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41.
Regions of freshwater influence (ROFIs) are dynamic areas within the coastal seas that experience cycles of stability driven by density gradients and the spring-neap tidal cycle. As a result, pulses of biological production may occur on a more frequent timescale than the classic seasonal cycle. Net community production (NCP) rates and chlorophyll a concentration are presented from a site within the ROFI of Liverpool Bay and compared to similar measurements made at a site outside the ROFI during 2009. The influence of water column stability on biological production in the ROFI was also investigated using high-frequency observations from a Cefas Smartbuoy. Both sites were autotrophic from spring to autumn before becoming heterotrophic over winter. NCP at the inshore site was estimated to range from 30.8 to 50.4 gC m−2 year−1. A linear relationship detected between chlorophyll a and NCP from both sites was used to estimate metabolic balance over 1 year at the ROFI site using high-resolution chlorophyll a concentrations from the Smartbuoy but was found to poorly replicate NCP rates compared to those derived from dissolved oxygen fluxes. There was no clear biological response to periods of stratification within the ROFI, and it is proposed that changes in light attenuation in the Liverpool Bay ROFI, driven not only by stratification but also by fluctuations in riverine sediment load, most likely play an important role in controlling phytoplankton growth in this region.  相似文献   
42.
Cristobalite in a rhyolitic lava dome: evolution of ash hazard   总被引:1,自引:1,他引:0  
Prolonged and heavy exposure to particles of respirable, crystalline silica-rich volcanic ash could potentially cause chronic, fibrotic disease, such as silicosis, in individuals living in areas of frequent ash fall. Here, we show that the rhyolitic ash erupted from Chaitén volcano, Chile, in its dome-forming phase, contains increased levels of the silica polymorph cristobalite, compared to its initial plinian eruption. Ash erupted during the initial, explosive phase (2–5 May 2008) contained approximately 2 wt.% cristobalite, whereas ash generated after dome growth began (from 21 May 2008) contains 13–19 wt.%. The work suggests that active obsidian domes crystallise substantial quantities of cristobalite on time-scales of days to months, probably through vapour-phase crystallisation on the walls of degassing pathways, rather than through spherulitic growth in glassy obsidian. The ash is fine-grained (9.7–17.7 vol.% <4 μm in diameter, the respirable range) and the particles are mostly angular. Sparse, fibre-like particles were confirmed to be feldspar or glass.  相似文献   
43.
44.
We present a revised method for the determination of concentrations of rare earth (REE) and other trace elements (Y, Sc, Zr, Ba, Hf, Th) in geological samples. Our analytical procedure involves sample digestion using alkaline fusion (NaOH-Na2O2) after addition of a Tm spike, co-precipitation on iron hydroxides, and measurement by sector field-inductively coupled plasma-mass spectrometry (SF-ICP-MS). The procedure was tested successfully for various rock types (i.e., basalt, ultramafic rock, sediment, soil, granite), including rocks with low trace element abundances (sub ng g−1). Results obtained for a series of nine geological reference materials (BIR-1, BCR-2, UB-N, JP-1, AC-E, MA-N, MAG-1, GSMS-2, GSS-4) are in reasonable agreement with published working values.  相似文献   
45.
Several different inventories of global and regional anthropogenic and biomass burning emissions are assessed for the 1980?C2010 period. The species considered in this study are carbon monoxide, nitrogen oxides, sulfur dioxide and black carbon. The inventories considered include the ACCMIP historical emissions developed in support of the simulations for the IPCC AR5 assessment. Emissions for 2005 and 2010 from the Representative Concentration Pathways (RCPs) are also included. Large discrepancies between the global and regional emissions are identified, which shows that there is still no consensus on the best estimates for surface emissions of atmospheric compounds. At the global scale, anthropogenic emissions of CO, NOx and SO2 show the best agreement for most years, although agreement does not necessarily mean that uncertainty is low. The agreement is low for BC emissions, particularly in the period prior to 2000. The best consensus is for NOx emissions for all periods and all regions, except for China, where emissions in 1980 and 1990 need to be better defined. Emissions of CO need better quantification in the USA and India for all periods; in Central Europe, the evolution of emissions during the past two decades needs to be better determined. The agreement between the different SO2 emissions datasets is rather good for the USA, but better quantification is needed elsewhere, particularly for Central Europe, India and China. The comparisons performed in this study show that the use of RCP8.5 for the extension of the ACCMIP inventory beyond 2000 is reasonable, until more global or regional estimates become available. Concerning biomass burning emissions, most inventories agree within 50?C80%, depending on the year and season. The large differences between biomass burning inventories are due to differences in the estimates of burned areas from the different available products, as well as in the amount of biomass burned.  相似文献   
46.
We have developed cleaning methods for extracting diatomopal from bulk marine sediment samples, for measurement of both zinc (Zn) abundance and isotope composition. This cleaning technique was then applied to a set of Holocene core-top samples from the Southern Ocean. The measured δ66Zn (reported relative to the JMCLyon standard) and Zn/Si ratios from the Southern Ocean diatomopal samples range from 0.7 to 1.5‰, and from 14 to 0.9 μmol/mol, respectively. The Zn abundance and isotope composition data show a clear correlation with opal burial rates and other oceanographic parameters. In common with previous work, we interpret the systematic changes in the Zn/Si ratio to be linked to the variability in the concentrations of bioavailable Zn in the ambient surface seawater where the diatom opal is formed. This variability is likely to be primarily controlled by the degree to which Zn is taken up into phytoplankton biomass. The observed systematic pattern in the δ66Zn compositions of the diatomopal core-top samples is, similarly, likely to reflect changes in the δ66Zn composition of the ambient Zn in the surface waters above the core-top sites, which is progressively driven towards isotopically heavier values by preferential incorporation of the lighter isotopes into phytoplankton organic material. Thus, the systematic relationship between Zn isotopes and abundance observed in the core-top diatomopal samples suggests a potential tool for investigating the biogeochemical cycling of Zn in the past surface ocean for down-core diatomopal material. In this respect, it may be possible to test hypotheses that attribute variations in atmospheric CO2 on glacial–interglacial timescales to the degree to which trace metals limited primary productivity in HNLC zones.  相似文献   
47.
