Parallel Implementation of Dispersive Tsunami Wave Modeling with a Nesting Algorithm for the 2011 Tohoku Tsunami     

Toshitaka Baba  Narumi Takahashi  Yoshiyuki Kaneda  Kazuto Ando  Daisuke Matsuoka  Toshihiro Kato 《Pure and Applied Geophysics》2015,172(12):3455-3472

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Influence of Redox Mediators and Electron Donors on the Anaerobic Removal of Color and Chemical Oxygen Demand from Textile Effluent     

Sandra M. Amorim  Mario T. Kato  Lourdinha Florencio  Sávia Gavazza 《洁净——土壤、空气、水》2013,41(9):928-933

Color removal was evaluated in anaerobic assays using synthetic (SE) and real (RE) effluents containing the dye Direct Black 22 (DB22). The focus was on the individual influence of two electron donors (EDs), sucrose and ethanol; and their combination with two redox mediators (RMs), lawsone and riboflavin. In addition to SE assays, the EDs were combined with sulfate which was present in the RE. Distinct behavior was observed with both assays. In the case of SE, using the EDs sucrose and ethanol resulted in DB22 removal efficiency of 93 and 83%, respectively; but only 27% in the control. The respective removal rates were 27.8‐ and 4.4‐fold higher than that of the control. Using the EDs with the RM lawsone resulted in color removal higher than that with riboflavin. Interestingly, in the ethanol + sulfate assay, late release of the last was observed, possibly due to the desulfonation reaction of the aromatic structures during the DB22 molecule breakdown. In the case of RE, no improvement was observed with either EDs; and some combinations with the RMs even resulted in decreased color removal. Therefore, the used EDs and RMs showed positive effect on color removal in SEs; but unexpectedly not in REs.  相似文献   

The early Miocene (~25 Ma) volcanism in the northern Kyushu-Palau Ridge,enriched mantle source injection during rifting prior to the Shikoku backarc basin opening   总被引：2，自引：1，他引：1  

Satoru Haraguchi  Teruaki Ishii  Jun-Ichi Kimura  Yasuhiro Kato 《Contributions to Mineralogy and Petrology》2012,163(3):483-504

The northern Kyushu-Palau Ridge (KPR), remnant conjugate arc of the Izu-Ogasawara (Bonin)-Mariana (IBM) active arc, is dominated by basalt-andesite except for the Komahashi-Daini Seamount where acidic plutonic rocks of 38 Ma were recovered. These mafic to intermediate volcanics are produced by the rifting volcanism in the proto-IBM arc associated with spreading of the Shikoku Basin. The HFSE and HREE contents and ratios of these volcanics indicate enriched source mantle composition compared to recent volcanic front. The LILE ratios exhibit similar characteristics to reararc volcanism of the recent Izu arc, and some enriched volcanics exhibit high abundance of sediment melt inputs. Based on these observations and compilations of the published data set, the replacement event of the wedge mantle under the IBM arc occurred two times. The first event occurred between 45 and 38 Ma, with Pacific type mantle being replaced by depleted Indian type mantle. The second event occurred between 36 and 25 Ma, enriched mantle flowed from reararc side. The slab component during the proto-IBM arc rifting was a similar characteristic to recent reararc volcanism of the Izu arc, and sediment melt added in a local area.  相似文献   

Organic micropollutants in marine plastics debris from the open ocean and remote and urban beaches   总被引：2，自引：0，他引：2  

Hirai H  Takada H  Ogata Y  Yamashita R  Mizukawa K  Saha M  Kwan C  Moore C  Gray H  Laursen D  Zettler ER  Farrington JW  Reddy CM  Peacock EE  Ward MW 《Marine pollution bulletin》2011,62(8):1683-1692

