Quantitative C NMR of whole and fractionated Iowa Mollisols for assessment of organic matter composition     

Xiaowen Fang  Klaus Schmidt-Rohr 《Geochimica et cosmochimica acta》2010,74(2):584-4827

Both the concentrations and the stocks of soil organic carbon vary across the landscape. Do the amounts of recalcitrant components of soil organic matter (SOM) vary with landscape position? To address this question, we studied four Mollisols in central Iowa, two developed in till and two developed in loess. Two of the soils were well drained and two were poorly drained. We collected surface-horizon samples and studied organic matter in the particulate organic matter (POM) fraction, the clay fractions, and the whole, unfractionated samples. We treated the soil samples with 5 M HF at ambient temperature or at 60 °C for 30 min to concentrate the SOM. To assess the composition of the SOM, we used solid-state nuclear magnetic resonance (NMR) spectroscopy, in particular, quantitative ¹³C DP/MAS (direct-polarization/magic-angle spinning), with and without recoupled dipolar dephasing. Spin counting by correlation of the integral NMR intensity with the C concentration by elemental analysis showed that NMR was ?85% quantitative for the majority of the samples studied. For untreated whole-soil samples with <2.5 wt.% C, which is considerably less than in most previous quantitative NMR analyses of SOM, useful spectra that reflected ?65% of all C were obtained. The NMR analyses allowed us to conclude (1) that the HF treatment (with or without heat) had low impact on the organic C composition in the samples, except for protonating carboxylate anions to carboxylic acids, (2) that most organic C was observable by NMR even in untreated soil materials, (3) that esters were likely to compose only a minor fraction of SOM in these Mollisols, and (4) that the aromatic components of SOM were enriched to ∼53% in the poorly drained soils, compared with ∼48% in the well drained soils; in plant tissue and particulate organic matter (POM) the aromaticities were ∼18% and ∼32%, respectively. Nonpolar, nonprotonated aromatic C, interpreted as a proxy for charcoal C, dominated the aromatic C in all soil samples, composing 69-78% of aromatic C and 27-36% of total organic C in the whole-soil and clay-fraction samples.  相似文献   

Localization and characterization of an active fault in an urbanized area in central Guatemala by means of geoelectrical imaging     

Barbara Suski  Gilles Brocard  Christine Authemayou  Beatriz Consenza Muralles  Christian Teyssier  Klaus Holliger 《Tectonophysics》2010,480(1-4):88-98

The Polochic and Motagua faults define the active plate boundary between the North American and Caribbean plates in central Guatemala. A splay of the Polochic Fault traverses the rapidly growing city of San Miguel Uspantán that is periodically affected by destructive earthquakes. This fault splay was located using a 2D electrical resistivity tomography (ERT) survey that also characterized the fault damage zone and evaluated the thickness and nature of recent deposits upon which most of the city is built. ERT images show the fault as a ~50 m wide, near-vertical low-resistivity anomaly, bounded within a few meters by high resistivity anomalies. Forward modeling reproduces the key aspects of the observed electrical resistivity data with remarkable fidelity thus defining the overall location, geometry, and internal structure of the fault zone as well as the affected lithologies. Our results indicate that the city is constructed on a ~20 m thick surficial layer consisting of poorly consolidated, highly porous, water-logged pumice. This soft layer is likely to amplify seismic waves and to liquefy upon moderate to strong ground shaking. The electrical conductivity as well as the major element chemistry of the groundwater provides evidence to suggest that the local aquifer might, at least in part, be fed by water rising along the fault. Therefore, the potential threat posed by this fault splay may not be limited to its seismic activity per se, but could be compounded its potential propensity to enhance seismic site effects by injecting water into the soft surficial sediments. The results of this study provide the basis for a rigorous analysis of seismic hazard and sustainable development of San Miguel Uspantán and illustrate the potential of ERT surveying for paleoseismic studies.  相似文献   

