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81.
The reduction and equalization of the salt concentrations in the River Werra have resulted in a gradual recovery of the aquatic flora. Spatial high-resolution macrophyte mappings document the spread of the aquatic vascular plants in the middle and lower River Werra. Simultaneously, the plankton blooms have declined. Changes in the composition of the algal communities including diatoms also indicated lower salinity. In addition to the salinity, high nutrient concentrations, waste water discharges and structural degradation are important stressors in the River Werra as shown by e.g. low species richness of vascular plants and the common occurrence of pollution tolerant diatoms. From the existing data it is clear that an encompassing improvement of the ecological conditions in the River Werra can only be achieved by further restoration measures considering all stressors.  相似文献   
82.
The acid chemistry of confined waters in smectite interlayers have been investigated with first principles molecular dynamics (FPMD) simulations. Aiming at a systematic picture, we establish the model systems to take account of the three possible controlling factors: layer charge densities (0 e, 0.5 e and 1.0 e per cell), layer charge locations (tetrahedral and octahedral) and interlayer counterions (Na+ and Mg2+). For all models, the interlayer structures are characterized in detail. Na+ and Mg2+ show significantly different hydration characteristics: Mg2+ forms a rigid octahedral hydration shell and resides around the midplane, whereas Na+ binds to a basal oxygen atom and forms a very flexible hydration shell, which consists of five waters on average and shows very fast water exchanges. The method of constraint is employed to enforce the water dissociation reactions and the thermodynamic integration approach is used to derive the free-energy values and the acidity constants. Based on the simulations, the following points have been gained. (1) The layer charge is found to be the direct origin of water acidity enhancement in smectites because the neutral pore almost does not have influences on water dissociations but all charged pores do. (2) With a moderate charge density of 0.5 e per cell, the interlayer water shows a pKa value around 11.5. While increasing layer charge density to 1.0 e, no obvious difference is found for the free water molecules. Since 1.0 e is at the upper limit of smectites’ layer charge, it is proposed that the calculated acidity of free water in octahedrally substituted Mg2+-smectite, 11.3, can be taken as the lower limit of acidities of free waters. (3) In octahedrally and tetrahedrally substituted models, the bound waters of Mg2+ show very low pKa values: 10.1 vs 10.4. This evidences that smectites can also promote the dissociations of the coordinated waters of metal cations. The comparison between the two Mg2+-smectites reveals that different layer charge locations do not lead to obvious differences for bound and free water acidities.  相似文献   
83.
The Dawn mission has provided new evidence strengthening the identification of asteroid Vesta as the parent body of the howardite, eucrite, and diogenite (HED) meteorites. The evidence includes Vesta's petrologic complexity, detailed spectroscopic characteristics, unique space weathering, diagnostic geochemical abundances and neutron absorption characteristics, chronology of surface units and impact history, occurrence of exogenous carbonaceous chondritic materials in the regolith, and dimensions of the core, all of which are consistent with HED observations and constraints. Global mapping of the distributions of HED lithologies by Dawn cameras and spectrometers provides the missing geologic context for these meteorites, thereby allowing tests of petrogenetic models and increasing their scientific value.  相似文献   
84.
We present an uncertainty analysis of ecological process parameters and CO2 flux components (Reco, NEE and gross ecosystem exchange (GEE)) derived from 3 years’ continuous eddy covariance meas-urements of CO2 fluxes at subtropical evergreen coniferous plantation, Qianyanzhou of ChinaFlux. Daily-differencing approach was used to analyze the random error of CO2 fluxes measurements and bootstrapping method was used to quantify the uncertainties of three CO2 flux components. In addition, we evaluated different ...  相似文献   
85.
基于GIS矿产勘查靶区优选技术   总被引:1,自引:0,他引:1  
靶区优选是矿产勘查中的一个关键环节, 它既是矿产资源预测成果的直接体现形式, 同时又是联系矿产资源预测与勘查工作部署的桥梁.然而, 由于人们认识上的不完备性和缺乏相应的技术手段支撑, 使得靶区优选常被忽视或简化.探讨了靶区优选的地质基础原则, 建立了靶区优选的技术流程, 研发了基于GIS支持下靶区优选计算机辅助决策模块, 并以云南省个旧地区与岩浆活动有关的锡铜多金属矿靶区为例进行了示范研究.结果表明靶区优选技术及相应的软件能够客观地反映不同靶区的特征, 提高靶区优选的智能化程度和工作效率.   相似文献   
86.
Structures of the Bohai Petroliferous Area, Bohai Bay Basin   总被引:3,自引:0,他引:3  
This paper, for the first time, deals with a more systematic study of the structures in the Bohaipetroliferous area that covers nearly one third of the Bohai Bay basin. The study mainly involves the effects of preexisting basement faults on the basin formation, the characteristics of basin geometry and kinetics, the modelling of the tectonic-thermal history, the polycyclicity and heterogeneity in the structural evolution and the natural seismic tomographic images of the crust and upper mantle. The authors analyze the features of the dynamic evolution of the basin in the paper and point out that the basin in the Bohai petroliferous area is an extensional pull-apart basin.  相似文献   
87.
1 Introduction1.1 Introduction to Liaocheng PrefectureLiaocheng Prefecture lies in northwest of Shandong Province and slightly north to the center of the Huang-Huai-Hai Plain with latitudes between 35(47'N and 37(02'N and longitudes between 115(16'E and 116(32'E. Administratively, it consists of two cities (Liaocheng and Linqing) and six counties (Yanggu, Shenxian, Chiping, Dong'e, Guanxian and Gaotang). It covers a total area of 8590 km2 with a maximum distance of 114 km from eas…  相似文献   
88.
The goal of this study was to statistically analyse the variability of global irradiance and ultraviolet erythemal (UVER) irradiance and their interrelationships with global and UVER irradiance, global clearness indices and ozone. A prediction of short-term UVER solar irradiance values was also obtained. Extreme values of UVER irradiance were included in the data set, as well as a time series of ultraviolet irradiance variability (UIV). The study period was from 2005 to 2014 and approximately 250,000 readings were taken at 5-min intervals. The effect of the clearness indices on global irradiance variability (GIV) and UIV was also recorded and bi-dimensional distributions were used to gather information on the two measured variables. With regard to daily GIV and UIV, it is also shown that for global clearness index (kt) values lower than 0.6 both global and UVER irradiance had greater variability and that UIV on cloud-free days (kt higher than 0.65) exceeds GIV. To study the dependence between UIV and GIV the χ2 statistical method was used. It can be concluded that there is a 95% probability of a clear dependency between the variabilities. A connection between high kt (corresponding to cloudless days) and low variabilities was found in the analysis of bi-dimensional distributions. Extreme values of UVER irradiance were also analyzed and it was possible to calculate the probable future values of UVER irradiance by extrapolating the values of the adjustment curve obtained from the Gumbel distribution.  相似文献   
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