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41.
We examine the performance of several methods to estimate meteorological inputs for modelling dispersion in urban areas during convective conditions. Sensible heat flux, surface friction velocity and turbulent velocities are estimated from measurements of mean wind speed and the standard deviation of temperature fluctuations at a single level on a tower at two suburban sites and at one urban site in Riverside, California. These estimates are compared with observations made at these sites during a field study conducted in 2007. The sensible heat flux is overestimated in the urban area, while it is underestimated at a suburban site when temperature fluctuations are used in the free convection formulation to estimate heat flux. The bias in heat flux estimates can be reduced through a correction that depends on stability. It turns out that the bias in heat flux estimates has a minor effect on the prediction of surface friction velocity and turbulent velocities. Estimates of sensible heat flux, surface friction velocity and turbulent velocities are sensitive to estimates of aerodynamic roughness length, and we suggest estimating the aerodynamic roughness length through detailed micrometeorological measurements made during a limited field study. An examination of the impact of the uncertainty in estimating surface micrometeorology on concentrations indicates that, at small distances from a surface release, ground-level concentrations computed using estimates of heat flux and surface friction compare well with the those based on observed values: the bias is small and the 95% confidence interval of the ratio of the two concentrations is 1.7. However, at distances much larger than the Obukhov length, this confidence interval is close to 2.3 because errors in both friction velocity and heat flux affect plume spread. Finally, we show that using measurements of temperature fluctuations in estimating heat flux is an improvement on that based on the surface energy balance, even when net radiation measurements are available.  相似文献   
42.
Abstract— A new olivine‐pigeonite ureilite containing abundant diamonds and graphite was found in the United Arab Emirates. This is the first report of a meteorite in this country. The sample is heavily altered, of medium shock level, and has a total weight of 155 g. Bulk rock, olivine (Fo79.8–81.8) and pyroxene (En73.9–75.2, Fs15.5–16.9, Wo8.8–9.5) compositions are typical of ureilites. Olivine rims are reduced with Fo increasing up to Fo96.1–96.8. Metal in these rims is completely altered to Fehydroxide during terrestrial weathering. We studied diamond and graphite using micro‐Raman and in situ synchrotron X‐ray diffraction. The main diamond Raman band (LO = TO mode at ?1332 cm?1) is broadened when compared to well‐ordered diamond single crystals. Full widths at half maximum (FWHM) values scatter around 7 cm?1. These values resemble FWHM values obtained from chemical vapor deposition (CVD) diamond. In situ XRD measurements show that diamonds have large grain sizes, up to >5 μm. Some of the graphite measured is compressed graphite. We explore the possibilities of CVD versus impact shock origin of diamonds and conclude that a shock origin is much more plausible. The broadening of the Raman bands might be explained by prolonged shock pressure resulting in a transitional Raman signal between experimentally shock‐produced and natural diamonds.  相似文献   
43.
The Variscan Upper Allochthon is a continental‐affinity terrane that recorded a CambrianEdiacaran magmatic arc generation, a subsequent transition to a passive margin, and a collision‐related high‐P metamorphism during the DevonianCarboniferous amalgamation of Pangea. The objective of this article is to decipher which continental margin subducted in the Devonian high‐P–high‐T (HP–HT) event. To do so, a provenance study is presented using combined UPb (n = 613) and LuHf (n = 463) isotopic LAICPMS zircon analyses and SmNd whole–rock (n = 5) determinations. These analyses have been performed on five samples of the Banded Gneisses (Cabo Ortegal Complex, NW Iberia), which forms a part of the HP–HT bottom member of the Upper Allochthon. Palaeozoic–Neoproterozoic zircon ages (34.7%) have a maximum abundance at 522–512 Ma, peaks at 575, 561, 545 Ma and minor abundance peaks between 780 and 590 Ma, and show from their Lu–Hf compositions a volcanic arc mixing pattern. This arc was probably related to the Cadomian arc system. The Mesoproterozoic population is scarce and scattered (2.8%), and due to its Lu–Hf pattern, it is proposed that this population is also West Africa Craton derived. The Paleoproterozoic population (39.6%) is concentrated at 2.07 Ga and it is linked to the Eburnean Orogeny, where depleted mantle derived magmas intruded an Archean craton margin. This craton is represented by the Archean population (22.8%), which is grouped at 3.0, 2.68‐2.61 and 2.52‐2.48 Ga, and shows long‐term reworking processes and at least two juvenile magma intrusions. These data show that the Variscan Upper Allochthon has a West African provenance and therefore, it strongly suggests that the NW Iberian allochthonous complexes and their correlative European terranes are also West Africa derived. These results allow us to finally clarify that the first high‐P event, recorded during the eo‐Variscan amalgamation of Pangea, was attained by the subduction of the margin of Gondwana under Laurussia.  相似文献   
44.
This paper presents a comparison of persistent scatterer interferometry (PSI) monitoring results with in situ displacement measurements at the November 1990 landslide at the Bor?t uranium mill tailing deposit site after heavy rain. Although the landslide did not directly endanger people, site remediation works were undertaken due to the subsequent environmental problems. Additionally, in situ monitoring with benchmarks was established in order to detect the ground motion of the landslide body. PSI campaigning in the ?kofjelo?ko-Cerkljansko area, where the uranium mill tailing is situated, performed for the purpose of measuring displacements of natural targets near the active landslide area, also detected displacements, most probably indicating a creeping process. When comparing the pre- and post-remediation velocities at the benchmarks located on the landslide with persistent scatterers (PSs) located near the landslide, the rates could be regarded as background. The results show that the remediation works in the form of a drainage tunnel were very effective as post-remediation velocities at the landslide closer to the PSs resembled the velocities of the PSs, while the velocities of the landslide mass above the drainage tunnel slowed down, even to below the background velocities. The high correlation values between the movements of the benchmarks and the PSs also confirm that the remediation works were effective as the fluctuations in the displacement values of the landslide were very similar to those of the PSs. Nevertheless, although there are several limitations in comparing the two different datasets, the PSI technique can be complementary to conventional in situ methods.  相似文献   
45.