Learning from (small) disasters     

Martin Voss  Klaus Wagner 《Natural Hazards》2010,55(3):657-669

In this article, disasters are understood as processes that have different impacts on social routines in terms of scale, scope and duration. The extent of adaptive processes in society can provide the ground for a rough classification of disaster types. Such classification has, on the one hand, practical and analytical advantages. On the other hand, they harbour the danger of overlooking transitions of scale and discourage comprehensive scale-related learning forms. Based on the disaster scale by Fischer (Int J Mass Emerg Disasters 1:91–107, 2003), flash floods in mountain rivers and torrents are described as extreme emergencies or small-town disasters. Three given examples will clearly show that learning rarely takes place within an institutional setting that is subjected to small disasters, because the stakeholder’s focus remains on only one level. Therefore, we propose to implement a system of self-organised and scale-independent learning, so called deutero learning, within the political subsystem. Following a damaging event, participative processes that involve all levels should be initialised. Their task would be to assess the combination of causes and draw conclusions for mitigation measures. An aggregation of these assessments would help the responsible political subsystems to adapt the current natural disasters policy to the changing environmental conditions.  相似文献   

Description of an aerodynamic levitation apparatus with applications in Earth sciences     

Andreas Pack  Katrina Kremer  Nina Albrecht  Klaus Simon  Andreas Kronz 《Geochemical transactions》2010,11(1):4

Background  

In aerodynamic levitation, solids and liquids are floated in a vertical gas stream. In combination with CO₂-laser heating, containerless melting at high temperature of oxides and silicates is possible. We apply aerodynamic levitation to bulk rocks in preparation for microchemical analyses, and for evaporation and reduction experiments.  相似文献   

Present and projected degree days in China from observation,reanalysis and simulations   总被引：1，自引：0，他引：1  

Qinglong You  Klaus Fraedrich  Frank Sielmann  Jinzhong Min  Shichang Kang  Zhenming Ji  Xiuhua Zhu  Guoyu Ren 《Climate Dynamics》2014,43(5-6):1449-1462

Degree days are usually defined as the accumulated daily mean temperature varying with the base temperature, and are one of the most important indicators of climate changes. In this study, the present-day and projected changes of four degree days indices from daily mean surface air temperature output simulated by Max Planck Institute, Earth Systems Model of low resolution (MPI-ESM-LR) model are evaluated with the high resolution gridded-observation dataset and two modern reanalyses in China. During 1979–2005, the heating degree days (HDD) and the numbers of HDD (NHDD) have decreased for observation, reanalyses (ERA-Interim and NCEP/NCAR) and model simulations (historical and decadal experiments), consistent with the increasing cooling degree days (CDD) and the numbers of CDD (NCDD). These changes reflect the general warming in China during the past decades. In most cases, ERA-Interim is closer to observation than NCEP/NCAR and model simulations. There are discrepancies between observation, reanalyses and model simulations in the spatial patterns and regional means. The decadal hindcast/forecast simulation performance of MPI-ESM-LR produce warmer than the observed mean temperature in China during the entire period, and the hindcasts forecast a trend lower than the observed. Under different representative concentration pathway (RCP) emissions scenarios, HDD and NHDD show significant decreases, and CDD and NCDD consistently increase during 2006–2100 under RCP8.5, RCP4.5 and RCP2.6, especially before the mid-21 century. More pronounced changes occur under RCP8.5, which is associated with a high rate of radiative forcing. The 20th century runs reflect the sensitivity to the initial conditions, and the uncertainties in terms of the inter-ensemble are small, whereas the long-term trend is well represented with no differences among ensembles.  相似文献   

Origin and age of ultramafic rocks and gabbros in the southern Puna of Argentina: an alleged Ordovician suture revisited     

Udo Zimmermann  Heinrich Bahlburg  Klaus Mezger  Jasper Berndt  Suzanne Mahlburg Kay 《International Journal of Earth Sciences》2014,103(4):1023-1036

