In Situ U‐Th‐Pb Dating and Sr‐Nd Isotope Analysis of Bastnäsite by LA‐(MC)‐ICP‐MS     

Yue‐Heng Yang  Fu‐Yuan Wu  Qiu‐Li Li  Yamirka Rojas‐Agramonte  Jin‐Hui Yang  Yang Li  Qian Ma  Lie‐Wen Xie  Chao Huang  Hong‐Rui Fan  Zi‐Fu Zhao  Cheng Xu 《Geostandards and Geoanalytical Research》2019,43(4):543-565

Bastnäsite is the end member of a large group of carbonate–fluoride minerals with the common formula (REE) CO₃F·CaCO₃. This group is generally widespread and, despite never occurring in large quantities, represents the major economic light rare earth element (LREE) mineral in deposits related to carbonatite and alkaline intrusions. Since bastnäsite is easily altered and commonly contains inclusions of earlier‐crystallised minerals, in situ analysis is considered the most suitable method to measure its U‐Th‐Pb and Sr‐Nd isotopic compositions. Electron probe microanalysis and laser ablation (multi‐collector) inductively coupled plasma‐mass spectrometry of forty‐six bastnäsite samples from LREE deposits in China, Pakistan, Sweden, Mongolia, USA, Malawi and Madagascar indicate that this mineral typically has high Th and LREE and moderate U and Sr contents. Analysis of an in‐house bastnäsite reference material (K‐9) demonstrated that precise and accurate U‐Th‐Pb ages could be obtained after common Pb correction. Moreover, the Th‐Pb age with its high precision is preferable to the U‐Pb age because most bastnäsites have relatively high Th rather than U contents. These results will have significant implications for understanding the genesis of endogenous ore deposits and formation processes related to metallogenic geochronology research.  相似文献   

Basaltic and Solution Reference Materials for Iron,Copper and Zinc Isotope Measurements     

Jin Li  Suo‐han Tang  Xiang‐kun Zhu  Zhi‐hong Li  Shi‐Zhen Li  Bin Yan  Yue Wang  Jian Sun  Yao Shi  Aiguo Dong  Nick S. Belshaw  Xingchao Zhang  Sheng‐ao Liu  Ji‐hua Liu  Deli Wang  Shao‐yong Jiang  KeJun Hou  Anthony S. Cohen 《Geostandards and Geoanalytical Research》2019,43(1):163-175

Iron, Cu and Zn stable isotope systems are applied in constraining a variety of geochemical and environmental processes. Secondary reference materials have been developed by the Institute of Geology, Chinese Academy of Geological Sciences (CAGS), in collaboration with other participating laboratories, comprising three solutions (CAGS‐Fe, CAGS‐Cu and CAGS‐Zn) and one basalt (CAGS‐Basalt). These materials exhibit sufficient homogeneity and stability for application in Fe, Cu and Zn isotopic ratio determinations. Reference values were determined by inter‐laboratory analytical comparisons involving up to eight participating laboratories employing MC‐ICP‐MS techniques, based on the unweighted means of submitted results. Isotopic compositions are reported in per mil notation, based on reference materials IRMM‐014 for Fe, NIST SRM 976 for Cu and IRMM‐3702 for Zn. Respective reference values of CAGS‐Fe, CAGS‐Cu and CAGS‐Zn solutions are as follows: δ⁵⁶Fe = 0.83 ± 0.07 and δ⁵⁷Fe = 1.20 ± 0.13, δ⁶⁵Cu = 0.57 ± 0.06, and δ⁶⁶Zn = ?0.79 ± 0.12 and δ⁶⁸Zn = ?1.65 ± 0.24, respectively. Those of CAGS‐Basalt are δ⁵⁶Fe = 0.15 ± 0.07, δ⁵⁷Fe = 0.22 ± 0.10, δ⁶⁵Cu = 0.12 ± 0.08, δ⁶⁶Zn = 0.17 ± 0.13, and δ⁶⁸Zn = 0.34 ± 0.26 (2s).  相似文献   

Identifying parameters of advanced soil models using an enhanced transitional Markov chain Monte Carlo method     

Jin  Yin-Fu  Yin  Zhen-Yu  Zhou  Wan-Huan  Horpibulsuk  Suksun 《Acta Geotechnica》2019,14(6):1925-1947

Acta Geotechnica - Parameter identification using Bayesian approach with Markov Chain Monte Carlo (MCMC) has been verified only for certain conventional simple constitutive models up to now. This...  相似文献   

基于伪随机信号的磁电法渗漏模型试验     

张化鹏  钱卫  刘瑾  武立林  宋泽卓 《物探与化探》2022,(1):198-205

磁电法是近些年在国内兴起的一种电磁勘探方法,该方法在探测地下渗流等长走向的良导地质体方面具有技术优势,但是其抗干扰能力差,易受外部噪声影响,一直未能推广.近年来,伪随机信号在物探领域开始广泛应用,该技术通过对冲激响应及阶跃响应进行卷积运算来达到降噪目的 ,可极大地提升抗干扰能力,因此,本文结合磁电法的勘探原理及伪随机辨...  相似文献   

