Structure and dynamics of water on muscovite mica surfaces     

Hiroshi Sakuma  Katsuyuki Kawamura 《Geochimica et cosmochimica acta》2009,73(14):4100-16115

The structure and dynamics of water on muscovite mica (0 0 1) surfaces have been investigated by molecular dynamics simulations. X-ray reflectivity profiles highly reflecting the interfacial structure are directly calculated and compared with those of experiments. The direct comparison has validated the usefulness of MD simulations to understand the real interfacial structure of the mica−water system. We observed five distinguished peaks in the density profile of oxygen present in water, and these peaks are attributable to the water molecules directly adsorbed on mica, hydrated to the K⁺ ions on the mica surface, and ordered due to hydrogen bonds between hydrated K⁺ ions. The hydrated K⁺ ions make an inner-sphere complex and have an explicit first hydration shell with a radius of 3.6 Å and a hydration number of 2.9. The change of the viscosity of water located above 1 nm apart from the mica surface was not observed. This feature is in good agreement with a recent experimental study in which the shear measurement was conducted using a surface forces apparatus. The increase of the viscosity by a factor of ca. 2-3 relative to that of the bulk water was observed at water located within 1 nm from the isolated mica surface.  相似文献   

Hydrogen isotopic ratios of plant wax n-alkanes in a peat bog deposited in northeast China during the last 16 kyr     

Osamu Seki  Philip A. Meyers  Kimitaka Kawamura  Yanhong Zheng  Weijian Zhou 《Organic Geochemistry》2009,40(6):671-677

Based on paleoclimatic reconstructions using various proxies, the Holocene Climate Optimum (10.5–6 ka) has been characterized as a warmer and wetter period in most of East Asia. The summer monsoons associated with the East Asian Monsoon evidently intensified and extended further inland from the Pacific Ocean, a source region of moisture. A notable exception to this general pattern exists in northeast China, where less wet conditions are recorded. We determined molecular compositions of individual plant wax hydrocarbons and their hydrogen isotope compositions (δD values) in a radiocarbon-dated peat core recovered from the Hani marsh in Jilin Province (China) and confirmed that the temperature-dependent effective precipitation in northeast China decreased during the Holocene Climate Optimum. A combination of P_aq, an indicator of the relative contribution of aquatic to terrestrial plants, and the difference in δD between low (C₂₃, C₂₅ and C₂₇) and high molecular weight (C₃₁) n-alkanes in the Hani peat bog indicates a dramatic change in vegetation from the deglaciation to the Holocene. No significant differences were observed between the δD values of low and high molecular weight n-alkanes with relatively high δD values and low P_aq during the early Holocene, indicating that all n-alkanes were produced by evapotranspiration-sensitive terrestrial plants during that time. However, lower δD values of mid-chain n-alkanes (C₂₃, C₂₅ and C₂₇) relative to the long chain n-alkane (C₃₁), together with higher P_aq values during the deglaciation (14–11 ka), suggest an increase in the contribution of aquatic plants and a higher water level during the period. The study demonstrates that northeast China was under a markedly wetter climate condition during the late deglaciation. For the 16 kyr record in the Hani peat sequence, we infer that moisture delivery by the East Asian Monsoon was relatively invariable in northeast China, but increased evaporation during the warmer Holocene Climate Optimum reduced the effective precipitation, defined by the balance between precipitation and evaporation.  相似文献   

The behavior and the role of the anti-cyclonic eddy in the Kuroshio large meander development     

Futoki Sakaida  Daisuke Egusa  Hiroshi Kawamura 《Journal of Oceanography》1998,54(1):101-114

