A New Appraisal of Sri Lankan BB Zircon as a Reference Material for LA‐ICP‐MS U‐Pb Geochronology and Lu‐Hf Isotope Tracing          下载免费PDF全文

Maristella M. Santos  Cristiano Lana  Ricardo Scholz  Ian Buick  Mark D. Schmitz  Sandra L. Kamo  Axel Gerdes  Fernando Corfu  Simon Tapster  Penelope Lancaster  Craig D. Storey  Miguel A.S. Basei  Eric Tohver  Ana Alkmim  Herminio Nalini  Klaus Krambrock  Cristiano Fantini  Michael Wiedenbeck 《Geostandards and Geoanalytical Research》2017,41(3):335-358

A potential zircon reference material (BB zircon) for laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) U‐Pb geochronology and Hf isotope geochemistry is described. A batch of twenty zircon megacrysts (0.5–1.5 cm³) from Sri Lanka was studied. Within‐grain rare earth element (REE) compositions are largely homogeneous, albeit with some variation seen between fractured and homogeneous domains. Excluding fractured cathodoluminescence bright domains, the variation in U content for all analysed crystals ranged from 227 to 368 μg g^?1 and the average Th/U ratios were between 0.20 and 0.47. The Hf isotope composition (0.56–0.84 g/100 g Hf) is homogeneous within and between the grains – mean ¹⁷⁶Hf/¹⁷⁷Hf of 0.281674 ± 0.000018 (2s). The calculated alpha dose of 0.59 × 10¹⁸ g^?1 for a number of BB grains falls within the trend of previously studied, untreated zircon samples from Sri Lanka. Aliquots of the same crystal (analysed by ID‐TIMS in four different laboratories) gave consistent U‐Pb ages with excellent measurement reproducibility (0.1–0.4% RSD). Interlaboratory assessment (by LA‐ICP‐MS) from individual crystals returned results that are within uncertainty equivalent to the TIMS ages. Finally, we report on within‐ and between‐grain homogeneity of the oxygen isotope systematic of four BB crystals (13.16‰ VSMOW).  相似文献   

Salmo salar in late medieval Scotland: competition and conservation for a riverine resource     

Richard C. Hoffmann 《Aquatic Sciences - Research Across Boundaries》2015,77(3):355-366

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How do granitoid magmas mix with each other? Insights from textures,trace element and Sr–Nd isotopic composition of apatite and titanite from the Matok pluton (South Africa)     

Oscar?LaurentEmail author  Armin?Zeh  Axel?Gerdes  Arnaud?Villaros  Katarzyna?Gros  Ewa?S?aby 《Contributions to Mineralogy and Petrology》2017,172(9):80

In plutonic systems, magma mixing is often modelled by mass balance based on whole-rock geochemistry. However, magma mixing is a chaotic process and chemical equilibration is controlled by non-linear diffusive–advective processes unresolved by the study of bulk samples. Here we present textural observations, LA-(MC-)ICP-MS trace element and Sr–Nd isotopic data of accessory apatites and titanites from a hybrid granodiorite of the Neoarchean Matok pluton (South Africa), collected in a zone of conspicuous mixing between mafic and felsic magmas. Apatite grains mostly show a pronounced zoning in CL images, corresponding to abrupt changes in REE and HFSE concentrations recording their transfer through compositionally different melt domains during mixing. These grains crystallized early, at temperatures of 950–1000 °C. Titanite grains crystallized at temperatures of 820–900 °C (Zr-in-sphene thermometry). They show limited intra-grain chemical variations but huge inter-grain compositional scatter in REE and HFSE, pinpointing crystallization within a crystal mush, from isolated melt pockets having different composition from one another owing to incomplete chemical homogenization and variable Rayleigh fractionation. These chemical–textural characteristics, in combination with partitioning models and Polytopic Vector Analysis, point to “self-mixing” between co-genetic dioritic and granodioritic/granitic magmas. Both resulted from differentiation of mantle-derived mafic melts, showing that mixing does not necessarily involve magmas from contrasted (crust vs. mantle) sources. Systematic variations in εNd _t (?4.5 to ?2.5) and ⁸⁷Sr/⁸⁶Sr_(i) (0.703–0.707) of titanite and apatite grains/domains crystallized from the two magmas point to an isotopically inhomogeneous mantle source, which is not resolved by bulk-rock isotopic data. Interaction between the two magmas must have occurred at relatively high temperatures (ca. 900°C) so that their viscosity contrast remained low, allowing efficient mechanical mixing. Despite this, chemical homogenization was incomplete, as recorded by diffusive fractionation between REE–HFSE and Sr. Modelling thereof reveals that chemical exchange between the liquid phases of the two mixed magmas did not last more than a few tens to hundreds of years. The chemical equilibration between mixed magmas thus strongly depends on the considered elements and observational length scales.  相似文献   

