Bond length and radii variations in fluoride and oxide molecules and crystals     

J. S. Nicoll  G. V. Gibbs  M. B. Boisen Jr.  R. T. Downs  K. L. Bartelmehs 《Physics and Chemistry of Minerals》1994,20(8):617-624

Molecular orbital calculations completed on fluoride molecules containing first and second row cations have generated bond lengths, R, that match those observed for coordinated polyhedra in crystals to within ～0.04 Å, on average. The calculated bond lengths and those observed for fluoride crystals can be ranked with the expression R=Kp ^?0.22, where p=s/r, s is the Pauling strength of the bond, r is the row number of the cation and K=1.34. The exponent -0.22 (≈ -2/9) is the same as that observed for oxide, nitride and sulfide molecules and crystals. Bonded radii for the fluoride anion, obtained from theoretical electron density maps, increase linearly with bond length. Those calculated for the cations as well as for the fluoride anion match calculated promolecule radii to within ～0.03 Å, on average, suggesting that the electron density distributions in the vicinity of the minima along the bond paths possess a significant atomic component despite bond type. Bonded radii for Si and O ions provided by experimental electron density maps measured for the oxides coesite, danburite and stishovite match those calculated for a series of monosilicic acid molecules. The resulting radii increase with bond length and coordination number with the radius of the oxide ion increasing at a faster rate than that of the Si cation. The oxide ion within danburite exhibits several distinct radii, ranging between 0.9 and 1.2 Å, rather than a single radius with each exhibiting a different radius along each of the nonequivalent bonds with B, Si and Ca. Promolecule radii calculated for the coordinated polyhedra in danburite match procrystal radii obtained in a structure analysis to within 0.002 Å. The close agreement between these two sets of radii and experimentally determined bonded radii lends credence to Slater's statement that the difference between the electron density distribution observed for a crystal and that calculated for a procrystal (IAM) model of the crystal “would be small and subtle, and very hard to determine by examination of the total charge density.”  相似文献   

Calculated mineral equilibria in the greenschist-blueschist-eclogite facies in Na2O−FeO−MgO−Al2O3−SiO2−H2O     

Michel Guiraud  Tim Holland  Roger Powell 《Contributions to Mineralogy and Petrology》1990,104(1):85-98

The new, greatly expanded internally-consistent dataset of Holland and Powell includes thermodynamic data for a wide range of mineral end-members in common rock-forming minerals, in particular, including FeMg_-1 substitutions in glaucophane, garnet, chloritoid and carpholite, and FeMg_-1 and MgSiAl_-1Al_-1 substitutions in talc and chlorite. Moreover, we have the uncertainties and correlations for these data. With the data, we have calculated the full pressure-temperature phase diagram for the system Na₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (NFMASH) for quartz (or coesite) and H₂O in excess, in the range 300°–800°C and 5–50 kbars. By solving the set of non-linear equations formed by the equilibrium relationships for an independent set of equations between the end-members in an assemblage in NFMASH, the compositions of the minerals (and PT) can be calculated. Thus the changes in MgSiAl_-1Al_-1 along NMASH reactions, and FeSiAl_-1Al_-1 along NFASH reactions, are calculated, and the changes in FeMg_-1 and MgSiAl_-1Al_-1 along NFMASH reactions are calculated. From this information it is straightforward to generate PT diagrams for specific rock compositions. Mineral assemblages and mineral compositional changes in the phase diagram are discussed in relation to greenschist, blueschist and eclogite facies assemblages in metapelitic rocks. It is found that the correspondence between the predictions of the phase diagrams and the observations on rocks is remarkably good. When semiquantitative extensions of the phase diagram to include Ca(MgFe)_-1, NaSiCa_-1Al_-1, Fe³⁺Al_-1 and KNa_-1 substitutions are taken into account the agreement is essentially complete.  相似文献   

Model for Predicting Virus Movement Through Soils   总被引：3，自引：0，他引：3  

Udoyara S. Tim  Saied Mostaghimi 《Ground water》1991,29(2):251-259

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Alluvial gold in Kalimantan, Indonesia: A colloidal origin?     

