The effects of possible contamination by sample holders on samples to be returned by Hayabusa2     

Naoki Shirai  Yuzuru Karouji  Kazuya Kumagai  Masayuki Uesugi  Kaori Hirahara  Motoo Ito  Naotaka Tomioka  Kentaro Uesugi  Akira Yamaguchi  Naoya Imae  Takuji Ohigashi  Toru Yada  Masanao Abe 《Meteoritics & planetary science》2020,55(7):1665-1680

Chemical compositions of materials used for new sample holders (vertically aligned carbon nanotubes [VACNTs] and polyimide film), which were developed for the analysis of Hayabusa2‐return samples, were determined by instrumental neutron activation analysis and/or instrumental photon activation analysis, to estimate contamination effects from the sample holders. The synthetic quartz plate used for the sample holders was also analyzed. Ten elements (Na, Al, Cr, Mn, Fe, Ni, Eu, W, Au, and Th) and 14 elements (Na, Al, K, Sc, Ti, Cr, Zn, Ga, Br, Sb, La, Eu, Ir, and Au) could be detected in the VACNTs and polyimide film, respectively. The VACNT data show that contamination by this material with respect to the Murchison meteorite is negligible in terms of the elemental ratios (e.g., Fe/Mn, Na/Al, and Mn/Cr) used for the classification of meteorites due to the extremely low density of VACNTs. However, for the Au/Cr ratio, even small degrees (1.7 wt%) of contamination by VACNTs will change the Au/Cr ratio. Elemental ratios used for the classification of meteorites are only influenced by large amounts of contamination (>60 wt%) of polyimide film, which is unlikely to occur. In contrast, detectable effects on Ti isotopic compositions are caused by >0.1 and >0.3 wt% contamination by VACNTs and polyimide film, respectively, and Hf isotopic changes are caused by >0.1 wt% contamination by VACNTs. The new sample holders (VACNTs and polyimide film) are suitable for chemical classification of Hayabusa2‐return samples, because of their ease of use, applicability to multiple analytical instruments, and low contamination levels for most elements.  相似文献   

Theoretical and experimental investigation of nickel isotopic fractionation in species relevant to modern and ancient oceans     

Toshiyuki Fujii  Frédéric Moynier  Minori Abe 《Geochimica et cosmochimica acta》2011,75(2):469-7643

Nickel plays a central role as an enzyme co-factor in the metabolism of methanogenic Archaea. Methanogens can fractionate Ni isotopes during assimilation, opening the possibility of using the stable isotopic composition of Ni as a biomarker. However, other sources of Ni isotopic variations need to be evaluated before one can establish Ni isotopes as an unambiguous tracer of methanogenesis in the rock record. Equilibrium exchange of Ni between the different species present in the ocean is a potential source of isotopic fractionation. Through controlled laboratory experiments and theoretical calculations, we quantify equilibrium Ni isotope fractionation between different species relevant to the modern and ancient ocean: Ni(H₂O)₆²⁺, Ni(H₂O)₁₈²⁺, NiOH(H₂O)₅⁺, Ni(OH)₂(H₂O)₄, NiCl(H₂O)₅⁺, cis-NiCl₂(H₂O)₄, trans-NiCl₂(H₂O)₄, NiHS(H₂O)₅⁺, Ni(HS)₂(H₂O)₄, NiSO₄(H₂O)₄, NiHCO₃(H₂O)₄⁺, NiCO₃(H₂O)₄, and organic ligands (crown ether and oxalic acid). The magnitude of ligand-controlled Ni isotopic fractionation, approximately 1.25‰/amu (2.5‰ for the ⁶⁰Ni/⁵⁸Ni ratio), is similar to that previously measured in cultures of methanogenic Archaea.  相似文献   

Breaking Up: Comminution Mechanisms in Sheared Simulated Fault Gouge   总被引：1，自引：0，他引：1  

