The role of sediments in the phosphorus cycle in Lake Lugano. I. Geochemical approach     

D. Span  J. Dominik  M. A. Lazzaretti  J. -P. Vernet 《Aquatic Sciences - Research Across Boundaries》1992,54(3-4):277-284

The bottom sediment from three coring stations in Lake Lugano (Lago di Lugano) show major differences in their role in the P-cycles related to their geochemistry and characteristics of sedimentation. In the northern basin, the deepest sediment may be considered practically inactive, due to a permanently reduced condition at the sediment-water interface. In the southern basin, the sediments are active with respect to P-recycling with strong seasonal variations. One of the sites (Figino) behaves as a sink for P due to a high iron content and an important rate of detrital sedimentation.  相似文献   

Time resolved simulation of lightning by lip     

Jebens DS  Lakkaraju HS  McKay CP  Borucki WJ 《Geophysical research letters》1992,19(3):273-276

In this letter, we report results of time resolved spectra of lightning simulation in air by laser-induced plasma (LIP). The measured electron temperatures varied from (1.7 +/- 0.1)X10(4) K at 600 ns to (1.2 +/- 0.1)X10(4)K at 4 microseconds after the ignition of the plasma. Electron densities in the plasma varied from (7.0 +/- 1.4)X10(17)/cm3 to (9.0 +/- 1.8)X10(16)/cm3 for the above times. We also present, for the first time, a comparison of state variables for LIP and natural lightning. We find that immediately following the ignition both natural lightning and LIP reach temperatures in excess of 16,000K and relax to ambient pressure with different rates. They are expected to approach 2000 - 4000 K temperature range, which is important to chemical synthesis, in an asymptotically similar fashion.  相似文献   

Periodicities in the time series of annual minimum temperatures for the United States Gulf Coast region     

R. P. Kane  D. Gobbi 《Pure and Applied Geophysics》1992,138(2):323-333

The minimum winter temperature series for the United States Gulf Coast for 1799–1988 (190 values) was subjected to Maximum Entropy Spectral Analysis. Significant periodicities in the QBO region (T-2–3 years) and atT=3.7, 4.5, 5.5, 6.5, 7.5, 12.9, 15.5 and 22 years were detected. Some of these were present in the first half only (1799–1893) while others in the latter half only (1894–1988), indicating a transient nature. Also, more than 50% of the variance was random. Many of the significant periodicities are seen in other geophysical parameters. Some may be harmonics of the 11-year sunspot cycle and the 22-year Hale magnetic sunspot cycle.  相似文献   

The influence of amphibole fractionation on the evolution of calc-alkaline andesite and dacite tephra from the central Aleutians,Alaska   总被引：3，自引：1，他引：2  

Jay D. Romick  Suzanne Mahlburg Kay  Robert W. Kay 《Contributions to Mineralogy and Petrology》1992,112(1):101-118

Petrologic studies of tephra from Kanaga, Adak, and Great Sitkin Islands indicate that amphibole fractionation and magma mixing are important processes controlling the composition of calc-alkaline andesite and dacite magmas in the central Aleutians. Amphibole is ubiquitous in tephra from Kanaga and Adak Islands, whereas it is present only in a basaltic-andesite pumice from Great Sitkin. Dacitic tephra from Great Sitkin do not contain amphibole. Hornblende dacite tephra contain HB+PLAG+OX±OPX±CPX phenocrysts with simple zoning patterns, suggesting that the dacites evolved in isolated magma chambers. Andesitic tephra from Adak contain two pyroxene and hornbelende populations, and reversely zoned plagioclase, indicating a more complex history involving mixing and fractional crystallization. Mass balance calculations suggest that the andesitic tephra may represent the complements of amphibole-bearing cumulate xenoliths, both formed during the evolution of high-Al basalts. The presence of amphibole in andesitic and dacitic tephra implies that Aleutian cale-alkaline magmas evolve in the mid to lower crust under hydrous (>4 wt.% H₂O) and oxidizing (Ni–NiO) conditions. Amphibole-bearing andesites and pyroxene-bearing dacites from Great Sitkin indicates fractionation at several levels within the arc crust. Despite its absence in many calc-alkaline andesite and dacite lavas, open system behavior involving amphibole fractionation can explain the trace element characteristies of lavas found on Adak Island. Neither open nor closed system fractionation involving a pyroxene-bearing assemblage is capable of explaining the trace element concentrations or ratios found in the Adak suite. We envision a scenario where amphibole was initially a liquidus phase in many calc-alkaline magmas, but was later replaced by pyroxenes as the magmas rose to shallow levels within the crust. The mineral assemblage in these evolved lavas reflects shallow level equilibration of the magma, whereas the trace element chemistry provides evidence for a earlier, amphibole-bearing, mineral assemblage.  相似文献   

