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1.
Chromium isotopic data of physically separated components (chondrules, CAIs, variably magnetic size fractions) of the carbonaceous chondrites Allende and Murchison and bulk rock data of Allende, Ivuna, and Orgueil are reported to evaluate the origin of isotopic heterogeneity in these meteorites. Allende components show ε53Cr and ε54Cr from ?0.23 ± 0.07 to 0.37 ± 0.05 and from ?0.43 ± 0.08 to 3.7 ± 0.1, respectively. In components of Murchison, ε53Cr and ε54Cr vary from ?0.06 ± 0.08 to 0.5 ± 0.1 and from 0.7 ± 0.2 to 1.7 ± 0.1, respectively. The non‐systematic variations of ε53Cr and 55Mn/52Cr in the components of Allende and Murchison were likely caused by small‐scale, alteration‐related redistribution of Mn >20 Ma after formation of the solar system. Chondrule fractions show the lowest 55Mn/52Cr and ε54Cr values of all components, consistent with evaporation of Mn and ε54Cr‐rich carrier phases from chondrule precursors. Components other than the chondrules show higher Mn/Cr and ε54Cr, suggestive of chemical and isotopic complementarity between chondrules and matrix‐rich fractions. Bulk rock compositions calculated based on weighted compositions of components agree with measured Cr isotope data of bulk rocks, in spite of the Cr isotopic heterogeneity reported by the present and previous studies. This indicates that on a sampling scale comprising several hundred milligrams, these meteorites sampled isotopically and chemically homogeneous nebular reservoirs. The linear correlation of 55Mn/52Cr with ε53Cr in bulk rocks likely was caused by variable fractionation of Mn/Cr, subsequent mixing of phases in nebular domains, and radiogenic ingrowth of 53Cr.  相似文献   

2.
Abstract— We have measured O‐isotopic ratios in a variety of olivine grains in the CO3 chondrite Allan Hills (ALH) A77307 using secondary ion mass spectrometry in order to study the chondrule formation process and the origin of isolated olivine grains in unequilibrated chondrites. Oxygen‐isotopic ratios of olivines in this chondrite are variable from δ17O = ?15.5 to +4.5% and δ18O = ?11.5 to +3.9%, with Δ17O varying from ?10.4 to +3.5%. Forsteritic olivines, Fa<1, are enriched in 16O relative to the bulk chondrite, whereas more FeO‐rich olivines are more depleted in 16O. Most ratios lie close to the carbonaceous chondrite anhydrous minerals (CCAM) line with negative values of Δ17O, although one grain of composition Fa4 has a mean Δ17O of +1.6%. Marked O‐isotopic heterogeneity within one FeO‐rich chondrule is the result of incorporation of relic, 16O‐rich, Mg‐rich grains into a more 16O‐depleted host. Isolated olivine grains, including isolated forsterites, have similar O‐isotopic ratios to olivine in chondrules of corresponding chemical composition. This is consistent with derivation of isolated olivine from chondrules, as well as the possibility that isolated grains are chondrule precursors. The high 16O in forsteritic olivine is similar to that observed in forsterite in CV and CI chondrites and the ordinary chondrite Julesburg and suggests nebula‐wide processes for the origin of forsterite that appears to be a primitive nebular component.  相似文献   

3.
Abstract— The metal‐rich chondrites Hammadah al Hamra (HH) 237 and Queen Alexandra Range (QUE) 94411, paired with QUE 94627, contain relatively rare (<1 vol%) calcium‐aluminum‐rich inclusions (CAIs) and Al‐diopside‐rich chondrules. Forty CAIs and CAI fragments and seven Al‐diopside‐rich chondrules were identified in HH 237 and QUE 94411/94627. The CAIs, ～50–400 μm in apparent diameter, include (a) 22 (56%) pyroxene‐spinel ± melilite (+forsterite rim), (b) 11 (28%) forsterite‐bearing, pyroxene‐spinel ± melilite ± anorthite (+forsterite rim) (c) 2 (5%) grossite‐rich (+spinel‐melilite‐pyroxene rim), (d) 2 (5%) hibonite‐melilite (+spinel‐pyroxene ± forsterite rim), (e) 1 (2%) hibonite‐bearing, spinel‐perovskite (+melilite‐pyroxene rim), (f) 1 (2%) spinel‐melilite‐pyroxene‐anorthite, and (g) 1 (2%) amoeboid olivine aggregate. Each type of CAI is known to exist in other chondrite groups, but the high abundance of pyroxene‐spinel ± melilite CAIs with igneous textures and surrounded by a forsterite rim are unique features of HH 237 and QUE 94411/94627. Additionally, oxygen isotopes consistently show relatively heavy compositions with Δ17O ranging from ?6%0 to ?10%0 (1σ = 1.3%0) for all analyzed CAI minerals (grossite, hibonite, melilite, pyroxene, spinel). This suggests that the CAIs formed in a reservoir isotopically distinct from the reservoir(s) where “normal”, 16O‐rich (Δ17O < ?20%0) CAIs in most other chondritic meteorites formed. The Al‐diopside‐rich chondrules, which have previously been observed in CH chondrites and the unique carbonaceous chondrite Adelaide, contain Al‐diopside grains enclosing oriented inclusions of forsterite, and interstitial anorthitic mesostasis and Al‐rich, Ca‐poor pyroxene, occasionally enclosing spinel and forsterite. These chondrules are mineralogically similar to the Al‐rich barred‐olivine chondrules in HH 237 and QUE 94411/94627, but have lower Cr concentrations than the latter, indicating that they may have formed during the same chondrule‐forming event, but at slightly different ambient nebular temperatures. Aluminum‐diopside grains from two Al‐diopside‐rich chondrules have O‐isotopic compositions (Δ17O ? ?7 ± 1.1 %0) similar to CAI minerals, suggesting that they formed from an isotopically similar reservoir. The oxygen‐isotopic composition of one Ca, Al‐poor cryptocrystalline chondrule in QUE 94411/94627 was analyzed and found to have Δ17O ? ?3 ± 1.4%0. The characteristics of the CAIs in HH 237 and QUE 94411/94627 are inconsistent with an impact origin of these metal‐rich meteorites. Instead they suggest that the components in CB chondrites are pristine products of large‐scale, high‐temperature processes in the solar nebula and should be considered bona fide chondrites.  相似文献   

