation on the surface of the σ-MnO2. Considering (1) the effect-inhibiting factor of amine FA(β, Ka, pH) representing the complex potential of amine with Cu(II) in solution and (2) the acidic constant of −NH 3 + group in the amine molecule representing the ability of cation exchange of the amine with σ-MnO2, the inhibiting seqence of added amino acid of 20.00 ppm (Eq.(1)) is reasonable. Thus added amino acids do inhibit Cu(II)-σ-MnO2 ion exchange because (1) the amino acid and/ or amine, which is the decarboxylate of the corresponding amino acid, complex with Cu(II) in solution and compete with σ-MnO2 for Cu(II); (2) the cation exchange of the amino acid and/or amine reduce the exchange site on the surface of the σ-MnO2. The results obtained from the isotherms indicated that the theory of interfacial stepwise ion exchange can be extended to the Cu(II) σ-MnO2 ion exchange system in the presence of added amino acid.  相似文献   

6.
This paper proposes a new method for determining the intrinsic acidity constantsK a1 int andK aj int . The new method is a great improvement over the modified Langmuir plot method generally adopted in that determination of these constants is not dependent on the specific surface area of the marine solid particles. The new method was used to determineK a1 int ,K 2a int and for the main inorganic components of marine solid particles, including illite, montmorillonite, kaolinite, goethite, γ-AlOOH. amorphous ferric oxide, δ-MnO2, manganite, SiO2 and calcium carbonate, and can facilitate the study on the effect of solution constituents, solution temperature, ionic strength, etc. on the value of .  相似文献   

7.
In seawater, aside from metal elements and suspended particles, organic substances amount to about 500–2,000 ug carbon/l[8], which is not neglegible in comparison with that of minor metal elements. But in the study of the interaction of the three constituents (metal elements, organics, and suspended particles), the effect of organics in seawater on the surface reaction of metal element—suspended particles has usually been neglected. Recent theoretical research[1, 11] confirmed the importance of the effect of organics in seawater on the surface reaction of metal element—suspended particles. Generally, the effect of organics on the reaction of metal ions, especially Cu(II), on a solid surface is either promotive[2] or inhibitive[7, 9]. So far the fact that organics cannot affect the surface reaction of Cu(II) ions on solids has not been reported in literature. Our experimental results showed that none of the amino acids in seawater affect Cu(II)-goethite ion exchange under certain experimental condition (such as amino acid of lower concentration and lower pH). It was known that the metal ion-organics complex in a liquid competing with solids for metal ions may inhibit the surface reaction of metal ions on solids, but the mechanism of the complex reaction of metal ions competing with solids is not known yet. In fact, the decrease of surface site-exchanging due to the surface reaction of organics on solids is also inhibitive. It is also explained by the ion exchange isotherm of the “amino acid-Cu(II)-geothite” system. This result further demonstrates that the theory of interfacial stepwise ion exchange is applicable to the metal ion exchange isotherm with the presence of organic substances in the system. Projects supported by the Science Fund of the Chinese Academy of Sciences  相似文献   

8.
The isotherms of the interaction between the suspended particles and Cu2+, and the effects of lysine and asparaginic acid on the isotherms in the Huanghe (Yellow) River were studied by applying the theory and method of interfacial stepwise ion/coordination particle exchange. We obtained a new stepped river isotherm, formed by two curves joined together with a “plateau” in the middle. The adsorption equilibrium constantsK 1 andK 2 were calculated by using the isothermal equation of surface stepwise ion exchange. Amino acid in small amount promotes exchange adsorption of the suspended particles with Cu2+. The degree of promotive action relates to the isoelectric point of amino acid. The promotive effect of lysine is bigger than that of asparaginic acid. Project 29361001 supported by NSFC.  相似文献   

9.
This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.  相似文献   

10.
This article deals with the interaction of zinc with δ−MnO2, γ−MnOOH and manganite existing in natural water systems. The mechanism of the reaction has been studied in detail. From the fact that the “ratio of ion exchange(%)-pH” graph is an “S shaped” curve, it is possible to deduce that the chemical reaction is of the nature of cation exchange. And since the pH range of ion exchange=4, it is possible to further deduce that the reaction can be explained by the mechanism of monovalence cation exchange. The main result of this article is the discovery of a new type of isotherm which has not been mentioned in previous literature here and abroad. This isotherm cannot be represented by any presently available adsorption isotherm equations in marine chemistry. The characteristics of this new type of isotherm are as follows: the isotherm has two “knees” and three “plateaus”, the heights of these three “plateaus” are in the ratio 1:2:3. In order to explain theoretically our new isotherm, this article suggests the application of the principle of interfacial stepwise ion exchange for liquid-solid distribution of minor elements on suspended particulate matter. The corresponding isotherm equation was derived from this theory. The results obtained in this article will be of theoretical guiding significance in the study of the marine geochemistry of zinc. Projects supported by the Science Fund of the Chinese Academy of Sciences.  相似文献   