Geological,fluid inclusion and stable isotope studies of Mo mineralization,Galway Granite,Ireland     

V. Gallagher  M. Feely  H. Högelsberger  G. R. T. Jenkin  A. E. Fallick 《Mineralium Deposita》1992,27(4):314-325

Mo mineralization within the Galway Granite at Mace Head and Murvey, Connemara, western Ireland, has many features of classic porphyry Mo deposits including a chemically evolved I-type granite host, associated K- and Si-rich alteration, quartz vein(Mace Head) and granite-hosted (Murvey) molybdenite, chalcopyrite, pyrite and magnetite mineralization and a gangue assemblage which includes quartz, muscovite and K-feldspar. Most fluid inclusions in quartz veins homogenize in the range 100–350°C and have a salinity of 1–13 eq. wt.% NaCl. They display Th-salinity covariation consistent with a hypothesis of dilution of magmatic water by influx of meteoric water. CO₂-bearing inclusions in an intensely mineralized vein at Mace Head provide an estimated minimum trapping temperature and pressure for the mineralizing fluid of 355°C and 1.2 kb and are interpreted to represent a H₂O-CO₂ fluid, weakly enriched in Mo, produced in a magma chamber by decompression-activated unmixing from a dense Mo-bearing NaCl-H₂O-CO₂ fluid. ³⁴S values of most sulphides range from c. 0 at Murvey to 3–4 at Mace Head and are consistent with a magmatic origin. Most quartz vein samples have ¹⁸O of 9–10.3 and were precipitated from a hydrothermal fluid with ¹⁸O of 4.6–6.7. Some have ¹⁸O of 6–7 and reflect introduction of meteoric water along vein margins. Quartz-muscovite oxygen isotope geothermometry combined with fluid inclusion data indicate precipitation of mineralized veins in the temperature range 360–450°C and between 1 and 2 kb. Whole rock granite samples display a clear ¹⁸O-D trend towards the composition of Connemara meteoric waters. The mineralization is interpreted as having been produced by highlyfractionated granite magma; meteoric water interaction postdates the main mineralizing event. The differences between the Mace Head and Murvey mineralizations reflect trapping of migrating mineralizing fluid in structural traps at Mace Head and precipitation of mineralization in the granite itself at Murvey.  相似文献   

The energetics of interaction between oxygen vacancies in sillimanite: A model for the mullite structure     

S. Padlewski  V. Heine  G. D. Price 《Physics and Chemistry of Minerals》1992,19(3):196-202

A microscopic model is introduced to discuss the modulated structure of mullite. The oxygen vacancies of this aluminosilicate are known to play a central role. In particular, a single vacancy strongly orders its surrounding Al/Si tetrahedral sites. It is shown in this work that if two oxygen vacancies approach too closely to one another, their Al/Si dressing overlap. This situation results in repulsive interaction. The field of interaction between the vacancies is estimated with the use of an atomistic computer simulation. We use a Bragg-Williams type of theory to dicuss the ordering pattern of the vacancies. Due to frustration between the two dominant repulsive interactions, our model predicts a modulated phase transition in agreement with observation.  相似文献   

Phase Relations of an Armalcolite-Phlogopite Lamproite from Smoky Butte, Montana: Applications to Lamproite Genesis   总被引：1，自引：0，他引：1  

EDGAR  A. D.; CHARBONNEAU  H. E.; MITCHELL  R. H. 《Journal of Petrology》1992,33(3):505-520

