Variation in lipid relative abundance and composition among different particle size fractions of a forest soil     

Katell Quenea  Sylvie Derenne  Claude Largeau  Cornlia Rumpel  Andr Mariotti 《Organic Geochemistry》2004,35(11-12):1355

Most studies of soil organic matter are on humic substances although a substantial contribution of lipids is generally noted for soils. Moreover, soil lipids were shown to have a relatively high resistance to biodegradation. Thus, they could provide information on organic matter sources and diagenetic processes. Soil organic matter is highly heterogeneous and different dynamic pools are in evidenced. However the links between these pools and molecular structure have not yet been established. Soil lipids were investigated in three particle-size fractions of a forest soil. Lipids were shown to be preferentially located in the finest fraction. GC-MS analysis of free lipids has revealed different main sources depending on the particle-size fraction and differential degradation. Furthermore, the results obtained for the free lipids on the one hand, and the saponified lipids on the other hand, have indicated that different preservation mechanisms for lipids occur in this soil.  相似文献   

Diagenesis and the reconstruction of paleoenvironments: A method to restore original δO values of carbonate and phosphate from fossil tooth enamel     

Antoine Zazzo  Christophe Lécuyer  Simon M.F. Sheppard  André Mariotti 《Geochimica et cosmochimica acta》2004,68(10):2245-2258

Intra-tooth δ¹⁸O variations within the carbonate (δ¹⁸Oc) and phosphate (δ¹⁸Op) components of tooth apatite were measured for Miocene and Pliocene hypsodont mammals from Afghanistan, Greece and Chad in order to evaluate the resistance of enamel to diagenetic alteration. Application of water-apatite interaction models suggest that the different kinetic behaviours of the phosphate-water and carbonate-water systems can be used to detect subtle oxygen isotope disequilibria in fossil enamel when intra-individual variations are considered. Selective alteration of the oxygen isotope composition from the carbonate component of Afghan and Greek enamels suggests inorganic isotopic exchange processes. Microbially-induced isotopic exchange for phosphate is demonstrated for the first time in enamel samples from Chad, in association with extensive recrystallization. In Chad, δ¹⁸Op values were derived from partial isotopic exchange with fossil groundwater during early diagenesis. Mass balance calculations using average carbonate content in enamel as a proxy for recrystallization, and the lowest δ¹⁸Op value of dentine as a proxy for the isotopic composition of the diagenetic fluid, indicate that diagenesis can alter δ¹⁸Op by as much as 3‰ in some enamel samples. This diagenetic alteration is also responsible for a decrease in intra-individual variations of up to 1‰ in affected specimens. The effects of diagenesis on δ¹⁸Op values of fossil enamel are not systematic, however, and can only be estimated if sequential δ¹⁸Op and δ¹⁸Oc analyses are performed on fossil enamel and dentine. Reconstruction of large temporal- or spatial-scale paleoclimates based on δ¹⁸Op analyses from mammalian teeth cannot be considered valid if enamel has been affected by bacterial activity or if the data cannot be corrected for diagenetic effects.  相似文献   

Numerical Simulation of the 1969 Portuguese Tsunami by a Finite Element Method   总被引：2，自引：0，他引：2  

Guesmia  M.  Heinrich  Ph.  Mariotti  C. 《Natural Hazards》1998,17(1):31-46

On 28 February 1969, the coasts of Portugal, Spain and Morocco were affected by sea waves generated by a submarine earthquake (Ms = 7.3) with its epicenter located off Portugal. The propagation of this tsunami has been simulated by a finite element numerical model solving the Boussinesq equations. These equations have been discretized using the finite element Galerkin method and a Crank–Nicholson scheme in time. The model is validated by investigating the propagation of a solitary wave over a flat bottom. The grid sizes for the 1969 event have been determined by one-dimensional tests offshore and in shallow water regions. The two-dimensional simulation of the 1969 tsunami is carried out using the hydraulic source calculated from the geophysical model of Okada and seismic parameters of Fukao. The modeled waves are compared with the recorded ones with respect to travel times, maximum amplitudes and periods of the signal. The comparison between Boussinesq and shallow-water models shows that the effects of frequency dispersion are minor. Good agreement is found for most of the studied gauges.  相似文献   