J.R. Marko 《大气与海洋》2013,51(3):549-579
Abstract

Several sets of previously compiled data on iceberg size distributions in areas between North America and Greenland are compared and analyzed. The obtained results indicate that populations of icebergs with lengths L ≥ 20 m are well‐described by log‐normal and gamma distributions together with statistical parameters which are compatible with existing understanding of regional iceberg deterioration and change processes. A lesser amount of data on size distributions in Newfoundland icebergs with L < 20 m show occurrence probabilities which increase exponentially with decreasing iceberg length. Evidence is presented to show that these data are most consistent with the dominance of fracture processes in determining iceberg occurrence versus length relationships. Physical arguments are presented to suggest that the key fracture events are initiated in the larger icebergs by coincidences of wave‐generated bending stress maxima and randomly distributed structural flaws. Similar considerations and use of a simple sequential fracture model imply that size distributions in icebergs (and iceberg fragments) with L < 20 m are more consistent with the presence of an alternative, spontaneous failure mechanism also acting at randomly distributed structural defects. The implications of these results for forecasting and monitoring populations of small icebergs are discussed.  相似文献   
46.
47.
The concentrations and spatial distribution of nine potentially harmful elements (PHEs), namely Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn, and their relation to soil properties were investigated in thirty soil profiles (0–50 cm depth) sampled around the largest Serbian coal-fired power plant (CFPP) “Nikola Tesla A.” Soil properties were determined following standard procedures, and total contents of PHEs were analyzed by atomic absorption spectrometer. Concentrations of Cd, Co, Fe, Mn, Pb and Zn were the highest in soil profiles sampled 1 km away from the CFPP, concentrations of Ni and Cu gradually increased up to 4 km, and the highest Cr concentrations were measured in samples taken 6 km away from the CFPP. The highest concentration of PHEs analyzed, except Mn, corresponded with predominant wind directions. Depth did not show significant impact on distribution of any PHEs investigated. Among soil properties, the total organic carbon showed the closest relationship with the PHEs. Data were processed by a principal component analysis which enabled distinguishing anthropogenic from natural influences on soil properties and PHE contents. Although the impact of CFPP operations is obvious, assets of principal component analysis did not allow clear distinction of CFPP’s contribution from parent material in enrichment of PHE contents in the soil in the study area.  相似文献   
48.
The water balance of wetlands plays an integral role in their function. Developments adjacent to wetlands can affect their water balance through impacts on groundwater flow and increased discharge in the area, and they can cause lowering of the wetland water table. A 430 km2 area was selected for groundwater modelling to asses the effect of underground mining on the water balance of wetlands in north-eastern Estonia. A nature conservation area (encompassing Selisoo bog) is within 3 km of an underground oil-shale mine. Two future mining scenarios with different areal extents of mining were modeled and compared to the present situation. Results show that the vertical hydraulic conductivity of the subsurface is of critical importance to potential wetland dewatering as a result of mining. Significant impact on the Selisoo bog water balance will be caused by the approaching mine but there will be only minor additional impacts from mining directly below the bog. The major impact will arise before that stage, when the underground mine extension reaches the border of the nature conservation area; since the restriction of activities in this area relates to the ground surface, the conservation area’s border is not sufficiently protective in relation to underground development.  相似文献   
49.
Abstract– Maribo is a new Danish CM chondrite, which fell on January 17, 2009, at 19:08:28 CET. The fall was observed by many eye witnesses and recorded by a surveillance camera, an all sky camera, a few seismic stations, and by meteor radar observatories in Germany. A single fragment of Maribo with a dry weight of 25.8 g was found on March 4, 2009. The coarse‐grained components in Maribo include chondrules, fine‐grained olivine aggregates, large isolated lithic clasts, metals, and mineral fragments (often olivine), and rare Ca,Al‐rich inclusions. The components are typically rimmed by fine‐grained dust mantles. The matrix includes abundant dust rimmed fragments of tochilinite with a layered, fishbone‐like texture, tochilinite–cronstedtite intergrowths, sulfides, metals, and carbonates often intergrown with tochilinite. The oxygen isotopic composition: (δ17O = ?1.27‰; δ18O = 4.96‰; Δ17O = ?3.85‰) plots at the edge of the CM field, close to the CCAM line. The very low Δ17O and the presence of unaltered components suggest that Maribo is among the least altered CM chondrites. The bulk chemistry of Maribo is typical of CM chondrites. Trapped noble gases are similar in abundance and isotopic composition to other CM chondrites, stepwise heating data indicating the presence of gas components hosted by presolar diamond and silicon carbide. The organics in Maribo include components also seen in Murchison as well as nitrogen‐rich components unique to Maribo.  相似文献   
50.
The human mediated transfer of harmful organisms via shipping, specifically via ballast water transport, leading to the loss of biodiversity, alteration of ecosystems, negative impacts on human health and in some regions economic loss, has raised considerable attention especially in the last decade. Ballast water sampling is very important for biological invasions risk management. The complexity of ballast water sampling is a result of both the variety of organism diversity and behaviour, as well as ship design including availability of ballast water sampling points. Furthermore, ballast water sampling methodology is influenced by the objectives of the sampling study. In the course of research conducted in Slovenia, new sampling equipment for ships' ballast water was developed and tested. In this paper new ballast water sampling methods and equipment together with practical shipboard testing results are presented.  相似文献   
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