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1.
This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.  相似文献   

2.
The results obtained from the Cu(II)%-pH curve of the system in the presence of added amino acid indicated that the added amino acids of higher concentration can inhibit the Cu(II)-σ-MnO2 ion exchange and that their inhibiting effects decrease in the following sequence when the initial amino acid concentrations are 20.00 ppm: histidine > cystine > glutamic acid > proline > alanine > glycine. The determination of amino acid in solution performed with an amino acid analyser showed that added amino acids react chemically on the surface of the σ-MnO2 According to thermodynamic equilibria relations in the system, amino acids can be changed to amines because of their decarboxylation on the surface of the σ-MnO2. Considering (1) the effect-inhibiting factor of amine FA(β, Ka, pH) representing the complex potential of amine with Cu(II) in solution and (2) the acidic constant of −NH 3 + group in the amine molecule representing the ability of cation exchange of the amine with σ-MnO2, the inhibiting seqence of added amino acid of 20.00 ppm (Eq.(1)) is reasonable. Thus added amino acids do inhibit Cu(II)-σ-MnO2 ion exchange because (1) the amino acid and/ or amine, which is the decarboxylate of the corresponding amino acid, complex with Cu(II) in solution and compete with σ-MnO2 for Cu(II); (2) the cation exchange of the amino acid and/or amine reduce the exchange site on the surface of the σ-MnO2. The results obtained from the isotherms indicated that the theory of interfacial stepwise ion exchange can be extended to the Cu(II) σ-MnO2 ion exchange system in the presence of added amino acid.  相似文献   

3.
In seawater, aside from metal elements and suspended particles, organic substances amount to about 500–2,000 ug carbon/l[8], which is not neglegible in comparison with that of minor metal elements. But in the study of the interaction of the three constituents (metal elements, organics, and suspended particles), the effect of organics in seawater on the surface reaction of metal element—suspended particles has usually been neglected. Recent theoretical research[1, 11] confirmed the importance of the effect of organics in seawater on the surface reaction of metal element—suspended particles. Generally, the effect of organics on the reaction of metal ions, especially Cu(II), on a solid surface is either promotive[2] or inhibitive[7, 9]. So far the fact that organics cannot affect the surface reaction of Cu(II) ions on solids has not been reported in literature. Our experimental results showed that none of the amino acids in seawater affect Cu(II)-goethite ion exchange under certain experimental condition (such as amino acid of lower concentration and lower pH). It was known that the metal ion-organics complex in a liquid competing with solids for metal ions may inhibit the surface reaction of metal ions on solids, but the mechanism of the complex reaction of metal ions competing with solids is not known yet. In fact, the decrease of surface site-exchanging due to the surface reaction of organics on solids is also inhibitive. It is also explained by the ion exchange isotherm of the “amino acid-Cu(II)-geothite” system. This result further demonstrates that the theory of interfacial stepwise ion exchange is applicable to the metal ion exchange isotherm with the presence of organic substances in the system. Projects supported by the Science Fund of the Chinese Academy of Sciences  相似文献   

4.
The isotherms of the interaction between the suspended particles and Cu2+, and the effects of lysine and asparaginic acid on the isotherms in the Huanghe (Yellow) River were studied by applying the theory and method of interfacial stepwise ion/coordination particle exchange. We obtained a new stepped river isotherm, formed by two curves joined together with a “plateau” in the middle. The adsorption equilibrium constantsK 1 andK 2 were calculated by using the isothermal equation of surface stepwise ion exchange. Amino acid in small amount promotes exchange adsorption of the suspended particles with Cu2+. The degree of promotive action relates to the isoelectric point of amino acid. The promotive effect of lysine is bigger than that of asparaginic acid. Project 29361001 supported by NSFC.  相似文献   