双基雷达联合探测降水廓线的研究     

金鑫  朱元竞  王振会 《气候与环境研究》2001,6(2):191-196

利用1998年淮河流域能量和水循环试验(HUBEX)中的一次地面雷达与星载雷达(简称为双基雷达)联合探测雨强的资料,比较了现有的几种测雨雷达回波衰减订正方法.选取了一条比较有代表性的降水廓线,利用地基雷达数据对其进行衰减订正.结果表明,在雨区的中上部,星载雷达探测效果优于地基雷达;从"零度层亮带”往下至近地面,地基雷达探测效果优于星载雷达.  相似文献   

影响南海夏季风爆发因子的诊断研究   总被引：10，自引：0，他引：10  

陈隽  金祖辉 《气候与环境研究》2001,6(1):19-32

通过南海夏季风爆发偏早年和偏晚年前期冬春季东亚地区的环流、积雪及海温等要素特征的诊断分析,揭示了南海夏季风爆发时间早晚与前期冬季东亚大气环流、热带对流、热源及热带太平洋海温的异常分布有密切联系,南海夏季风爆发偏早年的前期有冬季风偏强,高原积雪偏少,海洋大陆地区的对流活跃、热源增强及LaNina型海温分布等主要特征;南海夏季风爆发偏晚年的前期特征则基本相反。根据1997～1998年冬春环流、积雪及海温等的特征作了1998年南海夏季风爆发时间的预测,其结果与1998年的实况基本一致。  相似文献   

我国西北地区21世纪季节气候变化情景分析   总被引：36，自引：2，他引：34  

徐影  丁一汇  赵宗慈  张锦 《气候与环境研究》2003,8(1):19-25

使用各国政府间气候变化专门委员会(IPCC)数据分发中心提供的7个全球海气耦合气候系统模式(CCC、CCSR、CSIRO、DKRZ、GFDL、HADL、NCAR)的模拟结果,对我国西北地区未来21世纪考虑温室气体增加(GG)和温室气体与硫化物气溶胶共同影响(GS)时,冬夏季的气候变化情景进行了分析.模式集成结果分析表明,我国西北地区的变暖趋势与全球、东亚和中国一致,但变暖幅度明显高于全球、东亚和中国.对未来100年各个季节线性倾向的分析表明,西北地区GG和GS时都是冬季变暖最大,可高达5～8℃/100a,且整个西北地区中新疆地区为最大变暖区.21世纪由于人类活动,西北地区最低温度和最高温度都将明显升高,其线性趋势可达4～6℃/100 a.由于全球气候模式对区域尺度的模拟存在较大的不确定性,未来需要作更多的深入研究.  相似文献   

冀东秦家峪中元古界高于庄组锰矿成因: 来自矿物学和地球化学的制约          下载免费PDF全文

靳松  马鹏飞  郭华  余文超  许灵通  林茜 《地球科学》2022,47(1):277-289

冀东秦家峪锰矿赋存于中元古界蓟县系高于庄组二段底部含锰岩系内,其成因尚不明确.以秦家峪锰矿ZK58-2钻孔样品为研究对象,通过显微薄片观察、电子探针分析及全岩地球化学分析等方法,探讨了高于庄组锰矿的锰质来源和沉积环境对成矿的贡献.显微薄片观察、电子探针分析表明,原生矿带中含锰矿物主要为菱锰矿、铁镁菱锰矿、钙菱锰矿、锰方...  相似文献   

Geological characteristics of the Qiaoyue Seamount and associated ultramafic-hosted seafloor hydrothermal system (～52.1°E,Southwest Indian Ridge)     

Yongjin Huang  Chunhui Tao  Jin Liang  Shili Liao  Yuan Wang  Dong Chen  Weifang Yang 《海洋学报(英文版)》2021,40(11):138-146

Hydrothermal vent incidence was once thought to be proportional to the spreading rate of the mid-ocean ridges (MORs). However, more and more studies have shown that the ultraslow-spreading ridges (e.g., Southwest Indian Ridge (SWIR)) have a relatively higher incidence of hydrothermal venting fields. The Qiaoyue Seamount (52.1°E) is located at the southern side of segment #25 of the SWIR, to the west of the Gallieni transform fault. The Chinese Dayang cruises conducted eight preliminary deep-towed surveys of hydrothermal activity in the area during 2009 and 2018. Here, through comprehensive analyses of the video and photos obtained by the deep-towed platforms, rock samples, and water column turbidity anomalies, a high-temperature, ultramafic-hosted hydrothermal system is predicted on the northern flank of the Qiaoyue Seamount. We propose that this hydrothermal system is most likely to be driven by gabboric intrusions. Efficient hydrothermal circulation channels appear against a backdrop of high rock permeability related to the detachment fault.  相似文献   

Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study     

Jin Liao  Chaoyong Hu  Xiuli Li  Jiaoyang Ruan 《水文研究》2021,35(4):e14163

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献