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1 INTRODUCTION Bioavailability to the biota and the biogeo-chemistry of trace metals in marine environment areaffected by their chemical speciation in the naturalsystem (Bruland et al., 1991; Van den Berg andDonat, 1992; Wells et al., 1998). Therefore, thesetwo parameters, the ligands concentrations andconditional stability constants, are important todetermine the complexing capacity. Sea surface microlayer (SML), the thin interfa-cial boundary between ocean and atmosphere, playsan imp…  相似文献   
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黄海春季表面海水溶解无机碳的分层研究   总被引:2,自引:0,他引:2       下载免费PDF全文
根据中国SOLAS计划2006年4月航次出海调查所得数据,系统地研究了春季黄海表面海水溶解无机碳(DIC)的分布规律,同时,与2005年3月、5月两个航次的DIC调查结果进行了对比。结果表明:(1)DIC浓度由近岸向外海逐渐降低;(2)DIC浓度在海水微表层中明显大于次表层和表层,呈现富集现象;(3)由于海水微表层的多层模型特征和海水微表层中Gibbs吸附异常的共同作用,使DIC含量在海水微表层、次表层和表层中变化趋势呈现非线性;(4)在连续站的周日变化研究中发现,DIC浓度在02:00~03:00时间范围内出现最大值,在13:00~15:00时间范围内出现最小值,呈“单峰”分布规律;(5)对比2005年研究结果,发现黄海春季表面海水中的DIC浓度在3,4,5月份依次降低;(6)DIC与温度和盐度均呈较明显的负相关性。  相似文献   
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中国近岸部分海域海水中金属络合配位体浓度的研究   总被引:7,自引:0,他引:7  
采用阳极溶出伏安法对黄河口、青岛近海、大亚湾和南海海域海水中的金属络合配位体的浓度进行了测定,同时探讨了其分布规律与相关参量的关系.结果发现:南海海域海水中的金属络合配体的浓度稍高于其他3个海域,且都明显高于大洋水的浓度;在微表层存在富集现象;在垂直分布上表层最大,然后随深度增加而降低,在底层有较大值;各海域配位体的性质呈复杂性;铜的络合配位体浓度大于镉和铅;总的来说与世界其他海域的分布规律是一致的.同时发现铜络合配位体浓度与BOD(生化需氧量)、COD(化学需氧量)、DOC(溶解有机碳)及黏度存在显著的正相关性.  相似文献   
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Surface water can be divided into three layers from top downward: surface microlayer (SML, thickness≤50 μm), subsurface layer (SSL, ≈25 cm) and surface layer (SL, 1–5m), among which the SML plays an important role on sea-air interaction because of its unique physical-chemical property. Carbon dioxide system including DIC (dissolved inorganic carbon), Alk (alkalinity), pH and pCO2 (partial pressure of CO2) in multilayered waters of the Yellow Sea was studied for the first time in March and May 2005. The results show that: DIC and Alk are obviously enriched in SML. The contents of DIC, Alk and pCO2 become lower in turn from SML, SSL to SL, higher in March and lower in May, whereas for pH it was opposite. The relationship between DIC and Alk is clearly positive, but negative between pH and pCO2. Meanwhile, pCO2 and temperature/salinity is also in positive relation, pCO2 decreases with latitude increase. DIC and Alk show a similar variation trend with the maximum at 02:00–03:00, but pH and pCO2 show an opposite pattern. In addition, the distribution patterns are similar to each other in the three layers. The Yellow Sea is shown to be a sink of atmospheric CO2 in spring by two methods: (1) comparing pCO2 in seawater and atmosphere; (2) turning direction of “pH-depth” curve. Calculation on the base of pCO2 data in SML in four models shows that carbon flux in spring in the area was about -6.96×106 t C.  相似文献   
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