11.
The exchange action of six types of organic phenols on clay surfaces in seawater is systematically studied in this work. The following significant conclusions are drawn from the experiments. (1) The interaction of organic phenols with montmorillonite, illite and kaolinite in seawater is monovalent anion exchage.(2) Their isotherms of stepwise exchage on clay surfaces belong to the Langmuir type or stepwise type.(3) The discovery of the"steric hindrance effects of stepwise exchange of organic phenols on clays surfaces", and revelation of an exchange mechanisrn diffeient from that in references are the greatest achieverments in this work.  相似文献   

12.
ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｖａｒｉｏｕｓｐｈｙｓｉｃａｌａｎｄｃｈｅｍｉｃａｌｒｅａｃｔｉｏｎｓｔｈａｔｏｃｃｕｒｂｅｔｗｅｅｎｔｈｅｓｕｓｐｅｎｄｅｄｐａｒｔｉｃｌｅｓ,ｓｅｄｉｍｅｎｔｓ,ｅｔｃ.ａｎｄｈｅａｖｙｍｅｔａｌｓｉｎａｎａｔｕｒａｌａｑｕａｔｉｃｓｙｓｔｅｍｐｌａｙｅｘｔｒｅｍｅｌｙｉｍｐｏｒｔａｎｔｐａｒｔｓｉｎｃｏｎｔｒｏｌｌｉｎｇｔｈｅｄｉｓｔｒｉｂｕｔｉｏｎｐａｔｔｅｒｎ,ｍｉｇｒａｔｉｏｎａｎｄｔｒａｎｓｆｏｒｍａｔｉｏｎｏｆｈｅａｖｙｍｅｔａｌｓｔｈｅｒｅ.Ｓｉｎｃｅ…  相似文献   

13.
R-phycoerythrin fromPorphyra haitanensis exists in two aggregation states with different molecular weights. A more highly aggregated form, RPE I, was chromatographed on Bio-Rex 70 column with urea solution (pH 3.0) as eluent, and the molecular weights of the 3 subunits (α, β, γ) obtained were determined on SDS-PAGE at 18000, 19200 and 30000, respectively. α subunit carried two phycoerythrobilin (PEB); β subunit, three PEB and one phycourobilin (PUB); γ subunit, one PEB and three PUB chromophores. The molar ratio of α, β, and γ subunits of RPE I was 6: 6: 1, and their subunit composition was confired to be (αβ)6γ on account of the molecular weight of RPE I, 232000. A lower aggregated form, RPE II, contained α and β subunits similar to those of RPE I, but its subunit composition was the (αβ) monomer of RPE. Contribution No. 2108 from the Institute of Oceanology, Chinese Academy of Sciences  相似文献   

14.
By the study of the effects of pH on the exchange ratio (%) of Cu(II) with clay(illite) in the presence of different concentrations of amino acids and fulvic acid, a new model of the mechanism of the effect of organics has been presented in this paper. Projects sponsored by the Natural Science Fund of the Chinese Academy of Sciences.  相似文献   

15.
In the present paper, determination of isotherms of the exchange reaction between Cu(II) and clays is presented, verifying again the “cation exchange—surface precipitation” isotherm worked out formerly in our laboratory. A modified BET equation was applied to treating the experimental data and describing the new isotherm. In addition, the mechanism of the effects of organics are further discussed and verified. Based on the isotherm equations and the estimates of the average area occupied by a single molecule on the surface, we put forward a new hypothesis which differs from the current one of “organic film”. Projects sponsored by the Science Fund of the Chinese Academy of Sciences.  相似文献   

16.
This article deals with a new type of isotherm discovered in sea water systems. The characteristics of this type of isotherm are the non-linear exponential relationship in the low concentration region and the isotherm composed of two or three “S” curves with one or two plateaus in the middle. This isotherm cannot be expressed by the isotherm equation used in marine chemistry at present.[7] Besides, there has been no report in literature about this type of isotherm in so far as the reaction of minor elements on hydrous oxides is concerned. In order to explain theoretically this type of isotherm, this article suggests the use of the theory of interfacial stepwise ion/coordination particle exchange (for simplicity, ion exchange is used herein-after) of suspended particles to deduce a corresponding isotherm equation. Proceeding from the isotherm of this article, we made theoretical analyses of these two characteristics as well as experiments in verification thereof. Twenty-four systems of experiments on this new type of isotherm and isotherm equation were designed and conducted. Experiment results agree with the theory reported here. Project supported by the Science Fund of the Chinese Academy of Sciences.  相似文献   

