Trace element compositions of jadeite (+omphacite) in jadeitites from the Itoigawa-Ohmi district, Japan: Implications for fluid processes in subduction zones   总被引：3，自引：0，他引：3  

Tomoaki  Morishita  Shoji  Arai  Yoshito  Ishida 《Island Arc》2007,16(1):40-56

Abstract   Trace-element compositions of jadeite (±omphacite) in jadeitites from the Itoigawa-Ohmi district of Japan, analyzed by a laser-ablation inductively coupled plasma mass spectrometry technique showed chemical zoning within individual grains and variations within each sample and between different samples. Primitive mantle-normalized patterns of jadeite in the samples generally showed high large-ion lithophile element contents, high light rare earth element/heavy rare earth element ratios and positive anomalies of high field strength elements. The studied jadeitites have no signatures of the protolith texture or mineralogy. Shapes and distributions of minerals coupled with chemical zoning within grains suggest that the jadeitites were formed by direct precipitation of minerals from aqueous fluids or complete metasomatic modification of the precursor rocks by fluids. In either case, the geochemical characteristics of jadeite are highly affected by fluids enriched in both large-ion lithophile elements and high field strength elements. The specific fluids responsible for the formation of jadeitites are related to serpentinization by slab-derived fluids in subduction zones. This process is followed by dissolving high field strength elements in the subducting crust as the fluids continue to circulate into the subducting crusts and serpentinized peridotites. The fluids have variations in chemical compositions corresponding to various degrees of water–rock interactions.  相似文献   

Statistical empirical index of chemical weathering in igneous rocks: A new tool for evaluating the degree of weathering   总被引：6，自引：0，他引：6  

Tohru Ohta  Hiroyoshi Arai 《Chemical Geology》2007,240(3-4):280-297

Chemical weathering indices are useful tools in characterizing weathering profiles and determining the extent of weathering. However, the predictive performance of the conventional indices is critically dependent on the composition of the unweathered parent rock. To overcome this limitation, the present paper introduces an alternative statistical empirical index of chemical weathering that is extracted by the principal component analysis (PCA) of a large dataset derived from unweathered igneous rocks and their weathering profiles. The PCA analysis yields two principal components (PC1 and PC2), which capture 39.23% and 35.17% of total variability, respectively. The extent of weathering is reflected by variation along PC1, primarily due to the loss of Na₂O and CaO during weathering. In contrast, PC2 is the direction along which the projections of unweathered felsic, intermediate and mafic igneous rocks appear to be best discriminated; therefore, PC1 and PC2 represent independent latent variables that correspond to the extent of weathering and the chemistry of the unweathered parent rock. Subsequently, PC1 and PC2 were then mapped onto a ternary diagram (MFW diagram). The M and F vertices characterize mafic and felsic rock source, respectively, while the W vertex identifies the degree of weathering of these sources, independent of the chemistry of the unweathered parent rock.

The W index has a number of significant properties that are not found in conventional weathering indices. First, the W index is sensitive to chemical changes that occur during weathering because it is based on eight major oxides, whereas most conventional indices are defined by between two and four oxides. Second, the W index provides robust results even for highly weathered sesquioxide-rich samples. Third, the W index is applicable to a wide range of felsic, intermediate and mafic igneous rock types. Finally, the MFW diagram is expected to facilitate provenance analysis of sedimentary rocks by identifying their weathering trends and thereby enabling a backward estimate of the composition of the unweathered source rock.  相似文献   

Application of laser ablation ICPMS to trace the environmental history of chum salmon Oncorhynchus keta     

Arai T  Hirata T  Takagi Y 《Marine environmental research》2007,63(1):55-66

Trace element levels in otoliths of chum salmon Oncorhynchus keta were examined by means of laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). A close linear relationship in the Sr:Ca ratios between EPMA (X-ray analysis with an electron microprobe) and LA-ICPMS analyses was found (p<0.0001), suggesting that the latter technique could be used to separate the marine and freshwater life phases. Mg:Ca, Cr:Ca, Zn:Ca and Ba:Ca ratios in either the core region or the oceanic growth zone of the otoliths varied among sites. These differences suggest that elemental compositions may reflect environmental variability among spawning (breeding) or habitat sites. Thus, those element ratios demonstrate the potential to be used to distinguish between fish spawning (breeding) sites and habitats for this species of salmon.  相似文献   

