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71.
Two-dimensional analytical elastic models are developed for evaluating dynamic characteristics, namely natural frequencies and modes of vibration of a wide class of earth dams in a direction parallel to the dam axis. In these models the non-homogeneity of the dam materials is taken into account by assuming a specific variation of the stiffness properties along the depth (due to the continuous increase in confining pressure). In addition, both shear and normal (axial) deformations are considered. Cases having constant elastic moduli, linear and trapezoidal variations of elastic moduli, and elastic moduli increasing as the one-half, one-third, two fifths, and a general (l/m)th powers of the depth are studied. Dynamic properties of three real earth dams in a seismically active area (Southern California) estimated from their earthquake records (input ground motion and crest response in the longitudinal direction) as well as results from full-scale dynamic tests on one of these dams (including ambient and forced vibration tests) are compared with those from the suggested models. It was found that the models in which the shear modulus and the modulus of elasticity of the dam material vary along the depth are the most appropriate representations for predicting the dynamic characteristics. The agreement between the experimental and earthquake data and the theoretical results from some of the models is reasonably good.  相似文献   
72.
The electrocatalytic activity of galena, pyrite and Co3S4 for oxygen reduction has been studied by potentiostatic methods. Open circuit potentials of the sulphide electrodes have also been measured as a function of pH in nitrogen, air and oxygen atmospheres and also in the presence of H2O2 and ethyl xanthate. The adsorption of xanthate on sulphides was followed by observing bubble attachment to the electrodes.The catalytic activity for oxygen (or H2O2) reduction (the cathodic currents), the electrode potentials and the xanthate adsorption as shown by bubble attachment within certain pH limits, all varied as Co3S4 > pyrite (≈ PbS in H2O2) ? PbS indicating considerable dependence of the redox processes in flotation on the d - electron character of the sulphides.In the absence of oxygen, xanthate is probably bonded to the water structure of the surface through hydrogen-bonding, thus keeping the surface hydrophilic. Such adsorption reduces the electrode potential and inhibits oxygen reduction.  相似文献   
73.
Fe-Cr-Ni particles and veinlets have been discovered in the top 15 m of the compressed zone with abundant shatter cones below the bottom of the Ries crater. The metallic particles are less than a few microns across. They occur in various minerals along healed intergranular and locally in intragranular microfractures in quartz diorite, amphibolite and chloritized granite of the basement crystalline rocks.The particles consist of major Fe, Cr, and Ni with minor Si and Ca. Origin due to contamination is absolutely ruled out. We believe that these Fe-Cr-Ni particles are probably condensed from the vaporized impacting body which produced the Ries crater. These particles were injected with high velocity into microfractures near the top of the compressed zone, implanted in and across various minerals before these microfractures were resealed. The presence of Si and Ca as well as the fact that the Cr content is nearly twice that of Ni, led us to conclude that the Ries impacting body is very likely not an iron meteorite but a stony meteorite.  相似文献   
74.
75.
The role of intellectual property rights (IPRs) in the development and transfer of climate change technologies has been a contentious issue in negotiations under the United Nations Framework Convention on Climate Change (UNFCCC). Irreconcilable differences seem to oppose those who believe IPRs are an inherent barrier to the transfer of climate change technologies and those who argue they are an essential incentive to innovation. After providing an overview of the polarized debate on this issue, this article reviews the existing literature and empirical evidence and looks into some practical initiatives and recent developments. Finally, it seeks to identify a way forward that could help overcome the current stalemate in international deliberations by suggesting a number of parameters to structure the discussion on this complex issue.  相似文献   
76.
77.
Abstract– The oxygen fugacities recorded in the nakhlites Nakhla, Yamato‐000593 (Y‐000593), Lafayette, and NWA998 were studied by applying the Fe,Ti‐oxide oxybarometer. Oxygen fugacities obtained cluster closely around the FMQ (Fayalite–Magnetite–Quartz) buffer (NWA998 = FMQ ? 0.8; Y‐000593 = FMQ ? 0.7; Nakhla = FMQ; Lafayette = FMQ + 0.1). The corresponding equilibration temperatures are 810 °C for Nakhla and Y‐000593, 780 °C for Lafayette and 710 °C for NWA998. All nakhlites record oxygen fugacities significantly higher and with a tighter range than those determined for Martian basalts, i.e., shergottites whose oxygen fugacities vary from FMQ ? 1 to FMQ ? 4. It has been known for some time that nakhlites are different from other Martian meteorites in chemistry, mineralogy, and crystallization age. The present study adds oxygen fugacity to this list of differences. The comparatively large variation in fO2 recorded by shergottites was interpreted by Herd et al. (2002) as reflecting variable degrees of contamination with crustal fluids that would also carry a light rare earth element (REE)‐enriched component. The high oxygen fugacities and the large light REE enrichment of nakhlites fit qualitatively in this model. In detail, however, it is found that the inferred contaminating phase in nakhlites must have been different from those in shergottites. This is supported by unique 182W/184W and 142Nd/144Nd ratios in nakhlites, which are distinct from other Martian meteorites. It is likely that the differences in fO2 between nakhlites and other Martian meteorites were established very early in the history of Mars. Parental trace element rich and trace element poor regions (reservoirs) of Mars mantle ( Brandon et al. 2000 ) must have been kept isolated throughout Martian history. Our results further show significant differences in closure temperature among the different nakhlites. The observed range in equilibration temperatures together with similar fO2 values is attributable to crystallization of nakhlites in the same cumulate pile or lava layer at different burial depths from 0.5 to 30 m below the Martian surface in agreement with Mikouchi et al. (2003) and is further confirmed by similar crystallization ages of about 1.3 Ga ago (e.g., Misawa et al. 2003 ).  相似文献   
78.