5.
ImODUcrION'Watervaporchenhatry"asanewsdencewasestablisedbyGu'slaboratorybasedontheirdiscoveryoftheruleof'witCr-watervaporconstanttransferoftracemetalionsinthenaturalwaterCyde';andwasprovedbyamodelexperimntofsea-airtransfer(Gu,l988,l99l,Gueta1.,l982,l986).Thertilehasnotorreationwiththethermody-nawhrsofthetracephySicochdricalsyStem(Gu,l99l,Guetal.,l984).ThispaperpresentSthefuflctionrelating'witCfvaporchedtry"ionconamtrationtothe'huantumchedtry"bondparametCr.FUimONThedatausedinthecurvea…  相似文献   

6.
This paper proposes a new method for determining the intrinsic acidity constantsK a1 int andK aj int . The new method is a great improvement over the modified Langmuir plot method generally adopted in that determination of these constants is not dependent on the specific surface area of the marine solid particles. The new method was used to determineK a1 int ,K 2a int and for the main inorganic components of marine solid particles, including illite, montmorillonite, kaolinite, goethite, γ-AlOOH. amorphous ferric oxide, δ-MnO2, manganite, SiO2 and calcium carbonate, and can facilitate the study on the effect of solution constituents, solution temperature, ionic strength, etc. on the value of .  相似文献   

7.
The analysis of twenty five existent snowline elevation values in West China indicates that snowline elevationH (meter) presents zonality change declining from south to north with latitude φ(degree) and the change declining from west to east with longitude which relates to the distance L (kilometer) to the east coastline. Therefore, the first order trend surface equation of the snowline in West China shows a plane incline from southwest to northeast. The second order trend surface equation of the snowline in West China truly represents the distribution law of the snowline in West China. Its form resembles a "overturned anticline" from southwest to northeast. The "raised axis" seems to be superimposed upon the first order trend surface.It reflects the effect of the relief. The snowline elevation in West China depends on horizontal zonality,distribution of ocean and land,and the relief.  相似文献   

8.
In the present paper, determination of isotherms of the exchange reaction between Cu(II) and clays is presented, verifying again the “cation exchange—surface precipitation” isotherm worked out formerly in our laboratory. A modified BET equation was applied to treating the experimental data and describing the new isotherm. In addition, the mechanism of the effects of organics are further discussed and verified. Based on the isotherm equations and the estimates of the average area occupied by a single molecule on the surface, we put forward a new hypothesis which differs from the current one of “organic film”. Projects sponsored by the Science Fund of the Chinese Academy of Sciences.  相似文献   

9.
It is well known that there are two patterns of potash deposition in lacustrine facies: “tear drop pattern” (the Dabsan saline lake is a typical example) and “bull's eye pattern”. Potash-forming in tear drop pattern is still continuing. The 2,678 m A. S. L. lake in the middle of the Qarhan playa in the Qaidam Basin covers an area of 210 km2, and has an average depth of 0.39 m. Its MgCl2 type surface brine is 280–340 g/l in salinity and mainly consists of Na, K, Mg and Cl. As a rule, the potash deposits occur as evaporite distributed in tear drop pattern at the northern and northeastern lakeshore zones. They mostly consist of carnallite and halite, occasionally sylvite. The deposition is very unstable and controlled principally by the varying supply of deposit materials from the Golmud River in the south. The potash deposits were formed when concentration of the surface brine reached a certain degree in the main evaporating season. Their forming process followed some crystalization paths in the phase diagram for the Na, K, Mg/Cl H2O equilibrium system. Such a sedimentary model of potash deposits in the lacustrine facies is relatively common in nature. Under the extremely arid climate, differential concentration of the nonhomogeneous potassium-rich surface brine produced the potash deposits. Qarhan Salt Lake also had the same pattern of potash depositions and so, in a sense, the Dabsan saline lake is the continuation of the Qarhan salt lake in terms of potash formation. Schmalz (1970) put forward two distributive patterns for evaporite: “tear drop pattern” and “bull's eye pattern”. These patterns exist in both marine and continental salt-bearing basins (including recent salt lakes), and are controlled by the conditions of physical geography, hydrogeology, sedimentology and climatology of each basin. In his works (Sun, 1981; 1984; 1986; 1988) on the origins of potash deposits, the author always referred to them as two models of potash formation. The “tear drop pattern” is one of the salt-forming models and also an important potash-forming model. This paper deals with the formative mechanism of the tear drop pattern potash deposition by presenting the Dabsan saline lake as an example and elucidates on the distributive characteristics and formative processes of potash deposits in the lake.  相似文献   