The processes underlying the development of the Kuroshio large meanders that occurred in 1986 and 1989 are investigated using a satellite SST data set and hydrographic data. In both processes visible on the satellite SST images, a round-shaped, lower SST region with a diameter of about 200 km is found to the east of the Kuroshio small “trigger” meander (Solomon, 1978) until the region became extinguished near theEnshu Nada. The lower SST region can be interpreted as an anti cyclonic eddy, mainly because of the existence of a warm water mass in the subsurface layer of this region. The warm water mass is characterized by a constant temperature of 18–19°C, the maximum thickness of which is about 400 m. The satellite images show that the eddy is closely related to the Kuroshio path transforming into a shape like the letter “S”. This means that the eddy plays an important role in the development of the Kuroshio large meander since this, too, tends to follow an “S”-shaped path. Added to this, the subsurface layer structure of the eddy is similar to that of the warm water mass offShikoku. This similarity, together with the eddy behavior visible on the satellite SST images, implies that the examined eddy corresponds to the warm water mass offShikoku. In other words, the warm water mass offShikoku can be advected near to theEnshu Nada when the Kuroshio large meander occurs.  相似文献   

OCTS mission overview     

Hiroshi Kawamura 《Journal of Oceanography》1998,54(5):383-399

The Ocean Color and Temperature Scanner (OCTS) on board the Advanced Earth Observing Satellite (ADEOS) observed the chlorophyll-a concentration in the surface layer and sea surface temperature in global oceans from October 1996 to June 1997. The OCTS team was formed in the National Space Development Agency of Japan (NASDA) Earth Observation Research Center (EORC) to develop algorithm, calibrate and validate OCTS products and promote OCTS data usage. Intensive efforts to improve the quality of the OCTS products were made after the launch of ADEOS. Much sea-truth data was collected, and the algorithms to retrieve the ocean parameters have been revised several times. The OCTS data were distributed to the user community through the Internet while OCTS was functioning. An overview of the OCTS mission is presented in this paper. The OCTS Team is formed by NASDA personnel and supporting scientists listed in Appendix 1.  相似文献   

Molecular dynamics simulation of the effect of the Al-O-Al linkage on the P&1macr;-I&1macr; phase transition of anorthite     

A. Miyake  K. Kawamura  M. Kitamura 《Physics and Chemistry of Minerals》1999,26(8):624-632

Molecular dynamics (MD) simulations of the influence of the Al-O-Al linkage on the P&1macr;-I&1macr; phase transition of pure anorthite (An) were carried out using two different types of structures with fully ordered (FO) and partially disordered (PD) arrangements of Al/Si in tetrahedral sites. Discontinuous changes in unit cell volumes and structure factors at the transition temperature were observed in FO-An but not in PD-An. These results show that the orders of the transitions of FO-An and PD-An are first and non-first, respectively. In both structures, the motions of the Ca atoms and the framework are strongly correlated with each other during the transition and Ca atoms dominate the system. Since high-temperature X-ray studies have shown that the transition of natural anorthite is non-first order, it is suggested that the natural anorthite has a partially disordered arrangement of Al and Si atoms. Received: 22 October 1998 / Revised, accepted: 12 March 1999  相似文献   

Thermal structure of hot events and their possible role in maintaining the warm isothermal layer in the Western Pacific warm pool     

Wirasatriya  Anindya  Kawamura  Hiroshi  Helmi  Muhammad  Sugianto  Denny Nugroho  Shimada  Teruhisa  Hosoda  Kohtaro  Handoyo  Gentur  Putra  Yoppik Disma Girindra  Koch  Magaly 《Ocean Dynamics》2020,70(6):771-786

Ocean Dynamics - The short-lived events of high SST are called hot events (HEs) and can only be generated under the conditions of large daily heat gain due to strong solar radiation and weak wind....  相似文献   

TIDAL FEATURES IN THE CHINA SEAS AND THEIR ADJACENT SEA AREAS AS DERIVED FROM TOPEX／POSEIDON ALTIMETER DATA   总被引：2，自引：0，他引：2  