Late Archaean Supracrustals of the Goa-Dharwar sector (GDS) are composed of a thick sequence of greywacke sequence with narrow intercalations of quartzite, BIF and carbonates. Mafic volcanics occupy the base of the sequence. The greywackes are predominantly tuffacious containing chlorite-sericite and hornblende. Arkosic variations containing biotite dominate the western part of the sector. Fine-grained variations occur as isolated narrow lenses within other types of greywackes. The conglomeratic greywackes are localized along the western and the eastern margins of the sector. All of the greywackes are all typically immature containing coarser clasts of mostly plagioclase (18–23%) and quartz (32–34%). Lithic fragments of felsic volcanic rocks are common. The matrix is dominated by mafic material. Biotite and amphibole are related to metamorphic recrystallization. Chlorite, sericite, epidote, carbonate and chert are products of the interplay of diagenesis and low-grade metamorphism. Fe-Ti oxide, sphene, apatite and zircon are usual accessories. But for slight enrichment in K2O, the major element chemistry of the GDS greywackes is similar to the chemistry of Late Archaean greywackes. They also compare in respect of V, Co, Hf contents, K2O/Na2O, SiO2/Al2O3, Na2O/Al2O3, Ba/Rb, Th/U, La/Th, Sm/Nd ratios, steep REE patterns with distinct LREE enrichment and HREE depletion. The GDS greywackes however are distinctly enriched in Rb, Ba, Sr, Th, U, Cu, Zr, Ce/Ce* and depleted in Cr, Ni, and Zn. The conglomeritic and biotite bearing verities contain considerable proportions of clasts derived from the basement tonalitic/granitic terrain. The common tuffacious greywackes containing hornblende and biotite-sericite however include only volcanic clasts and bear evidence of derivation from submarine weathering of predominantly felsic volcanics erupted on a large scale to form a magmatic arc in the later stages of geosynclinal deposition. Geochemical data suggest that the GDS greywackes were laid down in progressively changing basin geometry from a passive to active continental margin and island arc setting.  相似文献   
79.
The stable isotopes of oxygen and hydrogen have been implemented to assess the recharge mechanisms in an area in the UAE bounded to the northwestern part of the Gulf of Oman and the southeastern part of the Arabian Gulf. The conversion of stable isotopes to deuterium excess was utilized as a supportive tool to understand the process of groundwater recharge. The concluding results of this study showed that the origin of moisture is the Mediterranean Sea. The precipitation is the main source of recharge, in which the precipitation having undergone evaporation before recharge occurs. The comparison between regression line for data collected in 1996 and regression line for samples collected in 2006 suggests that the precipitation water which recharged the groundwater, was diluted with groundwater and this dilution is observed from decreasing of the deuterium excess of collected groundwater samples with increasing isotopes of oxygen. The dilution of groundwater with the recharge water suggests modern-day recharge as it is seen from high deuterium excess that exceeded the deuterium excess of LMWL and was close to MMWL.  相似文献   
80.
Metabasites were sampled from rock series of the subducted margin of the Indian Plate, the so-called Higher Himalayan Crystalline, in the Upper Kaghan Valley, Pakistan. These vary from corona dolerites, cropping out around Saif-ul-Muluk in the south, to coesite–eclogite close to the suture zone against rocks of the Kohistan arc in the north. Bulk rock major- and trace- element chemistry reveals essentially a single protolith as the source for five different eclogite types, which differ in fabric, modal mineralogy as well as in mineral chemistry. The study of newly-collected samples reveals coesite (confirmed by in situ Raman spectroscopy) in both garnet and omphacite. All eclogites show growth of amphiboles during exhumation. Within some coesite-bearing eclogites the presence of glaucophane cores to barroisite is noted whereas in most samples porphyroblastic sodic–calcic amphiboles are rimmed by more aluminous calcic amphibole (pargasite, tschermakite, and edenite). Eclogite facies rutile is replaced by ilmenite which itself is commonly surrounded by titanite. In addition, some eclogite bodies show leucocratic segregations containing phengite, quartz, zoisite and/or kyanite. The important implication is that the complex exhumation path shows stages of initial cooling during decompression (formation of glaucophane) followed by reheating: a very similar situation to that reported for the coesite-bearing eclogite series of the Tso Morari massif, India, 450 km to the south-east.  相似文献   
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