Behaviour of H₂O₂, NH₃, and black carbon in mixed-phase clouds during CIME     

Paolo Laj  Andrea I. Flossmann  Wolfram Wobrock  Sandro Fuzzi  Giordano Orsi  Loretta Ricci  Stephan Mertes  Alfons Schwarzenbck  Jost Heintzenberg  Harry Ten Brink 《Atmospheric Research》2001,58(4):256

We investigated the partitioning of trace substances during the phase transition from supercooled to mixed-phase cloud induced by artificial seeding. Simultaneous determination of the concentrations of H₂O₂, NH₃ and black carbon (BC) in both condensed and interstitial phases with high time resolution showed that the three species undergo different behaviour in the presence of a mixture of ice crystals and supercooled droplets. Both H₂O₂ and NH₃ are efficiently scavenged by growing ice crystals, whereas BC stayed predominantly in the interstitial phase. In addition, the scavenging of H₂O₂ is driven by co-condensation with water vapour onto ice crystals while NH₃ uptake into the ice phase is more efficient than co-condensation alone. The high solubility of NH₄⁺ in the ice could explain this result. Finally, it appears that the H₂O₂–SO₂ reaction is very slow in the ice phase with respect to the liquid phase. Our results are directly applicable for clouds undergoing limited riming.  相似文献   

Significance of orthopyroxene and major element constraints on the petrogenesis of Ferrar tholeiites from southern Prince Albert Mountains, Victoria Land, Antarctica     

G. Demarchi  P. Antonini  E. Piccirillo  G. Orsi  L. Civetta  M. D'Antonio 《Contributions to Mineralogy and Petrology》2001,142(2):127-146

The least evolved Jurassic Ferrar tholeiites from southern Prince Albert Mountains (Antarctica) are characterized by the occurrence of orthopyroxene (opx), a mineralogical feature virtually absent in the tholeiites from the large igneous provinces of Karoo (South Africa) and Paraná (Brazil). Petrography suggests that opx is the early phase in the sequence of crystallization and mineral chemistry indicates that it is in equilibrium with the host rock. In general, MELTS modeling predicts that opx is the liquidus phase in the Ferrar tholeiites with MgO higher than ~7 wt% at P=1.5-5 kbar, H₂O=0-1 wt% and % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavTnhis1MBaeXatLxBI9gBae % bbnrfifHhDYfgasaacH8YjY-vipgYlH8Gipec8Eeeu0xXdbba9frFj % 0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs0dXdbPYxe9 % vr0-vr0-vqpWqaaeaabiGaaiaacaqabeaabaqaamaaaOqaaiabdAga % MTWaaSbaaeaacqqGpbWtaeqaaWWaaSbaaeaadaWgaaqaaiabikdaYa % qabaaabeaakiabg2da9iabbgfarjabbAeagjabb2eanjabgkHiTiab % igdaXiaaysW7cyGGSbaBcqGGVbWBcqGGNbWzaaa!381A! = QFM - 1 f_{\rm O} _{_2 } = {\rm QFM} - 1\;\log unit conditions. MELTS results also show that the early crystallization of opx is primarily controlled by high SiO₂ and high SiO₂/CaO, chemical characteristics typical of the Ferrar tholeiites, but not shown by the Karoo and Paraná analogs with similar MgO content. Major element geochemistry of the least evolved Ferrar tholeiite has been modeled through fractional crystallization and fractional crystallization coupled with crustal assimilation processes, starting from natural peridotite-derived experimental melts. Mass balance and MELTS modeling support the argument that theoretical magma compositions suitable to be primary to the least evolved Ferrar tholeiites are compatible with hydrous (H₂O=0.3-0.5 wt%) and anhydrous melts obtained at 10-15 kbar by high melting degrees (>25%) of fertile and depleted spinel lherzolites, respectively, and later contaminated by the high-grade metamorphic rocks from the Victoria Land crystalline basement. The genesis of primary Ferrar tholeiites does not necessarily reflect the generally assumed depleted source mantle being also compatible with a fertile one.  相似文献   

Magmatic History of Somma-Vesuvius on the Basis of New Geochemical and Isotopic Data from a Deep Borehole (Camaldoli della Torre)   总被引：3，自引：0，他引：3  

Di Renzo  V.; Di Vito  M. A.; Arienzo  I.; Carandente  A.; Civetta  L.; D'antonio  M.; Giordano  F.; Orsi  G.; Tonarini  S. 《Journal of Petrology》2007,48(4):753-784