K. Mair  S. Abe 《Pure and Applied Geophysics》2011,168(12):2277-2288

The microstructural state and evolution of fault gouge has important implications for the mechanical behaviour, and hence the seismic slip potential of faults. We use 3D discrete element (DEM) simulations to investigate the fragmentation processes operating in fault gouge during shear. Our granular fault gouge models consist of aggregate grains, each composed of several thousand spherical particles stuck together with breakable elastic bonds. The aggregate grains are confined between two blocks of solid material and sheared under a given normal stress. During shear, the grains can fragment in a somewhat realistic way leading to an evolution of grain size, grain shape and overall texture. The ‘breaking up’ of the fault gouge is driven by two distinct comminution mechanisms: grain abrasion and grain splitting. The relative importance of the two mechanisms depends on applied normal stress, boundary wall roughness and accumulated shear strain. If normal stress is sufficiently high, grain splitting contributes significantly to comminution, particularly in the initial stages of the simulations. In contrast, grain abrasion is the dominant mechanism operating in simulations carried out at lower normal stress and is also the main fragmentation mechanism during the later stages of all simulations. Rough boundaries promote relatively more grain splitting whereas smooth boundaries favor grain abrasion. Grain splitting (plus accompanying abrasion) appears to be an efficient mechanism for reducing the mean grain size of the gouge debris and leads rapidly to a power law size distribution with an exponent that increases with strain. Grain abrasion (acting alone) is an effective way to generate excess fine grains and leads to a bimodal distribution of grain sizes. We suggest that these two distinct mechanisms would operate at different stages of a fault’s history. The resulting distributions in grain size and grain shape may significantly affect frictional strength and stability. Our results therefore have implications for the earthquake potential of seismically active faults with accumulations of gouge. They may also be relevant to the susceptibility of rockslides since non-cohesive basal shear zones will evolve in a similar way and potentially control the dynamics of the slide.  相似文献   

Under‐ice salinity and stable isotope distribution of Saroma‐ko Lagoon,Hokkaido, northern Japan     

Maki Morimoto  Kyoko Kawanobe  Osamu Abe  Takayoshi Kawai  Toshiyuki Kawamura  Kunio Shirasawa 《水文研究》2010,24(7):904-916

In winter, lakes and lagoons at high altitudes or high latitudes have interesting hydrological cycles that differ from those in other seasons or in other regions, because water surfaces are covered with ice. Hydrological balances of lakes and lagoons are complex dynamic systems, and to elucidate them, isotopic tracers of water have been used as effective tools along with observations of precipitation, evaporation, inflows, and outflows. Here, to understand hydrological processes during freezing periods in the brackish Saroma‐ko Lagoon, Hokkaido, northern Japan, we examined horizontal and vertical distributions of salinity and isotope compositions of lagoon water and ice in 2005 and 2006. Horizontal and vertical gradients of salinity and isotope compositions were observed from the river mouth to the sea channel, and factors determining these distributions were considered. The mixing of freshwater and seawater and a freezing effect were presumed to be factors in relationships between salinity and isotopes and in relationships between surface waters and ice just above the water. A simple box model for water balance was constructed based on these putative factors to reproduce the distributions of salinity and isotope compositions of surface waters and ice. An evaluation of the model revealed that this hydrological system is controlled primarily by horizontal advection of the epilimnion, freshwater influx, and the ice growth rate. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Relationship between Cd and PO4 in the Subtropical Sea near the Ryukyu Islands     

Kazuo Abe 《Journal of Oceanography》2002,58(4):577-588

The relationship between dissolved cadmium (Cd) and phosphate (PO₄) was examined at three stations in the subtropical area near the Ryukyu Islands in May 1999. Preformed PO₄ was obtained using the Redfield ratio in order to separate the surface water and the other layers in this study area. Almost 0 μM (−0.043 μM to 0.094 μM) was estimated in the layers above 300 m and 250 m at Sts. 1 and 3 and at St. 2, respectively. Up to these depths, water was considered to be uniform, and these layers were defined as the surface water in this study area. In the surface water, the slopes of the regression lines of the Cd-PO₄ plot were 0.162, 0.156, and 0.226 (nM/μM) at Sts. 1, 2, and 3, respectively, and these values were much closer to the estimated regenerated ratio of Cd to PO₄ from the Apparent Oxygen Utilization (AOU)-Cd/PO₄ plots, which was 0.197 (nM/μM) in this study area. Below surface layers, the slopes of the Cd-PO₄ plot changed to 0.371, 0.352, and 0.362 (nM//μM) at Sts. 1, 2, and 3, respectively. In the relationships between Cd and PO₄, clear deviations or kinks were observed at three stations at a PO₄ concentration of approximately 0.2 μM in the plot, which was attributable to the discontinuity of surface water and the other layers across the North Pacific subtropical mode water. In studies of the interaction between surface water and biogenic particles concerning the Cd/PO₄ ratio, separate analyses of seawater (surface water and the other layers) should be carried out to obtain the individual surface water ratio because the Cd/PO₄ ratio in the surface water is expected to differ from that of the underlying water. Furthermore, the biological fractionation of these constituents is based on the surface water ratio. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Bacteria on petroleum globules in the Philippine sea in January, 1973     

Humitake Seki  Hideshi Abe  Yukuya Yamaguchi  Shun-ei Ichimura 《Journal of Oceanography》1974,30(3):151-156

About 10⁶ of total bacteria (direct microscopic count) or heterotrophic bacteria (colony count with Medium 2216E) and about 10⁴ of petroleumlytic bacteria (oil-oxidizing bacteria) were enumerated per square centimeter of the surface of petroleum globules suspended in the topmost 10 meters of water from a station (22°00.2N, 125°51.9E) in the western North Pacific central water, where about 10⁷ of total bacteria, about 10³ of heterotrophic bacteria and about 10 of petroleumlytic bacteria were enumerated per liter of seawater.  相似文献   

