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T. KAWAI B. F. WINDLEY M. TERABAYASHI H. YAMAMOTO S. MARUYAMA Y. ISOZAKI 《Journal of Metamorphic Geology》2006,24(7):591-602
The 560–550 Ma blueschists and associated rocks in Anglesey, UK were derived from a subduction–accretion complex. The blueschist unit is divided into three mineral zones by two newly mapped metamorphic isograds; zone I sub-greenschist facies, (crossite isograd), zone II blueschist facies, (barroisite isograd), zone III epidote-amphibolite facies. The zones and isograds dip gently to the east, and decrease in metamorphic grade from the central high-pressure zone III to lower grade zones II and I to the west and east. The P – T conditions estimated from zoned amphibole indicate an anticlockwise P – T path following adjustment to a cold geotherm. This path is well preserved in the compositional zoning of Na–Ca amphibole that have a core of barroisite surrounded by a rim of crossite, although this is only locally developed. The sense of subduction was to the east and exhumation to the west, as indicated by the metamorphic isograds. The symmetrical arrangement of the metamorphic zones with the deepest high-pressure rocks in the middle suggests an isoclinal antiformal structure that formed by wedge extrusion during exhumation in the subduction zone. 相似文献
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Crustal thickening of the lower crust of the Kohistan arc (N. Pakistan) deduced from Al zoning in clinopyroxene and plagioclase 总被引：8，自引：0，他引：8
The lower-crustal rocks of the Kohistan complex (northern Pakistan) are mostly composed of metabasic rocks such as pyroxene granulites, garnet granulites and amphibolites. We have investigated P–T trajectories of the relic two-pyroxene granulites, which are the protolith of the amphibolites within the Kamila amphibolite belt. Aluminous pyroxene retains igneous textures such as exsolution lamellae developed in the core. The significant amount of Al in clinopyroxene is buffered by breakdown reactions of plagioclase accompanied by film-like quartz as a product at grain boundaries between plagioclase and clinopyroxene. Distinct Al zoning profiles are preserved in pyroxene with exsolution lamellae in the core and in plagioclase adjacent to clinopyroxene in pyroxene granulites. In the northern part of the Kamila amphibolite belt, Al in clinopyroxene increases towards the rim and abruptly decreases at the outer rim, and anorthite in plagioclase decreases towards the rim and abruptly increases near the grain boundary between plagioclase and clinopyroxene. In the southern part of the Kamila amphibolite belt, Al in clinopyroxene and anorthite in plagioclase simply increase towards the margins of the grains. The anorthite zoning in plagioclase is in agreement with the zoning profiles of Ca-Tschermaks and jadeite components inferred from variations of Al, Na, Ti and Fe3+ in clinopyroxene. Assuming that the growth surface between them was in equilibrium, geothermobarometry based on Al zoning in clinopyroxene coexisting with plagioclase indicates that metamorphic pressures significantly increased with increasing temperature under granulite facies metamorphism. The peak of granulite facies metamorphism occurred at conditions of about 800 °C and 800–1100 MPa. These prograde P–T paths represent a crustal thickening process of the Kohistan arc during the Early to Middle Cretaceous. The crustal thickening of the Kohistan arc was caused by accretion of basaltic magma at mid-crustal depths. 相似文献
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Rainer BARTOSCHEWITZ Ulrich OTT Luitgard FRANKE Siegfried HERRMANN Yukio YAMAMOTO Keisuke NAGAO Morten BILET Thomas GRAU 《Meteoritics & planetary science》2010,45(8):1380-1391
Abstract– The Moss meteorite is the first CO chondrite fall after a time period of 70 yr and the least terrestrially contaminated member of its group. Its cosmic‐ray exposure (CRE) age (T3 ～ 13.5 Ma; T21 ～ 14.6 Ma) is distinct among CO chondrites and, within witnessed falls is the shortest after Lancé, which we have reanalyzed. Gas retention ages are approximately 3.95 × 109 yr (U/Th‐He) and approximately 4.43 × 109 yr (K/Ar), respectively. Trapped Ar, Kr, and Xe are present in Moss in abundances typical for CO chondrites, with “planetary” elemental and isotopic compositions. Presence of HL‐xenon from presolar diamonds is observed in the stepwise release analysis of Lancé. It may also be present in Moss, but it is difficult to ascertain in single‐step bulk analyses. It follows from our new data combined with a survey of the literature that the abundance of trapped gases in CO chondrites is not a good indicator of their petrological subtype. 相似文献
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Yasuhito SEKINE Seiji SUGITA Takafumi SHIDO Takashi YAMAMOTO Yasuhiro IWASAWA Toshihiko KADONO Takafumi MATSUI 《Meteoritics & planetary science》2006,41(5):715-729
Abstract— Fischer‐Tropsch catalysis, by which CO and H2 are converted to CH4 on the surface of transition metals, has been considered to be one of the most important chemical reactions in many planetary processes, such as the formation of the solar and circumplanetary nebulae, the expansion of vapor clouds induced by cometary impacts, and the atmospheric re‐entry of vapor condensate due to asteroidal impacts. However, few quantitative experimental studies have been conducted for the catalytic reaction under conditions relevant to these planetary processes. In this study, we conduct Fischer‐Tropsch catalytic experiments at low pressures (1.3 times 10?4 bar ≤ P ≤ 5.3 times 10?1 bar) over a wide range of H2/CO ratios (0.25–1000) using pure iron, pure nickel, and iron‐nickel alloys. We analyze what gas species are produced and measure the CH4 formation rate. Our results indicate that the CH4 formation rate for iron catalysts strongly depends on both pressure and the H2/CO ratio, and that nickel is a more efficient catalyst at lower pressures and lower H2/CO ratios. This difference in catalytic properties between iron and nickel may come from the reaction steps concerning disproportionation of CO, hydrogenation of surface carbon, and the poisoning of the catalyst. These results suggest that nickel is important in the atmospheric re‐entry of impact condensate, while iron is efficient in circumplanetary subnebulae. Our results also indicate that previous numerical models of iron catalysis based on experimental data at 1 bar considerably overestimate CH4 formation efficiency at lower pressures, such as the solar nebula and the atmospheric re‐entry of impact condensate. 相似文献