Suprasolidus phase relations at pressures from 8 to 30 kb andtemperatures from 950 to 1380C have been determined experimentallyfor a glassy armalcolite–phlogopite lamproite from thechilled margin of a medium–grained lamproite from SmokyButte, Montana: The armalcolite-phlogopite lamproite has microphenocrystsof olivine in a groundmass of phlogopite, sanidine, armalcolite,clinopyroxene, chromite, priderite, apatite, and abundant glass.The lamproite is SiO₂-rich and has high F/H₂O relative to lamproitesthat have been investigated in previous experimental studies.Our data show that with decreasing temperature from the liquidusat pressures above 12 kb, melt coexists successively with:olivine; orthopyroxene + clinopyroxene; orthopyroxene + clinopyroxene+ phlogopite; clinopyroxene +phlogopite; and clinopyroxene +orthopyroxene + K-richterite. Below 12 kb, the assemblage successionis: olivine; olivine + clinopyroxene; olivine + clinopyroxene+ phlogopite; and olivine +clinopyroxene + phlogopite + armalcolite.The main difference from the natural paragenesis is that therock does not contain any orthopyroxene—a feature thatis rather remarkable inasmuch as it has 16% normative hypersthene—andthe rock differs also in that it contains sanidine and priderite.In the experiments, sanidine is observed only as ghostlike domainsin some of the glass and appears to have formed during quenching. The solid phases crystallized experimentally are generally compositionallysimilar to the minerals in the rock. These similarities andthe experimental phase relations support the concept of a rapidinitial magma ascent with only a small temperature drop andcrystallization of olivine, but not of orthopyroxene. At lowerpressures, less than 12 kb, it appears that the magma ascendedmore slowly with a larger temperature drop suggested by thesimilarity of the experimentally determined sequence of assemblagesto the paragenesis of the rock. No quasi-invariant multiphase-saturation point was found suchas might be indicative of pressure and temperature conditionsfor formation of the lamproite magma by eutectic-type partialmelting of a mantle source. The occurrence of olivine, orthopyroxene,and clinopyroxene near the liquidus, and the high proportionof normative hypersthene in the melt suggest that lherzoliteor harzburgite was probable in the magma source rock. The highSiO₂ and MgO contents of the Smoky Butte lamproites may indicatethat orthopyroxene was a source mineral even though it did notcrystallize under near-surface conditions. The curve definingthe appearance of phlogopite appears at progressively lowertemperatures from the liquidus as pressure increases, so itwould appear that either phlogopite was not the mantle K-reservoir,or it was entirely consumed during the partial melting process.The composition of the near-liquidus glass in the experimentsis likely to be the composition of the bulk rock less the verysmall amounts of olivine + clinopyroxene + orthopyroxene crystallizedwithin a few degrees below the liquidus. From the inferred compositionof this glass, anhydrous phlogopite is a potential mineral.The principal variable that determines whether phlogopite crystallizesas a near-liquidus mineral is F/H₂O; low values of this ratiopromote the presence of phlogopite as a near-liquidus mineralwhereas high values deter its crystallization. The common practiceof adding H₂O but not F in experiments to compensate for degassingmay obscure the role of phlogopite in the evolution of lamproitemagmas.  相似文献   

Iron in Precambrian rocks: implications for the global oxygen budget of the ancient Earth     

Kump LR  Holland HD 《Geochimica et cosmochimica acta》1992,56(8):3217-3223

Banded iron formations (BIF) are prominent in sediments older than 2 Ga. However, little is known about the absolute abundance of BIF in Archean and Early Proterozoic sediments, and the source of the Fe is still somewhat uncertain. Also unknown is the role that Fe may have played in the maintenance of low oxygen pressures in the Archean and Early Proterozoic atmosphere. An analysis of the chemical composition of Precambrian rocks provides some insight into the role of Fe in Precambrian geochemical cycles. The Fe content of igneous rocks is well correlated with their Ti content. Plots of Fe vs. Ti in Precambrian sandstones and graywackes fall very close to the igneous rock trend. Plots of Fe vs. Ti in Precambrian shales also follow this trend but show a definite scatter toward an excess of Fe. Phanerozoic shales and sandstones lie essentially on the igneous rock trend and show surprisingly little scatter. Mn/Ti relations show a stronger indication of Precambrian Mn loss, perhaps due to weathering under a less oxidizing early atmosphere. These data show that Fe was neither substantially added to nor significantly redistributed in Archean and early Proterozoic sediments. Enough hydrothermal Fe was added to these sediments to increase the average Fe content of shales by at most a factor of 2. This enrichment would probably not have greatly affected the near-surface redox cycle or atmospheric oxygen levels. Continued redistribution of Fe and mixing with weathered igneous rocks during the recycling of Precambrian sediments account for the excellent correlation of Fe with Ti in Phanerozoic shales and for the similarity between their Fe/Ti ratio and that of igneous rocks.  相似文献   