胡建宇  HiroshiKAWAMURA  洪华生  FumiakiKOBASHI  谢强 《中国海洋湖沼学报》2001,19(4):293-305

Some important tidal features of 8 major tidal constituents (M2, S2, K1, O1, P1,Sa, N2 and K2 ) in the china Seas and their adjacent sea areas were obtained using six years‘ TOPEX/POSEIDON altimeter data. The results showed that the obtained co-tidal and co-range charts for these major tidal constituents agreed well with those of previous researches using observational data from coastal tidal gauge stations and numerical models.  相似文献   

GMS proton flux observation during February 1978     

Tsugunobu Nagai  Masaynki Kuwashima  Makoto Kawamura  Tsuyoshi Kohno 《Planetary and Space Science》1979,27(7):1035-1037

It is suggested that the drop out of the 1.2–4 MeV proton flux, observed by the geostationary satellite GMS, was due to the Earthward shift of the particle boundary in all local time. The particle boundary motions are associated with substorm activities.  相似文献   

Multi‐species diffusion analysis in porous media under various dry density and temperature conditions: molecular dynamics simulation,homogenization analysis,and finite element method     

Jung Hae Choi  Katsuyuki Kawamura  Kazushi Kimoto  Yasuaki Ichikawa  Byung‐Gon Chae 《国际地质力学数值与分析法杂志》2014,38(16):1744-1760

In porous media, chemical species that dissolve in pore water can be transported via diffusion mechanisms or advective fluxes, close to or far away from where precipitation occurs. In the case of a high‐level radioactive waste disposal system, compacted bentonite is used in a buffer material in an engineering barrier system to minimize the amount of specific nuclides that breach into the surrounding host rock. To minimize breaching, it is very important to understand the transport mechanism of multiple chemical species in porous media. In the following research, we introduced FEM analysis methods using the results of the molecular dynamics simulation and homogenization analysis (MD/HA) method. First, the diffusion coefficients of ions (Cl^?, I^?, and Na⁺) in different water layers of Na‐beidellite were calculated using the MD/HA procedure under various dry density (1.2, 1.6, and 2.0 Mg/m³) and temperature (293, 323, and 363 K) conditions. Next, using FEM analysis that used the MD/HA results as input parameters, the diffusion behaviors of ions in porous media were calculated. The results indicate that the diffusion coefficients of the interlayer water in Na‐beidellite are different from the diffusion coefficients under dry density conditions. Further, the concentration profiles (C_t/C₀) of iodine and chloride are proportional to temperature but inversely proportional to dry density. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Modification of SAR spectra associated with surface wind fields in the sea off the Kii Peninsula: A case study     

Jian Sun  Hiroshi Kawamura 《Journal of Oceanography》2009,65(1):45-52

Using surface wave parameters and a high-resolution surface wind field derived from Synthetic Aperture Radar (SAR) image mode data, we have investigated the spatial modification of SAR spectra. We found a surface wind front, formed by sheltering effect of the Kii Mountains, separating high and low wind-speed regions in a sea area of an European Remote-Sensing Satellite (ERS) SAR image off the Kii Peninsula. A swell system propagating westward dominates in the whole sea area covered by the SAR image. The wavelength retrieved from the SAR spectra in the sheltered (non-sheltered) region is longer (shorter). Since the distributions of surface wave parameters and surface wind speed are so well correlated, it can be considered that the SAR spectra are modified differently by the sheltered/non-sheltered surface winds. In order to examine the phenomena observed on the SAR image we have estimated the wind-wave SAR spectrum using the SAR surface winds, a wind-wave spectrum model and a SAR wave imaging model. We assume that the SAR spectrum related to the swell is homogeneous in the area imaged by SAR, and that the SAR spectrum of the wind-wave components causes the observed SAR spectra modification. Differences between the observed SAR spectra and the estimated SAR spectra in the sheltered and non-sheltered regions agree well with each other. In the present case, it can be concluded that the observed SAR spectra can be regarded as a linear combination of the wind-wave SAR spectra and the swell SAR spectra.  相似文献