Clinopyroxene on the join CaMgSi2O6-CaFe3+AlSiO6-CaTiAl2O6 at low oxygen fugacity     

Masahide Akasaka 《Journal of Earth System Science》1990,99(1):39-48

Subsolidus phase relations on the join CaMgSi₂O₆-CaFe³⁺ AlSiO₆-CaTiAl₂O₆ were studied by the ordinary quenching method at \(f_{O_2 } = 10^{ - 11} \) atm and 1,100°C. Crystalline phases encountered are clinopyroxene_ss (ss:solid solution) (Cpx_ss), melilite (Mel), perovskite (Pv), spinel_ss (Sp_ss), magnetite_ss (Mt_ss) and anorthite (An). There is no Cpx_ss single phase field, and the following assemblages were found; Cpx_ss+Mel, Cpx_ss+Mel+Sp_ss, Cpx_ss+Mel+Pv, Cpx_ss+Mel+Sp_ss+Pv, Cpx_ss+Pv+Sp_ss+An, Sp_ss+Pv+Mel+An+Cpx_ss, Mel+Mt_ss+An+Sp_ss+Cpx_ss+liquid and Mel+Mt_ss+An+Sp_ss+Cpx_ss+Pv. Mössbauer spectral study revealed that Cpx_ss contains both Fe²⁺ and Fe³⁺ in the octahedral site, and it was confirmed that the CaFe³⁺ AlSiO₆ content in the Cpx_ss at low \(f_{O_2 } \) is considerably less than that in the Cpx_ss crystallized in air, whereas the CaFe²⁺Si₂O₆ component increases. The maximum solubility of CaTlAl₂O₆ component in the Cpx_ss at low \(f_{O_2 } \) is higher than that in air. The decrease of CaFe³⁺ AlSiO₆ in the Cpx_ss at low \(f_{O_2 } \) may cause increase of CaTial₂O₆ in the Cpx_ss.  相似文献   

Seasonal variations in the nitrogen isotopic composition of settling particles at station K2 in the western subarctic North Pacific     

Yoshihisa?MinoEmail author  Chiho?Sukigara  Makio?C.?Honda  Hajime?Kawakami  Kazuhiko?Matsumoto  Masahide?Wakita  Minoru?Kitamura  Tetsuichi?Fujiki  Kosei?Sasaoka  Osamu?Abe  Jan?Kaiser  Toshiro?Saino 《Journal of Oceanography》2016,72(6):819-836

Intensive observations using hydrographical cruises and moored sediment trap deployments during 2010 and 2012 at station K2 in the North Pacific Western Subarctic Gyre (WSG) revealed seasonal changes in δ ¹⁵N of both suspended and settling particles. Suspended particles (SUS) were collected from depths between the surface and 200 m; settling particles by drifting sediment traps (DST; 100–200 m) and moored sediment traps (MST; 200 and 500 m). All particles showed higher δ ¹⁵N values in winter and lower in summer, contrary to the expected by isotopic fractionation during phytoplankton nitrate consumption. We suggest that these observed isotopic patterns are due to ammonium consumption via light-controlled nitrification, which could induce variations in δ ¹⁵N(SUS) of 0.4–3.1 ‰ in the euphotic zone (EZ). The δ ¹⁵N(SUS) signature was reflected by δ ¹⁵N(DST) despite modifications during biogenic transformation from suspended particles in the EZ. δ ¹⁵N enrichment (average: 3.6 ‰) and the increase in C:N ratio (by 1.6) in settling particles suggests year-round contributions of metabolites from herbivorous zooplankton as well as TEPs produced by diatoms. Accordingly, seasonal δ ¹⁵N(DST) variations of 2.4–7.0 ‰ showed a significant correlation with primary productivity (PP) at K2. By applying the observed δ ¹⁵N(DST) vs. PP regression to δ ¹⁵N(MST) of 1.9–8.0 ‰, we constructed the first annual time-series of PP changes in the WSG. This new approach to estimate productivity can be a powerful tool for further understanding of the biological pump in the WSG, even though its validity needs to be examined carefully.  相似文献   

Coupled 1-D physical–biological model study of phytoplankton production at two contrasting time-series stations in the western North Pacific     

Yoshikazu Sasai  Chisato Yoshikawa  S. Lan Smith  Taketo Hashioka  Kazuhiko Matsumoto  Masahide Wakita  Kosei Sasaoka  Makio C. Honda 《Journal of Oceanography》2016,72(3):509-526

