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We used more than 25,000 nutrient samples to elucidate for the first time basin-scale distributions and seasonal changes of surface ammonium (NH4 +) and nitrite (NO2 ?) concentrations in the Pacific Ocean. The highest NH4 +, NO2 ?, and nitrate (NO3 ?) concentrations were observed north of 40°N, in the coastal upwelling region off the coast of Mexico, and in the Tasman Sea. NH4 + concentrations were elevated during May–October in the western subarctic North Pacific, May–December in the eastern subarctic North Pacific, and June–September in the subtropical South Pacific. NO2 ? concentrations were highest in winter in both hemispheres. The seasonal cycle of NH4 + was synchronous with NO2 ?, NO3 ?, and satellite chlorophyll a concentrations in the western subtropical South Pacific, whereas it was synchronous with chlorophyll-a but out of phase with NO2 ? and NO3 ? in the subarctic regions.  相似文献   
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We developed a multi-trophic level ecosystem model by coupling physical, biogeochemical-plankton and fish models. An oceanic general circulation model was coupled with a lower trophic level ecosystem model and a Japanese sardine migration model, and applied to the western North Pacific. To investigate the impact of global warming on the pelagic fish ecosystem, such as Japanese sardine, we conducted numerical experiments of growth and migration of Japanese sardine using physical fields for the present day and future with a global warming scenario simulated by a high-resolution climate model. The model results demonstrated possible impacts of global warming on the growth and migration pattern of Japanese sardine. The growths of fish in the current main spawning region under the global warming scenario were significantly slower than those under the present climate scenario. Fish in this region will be at disadvantage for their recruitment under the global warming condition. Prey conditions in the spawning region were projected not to markedly change under global warming condition while water temperature increased. As a result sardine spawning ground was projected to shift towards more north areas. During the feeding migration period in summer, geographical distribution of juveniles fish was projected to shift northwards by one to two degrees latitude under the global warming condition following the change in the distribution of optimal temperature region for feeding. However, this northwards shift of the optimal temperature for feeding was minimized adjacent to the western North Pacific by the cooler water supply by the intensification of the Oyashio.  相似文献   
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Pelitic schists of the Sanbagawa metamorphic belt contain several types of polymineralic veins that formed during the late stages of exhumation. The vein mineral assemblages are quartz + albite + K-feldspar + chlorite ± calcite (Type I, II) and quartz + albite + calcite (Type III). Type I and II veins contain quartz and albite with stretched-crystal and elongate-blocky textures, respectively. The mineral species within Type I veins vary with compositional bands within the host rocks. Type III veins are characterized by euhedral to subhedral quartz grains with concentric zoning and a homogeneous distribution along the vein length. The vein textures vary depending on the crack aperture during multiple crack-seal events: <0.08 mm for Type I, and 0.5–10 mm for Type III. Type II veins show intermediate features between Type I and III veins in terms of mineral distribution (weak dependence on the host rock composition) and apparent crack aperture (less than 1–15 mm). These observations suggest a transition in the dominant transport mechanism of vein components with increasing crack aperture, from diffusion from host rocks to fluid advection along cracks.  相似文献   
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Bubble and crystal textures provide information with regard to the kinetics of the vesiculation and crystallization processes. They also provide insights into the fluid mechanical behavior of magma in a conduit. We performed textural (bubble and crystal) and compositional analyses of pyroclasts that were obtained from the Tenjo pyroclastic flow, which resulted on account of the eruption in 838 A.D. on Kozu Island, about 200 km south of Tokyo, Japan. Pyroclasts in one flow unit (300∼2,060 kg/m3; average density 1330 kg/m3) can be classified into three types on the basis of vesicle textures. Type I pyroclasts have small isolated spherical bubbles with higher vesicularities (67–77 vol.