John B. Seeley  Tim J. Senden 《Journal of Geochemical Exploration》1994,50(1-3)

Extensive placer gold deposits occur in Quaternary palaeochannels in the Ampalit and Cempaga Buang drainage basins near Kasongan, Central Kalimantan, Indonesia. Broad interfluvial Pleistocene terraces surrounding the drainages also contain significant amounts of placer gold. The “channel” and “terrace” gold deposits together cover an area in excess of 180 km².Exploration for gold at Ampalit followed traditional alluvial methods, and assumed that mechanical and gravitational factors were the principal mechanisms affecting gold accumulation and concentration. Gold was considered to be physically reworked from terraces and redeposited in the present drainage channels or underlying, laterally displaced, palaeochannels. However, a comparison of gold grains from the Ampalit drainage channel and adjacent terraces indicates that gold grains in the drainage channels are possibly of colloidal origin and not mechanically transported to their present domain.The morphology of gold grains from the Ampalit drainage is compared with grains from adjacent terraces, using scanning electron microscopy and atomic force microscopy. The latter procedure allows for nondestructive analysis to give true three dimensional surface topography down to nanometre resolution. Evidence from force microscopy supports a colloidal origin for gold aggregates.The average purity of gold produced from the Ampalit dredging operation is 970 fine (970/1000) and the majority of examined gold grains extracted from beneath the drainage channel have a purity of 998 fine. This unusually high degree of purity suggests a selective dissolution/aggregation mechanism. We propose that gold is transported downward and laterally in groundwater percolating through the terrace sands and gravels to the current drainage as a humic acid-stabilised colloid. As the pregnant groundwater migrates toward the present drainage channels, it encounters a sleep chemical gradient and the colloid aggregates. The aggregation process occurs near clay zones within palaeochannel sands and gravels beneath the present river sediments. Here the colloidal aggregates form small grains (usually <1 mm) of extremely high purity.Today, the inherently unstable gold deposits at Ampalit are in a state of both aggregation and dissolution. Identification of low energy zones, location of point bar lags in palaeo and recent drainage channels, and the extrapolation of areas of low energy are not solely valid as exploration guides for gold accumulation in this environment. Exploration methods that also recognise ground water migration and composition, and the geochemical controls of dissolution and aggregation, will improve the ability to identify ore accumulations, thus contributing to improved economics of mining these deposits.  相似文献   

Determining Paleosol Topography Using Seismic Refraction     

Tim C. Rolph  John Shaw  Edward Derbyshire  An Zhisheng 《Quaternary Research》1994,42(3)

The seismic refraction reversed profiling technique has been used to investigate the topography of the last interglacial soil (paleosol S1) within the central Chinese Loess Plateau near Xifeng. The results suggest an essentially flat-lying soil at a depth which varies by only a few meters over an area of more than 10 km². In addition, the results indicate a high-velocity layer at 50-60 m depth which is thought to coincide with a layer of carbonate concretions at the base of paleosol S5. The results agree well with the local loess-paleosol stratigraphy for this area and indicate that the seismic refraction method is a rapid technique for investigating paleotopography.  相似文献   

Initiation and growth of salt-based thrust belts on passive margins: results from physical models   总被引：1，自引：0，他引：1  

Tim P. Dooley  Martin P. A. Jackson  Michael R. Hudec 《Basin Research》2007,19(1):165-177

Scaled sandbox models simulated primary controls on the kinematics of the early structural evolution of salt‐detached, gravity‐driven thrust belts on passive margins. Models had a neutral‐density, brittle overburden overlying a viscous décollement layer. Deformation created linked extension–translation–shortening systems. The location of initial brittle failure of the overburden was sensitive to perturbations at the base of the salt. Salt pinch‐out determined the seaward limit of the thrust belt. The thrust belts were dominated by pop‐up structures or detachment folds cut by break thrusts. Pop‐ups were separated by flat‐bottomed synclines that were partially overthrust. Above a uniformly dipping basement, thrusts initiated at the salt pinch‐out then consistently broke landward. In contrast, thrust belts above a seaward‐flattening hinged basement nucleated above the hinge and then spread both seaward and landward. The seaward‐dipping taper of these thrust belts was much lower than typical, frictional, Coulomb‐wedge models. Towards the salt pinch‐out, frictional resistance increased, thrusts verged strongly seawards and the dip of the taper reversed as the leading thrust overrode this pinch‐out. We attribute the geometry of these thrust belts to several causes. (1) Low friction of the basal décollement favours near‐symmetric pop‐ups. (2) Mobile salt migrates away from local loads created by overthrusting, which reduces the seaward taper of the thrust belt. (3) In this gravity‐driven system, shortening quickly spreads to form wide thrust belts, in which most of the strain overlapped in time.  相似文献   

Detrital record of Mesozoic shortening in the Yanshan belt, NE China: testing structural interpretations with basin analysis   总被引：3，自引：0，他引：3  

Tim D. Cope  Michael R. Shultz†  S. A. Graham‡ 《Basin Research》2007,19(2):253-272