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Ore and Skarn Mineralogy of the Yamato Mine,Yamaguchi Prefecture,Japan, with Emphasis on Silver‐, Bismuth‐, Cobalt‐, and Tin‐bearing Sulfides          下载免费PDF全文

Mariko Nagashima  Masahide Akasaka  Yoji Morifuku 《Resource Geology》2016,66(1):37-54

Assemblages and chemical compositions of ore minerals from the Yamato mine, Yamaguchi Prefecture, Japan, were investigated in detail to clarify its characteristics as a skarn deposit. Special attention was paid to silver‐, bismuth‐, cobalt‐, and tin‐bearing sulfide minerals and native gold at the mine, which are described here for the first time. Samples of arsenopyrite‐dominant massive ore, and garnet‐rich, clinopyroxene‐garnet‐rich, and wollastonite‐bearing skarn ores were collected from the mine dump. Arsenopyrite is the most abundant ore mineral (>80 vol.%) in the massive ore, in association with both As‐poor/free and As‐bearing pyrite. The major ore minerals in the skarn specimens are pyrite, pyrrhotite, arsenopyrite, chalcopyrite, galena, and sphalerite, along with minor argentite, Ag‐Pb‐Bi sulfate, matildite, bismuthinite, native bismuth, molybdenite, scheelite, stannite, stannoidite, cassiterite, cobaltite, gersdorffite, and Co‐rich violarite. In addition, native gold is observed in the interstices of gangue minerals. Based on the mineral assemblages and textures of the specimens examined, the major ore minerals formed in the early stage of mineralization, and the Bi‐, Ag‐, Co‐, Ni‐, As‐ and Sn‐mineralization occurred in the middle stage. Native gold was deposited in the late stage. The estimated formation temperature of the middle mineralization stage was 312±5 °C, according to iron and zinc partitioning between stannite and coexisting sphalerite. The mineralogical properties and mineralization process of the Yamato mine are consistent with those of common skarn‐ and vein‐type ore deposits associated with ilmenite‐series granitoids in the San‐yo and San‐in districts.  相似文献   

The distribution of Fe3+ and Ga3+ between two tetrahedral sites in melilites,Ca2(Mg,Fe3+, Ga,Si)3O7     

Masahide Akasaka  Haruo Ohashi  Isamu Shinno 《Physics and Chemistry of Minerals》1986,13(3):152-155

The distribution of Fe³⁺ and Ga³⁺ between the two tetrahedral sites in three synthetic melilites has been studied by using ⁵⁷Fe Mössbauer spectroscopy. In the melilite, (Ca₂Ga₂SiO₇)₅₀ (Ca₂Fe³⁺GaSiO₇)₅₀ (mol %), the distribution of Fe³⁺ and Ga³⁺ in T1 and T2 sites is apparently random, which can be explained in terms of the electrostatic valence rule. However in the melilites, (Ca₂MgSi₂O₇)₅₂ (Ca₂Fe³⁺GaSiO₇)₄₂ (Ca₂Ga₂SiO₇)₆ and (Ca₂MgSi₂O₇)₆₂ (Ca₂Fe³⁺GaSiO₇)₃₆ (Ca₂Ga₂SiO₇)₂ (mol %), Fe³⁺ shows preference for the more ionic T1 site and Ga³⁺ for the more covalent T2 site. If the electronegativity of Ga³⁺ is assumed to be larger than that of Fe³⁺, the mode of distribution of Fe³⁺ and Ga³⁺ can be explained in terms of our previous hypothesis that a large electronegativity induces a stronger preference for the more covalent T2 site.  相似文献   