%) and number density (10.8–11.7 log m−3). Type II pyroclasts have vesicularities similar to type I (61–69 vol.%), but most bubbles exhibit evidences of bubble coalescence, and lower number densities than type I (8.9–9.5 log m−3). Type III pyroclasts contain highly deformed bubbles with lower vesicularities (16–34 vol.%) and number densities (8.2–9.0 log m−3). The microlite volume fraction (DRE converted) also changes consistently across type I, type II, and type III as 0.06, 0.08, and 0.10–0.15, respectively. However, the number density of the microlites remains nearly invariant in all the pyroclast types. These facts indicate that the variation in the microlite volume fraction is controlled not by the number density (i.e., nucleation process), but by the size (i.e., growth process); the growth history of each type of microlite was different. Water content determinations show that the three types of pumices have similar H2O contents (2.6±0.2 wt%). This fact implies that all three types were quenched at nearly the same depth (35±5 MPa, assuming that the magma was water-saturated) in the conduit. If the crystal sizes are limited only by growth time, a variation in this parameter can be related to the residence time, which is attributed to the flow heterogeneity in the conduit. By assuming a laminar Poiseuille-type flow, these textural observations can be explained by the difference in ascent velocity and shearing motion across the conduit, which in turn results in the differences in growth times of crystals, degrees of deformation, and bubble coalescence. Consequently, for crystals in the inner part of the conduit, the crystal growth time from nucleation to quenching is shorter than that near the conduit wall. The vesicle texture variation of bubbles in types I, II, and III results from the difference in the deformation history, implying that the effect of degassing occurred primarily towards the conduit wall.  相似文献   
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During the early part of a seismic swarm preceding eruption and caldera formation at Miyakejima Volcano, discoloured sea surfaces were observed 1.5 km off the western coast of Miyakejima on 27 June 2000. A later survey of the area using a multi-beam side scan sonar and a remotely operated small submarine revealed four craters of 20–30 m diameter aligned east-west in a 100×10–30 m area on the seafloor, with hot water at 140°C being released from one of the centres. Each crater consists of submarine spatter overlain in part by scoria lapilli. Dredged spatter from the craters was fresh, and there was no evidence of activity of marine organisms on the spatter surface, indicating that the discoloured sea surface resulted from magmatic eruption on the seafloor. This eruption occurred when a westward-propagating seismic swarm, initiated beneath Miyakejimas summit, passed through the area. Finding new magma on the seafloor demonstrates that this seismic swarm was associated with intruding magma, moving outward from beneath Miyakejima. Submarine spatter shows flattened shapes with a brittle crust formed by cooling in water, and its composition is aphyric andesite of 54 wt% SiO2. The spatter is similar in whole rock and mineral composition to spatter erupted in 1983. However, the wide range of Cl in melt inclusions in plagioclase of the 27 June submarine spatter shows that it is not simply a remnant of the 1983 magma, which has only high Cl melt inclusions in plagioclase. The mixed character of melt inclusions suggests involvement of a magma with low Cl melt inclusions. The magma erupted explosively on 18 August from Miyakejimas summit, considered as the second juvenile magma in this eruption, contains low Cl melt inclusions in plagioclase. Based on these observations and the eruption sequence, we present the following model: (1) A shallow magma chamber was filled with a remnant of 1983 magma that had evolved to a composition of 54–55 wt% SiO2. (2) Injection of the 18 August magma into this chamber generated a mixed magma having a wide range of Cl in melt inclusions contained plagioclase. The magma mixing might have occurred shortly before the submarine eruption and could have been a trigger for the initiation of the removal of magma from the chamber as an extensive dyke, which eventually led to caldera subsidence.Editorial responsibility: S Nakada, T Druitt  相似文献   