10.
Surface water can be divided into three layers from top downward: surface microlayer (SML, thickness≤50 μm), subsurface layer (SSL, ≈25 cm) and surface layer (SL, 1–5m), among which the SML plays an important role on sea-air interaction because of its unique physical-chemical property. Carbon dioxide system including DIC (dissolved inorganic carbon), Alk (alkalinity), pH and pCO2 (partial pressure of CO2) in multilayered waters of the Yellow Sea was studied for the first time in March and May 2005. The results show that: DIC and Alk are obviously enriched in SML. The contents of DIC, Alk and pCO2 become lower in turn from SML, SSL to SL, higher in March and lower in May, whereas for pH it was opposite. The relationship between DIC and Alk is clearly positive, but negative between pH and pCO2. Meanwhile, pCO2 and temperature/salinity is also in positive relation, pCO2 decreases with latitude increase. DIC and Alk show a similar variation trend with the maximum at 02:00–03:00, but pH and pCO2 show an opposite pattern. In addition, the distribution patterns are similar to each other in the three layers. The Yellow Sea is shown to be a sink of atmospheric CO2 in spring by two methods: (1) comparing pCO2 in seawater and atmosphere; (2) turning direction of “pH-depth” curve. Calculation on the base of pCO2 data in SML in four models shows that carbon flux in spring in the area was about -6.96×106 t C.  相似文献   

11.
ＤｕｒｉｎｇｔｈｅｔｈｒｅｅＭｔ．ＱｏｍｏｌａｎｇｍａＥｘｐｅｄｉｔｉｏｎｓｏｆ１９５９－１９６０，１９６６－１９６８ａｎｄ１９７５，ＣｈｉｎｅｓｅｓｃｉｅｎｔｉｓｔｓｈａｄｏｂｔａｉｎｅｄｍａｎｙｄａｔａｏｆｇｌａｃｉｅｒｓｉｎｔｈｅｄｉｓｔｒｉｃｔｏｆＭｔ．Ｑｏｍｏｌａｎｇｍａ（Ｗａｎｇｅｔａｌ．，１９８０；Ｘｉｅｅｔａｌ．，１９７５；Ｚｈａｎｇｅｔａｌ．，１９７５）．ＩｎＭａｙ１９９７，Ｐｒｏｆ．ＱｉｎＤａｈｅａｎｄＰｒｏｆ．ＰａｕｌＡ．Ｍａｙｅｗｓｋｉｏｒｇａｎｉｚｅｄａｎｏｔｈｅ…  相似文献   

12.
A study on the curves of the exchange ratioE(%)- pH on the liquid-solid interface of the systems Zn (II) with clay minerals, (Kaolinite, illite and montmorillonite), Zn (II) with hydrous ferric oxides (amorphous ferric oxide, geothite and hematite), Zn (II) with hydrous manganese oxide (γ-MnOOH, manganite and δ-MnO2) etc. in seawater resulted in the discovery of new plateau type exchange ratioE(%)-pH curves not yet reported in literature. The two factors that decide the growth, decline and the change of the “plateau type” curve are: (1) the inherent characteristics of systems, which can be explained by the exchange constants (i=1, 2, 3, etc.) of interfacial stepwise ion/coordination particle exchange between liquid and solid; and (2) . The theory of interfacial stepwise ion/coordination particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratioE(%)-pH curves. The theoretically simulated and calculated curves coincided well with the experimental results. This paper provides new and powerful experimental basis to support the theory of interfacial stepwise ion/coordination particle exchange in seawater. The project was supported by the National Natural Science Foundation of China.  相似文献   