4.
Abstract— Anorthite‐rich chondrules in CR and CH carbonaceous chondrites consist of magnesian low‐Ca pyroxene and forsterite phenocrysts, FeNi‐metal nodules, interstitial anorthite, Al‐Ti‐Cr‐rich low‐Ca and high‐Ca pyroxenes, and crystalline mesostasis composed of silica, anorthite and high‐Ca pyroxene. Three anorthite‐rich chondrules contain relic calcium‐aluminum‐rich inclusions (CAIs) composed of anorthite, spinel, ±Al‐diopside, and ± forsterite. A few chondrules contain regions which are texturally and mineralogically similar to magnesian (type I) chondrules and consist of forsterite, low‐Ca pyroxene and abundant FeNi‐metal nodules. Anorthite‐rich chondrules in CR and CH chondrites are mineralogically similar to those in CV and CO carbonaceous chondrites, but contain no secondary nepheline, sodalite or ferrosilite. Relatively high abundances of moderately‐volatile elements such as Cr, Mn and Si in the anorthite‐rich chondrules suggest that these chondrules could not have been produced by volatilization of the ferromagnesian chondrule precursors or by melting of the refractory materials only. We infer instead that anorthite‐rich chondrules in carbonaceous chondrites formed by melting of the reduced chondrule precursors (olivine, pyroxenes, FeNi‐metal) mixed with the refractory materials, including relic CAIs, composed of anorthite, spinel, high‐Ca pyroxene and forsterite. The observed mineralogical and textural similarities of the anorthite‐rich chondrules in several carbonaceous chondrite groups (CV, CO, CH, CR) may indicate that these chondrules formed in the region(s) intermediate between the regions where CAIs and ferromagnesian chondrules originated. This may explain the relative enrichment of anorthite‐rich chondrules in 16O compared to typical ferromagnesian chondrules (Russell et al., 2000).  相似文献   

5.
Abstract— The CV (Vigarano‐type) chondrites are a petrologically diverse group of meteorites that are divided into the reduced and the Bali‐like and Allende‐like oxidized subgroups largely based on secondary mineralogy (Weisberg et al., 1997; Krot et al., 1998b). Some chondrules and calcium‐aluminum‐rich inclusions (CAIs) in the reduced CV chondrite Vigarano show alteration features similar to those in Allende: metal is oxidized to magnetite; low‐Ca pyroxene, forsterite, and magnetite are rimmed and veined by ferrous olivine (Fs40–50); and plagioclase mesostases and melilite are replaced by nepheline and sodalite (Sylvester et al., 1993; Kimura and Ikeda, 1996, 1997, 1998). Our petrographic observations indicate that Vigarano also contains individual chondrules, chondrule fragments, and lithic clasts of the Bali‐like oxidized CV materials. The largest lithic clast (about 1 times 2 cm in size) is composed of opaque matrix, type‐I chondrules (400–2000 μm in apparent diameter) surrounded by coarse‐grained and fine‐grained rims, and rare CAIs. The matrix‐chondrule ratio is about 1.1. Opaque nodules in chondrules in the clast consist of Cr‐poor and Cr‐rich magnetite, Ni‐ and Co‐rich metal, Ni‐poor and Ni‐rich sulfide; low‐Ni metal nodules occur only inside chondrule phenocrysts. Chromium‐poor magnetite is preferentially replaced by fayalite. Chondrule mesostases are replaced by phyllosilicates; low‐Ca pyroxene and olivine phenocrysts appear to be unaltered. Matrix in the clast consists of very fine‐grained (<1 μm) ferrous olivine, anhedral fayalite grains (Fa80–100), rounded objects of porous Ca‐Fe‐rich pyroxenes (Fs10–50Wo50), Ni‐poor sulfide, Ni‐ and Co‐rich metal, and phyllosilicates; magnetite is rare. On the basis of the presence of the Bali‐like lithified chondritic clast—in addition to individual chondrules and CAIs of both Bali‐like and Allende‐like materials—in the reduced CV chondrite Vigarano, we infer that (1) all three types of materials were mixed during regolith gardening on the CV asteroidal body, and (2) the reduced and oxidized CV materials may have originated from a single, heterogeneously altered asteroid.  相似文献   