Hydrous peridotites with Ti-rich chromian spinel as a low-temperature forearc mantle facies: evidence from the Happo-O’ne metaperidotites (Japan)   总被引：1，自引：0，他引：1  

Mohamed Zaki Khedr  Shoji Arai 《Contributions to Mineralogy and Petrology》2010,159(2):137-157

The Happo-O’ne peridotite complex is situated in the northeastern part of the Hida Marginal Tectonic Zone, central Japan, characterized by the high-P/T Renge metamorphism, and is considered as a serpentinite mélange of Paleozoic age. Peridotitic rocks, being massive or foliated, have been subjected to hydration and metamorphism. Their protoliths are mostly lherzolites to harzburgites with subordinate dunites. We found a characteristic mineral assemblage, olivine + orthopyroxene + tremolite + chlorite + chromian spinel, being stable at low-T, from 650 to 750°C, and high-P, from 16 to 20 kbar, tremolite–chlorite peridotites of the tremolite zone. Olivines are Fo₈₈–Fo_91, and orthopyroxenes (Mg# = 0.91) show low and homogenous distributions of Al₂O₃ (up to 0.25 wt%), Cr₂O₃ (up to 0.25 wt%), CaO (up to 0.36 wt%) and TiO₂ (up to 0.06 wt%) due to the low equilibration temperature. Chromian spinels, which are euhedral and enclosed mainly in the orthopyroxenes, have high TiO_2, 3.1 wt% (up to 5.7 wt%) on average, and high Cr# [=Cr/(Cr + Al) atomic ratio], 0.95 on average but low Fe³⁺ [=Fe³⁺/(Cr + Al + Fe³⁺) atomic ratio, <0.3]. The bulk-rock chemistry shows that the Happo-O’ne metaperidotites with this peculiar spinel are low in TiO₂ (0.01–0.02 wt%), indicating no addition of TiO₂ from the outside source during the metamorphism; the high TiO₂ of the peculiar spinel has been accomplished by Ti release from Ti-bearing high-T pyroxenes during the formation of low-T, low-Ti silicates (<0.1 wt% TiO₂) during cooling. Some dunites are intact from hydration: their olivine is Fo₉₂ and spinel shows high Cr#, 0.72. The Happo-O’ne metaperidotites (tremolite–chlorite peridotites), being in the corner of the mantle wedge, are representative of a hydrous low-T, high-P mantle peridotite facies transitional from a higher T anhydrous peridotite facies (spinel peridotites) formed by in situ retrograde metamorphism influenced by fluids from the subducting slab. They have suffered from low-T (<600°C) retrogressive metamorphism to form antigorite and diopside during exhumation of the Renge metamorphic belt.  相似文献   

Eocene continental dyke swarm from Central Iran (Khur area)     