The bearing of the system CaMgSi₂O₆CaAl₂SiO₆CaFeAlSiO₆ on fassaitic pyroxene     

Kosuke Onuma  Masahide Akasaka  Kenzo Yagi 《Lithos》1981,14(3):173-182

The system CaMgSi₂O₆CaAl₂SiO₆CaFeAlSiO₆ has been studied in air at 1 atm. The phase assemblage at subsolidus temperatures in the CaMgSi₂O₆-rich portion is Cpx + An + Mel and that in the CaMgSi₂O₆-poor portion Cpx + An + Mel + Sp. At subsolidus temperatures the sigle-phase field of clinopyroxene increases with an increase in the CaFeAlSiO₆ component of the system. The Al₂O₃ content of clinopyroxene, however, continues to increase beyond the single-phase field and attains at least 16.04 wt.% Al₂O₃ with 3.9 wt.% Fe₂O₃. The stability field of fassaite in the system over a range of pressures and oxygen fugacities has been estimated from data in the literature as well as the present data. The CaFeAlSiO₆ content of fassaite is dependent on oxygen fugacity, but is not influenced by pressure. The stability field is strongly influenced by oxygen fugacity at low and high pressure, and decreases with decreasing oxygen fugacity. Clinopyroxenes in both volcanic and metamorphic rocks from various localities, when plotted on the CaMgSi₂O₆CaAl₂SiO₆CaFeAlSiO₆ triangle, show that there is no compositional gap between diopside and fassaitic pyroxene in metamorphic rocks, and that the fassaitic pyroxene in alkalic rocks becomes richer in both CaAl₂SiO₆ and CaFeAlSiO₅ components as crystallization proceeds. These results agree with those obtained in the experimental study.  相似文献   

Ag-rich Tetrahedrite in the El Zancudo Deposit,Colombia: Occurrence,Chemical Compositions and Genetic Temperatures     

Alba Nury Gallego Hernández  Masahide Akasaka 《Resource Geology》2010,60(3):218-233

Chemical compositions of tetrahedrite—Ag-rich tetrahedrite—freibergite solid solutions (Ag-rich tetrahedrite_ss) and homogenization temperatures of fluid inclusions in quartz and carbonates of seventeen samples from nine veins in the El Zancudo deposit, Antioquia, Colombia, were investigated to reveal the origin of silver in Ag-rich tetrahedrite_ss, to derive their crystallization temperatures and to examine the relationship between chemical compositions of Ag-rich tetrahedrite_ss and their crystallization temperatures. The ores consist of arsenopyrite, pyrite, sphalerite, Ag-rich tetrahedrite_ss, galena, boulangerite, andorite, owyheeite, diaphorite, jamesonite, miargyrite, bournonite, chalcopyrite, and electrum. Ag-rich tetrahedrite_ss forms about 10 volume % of the total ores and is one of the most common and widely distributed sulfosalts in this deposit. Ag-rich tetrahedrite_ss is rich in Ag (1.13 to 31.02 wt%) and Sb (22.93 to 29.82 wt%), and poor in As (0.06 to 2.43 wt%), consistent with the reported incompatibilities of Ag and As in Ag-rich tetrahedrite_ss. The Zn/(Zn + Fe)-, Ag/(Ag + Cu)- and Sb/(Sb + As + Bi)-atomic ratios exhibit some variations among the veins. Ag-rich tetrahedrite_ss with higher Ag/(Ag + Cu) ratios coexist with diaphorite, whereas those with lower ratios are not associated with this sulfosalt. Ag-rich tetrahedrite_ss in the assemblages of Ag-rich tetrahedrite_ss+ sphalerite and of Ag-rich tetrahedrite_ss+ bournonite + galena shows no Zn ↔ Fe and Cu ↔ Ag variations between core and rim, respectively, negating the possibility of solid state reaction during cooling. Ag-rich tetrahedrite_ss is thus regarded as primary phase. Homogenization temperatures of primary fluid inclusions in quartz and carbonates co-existing with Ag-rich tetrahedrite_ss define the mineralization temperatures of 134 to 263°C. Independent crystallization temperatures of Ag-rich tetrahedrite estimated based on Zn/(Zn + Fe) and Ag/(Ag + Cu) ratios of the Ag-rich tetrahedrite_ss associated with silver minerals such as miargyrite, andorite and diaphorite using Sack's thermochemical database lie in a range between 170 and ∼250°C. Both results are thus in good agreement.  相似文献   

Precipitation chemistry and ozone and sulfate concentrations in the ocean atmosphere observed by multi-year cruising in East Asia and West Oceania (35°N–35°S, 100–135°E) in August and September     

Masahide Aikawa  Takatoshi Hiraki  Hitoshi Mukai 《Journal of Atmospheric Chemistry》2014,71(1):65-78