Local and Nonlocal Magnetic Diffusion and Alpha-Effect Tensors in Shear Flow Turbulence     

Axel Brandenburg  Dmitry Sokoloff 《地球物理与天体物理流体动力学》2013,107(4):319-344

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From Fish to Jellyfish in the Eutrophicated Limfjorden (Denmark)     

Hans Ulrik Riisgård  Per Andersen  Erik Hoffmann 《Estuaries and Coasts》2012,35(3):701-713

The heavily eutrophicated Limfjorden (Denmark) provides a good illustration of the value of long-term monitoring, especially if this is combined with an experimental, interdisciplinary research approach. Here, we first give a short overview of the environmental status of Limfjorden, including the historical development of nutrient overloading and subsequent oxygen depletion in near-bottom water, and how the annual landings of edible bottom-dwelling fish species (plaice, flounder, eel and others) caught in Limfjorden have decreased from about 2,500 t in the early 1920s to only about 20 t in recent years where the fish have been replaced by an increasing number of especially the moon jellyfish, Aurelia aurita, which mainly preys on zooplankton. Next, we evaluate the ecological consequences of the present high number of jellyfish, based on data from recent years’ research on the abundance of jellyfish, their population dynamics and predation impact. In Limfjorden, the benthic polyp stage of A. aurita ensures a large number of small ephyrae in the early spring and subsequently a large population of adult medusae that control the zooplankton during summer and autumn. The holopelagic invasive ctenophore Mnemiopsis leidyi, which was observed in Limfjorden for the first time in 2007, is a second carnivore adding additional predation pressure of the indigenous A. aurita so that copepods and other mesozooplankton organisms may be virtually absent, as observed in 2008 and 2009 where ciliates made up a substantial part of the zooplankton biomass. Marine environmental management programmes should be aware of the increasing importance of both indigenous and new invasive jellyfish species that may show mass occurrence in especially eutrophicated and over-fished areas.  相似文献   

StalAge – An algorithm designed for construction of speleothem age models     

Denis Scholz  Dirk L. Hoffmann 《Quaternary Geochronology》2011,6(3-4):369-382

Here we present a new algorithm (StalAge), which is designed to construct speleothem age models. The algorithm uses U-series ages and their corresponding age uncertainty for modelling and also includes stratigraphic information in order to further constrain and improve the age model. StalAge is applicable to problematic datasets that include outliers, age inversions, hiatuses and large changes in growth rate. Manual selection of potentially inaccurate ages prior to application is not required. StalAge can be applied by the general, non-expert user and has no adjustable free parameters. This offers the highest degree of reproducibility and comparability of speleothem records from different studies. StalAge consists of three major steps. Firstly, major outliers are identified. Secondly, age data are screened for minor outliers and age inversions, and the uncertainty of potential outliers is increased using an iterative procedure. Finally, the age model and corresponding 95%-confidence limits are calculated by a Monte-Carlo simulation fitting ensembles of straight lines to sub-sets of the age data.We apply StalAge to a synthetic stalagmite ’sample’ including several problematic features in order to test its performance and robustness. The true age is mostly within the 95%-confidence age limits of StalAge showing that the calculated age models are accurate even for very difficult samples. We also apply StalAge to three published speleothem datasets. One of those is annually laminated, and the lamina counting chronology agrees with the age model calculated by StalAge. For the other two speleothems the resulting age models are similar to the published age models, which are both based on smoothing splines. Calculated uncertainties are in the range of those calculated by combined application of Bayesian chronological ordering and a spline, showing that StalAge is efficient in using stratigraphic information in order to reduce age model uncertainty.The algorithm is written in the open source statistical software R and available from the authors or as an electronic supplement of this paper.  相似文献   

西藏甲玛铜多金属矿区成矿斑岩的岩浆混合作用:石英及长石斑晶新证据   总被引：6，自引：3，他引：3  

彭惠娟  汪雄武  Müller Axel  秦志鹏  侯林  周云 《矿床地质》2011,30(2):249-265

西藏甲玛矿区斑岩内石英和长石斑晶的阴极发光(CL)特征及元素含量变化有效记录了岩浆演化、混合及补给事件.石英斑晶的显微生长结构表明,原始岩浆经历过2次铁镁质岩浆混合作用.根据石英斑晶中Ti含量的变化可知,在2次溶蚀前后,石英结晶温度分别增高了约110℃和80℃.此外,斜长石斑晶的反环带及其Ba、Sr、Fe等元素的浓度梯...  相似文献   

Complex fluvial response to Lateglacial and Holocene allogenic forcing in the Lower Rhine Valley (Germany)     

