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51.
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The Denizli Basin is a fault‐bounded Neogene–Quaternary depression located in the Western Anatolian Extensional Province, Western Turkey. The basin is a unique geological site with abundant active and fossil (Quaternary) travertine and tufa deposits. Fluid inclusion microthermometry and isotopic analysis were applied to study the genesis of the Ball?k fossil travertine deposits, located in the south‐eastern part of the basin. Microthermometry on fluid inclusions indicates that the main travertine precipitating and cementing fluids are characterized by low salinity (<0·7 wt% NaCl equivalent) and variable temperatures that cluster at <50°C and ca 100°C. Fluids of meteoric origin have been heated by migration to the deeper subsurface, possibly in a local high geothermal gradient setting. A later uncommon cementation phase is related to a fluid with a significantly higher salinity (25·5 to 26·0 wt% bulk). The fluid obtained its salinity by interaction with Late Triassic evaporite layers. Strontium isotopes indicate that the parent carbonate source rock of the different travertine precipitates is very likely to be the Triassic limestone of the Lycian Nappes. Carbon isotopes suggest that the parent CO2 gas originated from thermal decarbonation of the Lycian limestones with minor contributions of magmatic degassing and organic soil CO2. Oxygen isotopes confirm the meteoric origin of the fluids and indicate disequilibrium precipitation because of evaporation and degassing. Results were integrated within the available geological data of the Denizli Basin in a generalized travertine precipitation model, which enhanced the understanding of fossil travertine systems. The study highlights the novel application of fluid inclusion research in unravelling the genesis of continental carbonates and provides several recommendations for hydrocarbon exploration in travertine‐bearing sedimentary basins. The findings suggest that travertine bodies and their parent carbonate source rocks have the potential to constitute interesting subsurface hydrocarbon reservoirs.  相似文献   
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A 15-m-thick, fluvial sedimentary record of the NW Iberian lower Miño River was studied. Grain-size analyses were performed and twelve samples were dated using optically stimulated luminescence dating techniques, documenting a 1300-yr-old reconstructed fluvial record that does not match with known climate fluctuations in the area, but is linked instead to the construction of a series of ancient fishing weirs (pesqueiras). The sedimentation phases are in agreement with known episodes of increased population density, which suggests active use of the pesqueiras. A number of sedimentation hiatuses in the fluvial record point towards damage to the pesqueiras during large-scale flooding in the Miño River basin, and a sudden drop in population probably due to the arrival of the plague in the 13th century AD. The oldest sedimentation phases started just after 700 AD, and we infer that the first pesqueiras were constructed around this time. This timing coincides with the transition of the NW Iberian landscape towards a more intensively used agricultural landscape, as evidenced from other geo-archeological investigations. The results demonstrate that the pesqueiras are several hundreds of years older than known from historical records, but not so old as to date back to the Roman occupation.  相似文献   
55.
Half a century of mercury research has provided scientists and policy makers with a detailed understanding of mercury toxicology, biogeochemical cycling and past and future impacts on human exposure. The complexity of the global biogeochemical mercury cycle has led to repeated and ongoing paradigm shifts in numerous mercury-related disciplines and outstanding questions remain. In this review, we highlight some of the paradigm shifts and questions on mercury toxicity, the risks and benefits of seafood consumption, the source of mercury in seafood, and the Arctic mercury cycle. We see a continued need for research on mercury toxicology and epidemiology, for marine mercury dynamics and ecology, and for a closer collaboration between observational mercury science and mercury modeling in general. As anthropogenic mercury emissions are closely tied to the energy cycle (in particular coal combustion), mercury exposure to humans and wildlife are likely to persist unless drastic emission reductions are put in place.  相似文献   
56.
Landscape evolution models (LEMs) simulate the three‐dimensional development of landscapes over time. Different LEMs have different foci, e.g. erosional behaviour, river dynamics, the fluvial domain, hillslopes or a combination. LEM LAPSUS is a relatively simple cellular model operating on timescales of centuries to millennia and using annual timesteps that has had a hillslope focus. Our objective was to incorporate fluvial behaviour in LAPSUS without changing the existing model equations. The model should be able to reproduce alternating aggradation and incision in the floodplains of catchments, depending on simulated conditions. Testing was done using an artificial digital elevation model (DEM) and a demonstration of the ability for fluvial simulation was performed for a real landscape (Torrealvilla catchment, southeast Spain). Model equations to calculate sediment dynamics and water routing were similar for both hillslope and fluvial conditions, but different parameter values were used for these domains, defined based on annual discharge. Parameters changing between the domains are convergence factor p, which is used in the multiple flow algorithm to route water, and discharge and gradient exponents m and n, used in transport capacity calculations. Erodibility and ‘sedimentability’ factors K and P were changed between cold (little vegetation, high erodibility) and warm conditions (more vegetation, lower erodibility). Results show that the adapted parameters reproduced alternating aggradation – due to divergent flow in the floodplain and sediment supply under cold conditions – and incision due to reduced sediment supply and resulting clean water erosion during simulated warm conditions. The simulated results are due to interactions between hillslopes and floodplains, as the former provide the sediments that are deposited in the latter. Similar behaviour was demonstrated when using the real DEM. Sensitivity and resolution analysis showed that the model is sensitive to changes in m, n and p and that model behaviour is influenced by DEM resolution. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
57.