A comprehensive study on the chemistry of deposition and the concentration of tropospheric ozone and particulate sulfate in the ocean atmosphere was carried out for the data sets in 1990’s. It is important to study the atmospheric situation over the past years as well as the latest, especially in the East Asian region where emission amount of anthropogenic air pollutants have increased year by year due to rapid economic growth. The survey was conducted for 5 years in East Asia and West Oceania (35°N–35°S, 100–135°E) in August and September in 1990’s. The purpose of the survey was to study and understand the chemistry of deposition and the concentration of tropospheric ozone and particulate sulfate in the ocean atmosphere comprehensively in one project. Rainfall over the ocean was insufficiently neutralized. Gas and aerosol over the ocean were mature, i.e., well-mixed, during the period of the transportation. The characteristic latitudinal dependence was observed in the tropospheric ozone concentration, namely, higher in the southern hemisphere and lower in the northern hemisphere (approximately 25 ppb in the 10–40°S region and 5–15 ppb in the 20–40°N region). On the other hand, high concentrations of tropospheric ozone of over 30 ppb were observed in the northern hemisphere, which was attributable to the long-range transportation. The TSP concentration was approximately under the level of 40 μg m^?3 irrespectively of the latitude; in contrast, the nss-SO₄ ^2- concentration showed a clear latitudinal dependence, i.e., higher in the northern hemisphere and lower in the southern hemisphere. The background levels of the nss-SO₄ ^2- concentration were approximately 0.5 μg m^?3 in the 10–40°S region and 2–3 μg m^?3 and 4–5 μg m^?3 in the 0–20°N and 20–40°N regions, respectively.  相似文献   

Real-time multi-model decadal climate predictions   总被引：1，自引：1，他引：0  

Doug M. Smith  Adam A. Scaife  George J. Boer  Mihaela Caian  Francisco J. Doblas-Reyes  Virginie Guemas  Ed Hawkins  Wilco Hazeleger  Leon Hermanson  Chun Kit Ho  Masayoshi Ishii  Viatcheslav Kharin  Masahide Kimoto  Ben Kirtman  Judith Lean  Daniela Matei  William J. Merryfield  Wolfgang A. Müller  Holger Pohlmann  Anthony Rosati  Bert Wouters  Klaus Wyser 《Climate Dynamics》2013,41(11-12):2875-2888

We present the first climate prediction of the coming decade made with multiple models, initialized with prior observations. This prediction accrues from an international activity to exchange decadal predictions in near real-time, in order to assess differences and similarities, provide a consensus view to prevent over-confidence in forecasts from any single model, and establish current collective capability. We stress that the forecast is experimental, since the skill of the multi-model system is as yet unknown. Nevertheless, the forecast systems used here are based on models that have undergone rigorous evaluation and individually have been evaluated for forecast skill. Moreover, it is important to publish forecasts to enable open evaluation, and to provide a focus on climate change in the coming decade. Initialized forecasts of the year 2011 agree well with observations, with a pattern correlation of 0.62 compared to 0.31 for uninitialized projections. In particular, the forecast correctly predicted La Niña in the Pacific, and warm conditions in the north Atlantic and USA. A similar pattern is predicted for 2012 but with a weaker La Niña. Indices of Atlantic multi-decadal variability and Pacific decadal variability show no signal beyond climatology after 2015, while temperature in the Niño3 region is predicted to warm slightly by about 0.5 °C over the coming decade. However, uncertainties are large for individual years and initialization has little impact beyond the first 4 years in most regions. Relative to uninitialized forecasts, initialized forecasts are significantly warmer in the north Atlantic sub-polar gyre and cooler in the north Pacific throughout the decade. They are also significantly cooler in the global average and over most land and ocean regions out to several years ahead. However, in the absence of volcanic eruptions, global temperature is predicted to continue to rise, with each year from 2013 onwards having a 50 % chance of exceeding the current observed record. Verification of these forecasts will provide an important opportunity to test the performance of models and our understanding and knowledge of the drivers of climate change.  相似文献   

Finite vertical oscillation of fluid parcel in a heterogeneous,incompressible sea water—Part II     

Masahide Tominaga 《Journal of Oceanography》1970,26(5):267-270

Observations of temperature fluctuations and simultaneous observations of temperature and salinity fluctuations conducted in the sea are carefully analyzed on the theoretical basis developed in Part I. Observed remarkable fluctuations of about 10 minutes period are considered to agree with the unstable oscillations obtained from the theory. Actual oscillations observed in the sea are regarded to have small wave length such that they satisfy the condition (F) described in the Section 1 of Part I.  相似文献