Modelling of submarine landslides of rock and soil     

C. Mariotti  P. Heinrich 《国际地质力学数值与分析法杂志》1999,23(4):335-354

Landslides and their hydraulic effects are studied by numerical and experimental means. A two-dimensional model based on Navier–Stokes equations has been developed considering the sediments and water as a mixture. A Bingham law written in effective stress and an erosion–diffusion law at the water–sediment interface have been introduced into the model. Laboratory experiments consisting in the sliding of a block, a coarse gravel and a fine sand have been carried out. The results are compared with the numerical model. These experiments show the importance of sediment rheology and interstitial pressure in slide velocity and water wave generation. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Cold seep communities in the deep eastern Mediterranean Sea: composition, symbiosis and spatial distribution on mud volcanoes   总被引：2，自引：0，他引：2  

Karine Olu-Le Roy  Myriam Sibuet  Aline Fiala-Mdioni  Serge Gofas  Carmen Salas  Andr Mariotti  Jean-Paul Foucher  John Woodside 《Deep Sea Research Part I: Oceanographic Research Papers》2004,51(12):1915-1936

Two mud volcano fields were explored during the French–Dutch MEDINAUT cruise (1998) with the submersible NAUTILE, one south of Crete along the Mediteranean Ridge at about 2000 m depth (Olimpi mud field) and the other south of Turkey between 1700 and 2000 m depth (Anaximander mud field) where high methane concentrations were measured. Chemosynthetic communities were observed and sampled on six mud volcanoes and along a fault scarp. The communities were dominated by bivalves of particularly small size, belonging to families commonly found at seeps (Mytilidae, Vesicomyidae, Thyasiridae) and to Lucinidae mostly encountered in littoral sulfide-rich sediments and at the shallowest seeps. Siboglinid polychaetes including a large vestimentiferan Lamellibrachia sp. were also associated. At least four bivalve species and one siboglinid are associated with symbiotic chemoautotrophic bacteria, as evidenced by Transmission Electronic Microscopy and isotopic ratio measurements. Among the bivalves, a mytilid harbors both methanotrophic and sulfide-oxidizing bacteria. Video spatial analysis of the community distribution on three volcanoes shows that dense bivalve shell accumulations (mainly lucinids) spread over large areas, from 10% to 38% of the explored areas (2500–15000 m²) on the different volcanoes. Lamellibrachia sp. had different spatial distribution and variable density in the two mud volcano fields, apparently related with higher methane fluxes in the Anaximander volcanoes and maybe with the instability due to brines in the Olimpi area. The abundance and richness of the observed chemosynthetic fauna and the size of some of the species contrast with the poverty of the deep eastern Mediterranean. The presence of a specialized fauna, with some mollusk genera and species shared with other reduced environments of the Mediterranean, but not dominated by the large bivalves usually found at seeps, is discussed.  相似文献   

The North Atlantic Oscillation and oceanic precipitation variability     

Annarita Mariotti  Phillip Arkin 《Climate Dynamics》2007,28(1):35-51

Global North Atlantic Oscillation (NAO) oceanic precipitation features in the latter half of the twentieth century are documented based on the intercomparison of multiple state-of-the-art precipitation datasets and the analysis of the NAO atmospheric circulation and SST anomalies. Most prominent precipitation anomalies occur over the ocean in the North Atlantic, where in winter a “quadrupole-like” pattern is found with centers in the western tropical Atlantic, sub-tropical Atlantic, high-latitude eastern Atlantic and over the Labrador Sea. The extent of the sub-tropical and high-latitude center and the amount of explained variance (over 50%) are quite remarkable. However, the tropical Atlantic center is probably the most intriguing feature of this pattern apparently linking the NAO with ITCZ variability. In summer, the pattern is “tripole-like” with centers in the eastern Mediterranean Sea, the North Sea/Baltic Sea and in the sub-polar Atlantic. In the eastern Indian Ocean, the correlation is positive in winter and negative in summer, with some link to ENSO variability. The sensitivity of these patterns to the choice of the NAO index is minor in winter while quite important in summer. Interannual NAO precipitation anomalies have driven similar fresh water variations in these “key” regions. In the sub-tropical and high-latitude Atlantic in winter precipitation anomalies have been roughly 15 and 10% of climatology per unit change of the NAO, respectively. Decadal changes of the NAO during the last 50 years have also influenced precipitation and fresh water flux at these time-scales, with values lower (higher) than usual in the high-latitude eastern North Atlantic (Labrador Sea) in the 1960s and the late 1970s, and an opposite situation since the early 1980s; in summer the North Sea/Baltic region has been drier than usual during the period 1965–1975 when the NAO was generally positive.  相似文献   

