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11.
William J. Chazey III Clive R. Neal Jinesh C. Jain William S. Kinman 《Geostandards and Geoanalytical Research》2003,27(2):181-192
The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1). 相似文献
12.
Cathleen E. McGinnis Jinesh C. Jain Clive R. Neal 《Geostandards and Geoanalytical Research》1997,21(2):289-305
High sensitivity and low detection limits would seem to make inductively coupled plasma-mass spectrometry (ICP-MS) an ideal analytical tool for determining low (sub-μg g-1 ) concentrations of the rare earth elements (REE), Y, Zr, Nb, Hf, Ta, Sn, W, Mo, Th, and U in most mafic materials (e.g. Hall and Plant 1992). However, the generally "sticky" nature exhibited by most of the high field strength elements (HFSEs: Zr, Nb, Hf, Ta, Th and U) as well as Sn, W and Mo can result in spurious results due to memory effects transmitted between unknowns and calibration samples. This, in turn, can seriously compromise the sensitivity, accuracy, and precision of ICP-MS analyses for these elements in geological materials. Data resulting from analyses with poor accuracy and precision can lead to erroneous interpretation and misleading petrogenetic modelling. To resolve this problem, we propose an effective wash protocol for these critical trace elements. 相似文献
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Holocene prograded coastal sequences at Becher/Rockingham, southern Western Australia, contain a detailed record of sea level over the last 6400 yr. Radiocarbon dating and use of a distinct stratigraphic indicator as a sea-level marker permit reconstruction of sea-level history and suggest that the sea was at least 2.5 m above present datum about 6400 yr B.P. before falling to its present level. No evidence was found for eustatic fluctuations of the scale proposed by R. W. Fairbridge [1961, in “Physics and Chemistry of the Earth” (L. H. Ahrens, F. Press, K. Rankema, and S. K. Runcorn, Eds.), Vol. 4, pp. 99–185, Pergamon, Oxford]. The sea-level record preserved on this coast can be explained by hydro-isostasy, tectonism, or eustasy, acting individually or in concert. Without a fixed reference point or analogous data from other locations, a firm conclusion on which mechanism(s) has(have) operated could not be reached. Published sea-level data from this and other coasts are often insufficiently detailed to compare with this study. Application of the techniques of this study to analogous sedimentary sequences elsewhere will provide data of comparable accuracy that would contribute to a more precise understanding of relative sea-level movements in the late Quaternary. 相似文献
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We propose that the Pacific-Kula ridge began spreading approximately 85 m.y. B.P., during Late Cretaceous time. Extrapolation of the Great Magnetic Bight backwards in time results in an implausible ridge configuration. This implies that plate velocity vectors for the Pacific, Kula, and Farallon plates were not constant during this interval. Evidence for splitting of the Kula plate from the Pacific plate along the Chinook trough is the relationship between the north-striking Amlia and Adak fracture zones, the Chinook and Emperor troughs, and the magnetic lineations south of the Aleutian trench. If this hypothesis is correct, it will require that Mesozoic reconstructions of the Pacific basin and their relation to Cenozoic reconstructions be re-examined. A previously unrecognized Mesozoic plate may be required. We propose calling this the Izanagi plate. 相似文献
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The Tibesti massif, one of the most prominent features of the Sahara desert, covers an area of some 100,000 km2. Though largely absent from scientific inquiry for several decades, it is one of the world’s major volcanic provinces, and
a key example of continental hot spot volcanism. The intense activity of the TVP began as early as the Oligocene, though the
major products that mark its surface date from Lower Miocene to Quaternary (Furon (Geology of Africa. Oliver & Boyd, Edinburgh
(trans 1963, orig French 1960), pp 1–377, 1963)); Gourgaud and Vincent (J Volcanol Geotherm Res 129:261–290, 2004). We present here a new and consistent analysis of each of the main components of the Tibesti Volcanic Province (TVP), based
on examination of multispectral imagery and digital elevation data acquired from the Advanced Spaceborne Thermal Emission
and Reflection Radiometer (ASTER). Our synthesis of these individual surveys shows that the TVP is made up of several shield
volcanoes (up to 80 km diameter) with large-scale calderas, extensive lava plateaux and flow fields, widespread tephra deposits,
and a highly varied structural relief. We compare morphometric characteristics of the major TVP structures with other hot
spot volcanoes (the Hawaiian Islands, the Galápagos Islands, the Canary and Cape Verdes archipelagos, Jebel Marra (western
Sudan), and Martian volcanoes), and consider the implications of differing tectonic setting (continental versus oceanic),
the thickness and velocity of the lithosphere, the relative sizes of main volcanic features (e.g. summit calderas, steep slopes
at summit regions), and the extent and diversity of volcanic features. These comparisons reveal morphologic similarities between
volcanism in the Tibesti, the Galápagos, and Western Sudan but also some distinct features of the TVP. Additionally, we find
that a relatively haphazard spatial development of the TVP has occurred, with volcanism initially appearing in the Central
TVP and subsequently migrating to both the Eastern and Western TVP regions.
Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users. 相似文献