6.
In Allende, a very complex compound chondrule (Allende compound chondrule; ACC) was found consisting of at least 16 subchondrules (14 siblings and 2 independents). Its overall texture can roughly be described as a barred olivine object (BO). The BO texture is similar in all siblings, but does not exist in the two independents, which appear as relatively compact olivine‐rich units. Because of secondary alteration of pristine Allende components and the ACC in particular, only limited predictions can be made concerning the original compositions of the colliding melt droplets. Based on textural and mineralogical characteristics, the siblings must have been formed on a very short time scale in a dense, local environment. This is also supported by oxygen isotope systematics showing similar compositions for all 16 subchondrules. Furthermore, the ACC subchondrules are isotopically distinct from typical Allende chondrules, indicating formation in or reaction with a more 16O‐poor reservoir. We modeled constraints on the particle density required at the ACC formation location, using textural, mineral‐chemical, and isotopic observations on this multicompound chondrule to define melt droplet collision conditions. In this context, we discuss the possible relationship between the formation of complex chondrules and the formation of macrochondrules and cluster chondrites. While macrochondrules may have formed under similar or related conditions as complex chondrules, cluster chondrites certainly require different formation conditions. Cluster chondrites represent a mixture of viscously deformed, seemingly young chondrules of different chemical and textural types and a population of older chondrules. Concerning the formation of ACC calculations suggest the existence of very local, kilometer‐sized, and super‐dense chondrule‐forming regions with extremely high solid‐to‐gas mass ratios of 1000 or more.  相似文献   

7.
Abstract— Minor element variations in MgAl2O4 spinel from the type B1 calcium‐aluminum‐rich inclusion (CAI) Allende TS‐34 confirm earlier studies in showing correlations between the minor element chemistry of spinels with their location within the inclusion and with the chemistry of host silicate phases. These correlations result from a combination of crystallization of a liquid produced by re‐melting event(s) and local re‐equilibration during subsolidus reheating. The correlation of the Ti and V in spinel inclusions with the Ti and V in the adjacent host clinopyroxene can be qualitatively explained by spinel and clinopyroxene crystallization prior to melilite, following a partial melting event. There are, however, difficulties in quantitative modeling of the observed trends, and it is easier to explain the Ti correlation in terms of complete re‐equilibration. The correlation of V in spinel inclusions with that in the adjacent host clinopyroxene also cannot be quantitatively modeled by fractional crystallization of the liquid produced by re‐melting, but it can be explained by partial re‐equilibration. The distinct V and Ti concentrations in spinel inclusions in melilite from the edge regions of the CAI are best explained as being affected by only a minor degree of re‐equilibration. The center melilites and included spinels formed during crystallization of the liquid produced by re‐melting, while the edge melilites and included spinels are primary. The oxygen isotope compositions of TS‐34 spinels are uniformly 16O‐rich, regardless of the host silicate phase or its location within the inclusion. Similar to other type B1 CAIs, clinopyroxene is 16O‐rich, but melilite is relatively 16O‐poor. These data require that the oxygen isotope exchange in TS‐34 melilite occurred subsequent to the last re‐melting event.  相似文献   