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This paper presents a study of the petrography, mineral chemistry, geochemistry, and Sr–Nd–Pb–C–O isotope systematics of carbonatite dykes and associated rocks from the northeastern part of the Song Da intracontinental rift in South Nam Xe (northwest Vietnam) aimed at constraining the origin of the carbonatite magmas. The carbonatites are characterized by SiO2 < 12.18 wt.% and by wide ranges in FeO, MgO and CaO content that define them as calciocarbonatite and ferrocarbonatite. On U–Th–Pb isochron diagrams, whole rocks and mineral separates from the ferrocarbonatites form linear arrays corresponding to ages of 30.2–31.6 Ma (Rupelian, Oligocene). The South Nam Xe carbonatites are extremely enriched in Sr, Ba, and light rare earth elements (LREE), and depleted in high field strength elements (HFSE) (e.g. Ti, Nb, Ta, Zr and Hf). The age–corrected Sr–Nd–Pb isotope ratios and C isotope data are relatively uniform (87Sr/86Sr(t) = 0.708193–0.708349; 143Nd/144Nd(t) = 0.512250–0.512267; εNd(t) = ?6.46 to ?6.80; 206Pb/204Pb(t) = 18.26–18.79; 207Pb/204Pb(t) = 15.62–15.64; 208Pb/204Pb(t) = 38.80–39.38; δ13CV-PDB = –2.7?‰ to ?4.1?‰). These isotopic compositions indicate source contamination that occurred before the production of the carbonatite magmas, and did not change noticeably during or after emplacement. The variation in oxygen isotopes is consistent with the change in mineral compositions and trace element abundances: the lower δ18O values (9.1–11.0?‰) coupled with Sr-rich, Mn-poor calcite, and igneous textures such as triple junctions among calcite grain boundaries, define a magmatic origin. However, the elevated δ18O values of the ferrocarbonatites (12.0–13.3?‰) coupled with a volatile-bearing mineral assemblages (including REE fluorcarbonates, sulfates, sulfides and fluorite) may be due to interaction with meteoric water during low-temperature alteration. High δ13C values and Sr–Pb ratios, and low Rb/Sr (0.00014–0.00301), Sm/Nd (0.089–0.141) and 143Nd/144Nd ratios, coupled with very high Sr-Nd concentrations, suggest the involvement of an enriched mantle component, which probably resulted from metasomatism due to the migration of subducted material. Because of the lack of tectonic data and the limited number of samples studied, this conclusion is still ambiguous and requires further study.  相似文献   
9.
Akira  Imai  Nobuo  Geshi  Taketo  Shimano  Setsuya  Nakada 《Island Arc》2007,16(1):83-92
Abstract   The variation of sulphur isotopic composition during the 2000 eruption of the Miyakejima Volcano was examined in order to monitor the temporal change of the volcanic activity. The δ34S values of water-soluble sulphate leached from volcanic ash effused during intermittent eruptions from July to September 2005 range from +5 to +11‰ with a fluctuation of ca 3‰ within a single eruption. The δ34S value of sulphuric acid mist collected with 'Cu-metal trap' placed on the flank of the volcano from December 2000 to January 2001 is +6.2‰. These sulphur isotopic compositions of sulphate, which were isotopically equilibrated in the subvolcanic hydrothermal system, indicate that the temperature of the hydrothermal system beneath the caldera increased after the period of intermittent phreatic and phreatomagmatic eruptions. Then, the δ34S value of sulphuric acid trapped from January to March 2001 was +9.0‰ and the δ34S value of water-soluble sulphate on volcanic ash emitted with minor eruption in May 2001 was +11.0‰, suggesting a decrease in temperature of the subvolcanic hydrothermal system.  相似文献   
10.
We develop an automatic system for the sampling of ash fall particles, to be used for continuous monitoring of magma ascent and eruptive dynamics at active volcanoes. The system consists of a sampling apparatus and cameras to monitor surface phenomena during eruptions. The Sampling Apparatus for Time Series Unmanned Monitoring of Ash (SATSUMA-I and SATSUMA-II) is less than 10 kg in weight and works automatically for more than a month with a 10-kg lead battery to obtain a total of 30 to 36 samples in one cycle of operation. The time range covered in one cycle varies from less than an hour to several months, depending on the aims of observation, allowing researchers to target minute-scale fluctuations in a single eruptive event, as well as daily to weekly trends in persistent volcanic activity. The latest version, SATSUMA-II, also enables control of sampling parameters remotely by e-mail commands. Durability of the apparatus is high: our prototypes worked for several months, in rainy and typhoon seasons, at windy and humid locations, and under strong sunlight. We have been successful in collecting ash samples emitted from Showa crater almost everyday for more than 4 years (2008–2012) at Sakurajima volcano in southwest Japan.  相似文献   
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