17.
Calcium carbonate （CaCO3） crystals in their preferred orientation were obtained in BG11 culture media inoculated with Synechocystis sp. PCC6803 （inoculated BG11）. In this study, the features of calcium carbonate deposition were investigated. Inoculated BGll in different calcium ion concentrations was used for the experimental group, while the BGll culture medium was used for the control group. The surface morphologies of the calcium carbonate deposits in the experimental and control groups were determined by scanning and transmission electron microscopy. The deposits were analyzed by electronic probe micro-analysis, Fourier transform infrared spectrum, X-ray diffraction, thermal gravimetric analysis and differential scanning calorimetry. The results show that the surfaces of the crystals in the experimental group were hexahedral in a scaly pattern. The particle sizes were micrometer-sized and larger than those in the control group. The deposits of the control group contained calcium （Ca）, carbon （C）, oxygen （O）, phosphorus （P）, iron （Fe）, copper （Cu）, zinc （Zn）, and other elements. The deposits in the experimental group contained Ca, C, and O only. The deposits of both groups contained calcite. The thermal decomposition temperature of the deposits in the control group was lower than those in the experimental group. It showed that the CaCO3 deposits of the experimental group had higher thermal stability than those of the control group. This may be due to the secondary metabolites produced by the algae cells, which affect the carbonate crystal structure and result in a close-packed structure. The algae cells that remained after thermal weight loss were heavier in higher calcium concentrations in BGll culture media. There may be more calcium- containing crystals inside and outside of these cells. These results shall be beneficial for understanding the formation mechanism of carbonate minerals.  相似文献   

18.
The surface path of the Kuroshio Extension’s western sector and the eddies on both sides are systematically analysed based on the GEK-measured surface current and temperature-salinity data from 1955–1985. The main results are shown as follows:1) According to the position and the features of distribution pattern, the surface path of the Kuroshio Extension’s western sector is classified into two kinds (straight and meander) and seven types (f. ne, Sc, Ui or Vi, Vdi or Udi, Ω, f+v). The straight kind accounts for 1/3 and the meander kind accounts for 2/3. 2) The warm eddies on the northern side originate mostly from the area off Sanriku and Joban of Japan. Their moving paths lie in two patterns: Pattern I, eddy moves northeastward or northward; Pattern II, eddy rotates about the original area. The cold eddies on the southern side originate mainly from the area off Boso Peninsula. Their moving paths also lie in two patterns: Pattern III. eddy moves from west to east; Pattern IV, eddy moves from north to south.  相似文献   

19.
Goethite widely exists among ocean sediments; it plays an important role in fixing heavy metals and adsorbing organic contaminants. So the understanding of the adsorbing process of water molecule on its surface will be very helpful to further reveal such environmental friendly processes. The configuration, electronic properties and interaction energy of water molecules adsorbed on pnma goethite (010) surface were investigated in detail by using density functional theory on 6-31G (d,p) basis set and projector- augment wave (PAW) method. The mechanism of the interaction between goethite surface and H2O was proposed. Despite the differences in total energy, there are four possible types of water molecule adsorption configurations on goethite (010) surface (Aa, Ab, Ba, Bb), forming coordination bond with surface Fe atom. Results of theoretical modeling indicate that the dissociation process of adsorbed water is an endothermic reaction with high activation energy. The dissociation of adsorbed water molecule is a proton transportation process between water’s O atoms and surface. PDOS results indicate that the bonding between H2O and (010) surface is due to the overlapping of water’s 2p orbitals and Fe’s 3d orbitals. These results clarify the mechanism on how adsorbed water is dissociated on the surface of goethite and potentially provide useful information of the surface chemistry of goethite.  相似文献   

20.
Based on the δ13C and δ18O fluctuation of lacustrine carbonate, CaCO3 content and sporo-pollen data, a palaeoclimatic history of Bosten Lake during the Holocene has been outlined, several stages of climatic changes are divided, and the following result es are obtained: (1) Palaeoclimatic changes revealed by carbonate isotope around Bosten Lake are basically identical with that revealed by other geological records in Xinjiang. Environmental changes presented apparent Westlies Style model: during cold period, relative humidity increased, δ18O, δ13C and CaCO3 appeared low; but in warm periods, the dry regime aggravated. (2) The temperature reflected by δ18O exist evident features being increase in the late period during the Holocene. Together with the δ13C, pollen and CaCO3 analyses, several cold and warm phases which are of broad regional significance can be identified. The warm peaks occurred at about 11.0 ka B.P., 9.4 ka B.P., 7.5 ka B.P., 5.0 ka B.P., 3.0 ka B.P. and 2.0 ka B.P.; the cold peaks at 11.5 ka B.P., 10.5 ka B.P., 8.8 ka B.P., 5.5 ka B.P., 3.3 ka B.P., 2.2 ka B.P. and 1.5 ka B.P.. (3) Several climatic events with the nature of “abrupt climatic changes” are revealed in the periods of 11.0 ka B.P. −10.5 ka B.P., 9.4 ka B.P. −8.8 ka B.P., 5.5 ka B.P. −5.0 ka B.P. and 2.0 ka B.P. −1.5 ka B.P.. (4) The results show that carbonate isotopic record of lacustrine sediment in arid area is very sensitive to climatic changes, and may be play a very important role in understanding the features and mechanism of palaeoclimatic changes.  相似文献   

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