8.
Abstract— We describe the mineralogy, petrology, oxygen, and magnesium isotope compositions of three coarse‐grained, igneous, anorthite‐rich (type C) Ca‐Al‐rich inclusions (CAIs) (ABC, TS26, and 93) that are associated with ferromagnesian chondrule‐like silicate materials from the CV carbonaceous chondrite Allende. The CAIs consist of lath‐shaped anorthite (An99), Cr‐bearing Al‐Ti‐diopside (Al and Ti contents are highly variable), spinel, and highly åkermanitic and Na‐rich melilite (Åk63–74, 0.4–0.6 wt% Na2O). TS26 and 93 lack Wark‐Lovering rim layers; ABC is a CAI fragment missing the outermost part. The peripheral portions of TS26 and ABC are enriched in SiO2 and depleted in TiO2 and Al2O3 compared to their cores and contain relict ferromagnesian chondrule fragments composed of forsteritic olivine (Fa6–8) and low‐Ca pyroxene/pigeonite (Fs1Wo1–9). The relict grains are corroded by Al‐Ti‐diopside of the host CAIs and surrounded by haloes of augite (Fs0.5Wo30–42). The outer portion of CAI 93 enriched in spinel is overgrown by coarse‐grained pigeonite (Fs0.5–2Wo5–17), augite (Fs0.5Wo38–42), and anorthitic plagioclase (An84). Relict olivine and low‐Ca pyroxene/pigeonite in ABC and TS26, and the pigeonite‐augite rim around 93 are 16O‐poor (Δ17O ～ ?1‰ to ?8‰). Spinel and Al‐Ti‐diopside in cores of CAIs ABC, TS26, and 93 are 16O‐enriched (Δ17O down to ?20‰), whereas Al‐Ti‐diopside in the outer zones, as well as melilite and anorthite, are 16O‐depleted to various degrees (Δ17O = ?11‰ to 2‰). In contrast to typical Allende CAIs that have the canonical initial 26Al/27Al ratio of ～5 × 10?5 ABC, 93, and TS26 are 26Al‐poor with (26Al/27Al)0 ratios of (4.7 ± 1.4) × 10?6 (1.5 ± 1.8) × 10?6 <1.2 × 10?6 respectively. We conclude that ABC, TS26, and 93 experienced remelting with addition of ferromagnesian chondrule silicates and incomplete oxygen isotopic exchange in an 16O‐poor gaseous reservoir, probably in the chondrule‐forming region. This melting episode could have reset the 26Al‐26Mg systematics of the host CAIs, suggesting it occurred ～2 Myr after formation of most CAIs. These observations and the common presence of relict CAIs inside chondrules suggest that CAIs predated formation of chondrules.  相似文献   

9.
Abstract— We have used the Manchester ISOLAB 54 ion microprobe to make in situ measurements of the 17O/16O and 18O/16O ratios of olivine grains in the Julesburg (L3.6) and Allende (CV3) chondrites. We have discovered a population of olivines in Julesburg characterised by (1) the most 16O-rich compositions yet reported for olivine from an ordinary chondrite; (2) cores of low-Fa olivine, which frequently shows blue cathodoluminesce; (3) thick coats of more Fa-rich (Fa ～20) olivine, which is also 16O-enriched. In an O isotopic plot, the Julesburg 16O-rich grains form a roughly linear array that is offset from the Allende mixing line. The presence of very low Fa olivine and, sometimes, well-defined Fa-rich coats indicates that these grains experienced significantly less thermal metamorphism than most of the olivine in the meteorite. Some 16O-rich Julesburg grains are associated with minor feldspar or pyroxene and are probably chondrule fragments. They are isotopically indistinguishable from forsterite in Allende; however, Allende forsterite grains do not have the thick Fa20 coats typical of those in Julesburg. These 16O-rich forsterite grains appear to be related to the “blue olivine” of Steele (1986). Both cores and coats of 16O-rich grains in Julesburg are isotopically distinct from olivine in Semarkona group A and group B chondrules.  相似文献   

10.
Abstract— The Mg‐isotopic compositions in five barred olivine (BO) chondrules, one coarse‐grained rim of a BO chondrule, a relic spinel in a BO chondrule, one skeletal olivine chondrule similar to BO chondrules in mineralogy and composition, and two non‐BO chondrules from the Allende meteorite have been measured by thermal ionization mass spectrometry. The Mg isotopes are not fractionated and are within terrestrial standard values (±2.0%o per amu) in seven of the eight analyzed ferromagnesian chondrules. A clump of relic spinel grain and its host BO chondrule R‐11 give well‐resolvable Mg fractionations that show an enrichment of the heavier isotopes, up to +2.5%‰ per amu. The Mg‐isotopic compositions of coarse‐grained rim are identical to those of the host chondrule with BO texture. The results imply that ferromagnesian and refractory precursor components of the Allende chondrule may have been formed from isotopically heterogeneous reservoirs. In the nebula region where Allende chondrules formed, recycling of chondrules and multiple high‐temperature heating did not significantly alter the chemical and isotopic memory of earlier generations. Chemical and isotopic characteristics of refractory precursors of carbonaceous chondrite chondrules and CAIs are more closely related than previously thought. One of the refractory chondrule precursors of CV Allende is enriched in the heavier Mg isotopes and different from those of more common ferromagnesian chondrule precursors. The most probable scenario at the location where chondrule R‐11 formed is as follows. Before chondrule formation, several high‐temperature events occurred and then RPMs, refractory oxides, and silicates condensed from the nebular gas in which Mg isotopes were fractionated. Then, this CAI was transported into the chondrule formation region and mixed with more common, ferromagnesian precursors with normal Mg isotopes, and formed the BO chondrule. Because Mg isotope heterogeneity among silicates and spinel are found in some CAIs (Esat and Taylor, 1984), we cannot rule out the possibility that Mg isotopes of a melted portion of the refractory precursor (i.e., outer portion of CAI) are normal or enriched in the light isotope. Magnesium isotopes in the R‐11 host are also enriched in the heavier isotopes, +2.5%o per amu, which suggests that effects of isotopic heterogeneity among silicates and spinel, if they existed, are not considered to be large. It is possible that CAI precursor silicates partially dissolved during the chondrule forming event, contributing Mg to the melt and producing a uniform Mg‐isotopic signature but enriched in the heavier Mg isotopes, +2.5%‰ per amu. Most Mg isotopes in more common ferromagnesian chondrules represent normal chondritic material. Chemical and Mg‐isotopic signatures formed during nebular fractionations were not destroyed during thermal processes that formed the chondrule, and these were partly preserved in relic phases. Recycling of Allende chondrules and multiple heating at high temperature did not significantly alter the chemical and Mg‐isotopic memory of earlier generations.  相似文献   

