Activity-composition relations in FeTiO3-MnTiO3 ilmenite solid solutions from EMF measurements at 1050–1300 K     

Hugh St. C. O'Neill  Mark I. Pownceby  Victor J. Wall 《Contributions to Mineralogy and Petrology》1989,103(2):216-222

The activity of FeTiO₃ in the binary ilmenitepyrophanite (FeTiO₃-MnTiO₃) solid solution has been determined for the temperature range 1050–1300 K by displacement of the reaction: 2 FeTiO₃=2 Fe+2 TiO₂+O₂ in T-O₂ space, using an electrochemical technique with calcia- and yttria-stabilized zirconia solid electrolytes. The activities show small positive deviations from ideality, which, although the data are unusually precise, may be perfectly described by the simple regular solution model, with an interaction parameter, W _Fe-Mn ^ilm , of 2.2±0.3 kJ g-atom^–1, which is independent of temperature. This value, together with the experimental data on the partitioning of Fe and Mn between ilmenite and garnet (Pownceby et al. 1987), gives W _Fe-Mn ^gt =1.2±0.5 kJ g-atom^–1 for the almandine-spessartine (Fe₃Al₂Si₃O₁₂-Mn₃Al₂Si₃O₁₂) solid solution.  相似文献   

Introduction     

C. Eva  Editor  N. Pavoni  Editor 《Tectonophysics》1985,117(1-2)

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Considerations on the seismotectonics of the Northern Apennines     

M. Boccaletti  M. Coli  C. Eva  G. Ferrari  G. Giglia  A. Lazzarotto  F. Merlanti  R. Nicolich  G. Papani  D. Postpischl 《Tectonophysics》1985,117(1-2)

The Northern Apennines have been subdivided into homogeneous zones, on the basis of recent structural evolution and crustal structure, in which the earthquake distribution can find a coherent framework. These zones, whose physiography is in strict connection with their structure, are: the Internal Peri-Tyrrhenian Belt; the External or Main Belt; the Buried Belt; and the Pede-Alpine Homocline. Earthquake activity has a tendency to cluster along well-defined bands, particularly in the easternmost border of the Peri-Tyrrhenian Belt, as well as along the zone between the External Belt and the Buried Belt, i.e. along the Padanian margin of the Northern Apennines.A minimum of seismic activity seems to be correlated with some zones of the External Belt, as well as with the Late Tertiary and Quaternary magmatic province of Tyrrhenian Southern Tuscany.The fault-plane solutions are coherent with the structural picture.A tentative seismotectonic model of the Northern Apennines is discussed.  相似文献   

A simple model of a building cumulus cloud     

Ivana Nemešová  Eva Smítková  Reviewer O. Zikmunda 《Studia Geophysica et Geodaetica》1982,26(2):176-186

Summary A model of a building cumulus structure is described. The one-stage model published in[1] was used to describe ascent of two cloudy parcels that a cloud is supposed to be formed of. The other ascent is assumed to take place after the first cloud element sinks back as a result of evaporative cooling. The numerical results and their evaluation are given for various rates of mixing at the cloud top level of the first cloud volume.  相似文献   

Investigation of the elastic characteristics of a three-storey steel structure using system identification     

Izak Kaya  Hugh D. McNiven 《地震工程与结构动力学》1982,10(3):433-445

In this report, three different models in increasing order of complexity have been used to identify the seismic behaviour of a three-storey steel structure subjected to arbitrary forcing functions, all of which excite responses within the elastic range. All of the models are constructed using system identification. In the first model, five parameters have been used to identify the frame. Treating the system as a shear building, we assign one stiffness coefficient to each floor and introduce Rayleigh-type damping with two additional parameters. The mass, assumed to be concentrated at a floor level, is kept constant throughout the study. The parameters are established using a modified Gauss-Newton algorithm. The match between measured and predicted quantities is satisfactory when these quantities are restricted to floor accelerations or displacements. To remove the constraint imposed by assuming that the frame deforms as a shear building, a second model with eight parameters is introduced, allowing rotations of the joints as independent degrees of freedom. Six of the eight parameters are related to the stiffness characteristics of the structural members while the remaining two are related to damping as before. In constructing the eight-parameter model, we learned that it is the effective lengths of the members that change during optimization. We also found that the independent response quantities, floor accelerations and joint rotations, must be used in the cost function for the optimization algorithm to converge. The match between measured and predicted quantities for the eight-parameter model is excellent. The set of parameters derived from the minimum squared error gives a model that shows very good correlation using information on the full duration of the pulse or only a portion of it. Also the same correlation exists between the coefficients obtained from different excitations. In an effort to explain the values of the parameters associated with the girders, an additional degree of freedom, namely, the pitching motion of the shaking table, is introduced as an additional degree of freedom. The paper presents, therefore, a five-, an eight- and, finally, a nine-parameter model.  相似文献   