Effects of fungal infection on lipid extract composition of higher plant remains: comparison of shoots of a Cenomanian conifer, uninfected and infected by extinct fungi     

Thanh Thuy Nguyen Tu  Sylvie Derenne  Claude Largeau  Andr Mariotti  Herv Bocherens  Denise Pons 《Organic Geochemistry》2000,31(12):25

The lipid fraction extracted from uninfected shoots of a fossil conifer, Frenelopsis alata, was analysed by gas-chromatography–mass-spectrometry, and compared with shoots of the same conifer infected by extinct epiphyllous fungi, so as to study the effects of fungal infection on the chemical composition of extracts from higher plant remains. The extracts from the uninfected shoots appeared to be composed of (i) common constituents of higher plant lipids such as n-alkanes and fatty acids, (ii) elemental sulphur, and (iii) substantial amounts of terpenoids characteristic of conifers, such as cadalene, beyerane, dehydroabietane and related compounds. Comparison of this extract with that of fungal-infected shoots revealed, in addition to the aforementioned compounds, the presence of substantial amounts of hydroxysuccinic acid and functionalised benzoic compounds that were interpreted as degradation products of lignin by fungi. This study afforded preliminary indications of the composition of extracts from higher plant remains infected by fungi.  相似文献   

Numerical study of rock and concrete behaviour by discrete element modelling     

F. Camborde  C. Mariotti  F. V. Donz 《Computers and Geotechnics》2000,27(4):225-247

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Present and future climatologies in the phase I CREMA experiment   总被引：1，自引：0，他引：1  

Erika Coppola  Filippo Giorgi  Francesca Raffaele  Ramon Fuentes-Franco  Graziano Giuliani  Marta LLopart-Pereira  Ashu Mamgain  Laura Mariotti  Gulilat Tefera Diro  Csaba Torma 《Climatic change》2014,125(1):23-38

We provide an overall assessment of the surface air temperature and precipitation present day (1976–2005) and future (2070–2099) ensemble climatologies in the Phase I CREMA experiment. This consists of simulations performed with different configurations (physics schemes) of the ICTP regional model RegCM4 over five CORDEX domains (Africa, Mediterranean, Central America, South America, South Asia), driven by different combinations of three global climate models (GCMs) and two greenhouse gas (GHG) representative concentration pathways (RCP8.5 and RCP4.5). The biases (1976–2005) in the driving and nested model ensembles compared to observations show a high degree of spatial variability and, when comparing GCMs and RegCM4, similar magnitudes and more similarity for precipitation than for temperature. The large scale patterns of change (2070–2099 minus 1976–2005) are broadly consistent across the GCM and RegCM4 ensembles and with previous analyses of GCM projections, indicating that the GCMs selected in the CREMA experiment are representative of the more general behavior of current GCMs. The RegCM4, however, shows a lower climate sensitivity (reduced warming) than the driving GCMs, especially when using the CLM land surface scheme. While the broad patterns of precipitation change are consistent across the GCM and RegCM4 ensembles, greater differences are found at sub-regional scales over the various domains, evidently tied to the representation of local processes. This paper serves to provide a reference view of the behavior of the CREMA ensemble, while more detailed and process-based analysis of individual domains is left to companion papers of this special issue.  相似文献   

Long-term climate change in the Mediterranean region in the midst of decadal variability     

Annarita Mariotti  Yutong Pan  Ning Zeng  Andrea Alessandri 《Climate Dynamics》2015,44(5-6):1437-1456

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