11.
Abstract— Petrographic, compositional, and isotopic characteristics were studied for three calcium‐aluminum‐rich inclusions (CAIs) and four plagioclase‐bearing chondrules (three of them Al‐rich) from the Axtell (CV3) chondrite. All seven objects have analogues in Allende (CV3) and other primitive chondrites, yet Axtell, like most other chondrites, contains a distinctive suite of CAIs and chondrules. In common with Allende CAIs, CAIs in Axtell exhibit initial 26Al/27Al ratios ((26Al/27Al)0) ranging from ～5 × 10?5 to <1.1 × 10?5, and plagioclase‐bearing chondrules have (26Al/27Al)0 ratios of ～3 × 10?6 and lower. One type‐A CAI has the characteristics of a FUN inclusion. The Al‐Mg data imply that the plagioclase‐bearing chondrules began to form >2 Ma after the first CAIs. As in other CV3 chondrites, some objects in Axtell show evidence of isotopic disturbance. Axtell has experienced only mild thermal metamorphism (<600 °C), probably not enough to disturb the Al‐Mg systematics. Its CAIs and chondrules have suffered extensive metasomatism, probably prior to final accretion. These data indicate that CAIs and chondrules in Axtell (and other meteorites) had an extended history of several million years before their incorporation into the Axtell parent body. These long time periods appear to require a mechanism in the early solar system to prevent CAIs and chondrules from falling into the Sun via gas drag for several million years before final accretion. We also examined the compositional relationships among the four plagioclase‐bearing chondrules (two with large anorthite laths and two barred‐olivine chondrules) and between the chondrules and CAIs. Three processes were examined: (1) igneous differentiation, (2) assimilation of a CAI by average nebular material, and (3) evaporation of volatile elements from average nebular material. We find no evidence that igneous differentiation played a role in producing the chondrule compositions, although the barred olivine compositions can be related by addition or subtraction of olivine. Methods (2) and (3) could have produced the composition of one chondrule, AXCH‐1471, but neither process explains the other compositions. Our study indicates that plagioclase‐bearing objects originated through a variety of processes.  相似文献   

12.
Abstract— It was suggested that multilayered accretionary rims composed of ferrous olivine, andradite, wollastonite, salite‐hedenbergitic pyroxenes, nepheline, and Ni‐rich sulfides around Allende calcium‐aluminum‐rich inclusions (CAIs) are aggregates of gas‐solid condensates which reflect significant fluctuations in physico‐chemical conditions in the slowly cooling solar nebula and grain/gas separation processes. In order to test this model, we studied the mineralogy of accretionary rims around one type A CAI (E104) and one type B CAI (E48) from the reduced CV3 chondrite Efremovka, which is less altered than Allende. In contrast to the Allende accretionary rims, those in Efremovka consist of coarse‐grained (20–40 μm), anhedral forsterite (Fa1–8), Fe, Ni‐metal nodules, amoeboid olivine aggregates (AOAs) and fine‐grained CAIs composed of Al‐diopside, anorthite, and spinel, ± forsterite. Although the fine‐grained CAIs, AOAs and host CAIs are virtually unaltered, a hibonite‐spinel‐perovskite CAI in the E48 accretionary rim experienced extensive alteration, which resulted in the formation of Fe‐rich, Zn‐bearing spinel, and a Ca, Al, Si‐hydrous mineral. Forsterites in the accretionary rims typically show an aggregational nature and consist of small olivine grains with numerous pores and tiny inclusions of Al‐rich minerals. No evidence for the replacement of forsterite by enstatite was found; no chondrule fragments were identified in the accretionary rims. We infer that accretionary rims in Efremovka are more primitive than those in Allende and formed by aggregation of high‐temperature condensates around host CAIs in the CAI‐forming regions. The rimmed CAIs were removed from these regions prior to condensation of enstatite and alkalies. The absence of andradite, wollastonite, and hedenbergite from the Efremovka rims may indicate that these rims sampled different nebular regions than the Allende rims. Alternatively, the Ca, Fe‐rich silicates rimming Allende CAIs may have resulted from late‐stage metasomatic alteration, under oxidizing conditions, of original Efremovka‐like accretionary rims. The observed differences in O‐isotope composition between forsterite and Ca, Fe‐rich minerals in the Allende accretionary rims (Hiyagon, 1998) suggest that the oxidizing fluid had an 16O‐poor oxygen isotopic composition.  相似文献   

