Carbonaceous chondrites as analogs for the composition and alteration of Ceres          下载免费PDF全文

Harry Y. McSween Jr.  Joshua P. Emery  Andrew S. Rivkin  Michael J. Toplis  Julie C. Castillo‐Rogez  Thomas H. Prettyman  M. Cristina De Sanctis  Carle M. Pieters  Carol A. Raymond  Christopher T. Russell 《Meteoritics & planetary science》2018,53(9):1793-1804

The mineralogy and geochemistry of Ceres, as constrained by Dawn's instruments, are broadly consistent with a carbonaceous chondrite (CM/CI) bulk composition. Differences explainable by Ceres’s more advanced alteration include the formation of Mg‐rich serpentine and ammoniated clay; a greater proportion of carbonate and lesser organic matter; amounts of magnetite, sulfide, and carbon that could act as spectral darkening agents; and partial fractionation of water ice and silicates in the interior and regolith. Ceres is not spectrally unique, but is similar to a few other C‐class asteroids, which may also have suffered extensive alteration. All these bodies are among the largest carbonaceous chondrite asteroids, and they orbit in the same part of the Main Belt. Thus, the degree of alteration is apparently related to the size of the body. Although the ammonia now incorporated into clay likely condensed in the outer nebula, we cannot presently determine whether Ceres itself formed in the outer solar system and migrated inward or was assembled within the Main Belt, along with other carbonaceous chondrite bodies.  相似文献   

Application of a Bayesian model to infer the contribution of coalbed natural gas produced water to the Powder River,Wyoming and Montana          下载免费PDF全文

Jason M. Mailloux  Kiona Ogle  Carol D. Frost 《水文研究》2014,28(4):2361-2381

The Powder River Basin (PRB) of Wyoming and Montana contains significant coal and coal bed natural gas (CBNG) resources. CBNG extraction requires the production of large volumes of water, much of which is discharged into existing drainages. Compared to surface waters, the CBNG produced water is high in sodium relative to calcium and magnesium, elevating the sodium adsorption ratio (SAR). To mitigate the possible impact this produced water may have on the quality of surface water used for irrigation, the State of Montana passed water anti‐degradation legislation, which could affect CBNG production in Wyoming. In this study, we sought to determine the proportion of CBNG produced water discharged to tributaries that reaches the Powder River by implementing a four end‐member mixing model within a Bayesian statistical framework. The model accounts for the ⁸⁷Sr/⁸⁶Sr, δ¹³C_DIC, [Sr] and [DIC] of CBNG produced water and surface water interacting with the three primary lithologies exposed in the PRB. The model estimates the relative contribution of the end members to the river water, while incorporating uncertainty associated with measurement and process error. Model results confirm that both of the tributaries associated with high CBNG activity are mostly composed of CBNG produced water (70–100%). The model indicates that up to 50% of the Powder River is composed of CBNG produced water downstream from the CBNG tributaries, decreasing with distance by dilution from non‐CBNG impacted tributaries from the point sources to ~10–20% at the Montana border. This amount of CBNG produced water does not significantly affect the SAR or electrical conductivity of the Powder River in Montana. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Megacryst-bulk rock isotopic disequilibrium as an indicator of contamination processes: The Edgecumbe Volcanic Field,SE Alaska     

Dennis J. Geist  James D. Myers  Carol D. Frost 《Contributions to Mineralogy and Petrology》1988,99(1):105-112

Sr and Nd isotopic ratios are reported from mineral separates and bulk rock samples from the Edgecumbe Volcanic Field in southeast Alaska, a suite of lavas that has developed by assimilation. Megacrysts in the basaltic unit and the rhyodacites are in isotopic equilibrium with their matrices. Because the rhyodacites developed as the result of assimilation, the assimilate must have been completely dissolved. In contrast, megacrysts in the two andesitic units are in isotopic disequilibrium with their matrix. These megacrysts must be a mixture of those inherited from the contaminant, crystals in equilibrium with the groundmass, and possibly crystals inherited from a mafic liquid.  相似文献   

Formic and acetic acids in atmospheric condensate in Wilmington,North Carolina     

Joan D. Willey  Carol A. Wilson 《Journal of Atmospheric Chemistry》1993,16(2):123-133

Formic and acetic acids occurred in atmospheric condensate with concentrations similar to rainwater collected in Wilmington, North Carolina, during the sampling period from June to October of 1990. Atmospheric concentrations of these acids (calculated from the condensate concentrations) were higher in continental versus maritime air masses. Concentrations of formic and acetic acids were correlated with each other in both condensate and air. Traffic was a source of acetic acid and of bisulfite to atmospheric condensate in this study.  相似文献   

Thermodynamic stability of CoOOH and its coprecipitation with manganese     

John D. Hem  Charles E. Roberson  Carol J. Lind 《Geochimica et cosmochimica acta》1985,49(3):801-810

A precipitate of cobalt oxyhydroxides formed by bubbling oxygen through a dilute solution of Co(NO₃)₂ held at pH 9.0 and 25°C was aged for 23 months in contact with the original solution, with access to atmospheric oxygen. Co₃O₄ and CoOOH were identified in the precipitate by X-ray diffraction. Chemical equilibria involving these solids were evaluated by measurements of solution pH and Co²⁺ activities and by redox potential measurements and gave a $\text{ΔG}{}_{\mathrm{coOOH}}{}^0$ of $\text{?92.3 ± 0.5 kcal/mole}$. This value and other thermodynamic data show relative feasibility of hypothetical reaction steps and changes in reaction paths during automated coprecipitation titrations and subsequent aging of a precipitate that finally contained βMnOOH, MnO₂ (birnessite) and CoOOH.  相似文献   

