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51.
Nadia Curetti Davide Levy Alessandro Pavese Gabriella Ivaldi 《Physics and Chemistry of Minerals》2006,32(10):670-678
The elastic properties of coexisting natural 3T and 2M
1 phengite samples (Cima Pal, Sesia Zone; Val Savenca; Western Alps, Italy) with similar chemical compositions have been studied by room temperature–high pressure powder diffraction, using synchrotron radiation on the ID9A beam-line at ESRF (Grenoble, France). The P–V curves have been modelled by the Birch–Murnaghan model; a third-order expansion fitted to the experimental data yields for 3T and 2M
1 K
0=60.4(±0.7) GPa, K′=5.79(±0.11) at V
0=703.8851 Å3, and K
0=57.3(±1.0) GPa, K′=6.97(±0.24) at V
0=938.8815 Å3, respectively. The relative stability of 3T vs. 2M
1 has been explored as a function of pressure and temperature in terms of configuration and deformation contributions to the Gibbs energy, using the elastic properties determined here and other thermodynamic parameters from earlier investigations. The results presented agree with the hypothesis of stability of the 3T polytype in the high pressure regime. 相似文献
52.
Sandro Fuzzi Maria Cristina Facchini Stefano Decesari Emanuela Matta Mihaiela Mircea 《Atmospheric Research》2002,64(1-4)
We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned. 相似文献
53.
The deformation pattern and the dynamics of the southern sector of the Aeolian archipelago are investigated. A study on the ground deformation, measured over the last 20 years in the trilateration geodetic network between the islands of Vulcano and Lipari, has been conducted. Analysis of the relative displacements and the uniform strain tensor parameters, as well as the comparison between areal dilatation and the vertical variations deduced by precise levelling, allow distinguishing different phases associated both with the regional dynamics and the local volcanic context of the area. These phases, however, appear to be closely interrelated. The analysis of the deformation pattern allows to constrain the predominance of a roughly E–W trending extension and a N–S contraction at a regional scale. This regime is consistent with right-lateral movements along a NW–SE striking fault system. 相似文献
54.
Traditional models of urban development are no longer adequate to describe current metropolitan transformations. These are
now at the centre of a debate concerning management and administration. In Italy, delays in resolving problems of urban and
metropolitan government, despite the legal framework provided by Law 142/90, have weighed heavily on the larger urban areas
of the country: Rome, Naples, Milan, which have not been able to tackle the issue of metropolitan government. Recent legislation,
while not providing a pre-defined institutional solution, allows separate administrative districts to collectively establish
metropolitan institutions of `variable geometry'. The Milan urban area is not one city, but a system of mutually-dependent
cities, linked to each other and the rest of the world by a transport network still requiring much investment. The vitality
of its economic structure (especially its small firms) is held back by seriously inadequate infrastructure and low external
economic efficiency. The provincial capital may boast `historic centrality' but the most interesting potential for development
is to be found on the periphery and in the administrative districts immediately surrounding it, in the recovery of derelict
industrial areas and dormitory towns established in the 1950s and 1960s, especially to the north. Recovery of derelict areas,
green areas, and better transport links within the urban area and with the outside world are the key elements in the reorganization
of `Greater Milan'. In this situation of rapid transformation the most appropriate political strategies involve negotiated
planning.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
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We present results of laboratory experiments to study the behavior of liquids moving in unsaturated wide-aperture fractures. A 5-mm-thick glass plate cut with a 1.7-mm aperture was used as a fractured rock analog to study behavior of film and capillary droplet flow modes. Flow rates ranged between 0.6 and 6.0 ml/min. Variability in the ambient barometric pressure, resulting from weather conditions, seemed to play a role in the natural selection of flow mode. For droplet mode, constant input conditions resulted in highly variable transport properties within the fracture. The advancing meniscus exhibited a dynamic contact angle that was a function of the droplet speed and much larger than the static contact angle. Flow rate was reduced due to the larger contact angle. Analytical expressions for droplet velocity and flow capacity are presented as a function of the dynamic rather than the static contact angle. 相似文献
60.