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121.
Acid mine drainage (AMD) is one of the severe environmental problems that coal mines are facing. Generation of AMD in the northeastern part of India due to the coal mining activities has long been reported. However detailed geochemical characterization of AMD and its impact on water quality of various creeks, river and groundwater in the area has never been reported. Coal and coal measure rocks in the study area show finely disseminated pyrite crystals. Secondary solid phases, resulted due to oxidation of pyrite, occur on the surface of coal, and are mainly consisting of hydrated sulphate complexes of Fe and Mg (copiapite group of minerals). The direct mine discharges are highly acidic (up to pH 2.3) to alkaline (up to pH 7.6) in nature with high concentration of SO42−. Acidic discharges are highly enriched with Fe, Al, Mn, Ni, Pb and Cd, while Cr, Cu, Zn and Co are below their maximum permissible limit in most mine discharges. Creeks that carrying the direct mine discharges are highly contaminated; whereas major rivers are not much impacted by AMD. Ground water close to the collieries and AMD affected creeks are highly contaminated by Mn, Fe and Pb. Through geochemical modeling, it is inferred that jarosite is stable at pH less than 2.5, schwertmannite at pH less than 4.5, ferrihydrite above 5.8 and goethite is stable over wide range of pH, from highly acidic to alkaline condition.  相似文献   
122.
This work details the role of fault reactivation in the development of tropical montane lakes by using basin morpho-structural analysis and seismostratigraphic studies. The upland lakes are severely faulted sinkholes, whose faults penetrate the Quaternary sedimentary units. Four main stages are related to the lake formation: (i) an Early Proterozoic tectonic deformation of the rocks along the southern border of the Carajás Structure, where the lake is placed; (ii) differential erosion by – and building of – the formation of the South Carajás Hill; (iii) Fe-rich crust formation by weathering and gravitational collapse faults following the E–W plateau border and the start of Violão Lake formation during the Pliocene–Pleistocene; and (iv) episodic fault-fracture reactivation by gravitational collapse causing pulses of subsidence in the lake and outlining its faulted borders. Dissolution of the lateritic crust and erosion by runoff drainage under wet climate conditions were coeval with fault activities, which allowed the deposition of relatively thick clastic deposits organized in three main seismostratigraphic units associated with major lake-level fluctuations. Initial fault reactivation under low-level water started lacustrine basin development with deposition of prograding fan deltas related to the main drainage. A second fault reactivation by gravitational collapse increased the lake accommodation space and resulted in the deposition of fine-grained sediments from dilute interflows or overflows until 36 000 cal year BP. At about 31 000 cal year BP, rapid decreases in the lake water level under redox conditions at the sediment/water interface allowed widespread siderite formation. A third gravitational collapse episode was responsible for the increase in the lake area and depth and the returning of clastic/organic deposition up to the present. This tropical montane lake can be seen as a representative example for understanding the formation of other upland lakes controlled by fault reactivation. © 2020 John Wiley & Sons, Ltd.  相似文献   
123.
Synthetic rock samples can offer advantages over natural rock samples when used for laboratory rock physical properties studies, provided their success as natural analogues is well understood. The ability of synthetic rocks to mimic the natural stress dependency of elastic wave, electrical and fluid transport properties is of primary interest. Hence, we compare a consistent set of laboratory multi-physics measurements obtained on four quartz sandstone samples (porosity range 20–25%) comprising two synthetic and two natural (Berea and Corvio) samples, the latter used extensively as standards in rock physics research. We measured simultaneously ultrasonic (P- and S-wave) velocity and attenuation, electrical resistivity, permeability and axial and radial strains over a wide range of differential pressure (confining stress 15–50 MPa; pore pressure 5–10 MPa) on the four brine saturated samples. Despite some obvious physical discrepancies caused by the synthetic manufacturing process, such as silica cementation and anisotropy, the results show only small differences in stress dependency between the synthetic and natural sandstones for all measured parameters. Stress dependency analysis of the dry samples using an isotropic effective medium model of spheroidal pores and penny-shaped cracks, together with a granular cohesion model, provide evidence of crack closure mechanisms in the natural sandstones, seen to a much lesser extent in the synthetic sandstones. The smaller grain size, greater cement content, and cementation under oedometric conditions particularly affect the fluid transport properties of the synthetic sandstones, resulting in lower permeability and higher electrical resistivity for a similar porosity. The effective stress coefficients, determined for each parameter, are in agreement with data reported in the literature. Our results for the particular synthetic materials that were tested suggest that synthetic sandstones can serve as good proxies for natural sandstones for studies of elastic and mechanical properties, but should be used with care for transport properties studies.  相似文献   
124.