To understand the spatial variation in concentrations and compositions of organic micropollutants in marine plastic debris and their sources, we analyzed plastic fragments (∼10 mm) from the open ocean and from remote and urban beaches. Polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), dichloro-diphenyl-trichloroethane and its metabolites (DDTs), polybrominated diphenyl ethers (PBDEs), alkylphenols and bisphenol A were detected in the fragments at concentrations from 1 to 10,000 ng/g. Concentrations showed large piece-to-piece variability. Hydrophobic organic compounds such as PCBs and PAHs were sorbed from seawater to the plastic fragments. PCBs are most probably derived from legacy pollution. PAHs showed a petrogenic signature, suggesting the sorption of PAHs from oil slicks. Nonylphenol, bisphenol A, and PBDEs came mainly from additives and were detected at high concentrations in some fragments both from remote and urban beaches and the open ocean.  相似文献   

Application of an S‐shaped curve model to the temporal development of tafoni of salt‐weathering origin     

Tsuguo Sunamura  Hisashi Aoki 《地球表面变化过程与地形》2011,36(12):1624-1631

To describe temporal change in tafone development, an S‐shaped curve equation is proposed: Z = Z_c [1 ? (n + 1) exp (? β t ) + n exp (? (1 + 1/n) β t )] , where Z is observed tafone depth, Z_c is ultimate tafone depth, t is time, and n and β are constants. The applicability of this model is examined using tafone data selected from seven sites, which are categorized into three different salt‐weathering environments: a spray/splash‐dominant (occasionally wave‐affected) supra‐tidal zone, aerosol‐affected coastal regions, and inland desert areas. The results indicate that the equation can well describe tafone development in each of these environments. An investigation based on the values of n and β, determined through a best fit of the equation to the data, suggests that n characterizes site‐specific environmental conditions and β reflects the magnitude of factors controlling the recession mechanism of tafone surfaces. It is found that (1) the maximum rate of tafone growth dramatically decreases from supra‐tidal, through coastal, to desert environments, and (2) the growing mode of tafoni is different depending on the environmental settings. The erosional force to facilitate the development of tafoni at supra‐tidal sites is estimated to be about 400 times greater than that in the general coastal area. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Empirical ocean-color algorithms to retrieve chlorophyll-a, total suspended matter, and colored dissolved organic matter absorption coefficient in the Yellow and East China Seas   总被引：4，自引：1，他引：3  

Eko Siswanto  Junwu Tang  Hisashi Yamaguchi  Yu-Hwan Ahn  Joji Ishizaka  Sinjae Yoo  Sang-Woo Kim  Yoko Kiyomoto  Keiko Yamada  Connie Chiang  Hiroshi Kawamura 《Journal of Oceanography》2011,67(5):627-650

A bio-optical dataset collected during the 1998?C2007 period in the Yellow and East China Seas (YECS) was used to provide alternative empirical ocean-color algorithms in the retrieval of chlorophyll-a (Chl-a), total suspended matter (TSM), and colored dissolved organic matter (CDOM) absorption coefficients at 440 nm (ag₄₄₀). Assuming that remote-sensing reflectance (Rrs) could be retrieved accurately, empirical algorithms for T_Chl (regionally tuned Tassan??s Chl-a algorithm) in case-1 waters (T_Chl2i in case-2 waters), T_TSM (regionally tuned Tassan??s TSM algorithm), and T_ag440 or C_ag440 (regionally tuned Tassan??s or Carder??s ag₄₄₀ algorithm) were able to retrieve Chl-a, TSM, and ag₄₄₀ with uncertainties as high as 35, 46, and 35%, respectively. Applying the standard SeaWiFS Rrs, T_Chl was not viable in the eastern part of the YECS, which was associated with an inaccurate SeaWiFS Rrs retrieval because of improper atmospheric correction. T_Chl behaved better than other algorithms in the turbid case-2 waters, although overestimation was still observed. To retrieve more reliable Chl-a estimates with standard SeaWiFS Rrs in turbid water (a proxy for case-2 waters), we modified T_Chl for data with SeaWiFS normalized water-leaving radiance at 555 nm (nLw₅₅₅) > 2 mW cm^?2 ??m^?1 sr^?1 (T_Chl2s). Finally, with standard SeaWiFS Rrs, we recommend switching algorithms from T_Chl2s (for case-2 waters) to MOC_Chl (SeaWiFS-modified NASA OC4v4 standard algorithm for case-1 waters) for retrieving Chl-a, which resulted in uncertainties as high as 49%. To retrieve TSM and ag₄₄₀ using SeaWiFS Rrs, we recommend empirical algorithms for T_TSM (pre-SeaWiFS-modified form) and MT_ag440 or MC_ag440 (SeaWiFS Rrs-modified forms of T_ag440 or C_ag440). These could retrieve with uncertainties as high as 82 and 52%, respectively.  相似文献   