A continuous-coring borehole recently drilled at Camaldoli dellaTorre on the southern slopes of Somma–Vesuvius providesconstraints on the volcanic and magmatic history of the Vesuvianvolcanic area since c. 126 ka BP. The cored sequence includesvolcanic units, defined on stratigraphical, sedimentological,petrological and geochemical grounds, emitted from both localand distal vents. Some of these units are of known age, suchas one Phlegraean pre-Campanian Ignimbrite, Campanian Ignimbrite(39 ka), Neapolitan Yellow Tuff (14· 9 ka) and VesuvianPlinian deposits, which helps to constrain the relative ageof the other units. The main rock types encountered are shoshonite,phonotephrite, latite, trachyte and phonolite. The sequenceincludes, from the base upwards: a thick succession of pyroclasticunits emplaced between 126 and 39 ka, most of them attributedto eruptions that occurred in the Phlegraean area; the CampanianIgnimbrite; the products of a local tuff cone formed between39 ka and the deposition of the products of the earliest activityof the Mt. Somma volcano; the products of the Somma–Vesuviusvolcano, which include from the base upwards a thick sequenceof lavas, pyroclastic rocks and the products of a local spattercone dated between 3· 7 ka and AD 79. The data obtainedfrom the study of the borehole show that, before the CampanianIgnimbrite eruption, low-energy explosive volcanism took placein the Vesuvian area, whereas mostly high-energy explosive eruptionscharacterized the Campi Flegrei activity. In the Vesuvian area,Campanian Ignimbrite deposition was followed by the eruptionof a local tuff cone and a long repose time, which predatedthe formation of the Mt. Somma edifice. Since 18· 3 ka(Pomici di Base eruption) the activity of Somma–Vesuviusbecame mostly explosive with rare lava effusions. The shallowestcored deposits belong to the Camaldoli della Torre cone, formedbetween the Pomici di Avellino and Pomici di Pompei eruptions(3· 7 ka–AD 79). New geochemical and Sr–Nd–Pb–B-isotopicdata on samples from the drilled core, together with those availablefrom the literature, allow us to further distinguish the volcanicrocks as a function of both their provenance (i.e. Phlegraeanor Vesuvian areas) and age, and to identify different magmaticprocesses acting through time in the Vesuvian mantle source(s)and during magma ascent towards the surface. Isotopically distinctmagmas, rising from a mantle source variably contaminated byslab-derived components, stagnated at mid-crustal depths (8–10km below sea level) where magmas differentiated and were probablycontaminated. Contamination occurred either with Hercynian continentalcrust, mostly during the oldest stages of Vesuvian activity(from 39 to 16 ka), or with Mesozoic limestone, mostly duringrecent Vesuvian activity. Energy constrained assimilation andfractional crystallization (EC-AFC) modelling results show thatcontamination with Hercynian crust probably occurred duringdifferentiation from shoshonite to latite. Contamination withlimestone, which is not well constrained with the availabledata, might have occurred only during the transition from shoshoniteto tephrite. From the ‘deep’ reservoir, magmas rosetowards a series of shallow reservoirs, in which they differentiatedfurther, mixed, and fed volcanic activity. KEY WORDS: Somma–Vesuvius; crustal contamination; source heterogeneity; radiogenic and stable isotopes; magmatic system  相似文献   

Contractivity-preserving explicit multistep Hermite–Obrechkoff series differential equation solvers     

Truong Nguyen-Ba  Thierry Giordano  Rémi Vaillancourt 《Celestial Mechanics and Dynamical Astronomy》2016,124(4):385-404

New optimal, contractivity-preserving (CP), explicit, d-derivative, k-step Hermite–Obrechkoff series methods of order p up to \(p=20\), denoted by CP HO(d, k, p), with nonnegative coefficients are constructed. These methods are used to solve nonstiff first-order initial value problems \(y'=f(t,y)\), \(y(t_0)=y_0\). The upper bound \(p_u\) of order p of HO(d, k, p) can reach, approximately, as high as 2.4 times the number of derivatives d. The stability regions of HO(d, k, p) have generally a good shape and grow with decreasing \(p-d\). We, first, note that three selected CP HO methods: 4-derivative 7-step HO of order 13, denoted by HO(4, 7, 13), 5-derivative 6-step HO of order 13, denoted by HO(5, 6, 13), and 9-derivative 2-step HO of order 13, denoted by CMDAHO(13) compare favorably with Adams–Cowell of order 13, denoted by AC(13), in solving standard N-body problems over an interval of 1000 periods on the basis of the relative error of energy as a function of the CPU time. Next, the three HO methods compare positively with AC(13) in solving standard N-body problems on the basis of the growth of relative positional error and relative energy error over 10, 000 periods of integration. Finally, these three methods compare also well with P-stable methods of Cash and Franco et al. on some quasi periodic, second-order linear and nonlinear problems. The coefficients of selected HO methods are listed in the appendix.  相似文献   

Omeonga—A possible large impact structure on the Eastern Kasai Province (D.R. Congo)?     

