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101.
Numerical simulations and tests with the recently redesigned land–air parameterization scheme (LAPS) are presented. In all experiments, supported either by one-point micrometeorological, 1D or 3D simulations, the attention has been directed to: (1) comparison of simulation outputs, expressing the energy transfer over and through heterogeneous and non-heterogeneous surfaces, versus observations and (2) analysis of uncertainties occurring in the solution of the energy balance equation at the land–air interface. To check the proposed method for aggregation of albedo, “propagating hole” sensitivity tests with LAPS over a sandstone rock grid cell have been performed with the forcing meteorological data for July 17, 1999 in Baxter site, Philadelphia (USA). Micrometeorological and biophysical measurements from the surface experiments conducted over crops and apple orchard in Serbia, Poland, Austria and France were used to test the operation of LAPS in calculating surface fluxes and canopy environment temperatures within and above plant covers of different densities. In addition, sensitivity tests with single canopy covers over the Central Europe region and comparison against the observations taken from SYNOP data using 3D simulations were made. Validation of LAPS performances over a solid surface has been done by comparison of 2 m air temperature observations against 5-day simulations over the Sahara Desert rocky ground using 3D model. To examine how realistically the LAPS simulates surface processes over a heterogeneous surface, we compared the air temperature measured at 2 m and that predicted by the 1D model with the LAPS as the surface scheme. Finally, the scheme behaviour over urban surface was tested by runs over different parts of a hypothetical urban area. The corresponding 1D simulations were carried out with an imposed meteorological dataset collected during HAPEX-MOBILHY experiment at Caumont (France). The quantities predicted by the LAPS compare well with the observations and the various subcomponents of the scheme appear to operate realistically.  相似文献   
102.
The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221) and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data were used to derive the Arrhenius expressions , , (in units of cm3 molecule−1 s−1). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO3, O3 and Cl have been calculated.  相似文献   
103.
The effects of growth of autoirrigated, shaded transplants of Pseudoscleropodium purum on the quantification of tissue concentrations of Cd, Cu, Hg, V and Zn, were investigated in 4 exposure periods, each of 56 days, at 7 sampling sites (contaminated and uncontaminated). Concentrations of the elements in the basal portions of the moss shoots were compared with the concentrations in the portions of the shoots that grew during the exposure period. Mercury and V were present at lower concentrations in the new portions of the shoots than in the basal portions, whereas the opposite was true for Cd, Cu and Zn. The magnitude of error introduced by growth was not negligible, and in some cases was higher than 40%, relative to the results obtained by analysis of the whole shoot. Devitalization of moss prior to its use as transplant material is recommended to avoid growth of the plant during the exposure period.  相似文献   
104.
We present a numerical study of the set of orbits of the planar circular restricted three body problem which undergo consecutive close encounters with the small primary, or orbits of second species. The value of the Jacobi constant is fixed, and we restrict the study to consecutive close encounters which occur within a maximal time interval. With these restrictions, the full set of orbits of second species is found numerically from the intersections of the stable and unstable manifolds of the collision singularity on the surface of section that corresponds to passage through the pericentre. A ‘skeleton’ of this set of curves can be computed from the solutions of the two-body problem. The set of intersection points found in this limit corresponds to the S-arcs and T-arcs of Hénon’s classification which verify the energy and time constraints, and can be used to construct an alphabet to describe the orbits of second species. We give numerical evidence for the existence of a shift on this alphabet that describes all the orbits with infinitely many close encounters with the small primary, and sketch a proof of the symbolic dynamics. In particular, we find periodic orbits that combine S-type and T-type quasi-homoclinic arcs.  相似文献   
105.
Mathematical Geosciences - EURO-CORDEX is an international initiative which provides regional climate projections based on multiple dynamical and empirical–statistical downscaling models. The...  相似文献   
106.
Páramos, a neotropical alpine grassland-peatland biome of the northern Andes and Central America, play an essential role in regional and global cycles of water, carbon, and nutrients. They act as water towers, delivering water and ecosystem services from the high mountains down to the Pacific, Caribbean, and Amazon regions. Páramos are also widely recognized as a biodiversity and climate change hot spots, yet they are threatened by anthropogenic activities and environmental changes. Despite their importance for water security and carbon storage, and their vulnerability to human activities, only three decades ago, páramos were severely understudied. Increasing awareness of the need for hydrological evidence to guide sustainable management of páramos prompted action for generating data and for filling long-standing knowledge gaps. This has led to a remarkably successful increase in scientific knowledge, induced by a strong interaction between the scientific, policy, and (local) management communities. A combination of well-established and innovative approaches has been applied to data collection, processing, and analysis. In this review, we provide a short overview of the historical development of research and state of knowledge of the hydrometeorology, flux dynamics, anthropogenic impacts, and the influence of extreme events in páramos. We then present emerging technologies for hydrology and water resources research and management applied to páramos. We discuss how converging science and policy efforts have leveraged traditional and new observational techniques to generate an evidence base that can support the sustainable management of páramos. We conclude that this co-evolution of science and policy was able to successfully cover different spatial and temporal scales. Lastly, we outline future research directions to showcase how sustainable long-term data collection can foster the responsible conservation of páramos water towers.  相似文献   
107.