Cathodoluminescence of high-pressure feldspar minerals as a shock barometer     

Masahiro Kayama  Toshimori Sekine  Naotaka Tomioka  Hirotsugu Nishido  Yukako Kato  Kiyotaka Ninagawa  Takamichi Kobayashi  Akira Yamaguchi 《Meteoritics & planetary science》2018,53(7):1476-1488

Cathodoluminescence (CL) analyses were carried out on maskelynite and lingunite in L6 chondrites of Tenham and Yamato-790729. Under CL microscopy, bright blue emission was observed in Na-lingunite in the shock veins. Dull blue-emitting maskelynite is adjacent to the shock veins, and aqua blue luminescent plagioclase lies farther away. CL spectroscopy of the Na-lingunite showed emission bands centered at ~330, 360–380, and ~590 nm. CL spectra of maskelynite consisted of emission bands at ~330 and ~380 nm. Only an emission band at 420 nm was recognized in crystalline plagioclase. Deconvolution of CL spectra from maskelynite successfully separated the UV–blue emission bands into Gaussian components at 3.88, 3.26, and 2.95 eV. For comparison, we prepared K-lingunite and experimentally shock-recovered feldspars at the known shock pressures of 11.1–41.2 GPa to measure CL spectra. Synthetic K-lingunite has similar UV–blue and characteristic yellow bands at ~550, ~660, ~720, ~750, and ~770 nm. The UV–blue emissions of shock-recovered feldspars and the diaplectic feldspar glasses show a good correlation between intensity and shock pressure after deconvolution. They may be assigned to pressure-induced defects in Si and Al octahedra and tetrahedra. The components at 3.88 and 3.26 eV were detectable in the lingunite, both of which may be caused by the defects in Si and Al octahedra, the same as maskelynite. CL of maskelynite and lingunite may be applicable to estimate shock pressure for feldspar-bearing meteorites, impactites, and samples returned by spacecraft mission, although we need to develop more as a reliable shock barometer.  相似文献   

Implications for behavior of volatile elements during impacts—Zinc and copper systematics in sediments from the Ries impact structure and central European tektites          下载免费PDF全文

Zuzana Rodovská  Tomáš Magna  Karel Žák  Chizu Kato  Paul S. Savage  Frédéric Moynier  Roman Skála  Josef Ježek 《Meteoritics & planetary science》2017,52(10):2178-2192

Moldavites are tektites genetically related to the Ries impact structure, located in Central Europe, but the source materials and the processes related to the chemical fractionation of moldavites are not fully constrained. To further understand moldavite genesis, the Cu and Zn abundances and isotope compositions were measured in a suite of tektites from four different substrewn fields (South Bohemia, Moravia, Cheb Basin, Lusatia) and chemically diverse sediments from the surroundings of the Ries impact structure. Moldavites are slightly depleted in Zn (~10–20%) and distinctly depleted in Cu (>90%) relative to supposed sedimentary precursors. Moreover, the moldavites show a wide range in δ⁶⁶Zn values between 1.7 and 3.7‰ (relative to JMC 3‐0749 Lyon) and δ⁶⁵Cu values between 1.6 and 12.5‰ (relative to NIST SRM 976) and are thus enriched in heavy isotopes relative to their possible parent sedimentary sources (δ⁶⁶Zn = ?0.07 to +0.64‰; δ⁶⁵Cu = ?0.4 to +0.7‰). In particular, the Cheb Basin moldavites show some of the highest δ⁶⁵Cu values (up to 12.5‰) ever observed in natural samples. The relative magnitude of isotope fractionation for Cu and Zn seen here is opposite to oxygen‐poor environments such as the Moon where Zn is significantly more isotopically fractionated than Cu. One possibility is that monovalent Cu diffuses faster than divalent Zn in the reduced melt and diffusion will not affect the extent of Zn isotope fractionation. These observations imply that the capability of forming a redox environment may aid in volatilizing some elements, accompanied by isotope fractionation, during the impact process. The greater extent of elemental depletion, coupled with isotope fractionation of more refractory Cu relative to Zn, may also hinge on the presence of carbonyl species of transition metals and electromagnetic charge, which could exist in the impact‐induced high‐velocity jet of vapor and melts.  相似文献   