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A coastal acoustic tomography experiment in the Tokyo Bay 总被引：1，自引：0，他引：1
KANEKO Arat YAMAGUCHI Keisuke YAMAMOTO Tokuo GOHDA Noriaki ZHENG Hong SYAMSUDIN Fadli LIN Ju NGUYEN Hong-Quang MATSUYAMA Masaji HACHIYA Hiroyuki HASHIMOTO Noriaki 《海洋学报(英文版)》2005,24(1):86-94
Eight sets of coastal acoustic tomography (CAT) systems were deployed during November 29 to December 10, 2002 at the coasts on both sides of Tokyo Bay to measure tidal current structures at 15-rain interval.Sound transmission across the Tokyo Bay (between Yokohama and Chiba)was successfillly traced,even under severe interference from ship generated wakes and bubbles.Tidal current fields changing from northward to southward flow are well reconstructed by the inverse analysis of travel-time difference data for a period with the best sound transmission condition. It is suggested that the CAT is the most powerful tool to continuously map tidal current fields in the coastal seas with heavy shipping traffic and fisheries activity. 相似文献
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The preliminary results of long-term CO2 flux measurements at forest sites in East Asia are explained and compared with each other. The features of seasonal variation of CO2 fluxes are different among deciduous-broadleaf, evergreen-coniferous, deciduous-coniferous and tropical forests in East Asia, and the causes of difference are discussed. The integrated yearly NEP (net ecosystem production) estimated from the CO2 flux by eddy covariance method in various forests of East Asia has a notable difference in the range of 2 to 8 tC ha-1 yr-1. The main factors of this difference are the annual mean temperature and tree species. Furthermore, the remaining issues are discussed, such as the quantitative estimation of the CO2 flux by the eddy covariance method and the synthetic analysis of the carbon budget under collaborations with biological survey. 相似文献
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The >3·0 Ga chert sequence of the Gorge Creek Group is exposed at Ord Ranges about 50 km east of Port Hedland in the Pilbara Block. The chert sequence examined in this study is 15 m thick and consists of oxide-rich laminated chert, grey chert (silicified clastic rock), carbonaceous black chert and carbonate-rich laminated chert. Although the cherts have undergone postdepositional silica enrichment, such as cementation and metasomatic silicification, primary precipitation of silica at the site of deposition is indicated by abundant microstructures (mosaic and spherulitic structures). Other primary to early diagenetic components were carbonates, sulphates (gypsum and anhydrite) and organic matter. Although these mineral associations, on the whole, correspond to those of modern marine evaporites, they are different from modern equivalents with respect to abundant precipitation of amorphous silica and presumed primary precipitation of iron-carbonate (siderite). This feature is a possible manifestation of peculiar physicochemical conditions in the water mass from which the chemical sediments were precipitated; compared with modern ocean waters, the concentrations of Fe and Si were significantly higher and the pH value might have been lower. These conditions could be obtained by contributions of Fe- and Si-enriched hydrothermal solutions and continental run-off to the site of deposition. Grey cherts contain detrital quartz and altered Fe–Ti oxides and were formed in a period of input of terrigenous detrital materials. They are characterized by higher concentrations of TiO2, Al2O3, Cr, Ni, Zn, Rb and Zr compared with the other types of chert and by very low (< 4) Al2O3/TiO2 values. These features are attributed to the supply of terrigenous detrital materials that contain abundant Fe–Ti oxides (ilmenite and titanomagnetite) and fine TiO2 particles. Such detrital materials might have been formed by extensive chemical alteration of source rocks and residual enrichment of Ti relative to Al. 相似文献
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T. RUSKOV I. SPIROV M. GEORGIEVA S. YAMAMOTO H. W. GREEN C. A. McCAMMON L. F. DOBRZHINETSKAYA 《Journal of Metamorphic Geology》2010,28(5):551-560
Mössbauer spectroscopy was applied to study the valence state of iron in chromite from massive, nodular and disseminated podiform chromitite ores of the Luobasa ophiolite massif of Tibet. The results show that Fe3+/ΣFe = 0.42 in chromite from massive ore, and Fe3+/ΣFe = 0.22 in chromite from nodular and disseminated ores. The massive ore records traces of ultra high pressure mineralogical assemblages, such as diamond inclusions in OsIr alloys, exsolution lamellae of coesite and diopside in chromite, inclusions of metal‐nitrides, native iron and others, which suggests a strongly reducing environment. In contrast, chromite from nodular and disseminated ore contains abundant low‐pressure OH‐bearing mineral inclusions whose formation requires a more oxidizing environment. The high value of Fe3+/ΣFe in the ‘reduced’ massive ore is explained by crystallographic stabilization of Fe3+ in a high‐pressure polymorph of chromite deep in the upper mantle despite low ambient fO2 conditions. The presence of high‐pressure phases within the massive chromitite ore requires that the latter, together with its host peridotite, was transported in the solid state from a highly reduced deep mantle environment to shallow depths beneath an ocean spreading centre. It is suggested that in the low‐pressure environment of the spreading centre, the deep‐seated, reduced, massive chromitites partially reacted with their host peridotite in the presence of hydrous melt, yielding the nodular and disseminated chromitite ores. The preponderance of evidence suggests that the latter interaction involved boninitic melts in a supra‐subduction zone environment as proposed previously. 相似文献