Giovanni MONEGATO  Matteo MASSIRONI  Elena MARTELLATO  Giordano TEZA 《Meteoritics & planetary science》2011,46(12):1804-1813

Abstract– The Omeonga ring structure (D.R. Congo) shows a remarkable drainage pattern encircling an area up to 45 km wide and encompassing a central smoothed relief 20 km wide. This inner circular ridge is elevated about 70 m above the ring depression corresponding to the bed of the Unia River, which flows between the inner ridge and an outer irregular ridge. Landsat 7 ETM and ASTER DEM show that the structural characteristics resemble those of several wide impact structures known on Earth. Other geological modes of origin that could produce ring structures, such as magmatic activity, salt diapirism, and karst dissolution have been considered. However, after evaluating the regional stratigraphy, the distribution of volcanism, and morphometry, these processes seem to be rather unlikely. If of impact origin, the age of the Omeonga structure can be constrained to the Late Cretaceous‐Cenozoic according to the youngest units in which the ring structure was formed.  相似文献   

A Fe K-edge XAS study of amethyst     

Francesco Di Benedetto  Francesco D’Acapito  Gabriele Fornaciai  Massimo Innocenti  Giordano Montegrossi  Luca A. Pardi  Silvia Tesi  Maurizio Romanelli 《Physics and Chemistry of Minerals》2010,37(5):283-289

An X-ray absorption spectroscopy (XAS) study of the Fe local environment in natural amethyst (a variety of α-quartz, SiO₂) has been carried out. Room temperature measurements were performed at the Fe K-edge (7,112 eV), at both the X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) regions. Experimental results were then compared with DFT calculations. XANES experimental spectra suggest Fe to occur mainly in the trivalent state, although a fraction of Fe²⁺ is identified. EXAFS spectra, on the other hand, reveal an unusual short distance for the first coordination shell:  = 1.78(2) Å, the coordination number being 2.7(5). These results allow to establish that Fe replaces Si in its tetrahedral site, and that numerous local distortions are occurring as a consequence of the presence of Fe³⁺ variably compensated by protons and/or alkaline ions, or uncompensated. The formal valence of Fe, on the basis of both experimental and DFT structural features, can be either 4+ or 3+. Taking into account the XANES evidences, we suggest that Fe mainly occurs in the trivalent state, compensated by protons, and that a minor fraction of Fe⁴⁺ is stabilised by the favourable local structural arrangement.  相似文献   

Robe's restricted three-body problem with drag     

C. M. Giordano  A. R. Plastino  A. Plastino 《Celestial Mechanics and Dynamical Astronomy》1996,66(2):229-242

Robe's restricted three-body problem is investigated with regards to the effects of a linear drag force. In particular. the stability of the model's equilibrium points is studied in this respect. Two scenarios are envisaged: the one originally discussed by Robe himself and the one suggested by him and recently analyzed by the present authors, that assumes for the fluid body the structure of a Roche's ellipsoid.  相似文献   

Erratum to “Laser scanning-based recognition of rotational movements on a deep seated gravitational instability: The Cinque Torri case (North-Eastern Italian Alps)” [Geomorphology 122 (2010) 191-204]     

Alessia Viero  Giordano Teza  Matteo MassironiMichel Jaboyedoff  Antonio Galgaro 《Geomorphology》2012,138(1):420

  相似文献   

Shoshonite and sub-alkaline magmas from an ultrapotassic volcano: Sr–Nd–Pb isotope data on the Roccamonfina volcanic rocks,Roman Magmatic Province,Southern Italy     

Sandro Conticelli  Sara Marchionni  Davide Rosa  Guido Giordano  Elena Boari  Riccardo Avanzinelli 《Contributions to Mineralogy and Petrology》2009,157(1):41-63