Bulk density effects on soil hydrologic and thermal characteristics: A numerical investigation          下载免费PDF全文

Yuki Kojima  Joshua L. Heitman  Masaru Sakai  Chihiro Kato  Robert Horton 《水文研究》2018,32(14):2203-2216

Soil bulk density (ρ_b) is commonly treated as static in studies of land surface dynamics. Magnitudes of errors associated with this assumption are largely unknown. Our objectives were to (a) quantify ρ_b effects on soil hydrologic and thermal properties and (b) evaluate effects of ρ_b on surface energy balance and heat and water transfer. We evaluated 6 soil properties, volumetric heat capacity, thermal conductivity, soil thermal diffusivity, water retention characteristics, hydraulic conductivity, and vapour diffusivity, over a range of ρ_b, using a combination of 6 models. Thermal conductivity, water retention, hydraulic conductivity, and vapour diffusivity were most sensitive to ρ_b, each changing by fractions greater than the associated fractional changes in ρ_b. A 10% change in ρ_b led to 10–11% change in thermal conductivity, 6–11% change in saturated and residual water content, 49–54% change in saturated hydraulic conductivity, and 80% change in vapour diffusivity. Subsequently, 3 field seasons were simulated with a numerical model (HYDRUS‐1D) for a range of ρ_b values. When ρ_b increased 25% (from 1.2 to 1.5 Mg m^?3), soil temperature variation decreased by 2.1 °C in shallow layers and increased by 1 °C in subsurface layers. Surface water content differed by 0.02 m³ m^?3 for various ρ_b values during drying events but differences mostly disappeared in the subsurface. Matric potential varied by >100 m of water. Surface energy balance showed clear trends with ρ_b. Latent heat flux decreased 6%, sensible heat flux increased 9%, and magnitude of ground heat flux varied by 18% (with a 25% ρ_b increase). Transient ρ_b impacted surface conditions and fluxes, and clearly, it warrants consideration in field and modelling investigations.  相似文献   

Layout design of rockbolts for natural ground reinforcement     

Junji Kato  Keiichiro Ishii  Kenjiro Terada  Takashi Kyoya 《国际地质力学数值与分析法杂志》2014,38(3):236-255

The present study addresses a layout design of rockbolts for reinforcing natural ground structures applying a special optimization method, called multiphase layout optimization. Rockbolts are used to tighten loosed natural ground, and the layout of rockbolts are determined without sufficient information about the physical properties of the ground materials. Because of this uncertainty, unexpected deformation often occurs at the excavation surface of natural ground. In that case, it is requested to determine an effective layout of the additional rockbolts promptly with respect to the actual deformation at the construction site. However, it is not easy to determine the optimal layout because of its complexity, and consequently, it has no choice but to determine the layout in an empirical way. This study introduces a numerical approach to determine an optimal layout of rockbolts with respect to arbitrarily possible deformation of natural ground. The objective is to maximize the stiffness of the overall ground structure reinforced with rockbolts. For optimization, a gradient‐based optimization scheme is applied because of its numerical efficiency. It was verified from a series of numerical examples that this method has great potential to improve the stiffness of the overall ground structure and shows a certain applicability to a practical design. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献