An approach to determination of phenolic compounds in seawater using SPME-GC-MS based on SWCNTs coating   总被引：1，自引：0，他引：1  

ZHU Jia  WANG Ying  ZENG Lin 《中国海洋大学学报(英文版)》2016,15(4):655-659

Phenolic compounds have become one kind of the important pollutants of the marine environment. Single-walled Carbon nanotubes, as one-dimensional nano materials, have light weight and perfect hexagonal structure of connections, with many unusual mechanical, chemical and electrical properties. In recent years, with the research of carbon nanotubes and other nano materials, the application prospect is also constantly discussed. In this paper, homemade single-walled carbon nanotubes(SWCNTs) coating was used for establishing an analytical approach to the determination of five kinds of phenolic compounds in seawater using SPME-GC-MS. Optimal conditions: After saturation was conducted with Na Cl, and p H was adjusted to 2.0 with H_2SO_4, the extract was immersed in a water bath at 40 for GC℃-MS determination through 40-min agitating extraction at 500 rmin~(-1) and 3-min desorption at 280℃. The liniearities ranged between 0.01-100 μg L~(-1), and the determination limits ranged between 1.5-10 ngL~(-1). The relative standard deviation(RSD, n = 5) was less than 6.5%. For the phenolic compounds obtained from the spiked recovery test for actual seawater samples, the rates of recovery were 87.5%-101.7%, and the RSDs were less than 8.8%, which met the requirements of determination. Due to its simplicity, high efficiency and low consumption, this approach is suitable for the analysis of trace amounts of phenolic compounds in marine waters.  相似文献   

中国省际人口迁移的多边效应机制分析   总被引：12，自引：6，他引：6  

蒲英霞  韩洪凌  葛莹  孔繁花 《地理学报》2016,71(2):205-176

区际人口迁移不仅与迁出地和目的地的要素特征以及距离有关,而且还受到周边迁移流的影响.基于网络自相关理论,利用"六普"省际人口迁移数据和相关统计资料,在重力模型的基础上考虑迁移流之间可能存在的几种空间依赖形式,构建中国省际迁移流的空间OD模型,初步揭示区域经济社会等因素及其空间溢出效应对省际人口迁移的影响,并就区域要素变化对整个省际人口迁移系统产生的"连锁反应"进行了模拟.结果表明:① 中国省际迁移流之间存在显著的网络自相关效应.目的地和迁出地的自相关效应皆为正,导致迁入和迁出流的空间效仿行为;迁出地和目的地周边则出现负的自相关效应,导致迁移流的空间竞争行为;② 区域经济社会等因素通过网络空间关系对周边地区产生的多边溢出效应导致迁移流在空间上集聚.其中,距离衰减效应位居各要素之首,其溢出效应进一步加剧距离的摩擦作用;对目的地而言,区域工资水平和迁移存量超过GDP的影响并产生正的溢出效应,促进周边地区吸引更多的外来人口;对迁出地而言,人口规模和迁移存量产生正的溢出效应,推动周边地区人口外迁;③ 区域要素变化潜在地对整个省际人口迁移系统产生一系列"连锁反应",震荡中心及其周边区域的迁移流波动较大.江苏省GDP增长5%的模拟结果表明,江苏迁往全国其他省份的人口数量都有不同程度地减少,而其他省份入迁人口均有所增加.相对而言,江苏周边省份的迁入或迁出流受到的波动较大,偏远省份波及较小,这是传统的重力模型所无法解释的.  相似文献   

伊犁盆地伊昭井田煤层煤质特征研究          下载免费PDF全文

裴重举  秦守萍  仇晓华 《山东国土资源》2016,32(2)

伊昭井田位于伊犁盆地中西部,煤层资源储量36亿t。赋煤层位为侏罗世水西沟群西山窑组,共含煤12层,其中可采煤层6层,3号煤层和5号煤层为井田主采煤层。对各煤层特征进行了研究,总结了各煤层特征及赋存规律及各煤层煤质特征及工业利用方向。对指导伊犁盆地的煤炭勘查、开发利用及生产布局具有积极意义。  相似文献   