13.
Based on high-resolution tree-ring data from Dulan area of Qinghai Province, five spells have been divided: the warm period before 230’s A. D., the cold period between 240’s A. D. and 800’s A. D., the significantly warm period between 810’s A. D. and 1070’s, i. e. “Medieval Warm Period”, the cold period including the “Little Ice Age” 1420’ – 1870’s and the warming period since 1880’s. All the eleven coldest or warmest decades and several great abrupt changes took place before the Middle Ages, indicating that climatic system operated in great instability during the period 150’s – 1100’s A. D., Comparison of the tree-ring data with other temperature proxy data from East China, Guliya ice core as well as the south of Qinghai-Xizang Plateau shows that such great climatic events as Eastern Han warm period between the beginning of the 1st century and the previous fifty years of the third century, the cold period covering the span of the Wei, the Jin, and the Southern and Northern dynasties, the well-known “Medieval Warm Period” as well as the “Little Ice Age” appeared in these series such as East China and Dulan area. Only the first two climatic events were recorded conspicuously in Guliya ice core while the “Medieval Warm Period” and “Little Ice Age” is far weaker. Also, the well-defined “Medieval Warm Period” didn’t occurred in the south of Qinghai-Xizang Plateau. The warming since the 20th century is the warmest in the last 2000 years Guliya ice core, the second in Dulan area and East China, but it scarcely seems pronounced in the eastern part of Qinghai-Xizang Plateau. Foundation item: Under the auspices of the projects of the Chinese Academy of Sciences (KZ951-A1-204-02 and KZ951-A1 402-03). Biography: YANG Bao(1971–), male, a native of Yanggao County, Shanxi Province, Ph. D. His research interestinclude global change.  相似文献   

14.
Using a “three parameters” bottom model, the average sound intensity in homogeneous shallow water with constant depth is found by a better expression to be finite for normal mode number of water layer. The space structure of the sound field and some factors controlling the near, middle and far fields are discussed with this expression. This paper was published in Chinese inOceanologia et Limnologia Sinica 14 (2): 198–202, 1983.  相似文献   

15.
A large-scale bloom occurred from May to June in 2011 in sea area near Qinhuangdao of the Bohai Sea, leading to huge damage of the scallop culture industry. Similar blooms have been observed in this region for three years. The causative species of the bloom, which dominated the phytoplankton community with the maximum cell density around 109 cell/L, could not be identified with morphological features due to the small cell size (~2 mm). A pigment analytical method was then adopted to analyze the pigment profile of the phytoplankton samples collected from the blooming sea area. It was found that pico-sized (<2 mm), nano-sized (2-20 mm), and bulk phytoplankton samples had similar pigment profile, representing the pigment signature of the bloom-causative species. The major pigments detected included 19-butanoyloxyfucoxanthin (But-fuco), fucoxanthin (Fuco), diadinoxanthin (Diad) and chlorophyll a (Chl a), and high content of But-fuco was the most significant characteristics of the phytoplankton samples. Based on the pigment composition and content, the bloom-causative species could be tentatively identified as pelagophyte, "type 8" group of haptophyte, or silicoflagellate. Some unique features of the bloom, such as the extremely high cell density, small-sized and But-fuco containing cells, occurring in early summer, and the feeding-cessation effects on scallops, suggest it be a "brown tide" event similar to those reported in the east coast of the United States of America. The recurrent "brown tide" events and their dramatic impacts on the shellfish mariculture industry in Qinhuangdao need close attention in the coming years.  相似文献   