13.
We present high‐precision measurements of the Mg isotopic compositions of a suite of types I and II chondrules separated from the Murchison and Murray CM2 carbonaceous chondrites. These chondrules are olivine‐ and pyroxene‐rich and have low 27Al/24Mg ratios (0.012–0.316). The Mg isotopic compositions of Murray chondrules are on average lighter (δ26Mg ranging from ?0.95‰ to ?0.15‰ relative to the DSM‐3 standard) than those of Murchison (δ26Mg ranging from ?1.27‰ to +0.77‰). Taken together, the CM2 chondrules exhibit a narrower range of Mg isotopic compositions than those from CV and CB chondrites studied previously. The least‐altered CM2 chondrules are on average lighter (average δ26Mg = ?0.39 ± 0.30‰, 2SE) than the moderately to heavily altered CM2 chondrules (average δ26Mg = ?0.11 ± 0.21‰, 2SE). The compositions of CM2 chondrules are consistent with isotopic fractionation toward heavy Mg being associated with the formation of secondary silicate phases on the CM2 parent body, but were also probably affected by volatilization and recondensation processes involved in their original formation. The low‐Al CM2 chondrules analyzed here do not exhibit any mass‐independent variations in 26Mg from the decay of 26Al, with the exception of two chondrules that show only small variations just outside of the analytical error. In the case of the chondrule with the highest Al/Mg ratio (a type IAB chondrule from Murchison), the lack of resolvable 26Mg excess suggests that it either formed >1 Ma after calcium‐aluminum‐rich inclusions, or that its Al‐Mg isotope systematics were reset by secondary alteration processes on the CM2 chondrite parent body after the decay of 26Al.  相似文献   

14.
Precise triple oxygen isotope compositions of 32 Allende bulk chondrules (ABCs) are determined using laser‐assisted fluorination mass spectrometry. Various chemically characterized chondrule types show ranges in δ18O that vary from ?4.80‰ to +1.10‰ (porphyritic olivine; PO, N = 15), ?3.10‰ to +1.50‰ (porphyritic olivine pyroxene; POP, N = 9), ?3.40‰ to +2.60‰ (barred olivine; BO, N = 4), and ?3.60‰ to +1.30‰ (porphyritic pyroxene; PP, N = 3). Oxygen isotope data of these chondrules yield a regression line referred to as the Allende bulk chondrule line (ABC line, slope = 0.86 ± 0.02). Most of our data fall closer to the primitive chondrule minerals line (PCM line, slope = 0.987 ± 0.013) and the carbonaceous chondrite anhydrous mineral line (CCAM line, slope = 0.94 ± 0.02) than the Allende anhydrous mineral line (AAML, slope = 1.00 ± 0.01) with a maximum δ18O value (+2.60‰) observed in a BO chondrule and a minimum δ18O value (?4.80‰) shown by a PO chondrule. Similarly, these chondrules depict variable ?17O values that range from ?5.65‰ to ?3.25‰ (PO), ?4.60‰ to ?2.80‰ (POP), ?4.95‰ to ?3.00‰ (BO), ?5.30‰ to ?3.20‰ (PP), and ?4.90‰ (CC). A simple model is proposed for the Allende CV3 chondrite with reference to the AAML and PCM line to illustrate the isotopic variations occurred due to the aqueous alteration processes. The estimated temperature ranging from 10 to 130 °C (mean ~60 °C) implies that the secondary mineralization in Allende happened in a warmer and relatively dry environment compared to Murchison. We further propose that thermal metamorphism could have dehydrated the Allende matrix at temperatures between >150 °C and <600 °C.  相似文献   

15.
Abstract– High‐precision isotope imaging analyses of reversely zoned melilite crystals in the gehlenitic mantle of Type A CAI ON01 of the Allende carbonaceous chondrite reveal that there are four types of oxygen isotopic distributions within melilite single crystals: (1) uniform depletion of 16O (δ18O ≈ ?10‰), (2) uniform enrichment of 16O (δ18O ≈ ?40‰), (3) variations in isotopic composition from 16O‐poor core to 16O‐rich rim (δ18O ≈ ?10‰ to ?30‰, ?20‰ to ?45‰, and ?10‰ to ?35‰) with decreasing åkermanite content, and (4) 16O‐poor composition (δ18O ≥ ?10‰) along the crystal rim. Hibonite, spinel, and perovskite grains are 16O‐rich (δ18O ≈ ?45‰), and adjoin 16O‐poor melilites. Gas‐solid or gas‐melt isotope exchange in the nebula is inconsistent with both the distinct oxygen isotopic compositions among the minerals and the reverse zoning of melilite. Fluid‐rock interaction on the parent body resulted in 16O‐poor compositions of limited areas near holes, cracks, or secondary phases, such as anorthite or grossular. We conclude that reversely zoned melilites mostly preserve the primary oxygen isotopic composition of either 16O‐enriched or 16O‐depleted gas from which they were condensed. The correlation between oxygen isotopic composition and åkermanite content may indicate that oxygen isotopes of the solar nebula gas changed from 16O‐poor to 16O‐rich during melilite crystal growth. We suggest that the radial excursions of the inner edge of the protoplanetary disk gas simultaneously resulted in both the reverse zoning and oxygen isotopic variation of melilite, due to mixing of 16O‐poor disk gas and 16O‐rich coronal gas. Gas condensates aggregated to form the gehlenite mantle of the Type A CAI ON01.  相似文献   