Ultramafic rocks and gabbros are exposed in the southern Puna (NW Argentina) in tectonic association with continental arc-related Ordovician (volcano) sedimentary successions and granitoids. The origin of this mafic rock suite has been debated for three decades as either representing an Ordovician terrane suture, primitive Ordovician arc-related rocks or relics of the pre-Ordovician basement in tectonic contact with the Ordovician retro-arc basin successions. We present the first U–Pb ages of primary and inherited zircon from gabbros of this mafic–ultramafic assemblage. LA-ICP-MS analyses on cores and rims of these zircon grains yielded a concordia age of 543.4 ± 7.2 Ma for the gabbroic rocks. Other analysed zircons have Mesoproterozoic, and Early Ediacaran core and rim ages indicating that the magmas also assimilated Meso- and Neoproterozoic crustal material prior to final crystallization. The mafic rocks witnessed higher metamorphic grade than associated Ordovician rocks, which are unmetamorphosed or only affected by anchimetamorphism. The gabbros are mostly tholeiitic and enriched in Zr, Th, as well as other incompatible elements and have εNd _t=540Ma ranging from 1.3 to 7.4 with most of the values between 5 and 7. ¹⁴⁷Sm/¹⁴⁴Nd ratios show evidence of weak crustal contamination. The mafic rocks do not reveal any affinity to mid-ocean ridge basalts in their geochemistry but point instead to an emplacement in an active plate margin arc environment. Chromites from ultramafic rocks show typical Ti, Al, Cr#, Fe³⁺ abundances found in magmatic arc rocks. The formation of the gabbros and the associated ultramafic rocks in the southern Argentine Puna is related to the evolution of the margin of the Pampia terrane, including the Puncoviscana basin, during the Late Neoproterozoic and earliest Cambrian. In contrast to previous interpretations, the rocks predate the Ordovician evolution of the Central proto-Andean active margin. Consequently, interpretations assuming these rocks to represent an oceanic terrane suture of Ordovician age have to be dismissed as much as all palaeotectonic models that define Ordovician terranes in the Central Andes based on assumption that the ultramafic rocks and gabbros exposed in the southern Puna mark plate boundaries.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987114000395     

Alfons van den Kerkhof  Andreas Kronz  Klaus Simon 《地学前缘(英文版)》2014,5(5):683-695

The study of fluid inclusions in high-grade rocks is especially challenging as the host minerals have been normally subjected to deformation, recrystallization and fluid-rock interaction so that primary in- clusions, formed at the peak of metamorphism are rare. The larger part of the fluid inclusions found in metamorphic minerals is typically modified during uplift. These late processes may strongly disguise the characteristics of the ＂original＂ peak metamorphic fluid. A detailed microstructural analysis of the host minerals, notably quartz, is therefore indispensable for a proper interpretation of fluid inclusions. Cathodoluminescence （CL） techniques combined with trace element analysis of quartz （EPMA, LA- [CPMS） have shown to be very helpful in deciphering the rock-fluid evolution. Whereas high-grade metamorphic quartz may have relatively high contents of trace elements like Ti and A1, low- temperature re-equilibrated quartz typically shows reduced trace element concentrations. The result- ing microstructures in CL can be basically distinguished in diffusion patterns （along microfractures and grain boundaries）, and secondary quartz formed by dissolution-reprecipitation. Most of these textures are formed during retrograde fluid-controlled processes between ca. 220 and 500 ℃, i.e. the range of semi-brittle deformation （greenschist-facies） and can be correlated with the fluid inclusions. In this way modified and re-trapped fluids can be identified, even when there are no optical features observed under the microscope.  相似文献   

Managing coastal area resources by stated choice experiments     

Xin Liu  Kai W. Wirtz 《Estuarine, Coastal and Shelf Science》2010,86(3):512-517

In many coastal regions, oil spills can be considered as one of the most important and certainly the most noticeable forms of marine pollution. Efficient contingency management responding to oil spills on waters, which aims at minimizing pollution effects on coastal resources, turns out to be critically important. Such a decision making highly depends on the importance attributed to different coastal economic and ecological resources. Economic uses can, in principal, be addressed by standard measures such as value added. However, there is a missing of market in the real world for natural goods. Coastal resources such as waters and beach cannot be directly measured in money terms, which increases the risk of being neglected in a decision making process. This paper evaluates these natural goods of coastal environment in a hypothetical market by employing stated choice experiments. Oil spill management practice in German North Sea is used as an example. Results from a pilot survey show that during a combat process, beach and eider ducks are of key concerns for households. An environmental friendly combat option has to be a minor cost for households. Moreover, households with less children, higher monthly income and a membership of environmental organization are more likely to state that they are willing to pay for combat option to prevent coastal resources from an oil pollution. Despite that choice experiments require knowledge of designing questionnaire and statistical skills to deal with discrete choices and conducting a survey is time consumed, the results have important implications for oil spill contingency management. Overall, such a stated preference method can offer useful information for decision makers to consider coastal resources into a decision making process and can further contribute to finding a cost-effective oil preventive measure, also has a wide application potential in the field of Integrated Coastal Zone Management (ICZM).  相似文献   