The Yanshan fold‐thrust belt is an exposed portion of a major Mesozoic orogenic system that lies north of Beijing in northeast China. Structures and strata within the Yanshan record a complex history of thrust faulting characterized by multiple deformational events. Initially, Triassic thrusting led to the erosion of a thick sequence of Proterozoic and Palaeozoic sedimentary strata from northern reaches of the thrust belt; Triassic–Lower Jurassic strata that record this episode are deposited in a thin belt south of this zone of erosion. This was followed by postulated Late Jurassic emplacement of a major allochthon (the Chengde thrust plate), which is thought to have overridden structures and strata associated with the Triassic event and is cut by two younger thrusts (the Gubeikou and Chengde County thrusts). The Chengde allochthon is now expressed as a major east–west trending, thrust‐bounded synform (the Chengde synform), which has been interpreted as a folded klippe 20 km wide underlain by a single, north‐vergent thrust fault. Two sedimentary basins, defined on the basis of provenance, geochronology and palaeodispersal trends, developed within the Yanshan belt during Late Jurassic–Early Cretaceous time and are closely associated with the Chengde thrust and allied structures. Shouwangfen basin developed in the footwall of the Gubeikou thrust and records syntectonic unroofing of the hanging wall of that fault. Chengde basin developed in part atop Proterozoic strata interpreted as the upper plate of the Chengde allochthon and records unroofing of the adjacent Chengde County thrust. Both the Chengde County thrust and the Gubeikou thrust are younger than emplacement of the postulated Chengde allochthon, and structurally underlie it, yet neither Shouwangfen basin nor Chengde basin contain a detrital record of the erosion of this overlying structure. In addition, facies, palaeodispersal patterns and geochronology of Upper Jurassic strata that are cut by the Chengde thrust suggest only limited (ca. 5 km) displacement along this fault. We suggest that the units forming the Chengde synform are autochthonous, and that the synform is bounded by two limited‐displacement faults of opposing north and south vergence, rather than a single large north‐directed thrust. This conclusion implies that the Yanshan belt experienced far less Late Jurassic shortening than was previously thought, and has major implications for the Mesozoic evolution of the region. Specifically, we argue that the bulk of shortening and uplift in the Yanshan belt was accomplished during Triassic–Early Jurassic time, and that Late Jurassic structures modified and locally ponded sediments from a well‐developed southward drainage system developed atop this older orogen. Although Upper Jurassic strata are widespread throughout the Yanshan belt, it is clear that these strata developed within several discrete intermontane basins that are not correlable across the belt as a single entity. Thus, the Yanshan has no obvious associated foreland basin, and determining where the Mesozoic erosional products of this orogen ultimately lie is one of the more intriguing unresolved questions surrounding the palaeogeography of North China.  相似文献   

Combining InSAR and seismology to study the 2003 Siberian Altai earthquakes—dextral strike-slip and anticlockwise rotations in the northern India–Eurasia collision zone     

Edwin Nissen  Brian Emmerson  Gareth J. Funning  Anatoly Mistrukov  Barry Parsons  David P. Robinson  Eugene Rogozhin  Tim J. Wright † 《Geophysical Journal International》2007,169(1):216-232

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Post-seismic motion following the 1997 Manyi (Tibet) earthquake: InSAR observations and modelling   总被引：2，自引：0，他引：2  

Isabelle Ryder  Barry Parsons  Tim J. Wright  Gareth J. Funning 《Geophysical Journal International》2007,169(3):1009-1027

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A device for measuring downwearing rates on cohesive shore platforms     

Richard Charman  Tim Cane  Cherith Moses  Rendel Williams 《地球表面变化过程与地形》2007,32(14):2212-2221

The device described in this paper, known as the traversing erosion beam, is believed to be the first to be designed specifically for measuring rates of downwearing of cohesive foreshores, such as clay shore platforms, under high‐energy wave conditions. It is primarily constructed of Flexlink Aluminium Structural System components and consists of a horizontal beam with a main leg and two further support legs. A sliding ‘dolly’ module is moved along the beam at precise intervals using a longitudinal scale as a reference. The topographic profile of the measurement surface is transferred to the dolly by a vertical sliding steel alloy rod, from which the relative height differences are measured by a separate engineer's digital height gauge placed on the dolly. The main leg of the device fits into a marine grade stainless steel box, which is deeply embedded into the foreshore or shore platform to act a permanent datum. The box is robust and can be expected to have a lifetime of at least a year, and possibly even five years or more. Sample data are provided from a clay shore platform at Warden Point in the Isle of Sheppey, Kent (UK), which demonstrate that the TEB can provide information on seasonal as well as annual rates of downwearing. The device has also been tested successfully on a peat and clay foreshore at Pett Level in Sussex and on a shore platform cut in glacial till at Easington, Yorkshire. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献