16.
Ti valence measurements in MgAl2O4 spinel from calcium‐aluminum‐rich inclusions (CAIs) by X‐ray absorption near‐edge structure (XANES) spectroscopy show that many spinels have predominantly tetravalent Ti, regardless of host phases. The average spinel in Allende type B1 inclusion TS34 has 87% Ti+4. Most spinels in fluffy type A (FTA) inclusions also have high Ti valence. In contrast, the rims of some spinels in TS34 and spinel grain cores in two Vigarano type B inclusions have larger amounts of trivalent titanium. Spinels from TS34 have approximately equal amounts of divalent and trivalent vanadium. Based on experiments conducted on CAI‐like compositions over a range of redox conditions, both clinopyroxene and spinel should be Ti+3‐rich if they equilibrated with CAI liquids under near‐solar oxygen fugacities. In igneous inclusions, the seeming paradox of high‐valence spinels coexisting with low‐valence clinopyroxene can be explained either by transient oxidizing conditions accompanying low‐pressure evaporation or by equilibration of spinel with relict Ti+4‐rich phases (e.g., perovskite) prior to or during melting. Ion probe analyses of large spinel grains in TS34 show that they are enriched in heavy Mg, with an average Δ25Mg of 4.25 ± 0.028‰, consistent with formation of the spinel from an evaporating liquid. Δ25Mg shows small, but significant, variation, both within individual spinels and between spinel and adjacent melilite hosts. The Δ25Mg data are most simply explained by the low‐pressure evaporation model, but this model has difficulty explaining the high Ti+4 concentrations in spinel.  相似文献   

17.
High‐precision secondary ion mass spectrometry (SIMS) was employed to investigate oxygen three isotopes of phenocrysts in 35 chondrules from the Yamato (Y) 82094 ungrouped 3.2 carbonaceous chondrite. Twenty‐one of 21 chondrules have multiple homogeneous pyroxene data (?17O 3SD analytical uncertainty: 0.7‰); 17 of 17 chondrules have multiple homogeneous pyroxene and plagioclase data. Twenty‐one of 25 chondrules have one or more olivine data matching coexisting pyroxene data. Such homogeneous phenocrysts (1) are interpreted to have crystallized from the final chondrule melt, defining host O‐isotope ratios; and (2) suggest efficient O‐isotope exchange between ambient gas and chondrule melt during formation. Host values plot within 0.7‰ of the primitive chondrule mineral (PCM) line. Seventeen chondrules have relict olivine and/or spinel, with some δ17O and δ18O values approaching ?40‰, similar to CAI or AOA‐like precursors. Regarding host chondrule data, 22 of 34 have Mg#s of 98.8–99.5 and ?17O of ?3.9‰ to ?6.1‰, consistent with most Acfer 094, CO, CR, and CV chondrite chondrules, and suggesting a common reduced O‐isotope reservoir devoid of 16O‐poor H2O. Six Y‐82094 chondrules have ?17O near ?2.5‰, with Mg#s of 64–97, consistent with lower Mg# chondrules from Acfer 094, CO, CR, and CV chondrites; their signatures suggest precursors consisting of those forming Mg# ~99, ?17O: ?5‰ ± 1‰ chondrules plus 16O‐poor H2O, at high dust enrichments. Three type II chondrules plot slightly above the PCM line, near the terrestrial fractionation line (?17O: ~+0.1‰). Their O‐isotopes and olivine chemistry are like LL3 type II chondrules, suggesting they sampled ordinary chondrite‐like chondrule precursors. Finally, three Mg# >99 chondrules have ?17O of ?6.7‰ to ?8.1‰, potentially due to 16O‐rich refractory precursor components. The predominance of Mg# ~99, ?17O: ?5‰ ± 1‰ chondrules and a high chondrule‐to‐matrix ratio suggests bulk Y‐82094 characteristics are closely related to anhydrous dust sampled by most carbonaceous chondrite chondrules.  相似文献   