On the relationship of thunderstorm ice hydrometeor characteristics and total lightning measurements   总被引：1，自引：0，他引：1  

Wiebke Deierling  John Latham  Walter A. Petersen  Scott M. Ellis  Hugh J. Christian  Jr.   《Atmospheric Research》2005,76(1-4):114

Satellite-borne and ground-based devices for the detection of lightning offer the opportunity to explore relationships–on all significant scales up to global–between lightning frequency, f, and other thundercloud parameters. Calculations predict that f is proportional to the product of the downflux p of solid precipitation and the upward mass flux, I, of ice crystals. This prediction has received support from limited computational studies. The physical reasons for such a relationship are explained in terms of the paramount role of ice in the electrification of thunderstorms. Herein, this prediction is subjected to further, preliminary examination through analysis of lightning and dual-polarimetric radar data collected during the STERAO experiment conducted in Northern Colorado during the summer of 1996. The analysis has yielded some highly provisional support for this flux hypothesis. Computed trends of radar derived hydrometeor fractions of solid precipitation and small ice show correlation to the total lightning frequency and raise the possibility of determining values of p and/or I from lightning measurements.It is shown that the extent to which the observed correlations between f and both solid precipitation and small ice trends are or are not strong can provide an indication as to whether the lightning activity is limited by the available concentrations of precipitating or non-precipitating ice in the upper regions of the charging zone of the thundercloud, where most of the charge transfer occurs. It is demonstrated that the most accurate determinations of precipitation rate p from measurements of lighting frequency f are likely to be for conditions where the field-growth is limited by the availability of graupel pellets. It is shown that the simultaneous time variations of f and solid precipitation trends of the type obtained in the STERAO experiment could enable us to determine the nature of the dominant glaciation process operative in the thunderclouds studied.  相似文献   

Reply     

T. Grant Caldwell  Hugh M. Bibby  Colin Brown 《Geophysical Journal International》2007,171(2):567-567

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'They don't like girls hanging around there': conflicts over recreational space in rural Northamptonshire     

Faith Tucker  & Hugh Matthews 《Area》2001,33(2):161-168

This paper provides new insights into girls' use of recreational spaces within rural areas. We draw upon data from in-depth discussion work with 10–14 year old girls undertaken in rural Northamptonshire to show how conflict between adults and children, rival groups of children, and boys and girls influences the social ownership of recreational spaces. In contrast to the rural childhood myth, we disclose geographies of anxiety, tension anddisharmony.  相似文献   

Contribution of waters of Atlantic and Pacific origin in the Northeast Water Polynya     

Eva Falck 《Polar research》2001,20(2):193-200

Measurements of nitrate and phosphate taken in the Northeast Water Polynya (NEWP) during the summer of 1993 have been used to identify the contribution of waters of Atlantic and Pacific origin in the polynya. Since waters from the northern Pacific exhibit a deficit in nitrate relative to phosphate due to denitrification in low oxygen waters, the relationship between nitrate and phosphate can be used to distinguish between oceanic waters of Pacific and Atlantic origin. The Pacific Water enters the Arctic Ocean through Bering Strait and flows along the northern coasts of Alaska and Canada. Some of this water exits through Fram Strait and may therefore enter the polynya which is situated above the continental shelf off the north-eastern coast of Greenland. Compared to data from the Greenland Sea, which only show a N–P relationship of typical Atlantic Water, the data from the Northeast Water Polynya show that the upper waters of the polynya bear a clear signal of waters of Pacific origin. In the surface mixed layer an average of about 90% is found to have Pacific N–P characteristics. Below the surface mixed layer the amount of Pacific derived water decreases through the halocline and from about 150 m to the bottom only typical Atlantic Water is found.  相似文献   

For a Europe of flexible regions and not of region-states divided by ethnicity     

Fabrizio Eva 《GeoJournal》2001,52(4):295-301

Discussion of the future of Europe continues to be a marginal political issue, partly because of the resistance of states, on both the practical (bureaucratic) and conceptual levels, created by the government leaders and heads of state. In turn, the nation-states are challenged from within by independent and separatist movements that have laid bare the fundamental hypocrisy of rhetorical discussions of the principle regarding the self-determination of peoples; interfering with states (and their borders) has proven to be a taboo for Europe. The growing flexibility of the globalised economy should be paralleled by a growing flexibility in the conception of the division and political organisation of territory, but this is not the case. Further inflexibility stems from the socio-economic inequity that we accept in our daily lives as normal, in particular as regards inequality in the use and division of territory. Equality, or better egaliberté (equality and liberty), is a sufficiently dynamic and flexible concept to be taken as a point of reference in envisaging the society, Europe, and world of tomorrow. It is only through the concept of egaliberté that we can imagine a Europe based on relations between regions that are conceived and organised on multiple scales and not as region-nations conceived on the basis of ethnicity or in the name of supposed cultural homogeneity.  相似文献