16.
IR spectra of Cu (II)-marine solid particle systems show that Cu(II)-marine solid particle ion exchange causes a stepwise change in the surface H-bonding hydroxyl groups on illite, montmorillonite, CaCO3, γ-AlOOH and goethite, but that this does not affect the surface free hydroxyl groups on illite, montmorillonite and CaCO3, and framework hydroxyl group on goethite and on γ-AlOOH. Over the range of Cu (II) exchange amounts in the present experiment, four stepwise changes were discovered for the surface H-bonding hydroxyl group on illite, while two stepwise changes were observed on the other marine solids. The interfacial stepwise ion exchange theory was first demonstrated by the above experimental evidence.  相似文献   

17.
A great quartity of cosmic dust(spherules) was found in deep-sea sediments during May to July,1983manganese nodule investigations by the R/V“XIANGYANGHONG 16”in the area 7°-11°N,167°-178°Win the Pacific.Comprehensive study of the cosmic dust and determination with Laser Raman MolecularMicroprobe(LRMM) of the molecules in it showed that besides Fe-Fe,Fe~(3+)-O,Fe-Ni,Al-O,Fe-Obr-Si and Si-Onb,it also contained the organic molecules C-H-O and C-H-S-O,various no fixed form molecules of C,CH_2,CH_3 and volatile molecules CO_2,H_2O,OH~- and H_2S,etc…The study result has very important applications for exploring the origin of interplanetary dust parti-cles and life material.  相似文献   

18.
In this paper, Shunde City is selected as a typical region standing for the Zhujiang Delta because of its excellent location and dike-pond system. There are three main characters of agricultural land use in this region. First, the most typical land use form is dike-pond system. It is a special form of artificial ecosystem of land-water interaction. Second, sandy field is also an important land type in this region. Third, land use is greatly influenced by export-oriented economy. Recently, with economic reforming and the opening up of the Zhujiang Delta, the structure of agricultural land use has been changed greatly. The area of mulberry dike has decreased and a variety of planting crops has increased. Various structure of dike-pond farming has emerged in the Zhujiang Delta such as “fruit dike-fish pond”, “flower dike-fish pond”, “grass dike-fish pond”, “vegetable dike-fish pond”. The area of water has slightly increased and its development tends to modernization due to the use of modern equipment and advanced breeding ways. The area for “three high” (high yield, high quality and high efficiency) agriculture has increased greatly.  相似文献   

19.
The meiotic process in Noctiluca scintillans were observed under light microscope.Some abnormal cell divisions, incompletely separated “zoospores” and the changes of the zoospores are described in this paper. Together with the fmdings of field samplings and the previous results by other researchers, the process of meiosis in N. scintillans was supposed to be a pathway to reduce the extra high density of NH3-N within the cell in order to ensure normal population growth.  相似文献   

20.
This article deals with the interaction of zinc with δ−MnO2, γ−MnOOH and manganite existing in natural water systems. The mechanism of the reaction has been studied in detail. From the fact that the “ratio of ion exchange(%)-pH” graph is an “S shaped” curve, it is possible to deduce that the chemical reaction is of the nature of cation exchange. And since the pH range of ion exchange=4, it is possible to further deduce that the reaction can be explained by the mechanism of monovalence cation exchange. The main result of this article is the discovery of a new type of isotherm which has not been mentioned in previous literature here and abroad. This isotherm cannot be represented by any presently available adsorption isotherm equations in marine chemistry. The characteristics of this new type of isotherm are as follows: the isotherm has two “knees” and three “plateaus”, the heights of these three “plateaus” are in the ratio 1:2:3. In order to explain theoretically our new isotherm, this article suggests the application of the principle of interfacial stepwise ion exchange for liquid-solid distribution of minor elements on suspended particulate matter. The corresponding isotherm equation was derived from this theory. The results obtained in this article will be of theoretical guiding significance in the study of the marine geochemistry of zinc. Projects supported by the Science Fund of the Chinese Academy of Sciences.  相似文献   

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