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1.
Water quality is often highly variable both in space and time, which poses challenges for modelling the more extreme concentrations. This study developed an alternative approach to predicting water quality quantiles at individual locations. We focused on river water quality data that were collected over 25 years, at 102 catchments across the State of Victoria, Australia. We analysed and modelled spatial patterns of the 10th, 25th, 50th, 75th and 90th percentiles of the concentrations of sediments, nutrients and salt, with six common constituents: total suspended solids (TSS), total phosphorus (TP), filterable reactive phosphorus (FRP), total Kjeldahl nitrogen (TKN), nitrate-nitrite (NOx), and electrical conductivity (EC). To predict the spatial variation of each quantile for each constituent, we developed statistical regression models and exhaustively searched through 50 catchment characteristics to identify the best set of predictors for that quantile. The models predict the spatial variation in individual quantiles of TSS, TKN and EC well (66%–96% spatial variation explained), while those for TP, FRP and NOx have lower performance (37%–73% spatial variation explained). The most common factors that influence the spatial variations of the different constituents and quantiles are: annual temperature, percentage of cropping land area in catchment and channel slope. The statistical models developed can be used to predict how low- and high-concentration quantiles change with landscape characteristics, and thus provide a useful tool for catchment managers to inform planning and policy making with changing climate and land use conditions.  相似文献   
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Studying seismic wave propagation across rock masses and the induced ground motion is an important topic, which receives considerable attention in design and construction of underground cavern/tunnel constructions and mining activities. The current study investigates wave propagation across a rock mass with one fault and the induced ground motion using a recursive approach. The rocks beside the fault are assumed as viscoelastic media with seismic quality factors, Qp and Qs. Two kinds of interactions between stress waves and a discontinuity and between stress waves and a free surface are analyzed, respectively. As the result of the wave superposition, the mathematical expressions for induced ground vibration are deduced. The proposed approach is then compared with the existing analysis for special cases. Finally, parametric studies are carried out, which includes the influences of fault stiffness, incident angle, and frequency of incident waves on the peak particle velocities of the ground motions.  相似文献   
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《Astroparticle Physics》2002,16(4):183-386
Frequency distributions of local muon densities in high-energy extensive air showers (EAS) are presented as signature of the primary cosmic ray energy spectrum in the knee region. Together with the gross shower variables like shower core position, angle of incidence, and the shower sizes, the KASCADE experiment is able to measure local muon densities for two different muon energy thresholds. The spectra have been reconstructed for various core distances, as well as for particular subsamples, classified on the basis of the shower size ratio Nμ/Ne. The measured density spectra of the total sample exhibit clear kinks reflecting the knee of the primary energy spectrum. While relatively sharp changes of the slopes are observed in the spectrum of EAS with small values of the shower size ratio, no such feature is detected at EAS of large Nμ/Ne ratio in the energy range of 1–10 PeV. Comparing the spectra for various thresholds and core distances with detailed Monte Carlo simulations the validity of EAS simulations is discussed.  相似文献   
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The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   
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Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32
Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献   
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