108.
Rapidly transforming headwater catchments in the humid tropics provide important resources for drinking water, irrigation, hydropower, and ecosystem connectivity. However, such resources for downstream use remain unstudied. To improve understanding of the behaviour and influence of pristine rainforests on water and tracer fluxes, we adapted the relatively parsimonious, spatially distributed tracer‐aided rainfall–runoff (STARR) model using event‐based stable isotope data for the 3.2‐km2 San Lorencito catchment in Costa Rica. STARR was used to simulate rainforest interception of water and stable isotopes, which showed a significant isotopic enrichment in throughfall compared with gross rainfall. Acceptable concurrent simulations of discharge (Kling–Gupta efficiency [KGE] ~0.8) and stable isotopes in stream water (KGE ~0.6) at high spatial (10 m) and temporal (hourly) resolution indicated a rapidly responding system. Around 90% of average annual streamflow (2,099 mm) was composed of quick, near‐surface runoff components, whereas only ~10% originated from groundwater in deeper layers. Simulated actual evapotranspiration (ET) from interception and soil storage were low (~420 mm/year) due to high relative humidity (average 96%) and cloud cover limiting radiation inputs. Modelling suggested a highly variable groundwater storage (~10 to 500 mm) in this steep, fractured volcanic catchment that sustains dry season baseflows. This groundwater is concentrated in riparian areas as an alluvial–colluvial aquifer connected to the stream. This was supported by rainfall–runoff isotope simulations, showing a “flashy” stream response to rainfall with only a moderate damping effect and a constant isotope signature from deeper groundwater (~400‐mm additional mixing volume) during baseflow. The work serves as a first attempt to apply a spatially distributed tracer‐aided model to a tropical rainforest environment exploring the hydrological functioning of a steep, fractured‐volcanic catchment. We also highlight limitations and propose a roadmap for future data collection and spatially distributed tracer‐aided model development in tropical headwater catchments.  相似文献   
109.
Late Quaternary (MIS 3 to Recent) oceanographic evolution of the Basque shelf has been analysed for the first time based on the sedimentological analysis of three cores obtained from the middle and outer shelves. The cores are located in two interfluves separated by the San Sebastian canyon. The variability of the percentage of the planktonic foraminifera species Neogloboquadrina pachyderma sin. and of δ18Obull allowed us to identify the influence of colder and warmer waters in the Basque shelf during the late Quaternary. From 56 cal. ka BP to the end of the Last Glacial Maximum (19 cal. ka BP) the sedimentary record shows a decreasing trend in the mean grain size that correlates with the eustatic sea‐level fall. The last Deglaciation (19–11.5 cal. ka BP) is characterized by a sea‐level rise that produced an important hiatus in the western outer shelf. During the Holocene, the middle and outer shelves present different behaviours. From 11.5 to 6.7 cal. ka BP, in the outer shelf the sea‐level rise that started during the Deglaciation produced a hiatus, whereas in the middle shelf the sedimentary succession records the presence of warm to temperate waters. Between 6.7–4.9 cal. ka BP, the entrance of cold surface water‐masses that only affected the middle shelf has been identified, and temperate to warm waters occurred in the outer shelf. The cold surface water‐masses retreated during 4.9–4.3 cal. ka BP in the middle shelf. Finally, from 4.3 cal. ka BP to Recent, the middle shelf registers a hiatus due to sea‐level stabilization after a generalized transgression, synchronous to a decrease in the energy of the water‐masses in the outer shelf. In conclusion, the environmental changes detected in the Basque shelf are attributed to both regional and eustatic sea‐level changes.  相似文献   
110.
The perspective of European National Mapping Agencies (NMA) on the role of citizen sensing in map production was explored. The NMAs varied greatly in their engagement with the community generating volunteered geographic information (VGI) and in their future plans. From an assessment of NMA standard practices, it was evident that much VGI was acquired with a positional accuracy that, while less than that typically acquired by NMAs, actually exceeded the requirements of the nominal data capture scale used by most NMAs. Opportunities for VGI use in map revision and updating were evident, especially for agencies that use a continuous rather than cyclical updating policy. Some NMAs had also developed systems to engage with citizen sensors and examples are discussed. Only rarely was VGI used to collect data on features beyond the standard set used by the NMAs. The potential role of citizen sensing and so its current scale of use by NMAs is limited by a series of concerns, notably relating to issues of data quality, the nature and motivation of the contributors, legal issues, the sustainability of data source, and employment fears of NMA staff. Possible priorities for future research and development are identified to help ensure that the potential of VGI in mapping is realized.  相似文献   
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