东昆仑东段巴隆地区朝火鹿陶勒盖花岗闪长岩体锆石U-Pb年龄、地球化学及其地质意义     

陈功  裴先治  李佐臣  李瑞保  陈有炘  刘成军  陈国超  王旭斌  桑继镇  杨森  邓文兵 《地质通报》2016,35(12):1990-2005

东昆仑造山带晚古生代—早中生代由于布青山-阿尼玛卿洋的俯冲发育有大量岛弧型花岗岩类。选取东昆北巴隆地区朝火鹿陶勒盖花岗闪长岩体寄主岩和闪长质暗色微粒包体进行了岩相学、LA-ICP-MS锆石U-Pb年代学及地球化学研究。结果表明,岩体寄主岩的结晶年龄为242.3±1.3Ma,暗色微粒包体结晶年龄为241.2±0.8Ma,显示其形成于中三叠世;寄主岩和暗色微粒包体A/CNK值介于0.86~1.06之间,为准铝质-弱过铝质;稀土元素总量分别为119×10~(-6)~170×10~(-6)、189×10~(-6),稀土元素配分模式显示右倾型,具有负Eu异常;岩石富集Rb、Ba、Th等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素,具有弧岩浆岩特征。野外及岩相学特征均显示包体为基性岩浆进入酸性岩浆快速冷凝形成的,为俯冲板片断离导致幔源岩浆上侵形成的岩浆混合作用的产物,是布青山-阿尼玛卿洋俯冲晚期的岩浆记录。  相似文献   

新疆东准乌须克劳格岩体LA-ICP-MS锆石U-Pb年龄、Hf同位素特征及其地质意义     

李高峰  孟贵祥  吴建  姜彦勇  雷印祥  童英 《地质通报》2016,35(7):1170-1183

新疆东准噶尔琼河坝地区近年来找矿获得重大突破,发现了一系列重要的矿产,这些矿产基本上围绕该地区出露面积最大的乌须克劳格岩体分布。该岩体组成比较复杂,主要岩性为二长花岗岩和花岗闪长岩。采用LA-ICP-MS技术测得花岗闪长岩和二长花岗岩锆石~(206)Pb/~(238)U年龄分别为428.9±1.9Ma和427.2±1.7Ma,被解释为岩石的结晶年龄。2类岩石都属于过铝质-钙碱性系列花岗岩,具有较高的铝、钙含量,K_2O/Na_2O值普遍偏低,介于0.15~0.40之间;稀土元素配分曲线呈现右倾特征,稀土元素总量较低,轻稀土元素相对富集,负Eu异常不明显;在微量元素原始地幔标准化蛛网图上,高场强元素Th、Nb、Ta、P、Ti等相对亏损,大离子亲石元素Rb、Ba、U、K、Sr等相对富集,具有高Ba、Sr含量和高(La/Yb)_N、Sr/Y值,显示出高Ba-Sr花岗岩的特征;同时岩体具有高正ε_(Hf)(t)值和年轻的模式年龄。这些地球化学和同位素特征表明,晚志留世乌须克劳格岩体是大陆边缘弧环境下大洋板片熔融的产物。  相似文献   

东昆仑东段布青山地区上二叠统格曲组物源分析及其构造意义   总被引：2，自引：1，他引：1  

杨森  裴先治  李瑞保  刘成军  陈有炘  李佐臣  王旭斌  桑继镇  陈功  邓文兵 《地质通报》2016,35(5):674-686

对东昆仑东段布青山得力斯坦地区出露的上二叠统格曲组砾岩层进行砾石成分、砾度统计及系统的LA-ICP-MS锆石UPb年龄谱分析。结果表明,格曲组砾岩层砾石成分以石英岩和花岗岩为主,硅质岩和基性岩次之,砂岩和灰岩较少,砾石的分散系数为1.54~2.02,该套砾岩为近源快速堆积的产物。砾岩碎屑锆石U-Pb年龄可分为3组:1早奥陶世—晚志留世年龄组为499~409Ma,峰值年龄为426Ma,对应早古生代末期原特提斯洋向北俯冲碰撞产生的一系列构造岩浆事件;2新元古代年龄组为744~619Ma,峰值年龄为744Ma,对应于全球Rodinia超大陆裂解事件;3古元古代年龄组为2443Ma,对应东昆仑地区古元古代构造岩浆热事件。结合碎屑锆石年龄及沉积学特征综合分析,花岗质砾石来源于北侧东昆仑造山带加里东期岩浆弧,沉积岩砾石则可能来自造山带早期的沉积地层,石英岩及其他变质岩砾石则多来自东昆仑基底变质岩系。综合判别,格曲组为一套沉积于活动大陆边缘环境的滨浅海相磨拉石建造,代表南侧古特提斯洋向北俯冲开始的构造阶段,是初始俯冲的沉积构造响应。  相似文献   