Ghodrat Torabi  Shoji Arai  Hamideh Abbasi 《Petrology》2014,22(6):617-632

The Eocene dyke swarm with east-west general trend intrudes the Cretaceous sedimentary rocks in ～25 km north of the Khur city (Central Iran). Some of the studied dykes can be followed for over 7 km, but the majority of exposures in the area are less than 5 km long. The dykes commonly exhibit a chilled contact with the wall rocks. These dykes are trachybasalt and basalt in composition. The trachybasalt dykes are much more abundant. The basaltic dykes cross cut the trachybasalt dykes in some locations, indicating that trachybasalt dykes are older than the basaltic ones. Primary igneous minerals of the basaltic dykes are olivine (chrysolite), clinopyroxene (diopside, augite), plagioclase (labradorite), sanidine, magnetite, orthopyroxene (enstatite), spinel and phlogopite, and secondary minerals are zeolite (natrolite and mesolite), chlorite (diabantite), calcite and serpentine. The trachybasalt dykes are composed of clinopyroxene (diopside), plagioclase (labradorite), sanidine, mica (biotite and phlogopite), amphibole (magnesio-hastingsite) and magnetite as primary minerals, and chlorite and calcite as secondary ones. Whole rocks geochemical data of the studied dykes indicate their basic and calc-alkaline nature and suggest that these two set of dykes were derived from the same parental magma. The chondrite-normalized REE patterns and the primitive mantle-normalized multi-elemental diagram of the Khur dykes show enrichment of light rare earth elements (LREE) relative to heavy rare earth elements (HREE), and negative anomalies of high field strength elements (HFSE) (e.g. Ti, Nb and Ta). These rocks show enrichment of the large ion lithophile elements (LILE) (e.g. Cs, Ba, Th and U) and depletion of the HREE and Y relative to MREE, Zr and Hf. In the chondrite-normalized REE diagram, the basalts show elevated REE abundances relative to the trachybasalt samples. Geochemical analyses of the studied samples suggest a spinel lherzolite from the mantle as the source rock and confirm the role of subduction in their generation. The chemical characteristics of the Khur dykes resemble those of continental arc rocks, and they were possibly formed by subduction of the Central-East Iranian microcontinent (CEIM) confining oceanic crust and decompression melting of a lithospheric subcontinental mantle spinel lherzolite enriched by subduction.  相似文献   

Podiform chromitite formation in a low-Cr/high-Al system: An example from the Southwest Indian Ridge (SWIR)   总被引：1，自引：0，他引：1  

Betchaida D. Payot  Shoji Arai  Henry J. B. Dick  Natsue Abe  Yuji Ichiyama 《Mineralogy and Petrology》2014,108(4):533-549

Recent reassessment of abyssal peridotites obtained during the dredging of the oblique supersegment and the easternmost subsection of the Southwest Indian Ridge by the R/V Knorr Cruise 162 and the R/V Yokosuka YK98-07 revealed the occurrence of dunites containing podiform chromitites and dunites with variable chromite concentration closely associated with lherzolite and harzburgite. The size of the chromitite pods varies from a few mm to 2 cm in width. Chromites in the podifom chromitites have very low Cr# (=0.22–0.23) and low TiO₂ (<0.17 wt%). They are almost free of silicate inclusions except for a few euhedral sulfide grains which occur far from cracks and lamellae and are considered primary in origin. The lherzolite which possibly represents the wallrock hosting the dunites with podiform chromitites also show low spinel Cr#(=0.16) and low Cr# in the clinopyroxenes (=0.09–0.10) and orthopyroxenes (=0.07–0.09). The small size of the SWIR podiform chromitites is strongly controlled by the low Cr/Al available in the wallrock and the invading melt. The presence of sulfide inclusions and the absence of PGEs further attest to the low Cr/Al (i.e. low refractoriness) in the system involved in the genesis of the SWIR podiform chromitites. Lastly, the discovery of podiform chromitites in the SWIR implies that the formation of podiform chromitite at mid-oceanic ridges, regardless of its spreading rate, is highly possible.  相似文献   

Fractionation of hydrogen isotopes during phytol biosynthesis     

Yoshito Chikaraishi  Ryouichi Tanaka  Ayumi Tanaka  Naohiko Ohkouchi 《Organic Geochemistry》2009,40(5):569-573

Deuterium (D) depletion in phytol relative to ambient water as well as other lipids has been widely observed in various biological and geological samples; however, the mechanism for the depletion remains unknown. We have determined the hydrogen isotopic compositions of phytol and its precursors in cucumber cotyledons and have evaluated the fractionation of hydrogen isotopes during phytol biosynthesis. The hydrogen isotopic compositions of geranylgeraniol, dihydrogeranylgeraniol, tetrahydrogeranylgeraniol and phytol are ?281‰, ?302‰, ?325‰ and ?345‰, respectively. The results suggest that significantly D-depleted hydrogen is incorporated stepwise during hydrogenation of geranylgeraniol to phytol. We conclude that hydrogenation is important in controlling D depletion in phytol.  相似文献   