Nonequilibrium models for predicting forms of precipitated manganese oxides     

John D. Hem  Carol J. Lind 《Geochimica et cosmochimica acta》1983,47(11):2037-2046

Manganese oxides precipitated by bubbling air through 0.01 molar solutions of MnCl₂, Mn(NO₃)₂, MnSO₄, or Mn(ClO₄)₂ at a constantly maintained pH of 8.5 to 9.5 at temperatures of 25°C or higher consisted mainly of hausmannite, Mn₃O₄. At temperatures near 0°C, but with other conditions the same, the product is feitknechtite, βMnOOH, except that if the initial solution is MnSO₄ and the temperature is near 0°C the product is a mixture of manganite, γMnOOH and groutite, αMnOOH.All these oxides are metastable in aerated solution and alter by irreversible processes to more highly oxidized species during aging. A two-step nonequilibrium thermodynamic model predicts that the least stable species, βMnOOH, should be most readily converted to MnO₂. Some preparations of βMnOOH aged in their native solution at 5°C attained a manganese oxidation state of +3.3 or more after 7 months. Hausmannite aged at 25°C altered to γMnOOH. The latter is more stable than a or βMnOOH, and manganese oxidation states above 3.0 were not reached in hausmannite precipitates during 4 months of aging. Initial precipitation of MnCO₃ rather than a form of oxide is likely only where oxygen availability is very low.Composition of solutions and oxidation state and morphology of solids were determined during the aging process by chemical analyses, X-ray and electron diffraction and transmission electron micrographs.  相似文献   

Quantifying geographic variations in associations between alcohol distribution and violence: a comparison of geographically weighted regression and spatially varying coefficient models   总被引：2，自引：1，他引：2  

Lance A. Waller  Li Zhu  Carol A. Gotway  Dennis M. Gorman  Paul J. Gruenewald 《Stochastic Environmental Research and Risk Assessment (SERRA)》2007,21(5):573-588

Past studies consistently indicate measurable local associations between alcohol distribution and the incidence of violence. These results, coupled with measurements of spatial correlation, reveal the importance of spatial analysis in the study of the interaction of alcohol and violence. While studies increasingly incorporate spatial correlation among model residuals to improve precision and reduce bias, to date, most analyses assume associations that are constant and independent of location, an assumption coming under increasing scrutiny in the quantitative geography literature. In this paper, we review and contrast two approaches for the estimation of and inference for spatially heterogeneous effects (i.e., associative factors whose impacts on the outcome of interest vary throughout geographic space). Specifically, we provide an in-depth comparison of “geographically weighted regression” models (allowing covariate effects to vary in space but only allowing relatively ad hoc inference) with “variable coefficient” models (allowing varying effects via spatial random fields and providing model-based estimation and inference, but requiring more advanced computational techniques). We compare the approaches with respect to underlying conceptual structures, computational implementation, and inferential output. We apply both approaches to violent crime, illegal drug arrest, and alcohol distribution data from Houston, Texas and compare results in light of the differing methodological structures of the two approaches.  相似文献   

Garnet growth in a metapelite from the Moinian rocks of Northern Sutherland,Scotland     

Carol A. Finlay  Alan Kerr 《Contributions to Mineralogy and Petrology》1979,71(2):185-191

Compositional profiles of a series of garnets, extracted from a pelitic schist occurring in the Moinian rocks of Northern Sutherland, have been established. The profiles are complex and do not conform to a simple fractionation model. A model to explain them is suggested.  相似文献   

Using Stable Isotopes of Water and Strontium to Investigate the Hydrology of a Natural and a Constructed Wetland   总被引：3，自引：0，他引：3  

Randall J. Hunt  Thomas D. Bullen  David P. Krabbenhoft  Carol Kendall 《Ground water》1998,36(3):434-443

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Assessment of δ13C and C/N ratios in bulk organic matter as palaeosalinity indicators in Holocene and Lateglacial isolation basin sediments,northwest Scotland     

Elizabeth A. V. Mackie  Jeremy M. Lloyd  Melanie J. Leng  Michael J. Bentley  Carol Arrowsmith 《第四纪科学杂志》2007,22(6):579-591

Carbon isotopes (δ¹³C) and C/N ratios from bulk organic matter have recently been used as alternative proxies for relative sea‐level (RSL) reconstruction where there are problems associated with conventional biological indictors. A previous study on a single isolation basin (Upper Loch nan Eala) in northwest Scotland has shown a clear relationship between δ¹³C, C/N ratios and palaeosalinity from Younger Dryas and Holocene aged sediments. In this paper we present results of δ¹³C and C/N ratio analyses from other isolation basins in northwest Scotland over the Holocene and the Lateglacial period in order to validate this technique. The results from the Holocene sequences support the earlier findings that this technique can be used to identify RSL change from isolation basins over the Holocene in this region. The relationship between δ¹³C, C/N ratios and RSL change is not apparent in sediments of Lateglacial age. Other environmental variables such as atmospheric CO₂ concentration, poor vegetation development and temperature influence δ¹³C values during this period. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献