The Roccamonfina volcano is characterised by two stages of volcanic activity that are separated by volcano-tectonic caldera collapses. Ultrapotassic leucite-bearing rocks are confined to the pre-caldera stage and display geochemical characteristics similar to those of other volcanoes in the Roman Province. After the major sector collapse of the volcano, occurred at ca. 400 ka, shoshonitic rocks erupted from cinder cones and domes both within the caldera and on the external flanks of the pre-caldera Roccamonfina volcano. On the basis of new trace element and Sr–Nd–Pb isotope data, we show that the Roccamonfina shoshonitic rocks are distinct from shoshonites of the Northern Roman Province, but are very similar to those of the Neapolitan volcanoes. The last phases of volcanic activity erupted sub-alkaline magmas as enclaves in trachytic domes, and as lavas within the Monte Santa Croce dome. Ultrapotassic rocks of the pre-caldera composite volcano are plagioclase-bearing leucitites characterised by high levels of incompatible trace elements with an orogenic signature having troughs at Ba, Ta, Nb, and Ti, and peaks at Cs, K, Th, U, and Pb. Initial values of ⁸⁷Sr/⁸⁶Sr range from 0.70926 to 0.70999, ¹⁴³Nd/¹⁴⁴Nd ranges from 0.51213 to 0.51217, while the lead isotope rations vary between 18.788–18.851 for ²⁰⁶Pb/²⁰⁴Pb, 15.685–15.701 for ²⁰⁷Pb/²⁰⁴Pb, and 39.048–39.076 for ²⁰⁸Pb/²⁰⁴Pb. Shoshonites show a similar pattern of trace element depletions and enrichments to the earlier ultrapotassic leucite-bearing rocks but have a larger degree of differentiation and lower concentrations of incompatible trace elements. On the other hand, shoshonitic rocks have Sr, Nd, and Pb isotopes consistently different than pre-caldera ultrapotassic leucite-bearing rocks. ⁸⁷Sr/⁸⁶Sr ranges from 0.70665 to 0.70745, ¹⁴³Nd/¹⁴⁴Nd ranges from 0.51234 to 0.51238, ²⁰⁶Pb/²⁰⁴Pb ranges from 18.924 to 19.153, ²⁰⁷Pb/²⁰⁴Pb ranges from 15.661 to 15.694, and ²⁰⁸Pb/²⁰⁴Pb ranges from 39.084 to 39.212. High-K calc-alkaline samples have intermediate isotopic values between ultrapotassic plagioclase leucitites and shoshonites, but the lowest levels of incompatible trace element contents. It is argued that ultrapotassic magmas were generated in a modified lithospheric mantle after crustal-derived metasomatism. Interaction between the metasomatic agent and lithospheric upper mantle produced a low-melting point metasomatised veined network. The partial melting of the veins alone produced pre-caldera leucite-bearing ultrapotassic magmas. It was possibly triggered by either post-collisional isotherms relaxation or increasing T°C due increasing heat flow through slab tears. Shoshonitic magmas were generated by further melting, at higher temperature, of the same metasomatic assemblage with addition 10–20% of OIB-like astenospheric mantle material. We suggest that addition of astenospheric upper mantle material from foreland mantle, flowing through slab tearing after collision was achieved. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Intermediate-mass black holes and ultraluminous X-ray sources in the Cartwheel ring galaxy     

M. Mapelli  B. Moore  L. Giordano  L. Mayer  M. Colpi  E. Ripamonti  S. Callegari 《Monthly notices of the Royal Astronomical Society》2008,383(1):230-246

Chandra and XMM–Newton observations of the Cartwheel galaxy show ∼17 bright X-ray sources  (≳5 × 10³⁸ erg s⁻¹)  , all within the gas-rich outer ring. We explore the hypothesis that these X-ray sources are powered by intermediate-mass black holes (IMBHs) accreting gas or undergoing mass transfer from a stellar companion. To this purpose, we run N -body/smoothed particle hydrodynamics simulations of the galaxy interaction which might have led to the formation of Cartwheel, tracking the dynamical evolution of two different IMBH populations: halo and disc IMBHs. Halo IMBHs cannot account for the observed X-ray sources, as only a few of them cross the outer ring. Instead, more than half of the disc IMBHs are pulled in the outer ring as a consequence of the galaxy collision. However, also in the case of disc IMBHs, accretion from surrounding gas clouds cannot account for the high luminosities of the observed sources. Finally, more than 500 disc IMBHs are required to produce ≲15 X-ray sources via mass transfer from very young stellar companions. Such number of IMBHs is very large and implies extreme assumptions. Thus, the hypothesis that all the observed X-ray sources in Cartwheel are associated with IMBHs is hardly consistent with our simulations, even if it is still possible that IMBHs account for the few (≲1–5) brightest ultraluminous X-ray sources.  相似文献