专题地质填图及有关问题讨论   总被引：2，自引：1，他引：1  

王涛  计文化  胡建民  李建星  胡道功  童英 《地质通报》2016,35(5):633-641

面积性地质调查及填图是今后地质调查的主要工作,如何做好这个工作,并实现地质调查和科研一体化,特别是在已有填图基础上,如何部署和开展新的填图工作,是一个亟待回答的新问题。专题地质填图是针对存在的重要地质或资源、环境问题,或是针对特定目标地质体等,以解决特定问题或满足社会特定需求为主要目的、填图与研究融为一体的地质填图,填图的范围和比例尺依据解决问题和目标地质体而定。专题地质填图是以问题和需求为驱动,是对已有的综合地质填图的补充和提高,是高效实现地调科研一体化的一种方式。论述了专题填图的内涵、必要性,以及开展专题填图的方式和方法。  相似文献   

Identifications of aquifer group classification by using environmental isotope and hydrogeochemistry method: a case study of Huabei plain,China     

Jiang Chen  Ying Wang  Zongyu Chen 《Environmental Earth Sciences》2016,75(19):1314

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Characteristics of deuterium excess parameters for geothermal water in Beijing     

Kai Liu  Xiaojuan Qiao  Baoling Li  Ying Sun  Zhiping Li  Conglin Pu 《Environmental Earth Sciences》2016,75(23):1485

This study investigates the characteristics of geothermal water in 10 geothermal fields in Beijing. The relationships between the deuterium excess parameter (d) and temperature, depth, age of geothermal groundwater, groundwater flow field, and Eh were investigated using geothermal groundwater samples. Results showed that (1) the average d value of geothermal water is 5.4, whereas that of the groundwater in normal temperature is 6.04. The differences are induced by the oxygen isotope exchange during the water–rock interaction, which may be more easily completed in geothermal water than in cold groundwater. (2) The d value increases remarkably with the age of the geothermal groundwater. The d value increases from 11.2 to 14.6 when the age of the geothermal water is 12,760 ± 130 a and 38,960 ± 630 a, respectively. Moreover, the isotope heat exchange for composition of the hydrogen and oxygen isotopes in the geothermal groundwater proceeds sufficiently with time. (3) The d value decreases from 5.72 to 3.03 when the depth increases from 125.13 to 3221 m. Generally, in the same area, the d value decreases with depth because the temperature is increasing. (4) The d value of the groundwater gradually reduces from the northern recharge area to the southern discharge area. The average d value is 7.31 in the northern recharge area and 5.68 in the middle Beijing Depression, whereas the d value in the southern area of Fengheying is ?9.20. The larger difference in d values between the recharge and discharge areas is due to the slower velocity of underwater flow, which induces longer time for oxygen exchange. (5) The relationship between the d and Eh is complex. When Eh is <200 mV, the d value of the geothermal water decreases with the decrease in Eh. When Eh is higher than 200 mV, the d value increases slightly with the decrease in Eh. The study of the characteristics of deuterium excess parameters for geothermal water could provide a scientific isotopic evidence for assessment and exploitation measures in geothermal groundwater systems.  相似文献   

Numerical Analysis of Gravity Coring Using Coupled Eulerian-Lagrangian Method and a New Corer     

Huawei Qin  Zhen Cai  Jianjun Wang  Wei Ye  Ying Chen 《Marine Georesources & Geotechnology》2016,34(5):403-408

The shortcomings of gravity corers in sampling marine sediments have been observed extensively in various field tests. In order to optimize the coring, this article provides an alternative numerical way to model the gravity coring and analyze the sampling effect. Based on this analysis, a new hydraulic hammer corer is devised. A coupled Eulerian-Lagrangian method with capability of simulating the problem involving extreme deformation, penetration is used to simulate the coring process. The results show that the hydrostatic pressure and deviator stress increase and reach their peak when the pile tip is slightly above or at the level of the observation point and then drop rapidly when the pile tip slides below the observation point. In addition, the stress path indicates that the soil element sustains plastic compression before yielding and then expands until recovering to the original state. The obvious “under-sampling” phenomenon is also well-captured by the finite element model.  相似文献