Fluid-rock interaction in the Mo-bearing Nebelstein greisen complex,Bohemian Massif (Austria)     

F. Koller  H. Högelsberger  C. Köeber 《Mineralogy and Petrology》1992,45(3-4):261-276

Summary In the Nebelstein area, molybdenite-bearing greisens occur together with peraluminous leucogranites. In the compositional change of the granites to the greisens, there is an almost complete loss of Na, combined with a decrease in Ca, Mg, Sr, and Ti concentrations. The progressive alteration is reflected by lower homogenization temperatures and increasing salinity in aqueous fluid inclusions. The fluid regime prior to greisenization was water-dominated with low salt contents, while the early stage of the greisen development was characterized by a mixed fluid containing carbon dioxide and water. This was succeeded by a moderate saline aqueous fluid which caused the mineralization by exchange of metal ions for Na⁺(Ca²⁺, K⁺). A negative correlation between salt content in fluid inclusions and Na₂O concentrations in the bulk rocks supports this model. Mass balance calculations for this interaction yield a minimum fluid-rock ratio of approximately 2 : I. Greisenization took place at a minimum pressure of 180 MPa (1.8 kb) and in a temperature range between 200 and < 400 °C.

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Fluid-Gestein-Wechselwirkung in dem Molybdänit führenden Greisenkomplex Nebelstein, Böhmische Masse (Österreich)

Zusammenfassung Die Molybdänglanz führenden Greisengesteine des Nebelsteins sind an peraluminöse Granite gebunden. Bei der Alteration der Granite ist für den Übergang Biotitgranit zu Greisen eine weitestgehende Verarmung an Na zu beobachten, gleichzeitig nehmen auch die Gehalte an Ca, Mg, Sr und Ti ab. Die fortschreitende Greisenbildung dokumentiert sich in den wäßrigen Flüssigkeitseinschlüssen durch steigende Salinität bei sinkenden Homogenisierungstemperaturen. Die fluide Phase war vor der Greisenbildung H₂O dominiert und niedrig salinar. Der Beginn der Alterationsprozesse ist durch CO₂ und H₂O hältige Fluide gekennzeichnet. Danach folgt ein Anstieg der Salinität, der auf den Austausch von Metallchloridlösungen gegen Na⁺, K^- und Ca^2- zurückgeführt wird. Dies läßt sich durch eine negative Korrelation der Salinität in den Flüssigkeitseinschlüssen mit dem Na-Gehalt der Gesteine belegen. Daraus wurde die Volumsbeziehung der den Granit durchströmenden fluiden Phase relativ zum Gestein mit mindestens 2 : 1 abgeleitet. Die Mineralisation fand bei einem Minimaldruck von 1,8 kb in einem Temperaturbereich von 200 - < 400 °C statt.

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This paper was presented at the IGCP 291 Project Symposium Metamorphic Fluids and Mineral Deposits, ETH Zürich, March21–23,1991.  相似文献   

TREK: A cosmic-ray experiment on the Russian space station MIR     

P. B. Price  D. M. Lowder  A. J. Westphal  R. D. Wilkes  R. A. Brennen  V. G. Afanasyev  V. V. Akimov  V. G. Rodin  G. K. Baryshnikov  L. A. Gorshkov  N. I. Shvets  O. S. Tsigankov 《Astrophysics and Space Science》1992,197(1):121-143

The goals of the TREK experiment, now in place on the MIR Space Station, are to resolve and measure the composition of both odd-Z and even-Z cosmic-ray nuclei up to uranium, to measure the isotopic composition of Fe-group nuclei, and to search for transuranic nucleic and exotic particles such as strangelets. To collect tracks of ultraheavy cosmic rays, exterior panels holding an array of BP-1 phosphate glass 1.2m² in area and 16 plates thick are now mounted outside the Kvant-2 module on MIR. Heaters and relays regulate the temperature of the glass at 25°±5°C. The detectors will record 10³ cosmic-ray tracks withZ50 during 2.5 years. An interior panel consisting of an array 0.09 m² in area and 32 plates thick and mounted on the inside wall of the Soyuz spacecraft (attached to the Space Station) will collect tracks of about 13000 Fe and 500 Ni nuclei.  相似文献