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There is still considerable uncertainty about precipitation at high elevation in mountain terrain due to the relatively few in situ measurements available and to the particular variability of the parameter. In this study, several spatialization techniques were tested, some for climatological time scale and others for daily fields, for precipitation over the western Alps for the period of 1990–2012. The study domain and period were chosen for the quality of available in situ observations and density of the network. First, a weather-type classification was established with a technique based on canonical correlation analysis combining large- and regional-scale data. The spatialization techniques applied for the climatological time scale were adapted from the Aurelhy method which uses elevation and principal components of the topography as predictors. The spatialization techniques applied to daily fields were based on kriging of daily rain gauges and used the climatological fields as predictors. This study aims to validate the advantage of using the climatology of the weather type of the day as predictor for daily fields over a monthly climatology. The climatology of the weather type of the day seems to demonstrate some small improvement.Finally, annual means over the period of 1990–2012 were produced using several methods, including some from accumulation of daily fields and others from the spatialization of in situ station means. Precipitation at high elevations and vertical climatological gradients were particularly scrutinized. Annual means based on sums of daily fields seem to have better performances.This paper only presents results for precipitation but temperature was also analysed.  相似文献   
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Due to their particular physiographic, geomorphic, soil cover, and complex surface-subsurface hydrologic conditions, karst regions produce distinct land–atmosphere interactions. It has been found that floods and droughts over karst regions can be more pronounced than those in non-karst regions following a given rainfall event. Five convective weather events are simulated using the Weather Research and Forecasting model to explore the potential impacts of land-surface conditions on weather simulations over karst regions. Since no existing weather or climate model has the ability to represent karst landscapes, simulation experiments in this exploratory study consist of a control (default land-cover/soil types) and three land-surface conditions, including barren ground, forest, and sandy soils over the karst areas, which mimic certain karst characteristics. Results from sensitivity experiments are compared with the control simulation, as well as with the National Centers for Environmental Prediction multi-sensor precipitation analysis Stage-IV data, and near-surface atmospheric observations. Mesoscale features of surface energy partition, surface water and energy exchange, the resulting surface-air temperature and humidity, and low-level instability and convective energy are analyzed to investigate the potential land-surface impact on weather over karst regions. We conclude that: (1) barren ground used over karst regions has a pronounced effect on the overall simulation of precipitation. Barren ground provides the overall lowest root-mean-square errors and bias scores in precipitation over the peak-rain periods. Contingency table-based equitable threat and frequency bias scores suggest that the barren and forest experiments are more successful in simulating light to moderate rainfall. Variables dependent on local surface conditions show stronger contrasts between karst and non-karst regions than variables dominated by large-scale synoptic systems; (2) significant sensitivity responses are found over the karst regions, including pronounced warming and cooling effects on the near-surface atmosphere from barren and forested land cover, respectively; (3) the barren ground in the karst regions provides conditions favourable for convective development under certain conditions. Therefore, it is suggested that karst and non-karst landscapes should be distinguished, and their physical processes should be considered for future model development.  相似文献   
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A newly recognized remnant of a Paleoproterozoic Large Igneous Province has been identified in the southern Bastar craton and nearby Cuddapah basin from the adjacent Dharwar craton, India. High precision U–Pb dates of 1891.1 ± 0.9 Ma (baddeleyite) and 1883.0 ± 1.4 Ma (baddeleyite and zircon) for two SE-trending mafic dykes from the BD2 dyke swarm, southern Bastar craton, and 1885.4 ± 3.1 Ma (baddeleyite) for a mafic sill from the Cuddapah basin, indicate the existence of 1891–1883 Ma mafic magmatism that spans an area of at least 90,000 km2 in the south Indian shield.This record of 1.9 Ga mafic/ultramafic magmatism associated with concomitant intracontinental rifting and basin development preserved along much of the south-eastern margin of the south Indian shield is a widespread geologic phenomenon on Earth. Similar periods of intraplate mafic/ultramafic magmatism occur along the margin of the Superior craton in North America (1.88 Ga Molson large igneous province) and in southern Africa along the northern margin of the Kaapvaal craton (1.88–1.87 Ga dolerite sills intruding the Waterberg Group). Existing paleomagnetic data for the Molson and Waterberg 1.88 Ga large igneous provinces indicate that the Superior and Kalahari cratons were at similar paleolatitudes at 1.88 Ga but a paleocontinental reconstruction at this time involving these cratons is impeded by the lack of a robust geological pin such as a Limpopo-like 2.0 Ga deformation zone in the Superior Province. The widespread occurrence of 1.88 Ga intraplate and plate margin mafic magmatism and basin development in numerous Archean cratons worldwide likely reflects a period of global-scale mantle upwelling or enhanced mantle plume activity at this time.  相似文献   
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The yields of carbonyl-containing reaction products from the ozonolysis of α-pinene have been investigated using concentrations of ozone found in the indoor environment ([O3] ≤ 100 ppb). An impinger was used to collect gas-phase oxidation products in water, where the derivatization agent O-tert-butylhydroxylamine hydrochloride (TBOX) and gas chromatography-mass spectrometry were used to identify carbonyl-containing species. Seven carbonyl-containing products were observed. The yield of the primary product, pinonaldehyde was measured to be 76 %. Using cyclohexane as a hydroxyl radical (?OH) scavenger, the yield of pinonaldehyde decreased to 46 %, indicating the influence secondary OH radicals have on α-pinene ozonolysis products. Furthermore, the use of TBOX, a small molecular weight derivatization agent, allowed for the acquisition of the first mass spectral data of oxopinonaldehyde, a tricarbonyl reaction product of α-pinene ozonolysis. The techniques described herein allow for an effective method for the collection and identification of terpene oxidation products in the indoor environment.  相似文献   
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Food is essential to life—yet the spatial and economic configuration of the conventional food system does not meet nutritional needs and exacerbates issues of food insecurity. Relevant options for policy change have been explored in light of evaluations of geographic disparities in food access, but the dominant ‘food desert’ discourse often focuses uncritically on insufficient conceptions of access. Understanding the complexity of food deserts is important for moving into meaningful policy action. We present a theoretical position to inspire future empirical research. The ecological model recognizes both endogenous and built environment factors in shaping health. Interventions in the food environment, however, often concentrate exclusively on structural determinants of health (e.g. retail-based initiatives). Yet retail-based interventions are difficult to implement due to governance systems which limit the ability of government bodies to influence private retail development. As well, recognizing the complexity of debates over the influence of structure and agency, we apply structuration theory to food deserts. Behavioral economics further informs both structural and behavioral determinants of health. This approach sidesteps the issue of victim-blaming, as all consumers are viewed as ‘predictably irrational’ in decision-making. In combining these theories, we challenge methodological and theoretical assumptions by showing the complexity of food desert interventions. Policy recommendations focus on behavioral determinants of health and the opportunities for empowerment through local food systems. These recommendations recognize the limits of translating research into policy and in devising effective food based interventions, and are sensitive to social, economic, and political constraints uncovered throughout the paper.  相似文献   
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