Sedimentological analyses of 289 years (AD 1718-2006) of varved sediment from Shadow Bay, southwest Alaska, were used to investigate hydroclimate variability during and prior to the instrumental period. Varve thicknesses relate most strongly to total annual discharge (r2 = 0.75, n = 43, p < 0.0001). Maximum annual grain size depends most strongly on maximum spring daily discharge (r2 = 0.63, n = 43, p < 0.0001) and maximum annual daily discharge (r2 = 0.61, n = 43, p < 0.0001), while varve thickness is poorly correlated with maximum annual grain size (r2 = 0.004, n = 287, p = 0.33). Relations between varve thickness and annual climate variables (temperature, precipitation, North Pacific (NP) and Pacific Decadal Oscillation (PDO) indices) are insignificant. On multidecadal timescales, however, regime shifts in varve thickness and total annual discharge coincide with shifts in NP and PDO indices. Periods with increased varve thickness and total annual discharge were associated with warm PDO phases and a strengthened Aleutian Low. The varve-inferred record of PDO suggests that any periodicity in the PDO varied over time, and that the early 19th century marked a transition to a more frequent or detectable shifts.  相似文献   
48.
This study, based in the Haushi‐Huqf area of central east Oman, aims to characterize the controls on facies distribution and geometries of some of the best preserved examples of Lower Cretaceous tidal flat facies within the Tethyan epeiric platform. Field, petrographic and geochemical data were acquired from the Barremian–Aptian Jurf and Qishn formations that crop out in a 500 × 1000 m2 butte, thus allowing for pseudo three‐dimensional quantitative data acquisition of the dimensions and spatial distributions of discontinuity surfaces and sedimentary bodies. The interpretation presented here suggests that the main processes impacting sedimentation in the Lower Cretaceous peritidal environment of the Haushi‐Huqf were transport and erosion processes related to storm waves and currents. The vertical evolution of the carbonate system is organized into six types of metre‐scale depositional sequences, from subtidal dominated sequences to supratidal‐capped sequences, which are bounded by regional discontinuity surfaces. At subaerial exposure and submarine erosion surfaces associated with a base level shift, sedimentary horizons along the entire depositional profile are cut by scours possibly created by storm events. Chemostratigraphy allows correlation between the Haushi‐Huqf and the age‐equivalent sections logged in the interior of the platform in Oman. The correlation suggests that the change from subtidal to intertidal depositional sequences during the late highstand is coeval with the development of rudist dominated shoals on the shelf. This study is the first to discuss the controls on Lower Cretaceous peritidal carbonate cyclicity of the Arabian epeiric platform. The results presented here also offer a unique quantitative dataset of the distribution and dimensions of peritidal carbonate shoals and storm scours in a regional sequence stratigraphic context.  相似文献   
49.
Tier-based approaches for landslide susceptibility assessment in Europe   总被引:3,自引:2,他引:1  
In the framework of the European Soil Thematic Strategy and the associated proposal of a Framework Directive on the protection and sustainable use of soil, landslides were recognised as a soil threat requiring specific strategies for priority area identification, spatial hazard assessment and management. This contribution outlines the general specifications for nested, Tier-based geographical landslide zonings at small spatial scales to identify priority areas susceptible to landslides (Tier 1) and to perform quantitative susceptibility evaluations within these (Tier 2). A heuristic, synoptic-scale Tier 1 assessment exploiting a reduced set of geoenvironmental factors derived from common pan-European data sources is proposed for the European Union and adjacent countries. Evaluation of the susceptibility estimate with national-level landslide inventory data suggests that a zonation of Europe according to, e.g. morphology and climate, and performing separate susceptibility assessments per zone could give more reliable results. To improve the Tier 1 assessment, a geomorphological terrain zoning and landslide typology differentiation are then applied for France. A multivariate landslide susceptibility assessment using additional information on landslide conditioning and triggering factors, together with a historical catalogue of landslides, is proposed for Tier 2 analysis. An approach is tested for priority areas in Italy using small administrative mapping units, allowing for relating socioeconomic census data with landslide susceptibility, which is mandatory for decision making regarding the adoption of landslide prevention and mitigation measures. The paper concludes with recommendations on further work to harmonise European landslide susceptibility assessments in the context of the European Soil Thematic Strategy.  相似文献   
50.
The biogeographic history of the African rain forests has been contentious. Phylogeography, the study of the geographic distribution of genetic lineages within species, can highlight the signatures of historical events affecting the demography and distribution of species (i.e. population fragmentation or size changes, range expansion/contraction) and, thereby, the ecosystems they belong to. The accumulation of recent data for African rain forests now enables a first biogeographic synthesis for the region. In this review, we explain which phylogeographic patterns are expected under different scenarios of past demographic change, and we give an overview of the patterns detected in African rain forest trees to discuss whether they support alternative hypotheses regarding the history of the African rain forest cover. The major genetic discontinuities in the region support the role of refugia during climatic oscillations, though not necessarily following the classically proposed scenarios. We identify in particular a genetic split between the North and the South of the Lower Guinean region. Finally we provide some perspectives for future study.  相似文献   
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