The algorithms for deriving vegetation biophysical parameters rely on the understanding of bi-directional interaction of radiation and its subsequent linkages with canopy radiative transfer models and their inversion. In this study, an attempt has been made to define the geometry of sensor and source position to best relate plant biophysical parameters with bidirectional reflectance of wheat varieties varying in canopy architecture and to validate the performance of PROSAIL (PROSPECT+SAIL) canopy radiative transfer model. A field experiment was conducted with two wheat cultivars varying in canopy geometry and phenology. The bidirectional measurements between 400nm–1100nm at 5nm interval were recorded every week at six view azimuth and four view zenith positions using spectro-radiometer. Canopy biophysical parameters were recorded synchronous to bi-directional reflectance measurements. The broadband reflectances were used to compute the NDVIs which were subsequently related to leaf area index and biomass. Results showed that the bidirectional reflectance increased with increase in view zenith from 200 to 600 irrespective of the sensor azimuth. For a given view zenith, the reflectance was observed to be maximum at 1500 azimuth where the difference between the sun and sensor azimuth was least. For sun azimuth of 1600 and zenith of 520, the view geometry defined by 1500 azimuth and 500 zenith corresponded to hotspot position. The measured bidirectional NDVI had significant logarithmic relationship with LAI and linear relationship with biomass for both the varieties of wheat and maximum correlation of NDVI with LAI and with biomass was obtained at the hotspot position. The PROSAIL validation results showed that the model simulated well the overall shape of spectra for all combination of view zenith and azimuth position for both wheat varieties with overall RMSE less than 5 per cent. The hotspot and dark spot positions were also well simulated and hence model performance may be suitable for deriving wheat biophysical parameters using satellite derived reflectances.  相似文献   
125.

Any sustainable resource utilization plan requires evaluation of the present and future environmental impact. The present research focuses on future scenario generation of environmental vulnerability zones based on grey analytic hierarchy process (grey-AHP). Grey-AHP combines the advantages of grey clustering method and the classical analytic hierarchy process (AHP). Environmental vulnerability index (EVI) considers twenty-five natural, environmental and anthropogenic parameters, e.g. soil, geology, aspect, elevation, slope, rainfall, maximum and minimum temperature, normalized difference vegetation index, drainage density, groundwater recharge, groundwater level, groundwater potential, water yield, evapotranspiration, land use/land cover, soil moisture, sediment yield, water stress, water quality, storage capacity, land suitability, population density, road density and normalized difference built-up index. Nine futuristic parameters were used for EVI calculation from the Dynamic Conversion of Land-Use and its Effects, Model for Interdisciplinary Research on Climate 5 and Soil and Water Assessment Tool. The resulting maps were classified into three classes: “high”, “moderate” and “low”. The result shows that the upstream portion of the river basin comes under the high vulnerability zone for the years 2010 and 2030, 2050. The effectiveness of zonation approach was between “better” and “common” classes. Sensitivity analysis was performed for EVI. Field-based soil moisture point data were utilized for validation purpose. The resulting maps provide a guideline for planning of detailed hydrogeological studies.

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126.
D. Karmakar  T. Sahoo   《Ocean Engineering》2008,35(7):598-615
Using the recently developed expansion formulae for wave structure interaction problems, the scattering of surface water waves by a semi-infinite floating membrane due to abrupt change in bottom topography is analyzed. Both the cases of finite and infinite steps are analyzed. In the present paper, the analysis is based on the linearized theory of water waves and small amplitude membrane response. Combining the linearized kinematic and dynamic surface conditions on the water surface with the dynamic pressure condition on the membrane, a third order differential equation is derived to describe the membrane covered free surface condition. General wave energy relation for wave scattering by floating horizontal membrane is derived by the application of law of conservation of energy flux and alternately by the direct application of Green's second identity. In the floating membrane covered region, the wave energy density is a combination of the kinetic and potential energy density due to the surface gravity waves, and the surface energy density which is due to the existence of the floating membrane on the free surface. Gravity wave transformations due to an abrupt change in bottom topography in the presence of a floating membrane in finite water depth are analyzed based on shallow water approximation. Numerical results are computed and analyzed to understand the wave transformation due to the floating membrane when there is an abrupt change in topography in different cases.  相似文献   
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