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81.
Given the continuous decline in global runoff data availability over the past decades, alternative approaches for runoff determination are gaining importance. When aiming for global scale runoff at a sufficient temporal resolution and with homogeneous accuracy, the choice to use spaceborne sensors is only a logical step. In this respect, we take water storage changes from Gravity Recovery And Climate Explorer (grace) results and water level measurements from satellite altimetry, and present a comprehensive assessment of five different approaches for river runoff estimation: hydrological balance equation, hydro-meteorological balance equation, satellite altimetry with quantile function-based stage–discharge relationships, a rudimentary instantaneous runoff–precipitation relationship, and a runoff–storage relationship that takes time lag into account. As a common property, these approaches do not rely on hydrological modeling; they are either purely data driven or make additional use of atmospheric reanalyses. Further, these methods, except runoff–precipitation ratio, use geodetic observables as one of their inputs and, therefore, they are termed hydro-geodetic approaches. The runoff prediction skill of these approaches is validated against in situ runoff and compared to hydrological model predictions. Our results show that catchment-specific methods (altimetry and runoff–storage relationship) clearly outperform the global methods (hydrological and hydro-meteorological approaches) in the six study regions we considered. The global methods have the potential to provide runoff over all landmasses, which implies gauged and ungauged basins alike, but are still limited due to inconsistencies in the global hydrological and hydro-meteorological datasets that they use.  相似文献   
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There is ongoing debate about the relative influence of aquatic production, flux, and sedimentation of aquatic and terrestrial organic matter on mercury accumulation in lake sediments. In this study, lake sediments spanning the past 4,250 years, were collected from remote, organic-rich Lake Hambre, Patagonia (53° S) and investigated for changes in the accumulation of pre-anthropogenic mercury and organic matter of aquatic and terrestrial origin. Natural mercury accumulation varied by up to a factor of four, comparable to the recent anthropogenic forcing of the mercury cycle (factor 3–5). Hydrogen and Oxygen indices (HI and OI, Rock–Eval©) and nitrogen/carbon ratios of the organic matter, combined with multi-element sediment data, reveal intense changes in aquatic productivity as well as influx of terrestrial organic matter into the lake. Evaluation of the multi-element dataset using Principal Component Analysis shows clear covariation of mercury with other soil-derived elements such as copper and yttrium. This covariance reflects a common transport mechanism, i.e. leaching of trace-element-bearing organic matter complexes from catchment soils. Correlation between changes in aquatic productivity and mercury concentrations occurs in some sections of the record, but we do not suggest they are linked by a direct causal relationship. Mass balance approaches suggest that mercury scavenging and accumulation in this organic-rich lake is controlled by the supply of mercury from catchment soils rather than the amount of organic material produced within the water column. A common controlling mechanism, i.e. changing climate, however, is thought to independently drive variations in both the flux of terrestrial organic matter mercury complexes and aquatic productivity.  相似文献   
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This paper develops an estimator for higher-order spatial autoregressive panel data error component models with spatial autoregressive disturbances, SARAR(R,S). We derive the moment conditions and optimal weighting matrix without distributional assumptions for a generalized moments (GM) estimation procedure of the spatial autoregressive parameters of the disturbance process and define a generalized two-stage least squares estimator for the regression parameters of the model. We prove consistency of the proposed estimators, derive their joint asymptotic distribution, and provide Monte Carlo evidence on their small sample performance.  相似文献   
87.
In this study, the electrical conductivity of synthetic and natural orthopyroxene single crystals containing various amounts of hydrogen and cation impurities (i.e., Al, Fe) was investigated using impedance spectroscopy. A new cell was developed to measure conductivities of submillimeter-sized oriented single crystals with impedances up to 1010?Ohm. In contrast to previous studies on olivine and orthopyroxene, results from this study do not show a simple correlation of the concentration of protons and the electrical conductivity. Instead, the electrical conductivity appears to be a complex function of iron content, hydrogen content, crystal orientation and concentration of other impurity cations and shows similar activation energies to hydrogen diffusion. Model calculations considering proton conduction rather exclude than suggest orthopyroxene as responsible phase for high-conductivity regions in the Earth’s upper mantle.  相似文献   
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Universal time from VLBI single-baseline observations during CONT08   总被引:2,自引:2,他引:0  
The IVS Intensive sessions are single-baseline, 1-h VLBI sessions carried out everyday in order to determine Universal Time (UT1). We investigate different possibilities to improve the results of such sessions. We do this investigation by extracting 2-h single-baseline sessions from the CONT08 data set. These are analysed like normal Intensives, and the results are compared to the results of the analysis of the full CONT08 data set. We find that tropospheric asymmetry is the major error source for the single-baseline sessions. It is possible to improve the accuracy of the estimated UT1 either by using accurate a priori tropospheric gradients or by estimating gradients in the data analysis.  相似文献   
89.
Exceptionally well-preserved pillowed and massive phenocryst-free metabasaltic lava flows in the uppermost part of the Palaeoarchaean Hooggenoeg Complex of the Barberton Greenstone Belt exhibit both flow banding and large leucocratic varioles. The flow banding is defined by blebs and bands of pale and dark green metabasalt and was the result of mingling of two types of basalt (Robins et al. in Bull Volcanol 72:579–592, 2010a). Varioles occur exclusively in the dark chlorite-, MgO- and FeO-rich metabasalt. Varioles are absent in the outermost rinds of pillows and increase in both abundance and size towards the centres of pillows. In the central parts of some pillows, they impinge to form homogeneous pale patches, bands or almost homogenous cores. Individual varioles consist essentially of radially orientated or outwardly branching dendritic crystals of albite. Many varioles exhibit concentric zones and finer-grained rims. Some varioles seem to have grown around tiny vesicles and vesicles appear to have been trapped in others between a core and a finer-grained rim. The matrix surrounding the ocelli contains acicular pseudomorphs of actinolite and chlorite after chain-like, skeletal Ca-rich pyroxenes that are partly overgrown by the margins of varioles. Varioles are enriched in the chemical constituents of feldspar but contain concentrations of immobile TiO2, Cr, Zr and REE that are similar to the host metabasalts. The shape, distribution, texture and composition of the varioles exclude liquid immiscibility and support an origin by spherulitic crystallisation of plagioclase from severely undercooled basalt melt and glass. Nucleation of plagioclase was strongly inhibited and took place on vesicles, on the bases of drainage cavities and along early fractures. Eruption in deep water and retention of relatively high concentrations of volatiles in the melt may be the principal cause of spherulitic crystallisation in the interiors of pillows rather than only in their margins as in younger submarine flows.  相似文献   
90.
Novel information and communication technologies have created new possibilities for transferring information and knowledge over distance. Although this might open up broad options for economic interaction, knowledge regarding the effects of these changes on the geographies of production and innovation is still incomplete. Under these circumstances, permanent co-location and face-to-face (F2F) interaction may be efficient in some contexts but not in others. Support by computer-mediated communication (CMC), temporary, and virtual interaction is increasingly becoming the basis for establishing trans-local production networks. By combining results from social psychology with economic geography, it is argued that there is no generally superior spatial fix for economic interaction. Different spatial configurations can be advantageous in different production and innovation contexts, even over large distances without permanent or even regular F2F contact. This paper systematically investigates the effects of new communication technologies and different organisational forms for economic interaction by emphasizing the potential of combining CMC with forms of temporary and permanent F2F interaction.  相似文献   
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