18.
We report microscopic, cathodoluminescence, chemical, and O isotopic measurements of FeO‐poor isolated olivine grains (IOG) in the carbonaceous chondrites Allende (CV3), Northwest Africa 5958 (C2‐ung), Northwest Africa 11086 (CM2‐an), and Allan Hills 77307 (CO3.0). The general petrographic, chemical, and isotopic similarity with bona fide type I chondrules confirms that the IOG derived from them. The concentric CL zoning, reflecting a decrease in refractory elements toward the margins, and frequent rimming by enstatite are taken as evidence of interaction of the IOG with the gas as stand‐alone objects. This indicates that they were splashed out of chondrules when these were still partially molten. CaO‐rich refractory forsterites, which are restricted to ?17O <?4‰ likely escaped equilibration at lower temperatures because of their large size and possibly quicker quenching. The IOG thus bear witness to frequent collisions in the chondrule‐forming regions.  相似文献   

19.
Abstract— We report the results of a mineralogical and O‐isotopic study of 362 chondrules disaggregated from the Bo Xian chondrite. The range of mineral compositions (Fa = 0.8–31.2%, mean = 23.5%, mode = 27–28%) are consistent with a reclassification of this meteorite from LL4 to LL3.9. Chondrule diameters range from 0.20 to 3.40 mm (mean = 0.74 mm) in the disaggregated population. A lower mean diameter (0.64 mm) calculated from thin‐section measurements partly reflects the high proportion of chondrule fragments. The chondrule size distribution, which is approximately log‐normal, is consistent with size‐sorting mechanisms. This sorting could be linked to the fragmentation of many chondrules on the parent body. However, in detail, the variation in diameter of different chondrule types and a hiatus in the size distribution at 0.6 mm indicate that there may have been complex controls perhaps partly being determined by the chondrule formation mechanism. Seven percent of the sectioned chondrules (102) contain chemically fractionated mineral assemblages: cristobalite‐bearing and Al‐rich. This significant degree of chemical heterogeneity probably resulted from both igneous and volatility controls. Oxygen‐isotopic compositions were determined on mineral separates and 16 of the sectioned chondrules. Three separate isotopic exchange events have been identified. The dominant one is a low‐temperature hydrous gas‐solid exchange event between 16O‐rich solid and 16O‐poor gas reservoirs that lay along a slope 1.0 line on three‐isotope plots. Partial equilibration with the gas by feldspar and cristobalite, which exchanged more rapidly than olivine or pyroxene, led to formation of a slope 0.77 mixing line for Bo Xian and other LL chondrites. Mineralogy is the dominant control on the extent of this exchange; no relationship between isotopic composition and chondrule texture or size was identified. The feldspar separate and cristobalite‐rich chondrules have the most 16O‐poor compositions. Subsequently, thermal metamorphism in the parent body led to partial isotopic equilibration between the different mineral phases. A third exchange event, predating the other two events, is probably shown by one of the Al‐rich chondrules. This has an 16O‐rich composition, lying below the terrestrial fractionation line. Another Al‐rich chondrule has a normal ordinary chondrite isotopic composition. It is not clear whether the isotopic fractionation recorded in some Al‐rich chondrules can be achieved by the dominant gas‐solid exchange. Instead, the precursor O to the mineral phases may have become 16O‐rich during an earlier phase of mass‐independent fractionation.  相似文献   

20.
Abstract— Two rare, spinel-bearing, Al-rich chondrules have been identified in new chondrite finds from Roosevelt County, New Mexico—RC 071 (L4) and RC 072 (L5). These chondrules have unusual mineralogies, dominated by highly and asymmetrically zoned, Al-Cr-rich spinels. Two alternatives exist to explain the origin of this zoning—fractional crystallization or metamorphism. It appears that fractional crystallization formed the zoning of the trivalent cations (Al, Cr) and caused a localized depletion in chromites around the large Al-Cr-rich spinels. The origin of the zoning of the divalent cations (Fe, Mg, Zn) is less certain. Diffusive exchange and partitioning of Fe and Mg between olivine and spinel during parent body metamorphism can explain the asymmetric zoning of these elements. Unfortunately, appropriate studies of natural and experimental systems to evaluate the formation of zoning of the divalent cations by fractional crystallization have not yet been conducted. The bulk compositions of the chondrules suggest affinities with the Na-Al-Cr-rich chondrules, as would be expected from the abundance of Al-Cr-rich spinels. Melting of rare and unusual precursors produced the compositions of Na-Al-Cr-rich chondrules, possibly including a spinel-rich precursor enriched in Cr2O3 and ZnO. The two chondrules we studied have larger modal abundances of Al-Cr-rich spinels than reported in other Na-Al-Cr-rich chondrules of similar composition, and Al-rich chondrules even more enriched in spinel are reported in the literature. These differences indicate that factors other than bulk composition control the mineralogy of the chondrules. The most important of these factors are the temperature to which the molten chondrule was heated and the cooling rate during crystallization. These two chondrules cooled rapidly from near the liquidus, as indicated by the zoning, occurrence and sizes of spinels, radiating chondrule textures and localized chromite depletions. The range of mineralogies in other Al-rich chondrules of similar composition reflect a range of peak temperatures and cooling rates. We see no reason to believe that this range is fundamentally different from the range of thermal histories experienced by “normal” Fe-Mg-rich chondrules.  相似文献   

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