Lower Cd/P ratio in settling particles than in surface seawater in the Okinawa Trough     

Kazuo Abe  Kazuo Iseki  Kazumaro Okamura  Yoko Kiyomoto 《Journal of Oceanography》2006,62(5):745-752

The characteristics of the ratios between cadmium (Cd) and phosphorus (P) in settling particles collected from the Okinawa Trough in the East China Sea were examined using a sediment trap, moored at a depth of 811 m for one year. The Cd/P ratios varied within a narrow range throughout the year, in spite of the large seasonal change in the total dry mass, Cd, and P fluxes. The average Cd/P ratio of settling particles was 0.062 (nmol/μmol), which was obviously lower than that of surface seawater around the study site (0.16). This lower ratio in the Okinawa Trough particles collected using the 811 m-moored trap certainly reflected the mixture of biologically produced organic matter around the study site and other components that were mainly transported as lateral flux from the shelf edge and slope area of the East China Sea.  相似文献   

Relationship between cadmium and phosphate in the northwest Pacific Ocean     

Katsuhiko Matsunaga  Kazuo Abe 《Journal of Oceanography》1985,41(3):193-197

The relationship between Cd and PO₄ in the Kuroshio and Oyashio regions and the Okhotsk Sea was examined. The resultant equations are as follows: Cd (ng l^–1)=37.0 PO₄ (M)+2.6; Cd(ng l^–1)=32.1 PO₄ (M)+1.2 and Cd (ng l^–1)=34.1 PO₄ (M)+7.9, respectively. These results are in good agreement with previously reported studies, and indicate that during removal from surface waters to deeper waters by biological assimilation and regeneration in deeper waters Cd and PO₄ maintain the same ratio in the open ocean. The relationship between Cd and PO₄ in coastal waters, however, differed from that in the open ocean.  相似文献   

Dissolution of silica accompanied by oxygen consumption in the bottom layer of Japan’s central Seto Inland Sea in summer     

Kazuo Abe  Norihisa Nakagawa  Katsuyuki Abo  Mutsumi Tsujino 《Journal of Oceanography》2014,70(3):267-276

Distribution of silicic acid (Si(OH)₄) in bottom water was investigated in the central Seto Inland Sea under stratified conditions in summer. Water samples were collected at 10 stations on April 24 and 25 and July 7 and 8, 2012. In July, stratification progressed, and a cold water mass (dome) of <20 °C appeared. In response to the cold dome, low oxygen content was observed in the bottom layer of the eastern part of Hiuchi-Nada. In this water mass site, apparent oxygen utilization values calculated from dissolved oxygen (DO) concentrations increased, coinciding with increase of Si(OH)₄ concentrations from April to July. This suggests that increase of Si(OH)₄ [dissolution of biogenic silica (diatom frustules)] was accompanied by DO consumption due to degradation of organic matter such as plankton soft tissue. These findings suggest that a bacterial degradation of the organic matrix that covers diatom frustules could accelerate the dissolution of biogenic silica in bottom water under stratified conditions.  相似文献   

Podiform chromitite formation in a low-Cr/high-Al system: An example from the Southwest Indian Ridge (SWIR)   总被引：1，自引：0，他引：1  

Betchaida D. Payot  Shoji Arai  Henry J. B. Dick  Natsue Abe  Yuji Ichiyama 《Mineralogy and Petrology》2014,108(4):533-549

Recent reassessment of abyssal peridotites obtained during the dredging of the oblique supersegment and the easternmost subsection of the Southwest Indian Ridge by the R/V Knorr Cruise 162 and the R/V Yokosuka YK98-07 revealed the occurrence of dunites containing podiform chromitites and dunites with variable chromite concentration closely associated with lherzolite and harzburgite. The size of the chromitite pods varies from a few mm to 2 cm in width. Chromites in the podifom chromitites have very low Cr# (=0.22–0.23) and low TiO₂ (<0.17 wt%). They are almost free of silicate inclusions except for a few euhedral sulfide grains which occur far from cracks and lamellae and are considered primary in origin. The lherzolite which possibly represents the wallrock hosting the dunites with podiform chromitites also show low spinel Cr#(=0.16) and low Cr# in the clinopyroxenes (=0.09–0.10) and orthopyroxenes (=0.07–0.09). The small size of the SWIR podiform chromitites is strongly controlled by the low Cr/Al available in the wallrock and the invading melt. The presence of sulfide inclusions and the absence of PGEs further attest to the low Cr/Al (i.e. low refractoriness) in the system involved in the genesis of the SWIR podiform chromitites. Lastly, the discovery of podiform chromitites in the SWIR implies that the formation of podiform chromitite at mid-oceanic ridges, regardless of its spreading rate, is highly possible.  相似文献