Lower Oligocene Calc-Alkaline Spessartitic Lamprophyres from Central Iran (East of Anarak Area); an Evidence from the Eastern Branch of Neotethys Subduction-Related Mantle Enrichment     

Nazari  Gh. H.  Torabi  Gh.  Arai  Sh.  Morishita  T. 《Geotectonics》2019,53(6):786-805

Geotectonics - The Lower Oligocene Kal-e-kafi (East of Anarak, Central Iran) lamprophyres occur as stocks and dikes, which cross-cut the Eocene volcanic and Cretaceous sedimentary rocks. The...  相似文献   

Rural Social Networks along Amazonian Rivers: Seeds,Labor and Soccer among Communities on the Napo River,Peru          下载免费PDF全文

Christian Abizaid  Oliver T. Coomes  Yoshito Takasaki  J. Pablo Arroyo‐Mora 《Geographical review》2018,108(1):92-119

Research on Amazonian communities has focussed more often on rural‐urban linkages than on links among rural communities. This is unsurprising, given the low density of population, limited intercommunity commerce, and importance of direct city‐market relations. Social relations among rural communities are also important in shaping rural livelihoods and lifeways. We report on the findings of a large‐scale census of communities in the Napo River basin in northeastern Peru (n=174). Data were gathered on intervillage crop seed acquisition and cooperative labor sharing as two key inputs in agriculture, and on intervillage soccer matches, which are integral to rural social life. We analyze the socio‐spatial networks of each practice, paying attention to settlement patterns, community ethnicity, and differential access to the uplands. We find that seeds and labor flow along soccer network lines. Rural social networks appear to be structured strongly by ethnicity (homophily) and reflect important complementarities between upland and lowland communities (weak ties).  相似文献   

http://dx.doi.org/10.1016/j.gsf.2016.11.007   总被引：1，自引：1，他引：0  

Tatsuyuki Arai  Shigenori Maruyama 《地学前缘(英文版)》2017,8(2):299-308

Lunar anorthosite is a major rock of the lunar highlands,which formed as a result of plagioclasefloatation in the lunar magma ocean(LMO).Constraints on the sufficient conditions that resulted in the formation of a thick pure anorthosite(mode of plagioclase 95 vol.%) is a key to reveal the early magmatic evolution of the terrestrial planets.To form the pure lunar anorthosite,plagioclase should have separated from the magma ocean with low crystal fraction.Crystal networks of plagioclase and mafic minerals develop when the crystal fraction in the magma(φ) is higher than ca.40-60 vol.%,which inhibit the formation of pure anorthosite.In contrast,when φ is small,the magma ocean is highly turbulent,and plagioclase is likely to become entrained in the turbulent magma rather than separated from the melt.To determine the necessary conditions in which anorthosite forms from the LMO,this study adopted the energy criterion formulated by Solomatov.The composition of melt,temperature,and pressure when plagioclase crystallizes are constrained by using MELTS/pMELTS to calculate the density and viscosity of the melt.When plagioclase starts to crystallize,the Mg~# of melt becomes 0.59 at 1291 C.The density of the melt is smaller than that of plagioclase for P 2.1 kbar(ca.50 km deep),and the critical diameter of plagioclase to separate from the melt becomes larger than the typical crystal diameter of plagioclase(1.8-3 cm).This suggests that plagioclase is likely entrained in the LMO just after the plagioclase starts to crystallize.When the Mg~# of melt becomes 0.54 at 1263 C,the density of melt becomes larger than that of plagioclase even for 0 kbar.When the Mg~# of melt decreases down to 0.46 at 1218 C,the critical diameter of plagioclase to separate from the melt becomes 1.5-2.5 cm,which is nearly equal to the typical plagioclase of the lunar anorthosite.This suggests that plagioclase could separate from the melt.One of the differences between the Earth and the Moon is the presence of water.If the terrestrial magma ocean was saturated with H_2O,plagioclase could not crystallize,and anorthosite could not form.  相似文献