Spinel-bearing,Al-rich chondrules in two chondrite finds from Roosevelt County,New Mexico: Indicators of nebular and parent body processes     

Timothy J. McCoy  Aurora Pun  Klaus Keil 《Meteoritics & planetary science》1991,26(4):301-309

Abstract— Two rare, spinel-bearing, Al-rich chondrules have been identified in new chondrite finds from Roosevelt County, New Mexico—RC 071 (L4) and RC 072 (L5). These chondrules have unusual mineralogies, dominated by highly and asymmetrically zoned, Al-Cr-rich spinels. Two alternatives exist to explain the origin of this zoning—fractional crystallization or metamorphism. It appears that fractional crystallization formed the zoning of the trivalent cations (Al, Cr) and caused a localized depletion in chromites around the large Al-Cr-rich spinels. The origin of the zoning of the divalent cations (Fe, Mg, Zn) is less certain. Diffusive exchange and partitioning of Fe and Mg between olivine and spinel during parent body metamorphism can explain the asymmetric zoning of these elements. Unfortunately, appropriate studies of natural and experimental systems to evaluate the formation of zoning of the divalent cations by fractional crystallization have not yet been conducted. The bulk compositions of the chondrules suggest affinities with the Na-Al-Cr-rich chondrules, as would be expected from the abundance of Al-Cr-rich spinels. Melting of rare and unusual precursors produced the compositions of Na-Al-Cr-rich chondrules, possibly including a spinel-rich precursor enriched in Cr₂O₃ and ZnO. The two chondrules we studied have larger modal abundances of Al-Cr-rich spinels than reported in other Na-Al-Cr-rich chondrules of similar composition, and Al-rich chondrules even more enriched in spinel are reported in the literature. These differences indicate that factors other than bulk composition control the mineralogy of the chondrules. The most important of these factors are the temperature to which the molten chondrule was heated and the cooling rate during crystallization. These two chondrules cooled rapidly from near the liquidus, as indicated by the zoning, occurrence and sizes of spinels, radiating chondrule textures and localized chromite depletions. The range of mineralogies in other Al-rich chondrules of similar composition reflect a range of peak temperatures and cooling rates. We see no reason to believe that this range is fundamentally different from the range of thermal histories experienced by “normal” Fe-Mg-rich chondrules.  相似文献   

Polarization and brightness opposition effects for the E-type Asteroid 64 Angelina     

Vera K. Rosenbush  Nikolai N. Kiselev  Klaus Jockers  Yuriy S. Efimov 《Icarus》2005,178(1):222-234

We present new polarimetric and photometric observations of the high-albedo Asteroid 64 Angelina in the UBVRI wavebands at phase angles ranging from 0.43° to 13.02° during oppositions in 1995, 1999, and 2000/2001. The polarization opposition effect has been observed in the form of a sharp peak of negative polarization with amplitude of about −0.4% centered at αmin≈1.8°, which is superimposed on the regular negative polarization branch. The amplitude of the polarization opposition effect appears to be apparition-dependent. Our photometric data confirm the early detected by Harris et al. [1989. Phase relations of high-albedo asteroids: The unusual opposition brightening of 44 Nysa and 64 Angelina. Icarus 81, 365-374] of a very strong and unusually narrow opposition spike, i.e., brightness opposition effect, for Angelina. Thus, 64 Angelina is the first asteroid for which both the polarization opposition effect and the brightness opposition effect have been detected. We observed that the polarization opposition effect as well as the regular negative polarization branch depends on the wavelength of scattered light, but in different manners. In addition, the colors B-V and V-R show little phase-angle dependence, while the color U-B increases with increasing phase angle, thus indicating that the amplitude of the brightness opposition effect is larger in the U band and almost the same in the B, V, and R bands. It appears that all colors indices begin to increase with decreasing phase angle to zero. The composite lightcurve computed with a period of 8.752 h has amplitude of 0.13 magnitude.  相似文献