Partial melting of mantle peridotite generates a physically and chemically layered oceanic lithosphere that is cycled back into the mantle in subduction zones. Stirring times of the mantle are too long to allow for complete re-homogenization of subducted basalt and harzburgite, given the low chemical diffusivity of the solid mantle. This suggests that the Earth's mantle is a mechanical mixture of basaltic and harzburgitic components. Using a recently developed thermodynamic formulism we determine the phase equilibria and the seismic properties of a mantle comprised of a mechanical mixture of basalt and harzburgite (MM) and a homogeneous mantle (EA) with identical pyrolitic bulk chemistry. We use the theoretical shear velocity profiles as a new thermometer of the mantle below the magma-genetic zone by modeling the difference ΔT410-660 between traveltimes of shear wave reflections off the 410-km and 660-km with the potential temperature TP. ΔT410-660 are measured from waveform stacks. They indicate that, over 1000+ km wave lengths, the temperature varies by about 200 K. Lowest and highest temperatures are resolved for the western Pacific subduction zones and the central Pacific, respectively. This variation is similar for the EA and MM and is in excellent agreement with estimates of transition zone thickness and shear velocity variations. The median value of TP for the EA is 1720 K. It is about 1625 K for the MM, a value that is in better agreement with the Normal-MORB values of 1610 ± 40 K inferred from olivine-liquid equilibria given that our sampling region encompasses the Western Pacific subduction zones and the oldest parts of the Pacific Plate. We argue therefore that a mechanical mixed mantle, with generally higher velocities and steeper velocities gradients, represents a better physical reference model than a model based on a fully equilibrated assemblage.  相似文献   
58.
The Early Jurassic Toarcian oceanic anoxic event (T-OAE) and concurrent negative carbon-isotope (δ13C) excursion have recently been attributed to either the release of methane (CH4) clathrates or thermogenic CH4 gas associated with the Karoo-Ferrar large igneous province (LIP) into coals and organic-rich shales. 12C-enriched thermogenic CH4 production associated with the Karoo-Ferrar would result in residual material being 12C-depleted nearer the intrusions. In this study, geochemical analyses (carbon isotopes, volatile matter (VM), vitrinite reflectance (Ro)) are reported for two coal transects associated with dykes intruding the No. 4L coal in the Highveld Coalfield, Karoo Basin, South Africa. VM decreases from over 35% to around 15% in one transect, and the second transect shows a less pronounced decrease (from > 25% to ~ 16%). Accompanying the decrease in VM content is an increase in Ro from background levels of around 0.7% to over 4% adjacent to the dyke; used as a palaeo-geothermometer, Ro values indicate background temperatures of ~ 100 °C increasing to > 300 °C close to the contact. Despite changes in VM and Ro, there are no significant changes in δ13C, certainly not of the magnitude that would be expected associated with large-scale thermogenic CH4 generation. These and other Gondwanan coals have low vitrinite and liptinite contents (components more prone to CH4 generation), in part explaining the modest decreases in VM adjacent to the dykes. This, combined with the relatively narrow metamorphic aureole surrounding the intrusions and the likelihood that at least some of the volatiles generated by the intrusion were trapped as coalbed CH4 or condensed as pyrolytic carbon, suggests only limited CH4 release. In addition, based on original estimates of moisture contents in these coals and the depth at time of intrusion (1,000–2,000 m) the dykes would have lost most of their energy heating and evaporating water, thus having very little remaining energy to generate thermogenic CH4.  相似文献   
59.
Aftershocks of the 2011 Tohoku-Oki great earthquake have a wide range of focal depths and fault plane mechanisms. We constrain the focal depths and focal mechanisms of 69 aftershocks with M w > 5.4 by modeling the waveforms of teleseismic P and its trailing near-surface reflections pP and sP. We find that the “thrust events” are within 10 km from the plate interface. The dip angles of these thrust events increase with depth from ~5° to ~25°. The “non-thrust events” vary from 60 km above to 40 km below the plate interface. Normal and strike-slip events within the overriding plate point to redistribution of stress following the primary great earthquake; however, due to the spatially variable stress change in the Tohoku-Oki earthquake, an understanding of how the mainshock affected the stresses that led to the aftershocks requires accurate knowledge of the aftershock location.  相似文献   
60.
We study the mechanical deformation of fractures under normal stress, via tangent and specific fracture stiffnesses, for different length scales using numerical simulations and analytical insights. First, we revisit an equivalent elastic layer model that leads to two expressions: the tangent stiffness is the sum of an “intrinsic” stiffness and the normal stress, and the specific stiffness is the tangent stiffness divided by the fracture aperture at current stress. Second, we simulate the deformation of rough fractures using a boundary element method where fracture surfaces represented by elastic asperities on an elastic half‐space follow a self‐affine distribution. A large number of statistically identical “parent” fractures are generated, from which sub‐fractures of smaller dimensions are extracted. The self‐affine distribution implies that the stress‐free fracture aperture increases with fracture length with a power law in agreement with the chosen Hurst exponent. All simulated fractures exhibit an increase in the specific stiffness with stress and an average decrease with increase in length consistent with field observations. The simulated specific and tangent stiffnesses are well described by the equivalent layer model provided the “intrinsic” stiffness slightly decreases with fracture length following a power law. By combining numerical simulations and the analytical model, the effect of scale and stress on fracture stiffness measures can be easily separated using the concept of “intrinsic” stiffness. We learn that the primary reason for the variability in specific stiffness with length comes from the fact that the typical aperture of the self‐affine fractures itself scales with the length of the fractures.  相似文献   
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