G. Erkens  T. Hoffmann  R. Gerlach  J. Klostermann 《Quaternary Science Reviews》2011,30(5-6):611-627

The Rhine catchment experienced strong changes in upstream allogenic forcing during the last 20,000 years. Climatic changes of the glacial–interglacial transition and steadily growing human impact during the second half of the Holocene forced the Rhine to adapt, resulting in changes in the fluvial morphology. The lower Rhine left two late Weichselian terraces and many Holocene palaeo-meanders in the Lower Rhine Valley (western Germany). This well-preserved terrace sequence is used to investigate the exact course of events of the lower Rhine response to changes in allogenic forcing. Five detailed cross-sections that integrate new and existing borehole data were constructed, and the deposits were analysed with regards to abandonment of terraces, changes in number of active channels, fluvial style, terrace gradients, and overbank sedimentation during the Lateglacial and Holocene. We improved and expanded the chronology of the Lower Rhine Valley deposits by dating new samples (¹⁴C, OSL), and integrated these with existing dating evidence (archaeological and historical data, cross-cutting relationships). Twice during the glacial–interglacial transition, the lower Rhine changed from braided to meandering fluvial style. During both transitional episodes (meandering) secondary channels existed alongside the main channel, with a life span up to 2500 years. The findings imply that the lower Rhine was inherently slow to complete the full morphological transition to a single thread meandering system. On specific aspects of response, the morphological response (point bar/terrace formation, contraction to a single thread) extended over relatively long periods of time, whereas discharge-related response (e.g. fluvial style change, abandonment of braidplains, channel bed lowering/incision) seems to have been near instantaneous. Reach-specific conditions determine the degree to which the geomorphic response is delayed and the complexity of the resultant morphology. Increased human-induced sediment delivery (last 2000–3000 years) is expressed as relative thicker and coarser overbank deposits in the entire study area. In the downstream part of the Lower Rhine Valley it accelerated high-stand deltaic backfilling and decreased incision. The response to human activities occurred relatively quickly in contrast to the long-term fluvial response to the glacial–interglacial transition, because the human impact mainly involved change in delivery of the suspended load.  相似文献   

Eco-hydrological versus supply-limited weathering regimes and the potential for biotic enhancement of weathering at the global scale     

Susanne Arens  Axel Kleidon 《Applied Geochemistry》2011

Biotic enhancement of weathering (BEW) has been proposed to substantially alter the geologic C cycle but the large scale impact of small scale biotic processes remains elusive, especially when compared to large scale drivers of weathering such as climate and crustal uplift. A global land surface model was used to estimate the potential strength of BEW for two contrasting types of weathering regimes that are either limited by the supply of fresh parent material by uplift or controlled by the climatic and eco-hydrological conditions. The biospheric effect on soil CO₂ in the model was then removed in order to determine the reduction of weathering rates and thereby to infer BEW. It was found that only those areas that are not supply limited are susceptible to biotic enhancement. This indicates that the potential for BEW depends directly on the supply of fresh material and thus on crustal uplift.  相似文献   

Magmato-sedimentary Carboniferous to Jurassic evolution of the western Tauern window,Eastern Alps (constraints from U-Pb zircon dating and geochemistry)     

Veselá Petra  Söllner Frank  Finger Friedrich  Gerdes Axel 《International Journal of Earth Sciences》2011,100(5):993-1027

New geochronological U-Pb (LA-ICP-MS) zircon data and geochemical analyses from the Variscan orthogneisses and metavolcanic rocks in the western Tauern window are presented and used to reconstruct the pre-Alpine evolution of this area. The late- and post-Variscan stage in the Tauern window was characterised by distinct magmatic pulses accompanied by the formation of volcano-sedimentary basins. The magmatic activity started in the Visean (335.4 ± 1.5 Ma) with the intrusion of a K-rich, durbachitic biotite-granite (protolith of the Ahorn gneiss). Following a period of exhumation and erosion, Westfalian–Stefanian volcanics were deposited (Grierkar meta-rhyodacite: 309.8 ± 1.5 Ma; Venntal meta-rhyolite: 304.0 ± 3.0 Ma). A renewed magmatic pulse occurred in the Early Permian, producing large volumes of tonalites and granodiorites (Tux meta-granodiorite: 292.1 ± 1.9 Ma). The youngest magmatism is characterised by pyroclastic and tuffitic deposits (Pfitsch meta-rhyolite: 280.5 ± 2.6 Ma; Schönach valley meta-andesite: 279.0 ± 4.8 Ma). This volcanism was probably related to crustal extensional faulting within an intra-continental graben and horst setting, asthenospheric upwelling and heat flow increase due to the onset of the Permian rifting. The Permo-Triassic peneplanation and subsidence is documented by shallow marine and evaporitic deposits. Probably in the Middle Jurassic times, the area was flooded and in the Late Jurassic the whole area was covered by limestones, representing post-rift sediments on the southern European continental margin.  相似文献